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    • 3. 发明授权
    • Cross-linkable monomers and polymers and the use thereof
    • 可交联的单体和聚合物及其用途
    • US08716519B2
    • 2014-05-06
    • US12674247
    • 2008-07-11
    • Martin JakobStefan Nogai
    • Martin JakobStefan Nogai
    • C07C309/21C07C309/22
    • C08F28/02C07C309/12C08F218/08C08F220/38C08F228/02C08F2220/382C08F2220/387C08L41/00
    • The invention relates to novel cross-linkable monomers that may be polymerized with ethylenically unsaturated comonomers to form cross-linkable copolymers. Said copolymers may particularly be used in the form of aqueous dispersions as formaldehyde-free adhesives or as coatings with good water resistance. The cross-linkable monomer is a compound in acid or salt form comprising an anion of the formula (I) and one or more cations for producing electrical neutrality, where R1 and R2 represent, independently of one another, hydrogen alkyl, cycloalkyl, aryl, aralkyl, —COOR5, —COO− cat+ or —CON(R6R7), R6 and R7 represent, independently of one another, hydrogen, alkyl, or aryl, cat+ represents a monovalent cation, and one of the groups R1 or R2 may also represent a group —X—R4—CR5(OH)SO3−), wherein X, R4, and R5 assume one of the meanings listed below, R3 represents hydrogen, alkyl, or aryl, X is selected from the group of direct C—C bond, —O—, —CH2—O—, —CH2—NR8—, —COO— or —CONR8—, R8 represents hydrogen, alkyl, or aryl, R4 represents alkylene, polyoxyalkylene, cycloalkylene, or arylene, and R5 represents hydrogen, alkyl, cycloalkyl, or aryl.
    • 本发明涉及可与烯属不饱和共聚单体聚合以形成可交联共聚物的新型可交联单体。 所述共聚物可特别以水分散体的形式用作不含甲醛的粘合剂或作为具有良好耐水性的涂料。 可交联单体是酸或盐形式的化合物,其包含式(I)的阴离子和一种或多种用于产生电中性的阳离子,其中R 1和R 2彼此独立地表示氢烷基,环烷基,芳基, 芳烷基,-COOR5,-COO- cat +或-CON(R6R7),R6和R7彼此独立地表示氢,烷基或芳基,cat +表示一价阳离子,R1或R2之一也可以表示 基团-X-R4-CR5(OH)SO3-),其中X,R4和R5具有下列含义之一,R3表示氢,烷基或芳基,X选自直接C-C 键,-O - , - CH 2 -O - , - CH 2 -NR 8 - , - COO-或-CONR 8 - ,R 8表示氢,烷基或芳基,R 4表示亚烷基,聚氧化烯,亚环烷基或亚芳基,R 5表示氢 ,烷基,环烷基或芳基。
    • 9. 发明申请
    • METHOD FOR PRODUCING AQUEOUS VINYL ESTER DISPERSIONS
    • 生产水性醋酸酯分散体的方法
    • US20100130679A1
    • 2010-05-27
    • US12307233
    • 2007-06-05
    • Martin JakobBernhard MomperJan-Erik JonnsonAnders Hansson
    • Martin JakobBernhard MomperJan-Erik JonnsonAnders Hansson
    • C08F2/22
    • C08F2/20C08F2/22C08F218/08C08F222/06
    • The preparation of vinyl ester homo- or copolymers by emulsion polymerization is described. The process is performed in the presence of a polymerization-retarding component in at least two phases, the concentration of the vinyl ester monomer in the polymerization mixture in the first phase having been depleted by not more than 50% at the end of the first phase compared to the concentration of the vinyl ester monomer in the polymerization mixture at the start of the first phase, and the concentration of the vinyl ester monomer in the polymerization mixture in the second phase being depleted compared to the concentration at the end of the first phase. The retarding component is depleted during the first phase. In the second phase, the heat of reaction is removed by evaporative cooling. In the first phase, the emulsion polymerization is effected at temperatures up to the boiling point of the vinyl ester-water azeotrope, and, in the second phase, at temperatures above the boiling point of the vinyl ester-water azeotrope.The process is notable for a short cycle time and high space-time yields and can be operated safely.
    • 描述了通过乳液聚合制备乙烯基酯均聚物或共聚物。 该方法在至少两相中在聚合阻滞组分存在下进行,第一相中的聚合混合物中的乙烯基酯单体的浓度在第一相结束时已经耗尽不超过50% 与第一阶段开始时聚合混合物中乙烯基酯单体的浓度相比,第二相中聚合混合物中乙烯基酯单体的浓度与第一阶段结束时的浓度相比有所减少 。 延迟成分在第一阶段耗尽。 在第二阶段,通过蒸发冷却除去反应热。 在第一阶段中,在高于乙烯基酯 - 水共沸物的沸点的温度下进行乳液聚合,而在第二相中,在高于乙烯基酯 - 水共沸物沸点的温度下进行。 该过程在短周期时间和高空时产量方面是显着的,并且可以安全地操作。
    • 10. 发明申请
    • Method for the production of aqueous polymer dispersions containing very few residual monomers and use thereof
    • 制备含有非常少的残留单体的聚合物水分散体的方法及其用途
    • US20050222374A1
    • 2005-10-06
    • US10527178
    • 2003-07-26
    • Harmin MullerMartin JakobCarsten HeldmannThomas Wirth
    • Harmin MullerMartin JakobCarsten HeldmannThomas Wirth
    • C08F6/00C08G63/02
    • C08F6/006
    • The invention relates to a method for reducing the amount of residual monomers in aqueous polymer dispersions means of chemical post-treatment. Post-treatment in the aqueous polymer dispersion is carried out by adding a redox system which contains a) 0.005-5 wt. % of an oxidation agent which contains an organic peroxide. and b) 0.005-5 wt. % of a reduction agent which contains sulfinic acids or salts thereof. Additionally. the redox system can, optionally, contain catalytic amounts of a polyvalent metallic ion which can be treated in several valent stages. Post-treatment can be carried out at a temperature ranging from 20-100° C. and at a PH-value ranging from 2-9. The invention also relates to the use of the inventive post-treated polymer dispersion for producing adhesives, coarings, powders, constructive chemical products or for refining textiles or paper.
    • 本发明涉及减少聚合物水分散体中化学后处理方法中残余单体量的方法。 在聚合物水分散体中的后处理是通过加入氧化还原体系进行的,所述氧化还原体系含有:a)0.005-5wt。 含有有机过氧化物的氧化剂的%。 和b)0.005-5wt。 %的还原剂含有亚磺酸或其盐。 另外。 氧化还原体系可以任选地含有催化量的多价金属离子,其可以在几个阶段中进行处理。 后处理可以在20-100℃的温度和2-9的PH值下进行。 本发明还涉及本发明的后处理聚合物分散体用于生产粘合剂,结焦,粉末,建构性化学产品或用于精制纺织品或纸的用途。