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1. 发明授权

US4268455A Chelating tertiary amino metal amides 失效
标题翻译：螯合叔氨基金属酰胺
公开(公告)号：US4268455A
公开(公告)日：1981-05-19
申请号：US713902
申请日：1976-08-12
申请人： Arthur W. Langer, Jr. , Thomas A. Whitney
发明人： Arthur W. Langer, Jr. , Thomas A. Whitney
IPC分类号： C07C29/42 , C07F5/06
CPC分类号： C07C29/42
摘要： Chelating tertiary amino metal amides selected from compounds having the formulae: Mg.sup. ++ [Chel N].sub.2.sup..crclbar. wherein [Chel N].sup..crclbar. is not ##STR1## [Chel N].sup..crclbar. M.sup..sym., [Chel N].sup..crclbar. M.sup..sym. M'H.sub.m R.sub.n X.sub.p, Z Mg.sup..sym. [Chel N--M'H.sub.m R.sub.n X.sub.p ].sup..crclbar., Mg.sup. ++ --[Chel N--M'H.sub.m R.sub.n X.sub.p ].sup..crclbar. [M'H.sub.m R.sub.n X.sub.p Z].sup..crclbar., Chel N-Mg.sym.[N--Mg.sup..sym. H.sub.m R.sub.n X.sub.p Z].sup..crclbar. and Mg.sup. ++ [Chel N--M'H.sub.m R.sub.n X.sub.p ].sub.2 .sup..crclbar., wherein M is a Group IA metal, M' is a metal selected from the group consisting of Li, Na, Mg, Be, Zn, Cd, B, Al, Ga, In, Zr, Ti, Sn and Cu and m and n=0 to 4, p=0 to 3 and (m+n+ p)=the valence of M' and (m+n)= at least 1 and X is a nonreactive group selected from the group consisting of chlorine, bromine, iodine, C.sub.1 to C.sub.20 alkoxide, C.sub.1 to C.sub.20 thioalkoxide, C.sub.2 to C.sub.40 hydrocarbyl secondary amide and C.sub.2 to C.sub.40 hydrocarbyl secondary phosphide, R is hydrocarbyl group and Z is selected from the group consisting of R, X and H.In an alternative embodiment, the instant invention relates to chiral optically active chelating tertiary amino metal amides selected from compounds having the formulae: [Chel*N].sup..crclbar. M.sup..sym. ; [Chel*N].sup..crclbar. M.sup..sym. M'H.sub.m R.sub.n X.sub.p, Z Mg.sup..sym. [Chel*N--M'H.sub.m R.sub.n X.sub.p ].sup..crclbar., Mg.sup. ++ [Chel*N--M'H.sub.m R.sub.n X.sub.p ].sup..crclbar. [M'H.sub.m R.sub.n X.sub.p Z].sup..crclbar., Chel*N--Mg.sup..sym. [M'H.sub.m R.sub.n X.sub.p ].sup..crclbar., Mg.sup. ++ [Chel*N--M'H.sub.m R.sub.n X.sub.p ].sub.2.sup..crclbar. and Mg.sup. ++ [Chel*N].sub.2 .sup..crclbar. wherein M, M', R, X, m, n, p and Z are as defined previously and where * denotes optical activity.The compounds of the instant invention are useful in metalations, synthesis, asymmetric synthesis and other reactions,. When chiral optically active chelating tertiary amino metal amides are used, the reactions which can be performed include all of the above, plus other reactions which produce chiral or stereoregular products.
摘要翻译：选择具有下式的化合物的螯合叔氨基金属酰胺：Mg ++ [Chel N] 2（ - ）其中[Chel N]（ - ）不是[Chel N]（ - ）M（+），[Chel （ - ）M（+）M'HmRnXp，Z Mg（+）[Chel N-M'HmRnXp]（ - ），Mg ++ - [Chel N-M'HmRnXp]（ - ）[M'HmRnXpZ] （ - ），Chel N-Mg（+）[N-Mg（+）HmRnXpZ]（ - ）和Mg ++ [Chel N-M'HmRnXp] 2（ - ），其中M是IA族金属，M' 是选自Li，Na，Mg，Be，Zn，Cd，B，Al，Ga，In，Zr，Ti，Sn和Cu中的金属，m和n = 0〜4，p = 0〜3 和（m + n + p）= M'的价数，（m + n）=至少1，X是选自氯，溴，碘，C1至C20烷氧基，C1至C20硫代烷氧化物的非反应性基团，C 2至C 40烃基仲酰胺和C 2至C 40烃基二次膦，R为烃基，Z选自R，X和H.在替代实施方案中，本发明涉及手性光学活性螯合叔氨基金属酰胺选自具有t的化合物他公式：[Chel * N]（ - ）M（+）; （ - ）M（+）M'HmRnXp，Z Mg（+）[Chel * N-M'HmRnXp]（ - ），Mg ++ [Chel * N-M'HmRnXp]（ - ）[ （+）[M'HmRnXp]（ - ），Mg ++ [Chel * N-M'HmRnXp] 2（ - ）和Mg ++ [Chel * N] 2（ - ）其中M，M'，R，X，m，n，p和Z如前所定义，其中*表示光学活性。本发明的化合物可用于金属化，合成，不对称合成和其它反应。当使用手性光学活性螯合叔氨基金属酰胺时，可以进行的反应包括以上所有的反应，加上产生手性或立构规整产物的其它反应。

2. 发明授权

US4088666A Reductions with chelated lithium hydridoaluminates or hydridoborates 失效
标题翻译：螯合锂氢化铝酸盐或氢化硼酸盐的减少
公开(公告)号：US4088666A
公开(公告)日：1978-05-09
申请号：US797766
申请日：1977-05-17
申请人： Arthur W. Langer, Jr. , Thomas A. Whitney
发明人： Arthur W. Langer, Jr. , Thomas A. Whitney
IPC分类号： C07F1/00 , C07F5/00 , C07F7/08 , C07F9/02 , C07F9/50 , C10L1/30 , C07F15/02
CPC分类号： C07F9/02 , C07F1/005 , C07F5/00 , C07F7/0818 , C07F9/50 , C10L1/301 , C10M2207/125 , C10M2207/129 , C10M2215/04 , C10M2215/042 , C10M2215/044 , C10M2215/062 , C10M2215/064 , C10M2215/066 , C10M2215/14 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06 , C10M2219/04 , C10M2219/082 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/02 , C10M2223/049 , C10M2223/06 , C10M2223/061 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/03
摘要： This invention relates to the use of chelated lithium hydridoaluminates or hydridoborates in hydride reductions of organic and inorganic substrates. Novel or improved reductions are obtained at increased rates or selectivities in hydrocarbon media.
摘要翻译：本发明涉及螯合锂氢化铝酸盐或氢化硼酸盐在有机和无机衬底的氢化物还原中的用途。在烃介质中以增加的速率或选择性获得新颖或改进的减少量。

3. 发明授权

US4156603A Reductions with chelated lithium hydridoaluminates or hydridoborates 失效
标题翻译：螯合锂氢化铝酸盐或氢化硼酸盐的减少
公开(公告)号：US4156603A
公开(公告)日：1979-05-29
申请号：US849316
申请日：1977-11-07
申请人： Arthur W. Langer, Jr. , Thomas A. Whitney
发明人： Arthur W. Langer, Jr. , Thomas A. Whitney
IPC分类号： C07F1/00 , C07F5/00 , C07F7/08 , C07F9/02 , C07F9/50 , C10L1/30 , C22B11/04 , C22B15/12 , C22B23/04
CPC分类号： C07F9/02 , C07F1/005 , C07F5/00 , C07F7/0818 , C07F9/50 , C10L1/301 , C10M2207/125 , C10M2207/129 , C10M2215/04 , C10M2215/042 , C10M2215/044 , C10M2215/062 , C10M2215/064 , C10M2215/066 , C10M2215/14 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06 , C10M2219/04 , C10M2219/082 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/02 , C10M2223/049 , C10M2223/06 , C10M2223/061 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/03
摘要： This invention relates to the use of chelated lithium hydridoaluminates or hydridoborates in hydride reductions of inorganic substrates. Novel or improved reductions are obtained at increased rates or selectivities in hydrocarbon media to recover metals.
摘要翻译：本发明涉及螯合锂氢化铝酸盐或氢化硼酸盐在无机底物氢化物还原中的用途。在烃介质中以增加的速率或选择性获得新的或改进的减少以回收金属。

4. 发明授权

US4152401A Chelated lithium aluminum compounds 失效
公开(公告)号：US4152401A
公开(公告)日：1979-05-01
申请号：US877354
申请日：1978-02-13
申请人： Arthur W. Langer, Jr. , Thomas A. Whitney
发明人： Arthur W. Langer, Jr. , Thomas A. Whitney
IPC分类号： C01B6/13 , C07F1/00 , C07F5/00 , C07F9/02 , C07F9/50 , C10L1/30 , C10M159/18
CPC分类号： C07F9/02 , C07F1/005 , C07F5/00 , C07F9/50 , C10L1/301 , C10M159/18 , C10M3/00 , C10M2207/125 , C10M2207/129 , C10M2215/04 , C10M2215/042 , C10M2215/044 , C10M2215/062 , C10M2215/064 , C10M2215/066 , C10M2215/14 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06 , C10M2219/04 , C10M2219/082 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/02 , C10M2223/049 , C10M2223/06 , C10M2223/061 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/03
摘要： Chelated lithium aluminum compounds are prepared by mixing a lithium aluminum compound such as a lithium aluminum hydride with a chelating agent wherein the agent contains at least one nitrogen atom. The chelating agent is a tertiary polyamine or aminoether. The resultant chelate is used for a variety of processes such as separations, catalytic reactions, substitution reactions, reductions, electrochemical reactions, and also as an oil and fuel additive.

5. 发明授权

US4165330A Asymmetric synthesis via optically active chelating agents 失效
标题翻译：通过光学活性螯合剂的不对称合成
公开(公告)号：US4165330A
公开(公告)日：1979-08-21
申请号：US877353
申请日：1978-02-13
申请人： Thomas A. Whitney , Arthur W. Langer, Jr.
发明人： Thomas A. Whitney , Arthur W. Langer, Jr.
IPC分类号： C07C29/14 , C07C29/143 , C07C29/40 , C07F1/02 , C07F7/08 , C07C31/18 , C07C33/00
CPC分类号： C07C29/143 , C07C29/14 , C07C29/40 , C07F1/02 , C07F7/0818 , C07F7/083 , C07B2200/07 , C07C2101/14 , C07C2102/10
摘要： An asymmetric synthesis process which involves addition of optically active chelated organometal compounds of lithium, sodium, beryllium, magnesium, zinc, copper and cadmium to prochiral unsaturated substrates. The optically active chelating agent is not consumed and can be recycled.
摘要翻译：一种不对称合成方法，其包括将锂，钠，铍，镁，锌，铜和镉的光学活性螯合有机金属化合物加入到前手性不饱和基质中。光学活性螯合剂不被消耗并可循环使用。

6. 发明授权

US4094876A Chelated lithium aluminum compounds 失效
标题翻译：螯合锂铝化合物
公开(公告)号：US4094876A
公开(公告)日：1978-06-13
申请号：US622840
申请日：1975-10-16
申请人： Arthur W. Langer, Jr. , Thomas A. Whitney
发明人： Arthur W. Langer, Jr. , Thomas A. Whitney
IPC分类号： C07F1/00 , C07F5/00 , C07F9/02 , C07F9/50 , C10L1/30 , C07D401/10 , C07D401/06 , C07F1/02 , C07F5/06
CPC分类号： C07F9/02 , C07F1/005 , C07F5/00 , C07F9/50 , C10L1/301 , C10M3/00 , C10M2207/125 , C10M2207/129 , C10M2215/04 , C10M2215/042 , C10M2215/044 , C10M2215/062 , C10M2215/064 , C10M2215/066 , C10M2215/14 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06 , C10M2219/04 , C10M2219/082 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/02 , C10M2223/049 , C10M2223/06 , C10M2223/061 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/03
摘要： Chelated lithium aluminum compounds are prepared by mixing a lithium aluminum compound such as a lithium aluminum hydride with a chelating agent wherein the agent contains at least one nitrogen atom. The chelating agent is a tertiary polyamine or aminoether. The resultant chelate is used for a variety of processes such as separations, catalytic reactions, substitution reactions, reductions, electrochemical reactions, and also as an oil and fuel additive.
摘要翻译：螯合锂铝化合物通过将锂铝化合物如氢化铝锂与其中所述试剂含有至少一个氮原子的螯合剂混合来制备。螯合剂是叔胺或氨基醚。所得螯合物用于各种方法，例如分离，催化反应，取代反应，还原，电化学反应，以及油和燃料添加剂。

7. 发明授权

US3933879A Chelated lithium aluminum compounds 失效
公开(公告)号：US3933879A
公开(公告)日：1976-01-20
申请号：US344230
申请日：1973-03-23
申请人： Arthur W. Langer, Jr. , Thomas A. Whitney
发明人： Arthur W. Langer, Jr. , Thomas A. Whitney
IPC分类号： C07F1/00 , C07F9/02 , C07F9/50 , C10L1/30 , C07F5/06
CPC分类号： C07F9/02 , C07F1/005 , C07F9/50 , C10L1/301 , C10M1/08 , C10M3/00 , C10M2207/125 , C10M2207/129 , C10M2215/04 , C10M2215/042 , C10M2215/044 , C10M2215/062 , C10M2215/064 , C10M2215/066 , C10M2215/14 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06 , C10M2219/04 , C10M2219/082 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/02 , C10M2223/049 , C10M2223/06 , C10M2223/061 , C10M2227/09 , C10N2210/01 , C10N2210/02 , C10N2210/03
摘要： Chelated lithium aluminum compounds are prepared by mixing a lithium aluminum compound such as a lithium aluminum hydride with a chelating agent wherein the agent contains at least one nitrogen atom. The chelating agent is a tertiary polyamine or aminoether. The resultant chelate is used for a variety of processes such as separations, catalytic reactions, substitution reactions, reductions, electrochemical reactions, and also as an oil and fuel additive.

8. 发明授权

US4293623A Electrolytes for alkali-metal electrochemical devices 失效
标题翻译：碱金属电化学器件电解液
公开(公告)号：US4293623A
公开(公告)日：1981-10-06
申请号：US165412
申请日：1980-07-03
申请人： Lawrence P. Klemann , Gerald H. Newman , Eugene L. Stogryn , Thomas A. Whitney , Dan Farcasiu
发明人： Lawrence P. Klemann , Gerald H. Newman , Eugene L. Stogryn , Thomas A. Whitney , Dan Farcasiu
IPC分类号： H01M6/16 , H01M10/0566
CPC分类号： H01M10/0566 , H01M6/166
摘要： An electrolyte for an alkali metal electrochemical device features (a) an organic solvent; and (b) at least one electrolytically active alkali-metal complex anion salt. The salt has the formula:ZMR.sub.x Q.sub.ywherein Z is an alkali-metal; wherein M is an element selected from a group consisting of B, Al, Ga, In, Tl, P, As, Zn, Cd and Sn (stannous); wherein Q represents at least one heteroatom grouping bonded to M, the core element, through a carbon-M bond; wherein R is selected from a group consisting of: heteroatom-containing groups bonded to M, the core element, through the heteroatom site, alkyls, aryls, alkaryls, aralkyls, halogens, halogen substituted aryls, halogen substituted alkaryls, and pseudohalides; and wherein x and y are positive integers, a sum of x plus y being equal to one plus the valence of the metal M, and further, wherein x can be zero.
摘要翻译：用于碱金属电化学装置的电解质具有（a）有机溶剂; 和（b）至少一种电解活性碱金属络合物阴离子盐。该盐具有下式：ZMRxQy其中Z是碱金属; 其中M是选自由B，Al，Ga，In，Tl，P，As，Zn，Cd和Sn（亚锡）组成的组中的元素; 其中Q表示至少一个通过碳-M键与M键合的杂原子基团，核心元素; 其中R选自：与M键合的含杂原子的基团，核心元素，通过杂原子位点，烷基，芳基，烷芳基，芳烷基，卤素，卤素取代的芳基，卤素取代的烷芳基和拟卤化物; 并且其中x和y是正整数，x + y的和等于1加上金属M的化合价，此外，其中x可以为零。

9. 发明授权

US4833050A Electrochemical cells 失效
标题翻译：电化学电池
公开(公告)号：US4833050A
公开(公告)日：1989-05-23
申请号：US125502
申请日：1987-11-25
申请人： Thomas A. Whitney , William L. Bowden , Arabinda N. Dey
发明人： Thomas A. Whitney , William L. Bowden , Arabinda N. Dey
IPC分类号： H01M20060101 , H01M4/48 , H01M4/58 , H01M6/00 , H01M6/16
CPC分类号： H01M4/58 , H01M4/48 , H01M6/00 , H01M6/16
摘要： This invention relates to electrochemical cells wherein the cathode comprises ceramics containing copper oxides characterized as perovskites.
摘要翻译：本发明涉及电化学电池，其中阴极包括以钙钛矿为特征的含有氧化铜的陶瓷。

10. 发明授权

US4117213A Alkali metal salts of complex anions containing heteroatom substituents and electrolyte compositions containing these 失效
标题翻译：含有异源取代基的复合阴离子和含有这些的电解质组合物的碱金属盐
公开(公告)号：US4117213A
公开(公告)日：1978-09-26
申请号：US870662
申请日：1978-01-19
申请人： Thomas A. Whitney , Lawrence P. Klemann
发明人： Thomas A. Whitney , Lawrence P. Klemann
IPC分类号： C07D205/04 , C07D207/32 , C07D209/08 , C07D233/02 , C07F1/00 , C07F5/02 , C07F5/06 , H01M6/16 , H01M6/14
CPC分类号： C07D207/32 , C07D205/04 , C07D209/08 , C07D233/02 , C07F1/005 , C07F5/027 , C07F5/066 , C07F5/069 , H01M6/162 , H01M6/166
摘要： Alkali metal salts of complex anions having heteroatom substituents are described. The compounds are those having the formula:ZMR.sub.x Q.sub.ywherein Z is an alkali metal selected from the group consisting of lithium and sodium, M is a metal selected from the group consisting of Zn, Cd, B, Al, Ga, Sn (stannous), P and As, the Rs are certain organic radicals, the Qs are certain heteroatom substituents, x is zero or a positive integer, and y is a positive integer, subject to the provisos that the sum of x plus y is equal to one plus the valence of the metal M and that, when M is boron, y is one, two or three. Also described are electrolyte compositions which comprise: (a) organic solvents selected from the group consisting of inertly substituted and unsubstituted ethers, esters, sulfones, organic sulfites, organic sulfates, organic nitrates andorganic nitro compounds; and (b) electrolytically active alkali metal salts including alkali metal complex anion salts described above.

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