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    • 2. 发明申请
    • CYCLICAL DEPOSITION OF REFRACTORY METAL SILICON NITRIDE
    • REFRACTORY金属硅化合物的循环沉积
    • US20060216928A1
    • 2006-09-28
    • US11422826
    • 2006-06-07
    • HUA CHUNGLING CHENBARRY CHIN
    • HUA CHUNGLING CHENBARRY CHIN
    • H01L21/4763
    • C23C16/45531C23C16/34H01L21/28562H01L21/76843
    • Embodiments of the invention relate to methods for depositing a metal silicon nitride layer on a substrate during an atomic layer deposition (ALD) process. In one embodiment, the method provides positioning a substrate within a process chamber containing a centralized expanding channel that conically tapers towards and substantially covers the substrate, flowing a process gas into the centralized expanding channel to form a circular flow pattern, exposing the substrate to the process gas having the circular flow pattern, and exposing the substrate sequentially to chemical precursors during an ALD process to form a metal silicon nitride material. In one example, the ALD process provides sequentially pulsing a metal precursor, a nitrogen precursor, and a silicon precursor into the process gas having the circular flow pattern. The metal silicon nitride material may contain tantalum or titanium. In other examples, the process gas or the substrate may be exposed to a plasma.
    • 本发明的实施例涉及在原子层沉积(ALD)过程中在衬底上沉积金属氮化硅层的方法。 在一个实施例中,该方法提供将衬底定位在处理室内,该处理室包含集中扩展通道,该中心膨胀通道朝向并基本上覆盖衬底的锥形渐缩,将工艺气体流入集中扩展通道以形成圆形流动图案,将衬底暴露于 具有圆形流动图案的工艺气体,并且在ALD工艺期间将衬底依次暴露于化学前体以形成金属氮化硅材料。 在一个实例中,ALD工艺顺序地将金属前体,氮前体和硅前体顺序地引入到具有圆形流动图案的工艺气体中。 金属氮化硅材料可以包含钽或钛。 在其它实例中,工艺气体或衬底可以暴露于等离子体。