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1. 发明授权

US5710228A Maleimide/.alpha.-olefin copolymers and their use as light stabilizers and stabilizers for organic material 失效
标题翻译：马来酰亚胺/α-烯烃共聚物及其用作有机材料的光稳定剂和稳定剂
公开(公告)号：US5710228A
公开(公告)日：1998-01-20
申请号：US644123
申请日：1996-05-10
申请人： Alfred Krause , Walter Denzinger , Albert Hettche , Alexander Aumueller , Hubert Trauth
发明人： Alfred Krause , Walter Denzinger , Albert Hettche , Alexander Aumueller , Hubert Trauth
IPC分类号： C08F2/06 , C08F8/32 , C08F210/14 , C08F222/40 , C08F210/00
CPC分类号： C08F8/32 , C08F210/14
摘要： Maleimide/.alpha.-olefin copolymers are composed of structural units I ##STR1## where R.sup.1 is a tetramethylpiperidinyl radical of the formula II ##STR2## R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, formyl, C.sub.2 -C.sub.6 -alkanoyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.5 - or C.sub.6 -cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula --CR.sup.4 =CH--CO--OR.sup.5, R.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl or a radical of the formula --CO--OR.sup.5, and R.sup.5 is C.sub.5 -C.sub.18 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.18 -aralkyl, phenyl or tolyl, and up to 8 mol %, based on II, of R.sup.1 may furthermore be hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.5 -C.sub.8 -cycloalkyl, and R.sup.2 is a mixture of C.sub.14 -C.sub.28 -alkyl groups, where two of these alkyl groups, which may differ by no more than two carbon atoms, each account for at least 30% of this mixture, having an average molecular weight of from 1,000 to 50,000. The copolymers described are suitable as light stabilizers and stabilizers for organic material, in particular plastics and coatings.
摘要翻译：马来酰亚胺/α-烯烃共聚物由结构单元Ⅰ（II）组成，其中R 1是式II的四甲基哌啶基，其中R 3是氢，C 1 -C 6烷基，甲酰基，C 2 -C 6 - 烷酰基，C 1 -C 12 - 烷氧基，C 5 - 或C 6 - 环烷氧基，氰基甲基，2-羟乙基，苄基或式-CR 4 = CH-CO-OR 5基团，R 4是氢，C 1 -C 6烷基或式-CO-OR5和R5是C5-C18-烷基，C5-C8-环烷基，C7-C18-芳烷基，苯基或甲苯基，并且基于II的至多8摩尔％的R 1还可以是氢， C 1 -C 22 - 烷基或C 5 -C 8 - 环烷基，并且R 2是C 14 -C 28 - 烷基的混合物，其中两个可以不超过两个碳原子的烷基各自占据至少30％的该混合物，其平均分子量为1,000至50,000。所述的共聚物适合用作有机材料的光稳定剂和稳定剂，特别是塑料和涂料。

2. 发明授权

US4559159A Copolymers, their preparation and their use as assistants in detergents and cleansing agents 失效
标题翻译：共聚物，它们的制备及其作为洗涤剂和清洁剂助剂的用途
公开(公告)号：US4559159A
公开(公告)日：1985-12-17
申请号：US580806
申请日：1984-02-16
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Richard Mueller , Paul Diessel , Albert Hettche
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Richard Mueller , Paul Diessel , Albert Hettche
IPC分类号： C08F8/00 , C08F8/14 , C08F220/04 , C11D3/37 , D06L1/12 , D06M13/02 , D06M13/188 , D06M13/322 , D06M13/325 , D06M13/328 , D06M13/402 , D06M15/263 , C08F220/06 , D06L3/02
CPC分类号： C08F220/04 , C08F8/14 , C11D3/3757 , C11D3/3769 , C11D3/3773
摘要： Water-soluble copolymers which consist of from 40 to 90% by weight of one or more ethylenically unsaturated monocarboxylic acids of 3 to 5 carbon atoms, from 60 to 10% by weight of one or more ethylenically unsaturated dicarboxylic acids of 4 to 8 carbon atoms and/or of the corresponding dicarboxylic acid anhydride and, if required, not more than 15% by weight, based on the total weight of the carboxyl-containing monomers, of one or more carboxyl-free monomers, and which are esterified with from 2 to 60% by weight, based on the total weight of the carboxyl-containing monomers, of one or more compounds which contain a terminal hydroxyl group and one or more alkylene oxide groups of 2 to 4 carbon atoms, the preparation of such water-soluble copolymers and their use as assistants in detergents, cleansing and dishwashing agents.
摘要翻译：由40至90重量％的含有3-5个碳原子的一种或多种烯属不饱和一元羧酸组成的水溶性共聚物，60至10重量％的一种或多种4-8个碳原子的烯键式不饱和二羧酸和/或相应的二羧酸酐，并且如果需要，不超过15重量％，基于含羧基单体的总重量，一种或多种无羧基单体，并且用2 至60重量％，基于含羧基单体的总重量，一种或多种含有末端羟基和一个或多个2至4个碳原子的氧化烯基团的化合物，制备这种水溶性共聚物及其用作洗涤剂，清洁剂和餐具洗涤剂中的助剂。

3. 发明授权

US5175361A Preparation of copolymers of monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids 失效
标题翻译：单烯属不饱和一元羧酸和二羧酸的共聚物的制备
公开(公告)号：US5175361A
公开(公告)日：1992-12-29
申请号：US625621
申请日：1990-11-30
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C08F220/04 , C08F222/02
CPC分类号： C08F222/02 , C08F220/04
摘要： A process for the preparation of copolymers which contain monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids as copolymerized monomer units, which comprises copolymerizinga) 10 to 60% by weight, based on the sum of the monomers, of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, -or an alkali metal salt thereof or, an anhydride thereof,b) 90 to 40% by weight of a monoethylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms or an alkali metal salt thereof andc) 0 to 20% by weight of another monoethylenically unsaturated monomer, not having carboxyl groups and which is copolymerizable with a) and b);in an aqueous medium in the presence of from 0.5 to 5% by weight, based on monomers, of a water-soluble initiator.
摘要翻译：一种制备包含单烯属不饱和一元羧酸和二羧酸作为共聚单体单元的共聚物的方法，其包括将基于单体总量的10-60重量％的单烯属不饱和二羧酸与4- 6个碳原子，或其碱金属盐或其酸酐，b）90〜40重量％的3〜10个碳原子的单烯属不饱和一元羧酸或其碱金属盐，c）0〜20重量％重量的不具有羧基且可与a）和b）共聚的另一单烯属不饱和单体; 在水介质中，以0.5至5重量％的单体为基础，存在水溶性引发剂。

4. 发明授权

US4725655A Preparation of copolymers of monoethylenically unsaturated mono- and dicarboxylic acids and anhydrides 失效
公开(公告)号：US4725655A
公开(公告)日：1988-02-16
申请号：US919583
申请日：1986-10-16
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C08F2/00 , C08F2/10 , C08F8/00 , C08F8/12 , C08F8/44 , C08F20/00 , C08F20/02 , C08F120/04 , C08F220/04 , C08F222/02 , C08F220/06 , C08F222/04
CPC分类号： C08F220/04 , C08F222/02
摘要： Copolymers which contain, as copolymerized monomer units, monoethylenically unsaturated mono- and dicarboxylic acids are prepared by a process in which(a) from 10 to 60% by weight of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, its salt and/or, if appropriate, its anhydride,(b) from 90 to 40% by weight of a monothylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms and/or its salt and(c) from 0 to 20% by weight of another, carboxyl-free monoethylenically unsaturated monomer which is copolymerizable with (a) and (b),the percentages being based on the sum of the monomers, are polymerized in the presence of from 0.5 to 5% by weight of a water-soluble free-radical-forming initiator in an aqueous medium at from 60.degree. to 150.degree. C., and, if appropriate, their anhydride groups are hydrolyzed, the monomers (a) and (b) being employed in a form such that from 20 to 80% of their amount is neutralized during the polymerization reaction, wherein the copolymerization is carried out continuously in a reactor cascade comprising several reactors, and an aqueous solution of a pre-prepared copolymer of (a), (b) and, if appropriate, (c) is initially introduced into all the reactors and heated to the required reaction temperature, the total amount of unneutralized or partially neutralized (a), not less than 40% by weight of unneutralized or partially neutralized (b), where relevant, all or some of (c), and some or all of the amount of initiator required for polymerization, with or without the amount of neutralizing agent required for the neutralization according to the definition, are metered into the first reactor, the remaining amount of unneutralized or neutralized (b) and, where relevant, (c), and any remaining amount of initiator and neutralizing agent which may be required are introduced into the second reactor or are distributed over the second reactor and the downstream reactors, and the reactants are allowed to react together during a residence time of from 0.5 to 8 hours. The above copolymers can be used as incrustation inhibitors or for scaling inhibition.

5. 发明授权

US4702858A Washing agents containing, as additives, carboxyl-containing copolymers which are neutralized or amidated with amines 失效
标题翻译：作为添加剂含有用胺中和或酰胺化的含羧基共聚物的洗涤剂
公开(公告)号：US4702858A
公开(公告)日：1987-10-27
申请号：US888957
申请日：1986-07-24
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Erhard Klahr , Albert Hettche
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Erhard Klahr , Albert Hettche
IPC分类号： C08F8/32 , C08F8/44 , C11D3/37
CPC分类号： C11D3/3761 , C11D3/3769
摘要： Washing agents contain, as additives for inhibiting redeposition and promoting the primary washing action, homopolymers of acrylic acid and of methacrylic acid, copolymers of acrylic acid and methacrylic acid and copolymers which contain, as essential components,(a) an ethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms and(b) acrylic acid, methacrylic acid and/or hydroxy-C.sub.2 -C.sub.6 -alkyl esters of ethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids as copolymerized units,where the homo- and copolymers in the form of the free acids have a weight average molecular weight of from 5000 to 500,000 in the neutralized or amidated form, the carboxyl groups of the homo- and copolymers in each case being partially or completely neutralized with amines of the formula ##STR1## where R is C.sub.8 -C.sub.18 -alkyl or R.sup.1 --O--CH.sub.2 --(CH.sub.2).sub.n --, n is from 1 to 3, R.sup.1 is C.sub.1 -C.sub.18 -alkyl, R.sup.2 and R.sup.3 are each H or C.sub.1 -C.sub.18 -alkyl and/or from 5 to 50% of the said carboxyl groups being in the form of amides derived from primary and secondary amines of the formula I.
摘要翻译：洗涤剂含有作为抑制再沉积和促进初次洗涤作用的添加剂，丙烯酸和甲基丙烯酸的均聚物，丙烯酸和甲基丙烯酸的共聚物以及含有作为必要成分的（a）烯属不饱和二羧酸 4至6个碳原子，和（b）丙烯酸，甲基丙烯酸和/或烯属不饱和C 3 -C 6 - 羧酸的羟基-C 2 -C 6烷基酯作为共聚单元，其中以自由基形式存在的均聚物和共聚物酸的中和或酰胺化形式的重均分子量为5000至500,000，每种情况下的均聚物和共聚物的羧基用式“IMAGE”的胺部分或完全中和，其中R为C8-C18 - 烷基或R 1 -O-CH 2 - （CH 2）n - ，n为1至3，R 1为C 1 -C 18烷基，R 2和R 3各自为H或C 1 -C 18 - 烷基和/或5至50％的所述羧基为衍生自原料的酰胺形式芳胺和仲胺。

6. 发明授权

US4698174A Additives for detergents and cleaning agents 失效
标题翻译：洗涤剂和清洁剂的添加剂
公开(公告)号：US4698174A
公开(公告)日：1987-10-06
申请号：US822610
申请日：1986-01-27
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C11D3/33 , C11D3/37
CPC分类号： C11D3/33 , C11D3/3761
摘要： Pulverulent and/or granular additives for pulverulent detergents and cleaning agents, consisting of(a) from 80 to 20% by weight of one or more copolymers comprising from 40 to 90% by weight of (meth)acrylic acid and from 60 to 10% by weight of maleic acid and/or one or more copolymers comprising from 10 to 45% by weight of (meth)acrylic acid, from 10 to 45% by weight of maleic acid and from 10 to 60% by weight of one or more hydroxyalkyl (meth)acrylates where hydroxyalkyl is of 2 to 6 carbon atoms, if appropriate in the form of a partially or completely neutralized water-soluble salt,(b) from 20 to 80% by weight of nitrilotriacetic acid or its mono-, di- or trisodium or mono-, di- or tripotassium salt and(c) from 0 to 20% by weight of one or more additives conventionally used for detergent and cleaning agent formulations, the use of these pulverulent and/or granular mixtures as additives for pulverulent and/or granular detergents and cleaning agents, and processes for the preparation of the said additives.
摘要翻译：用于粉状洗涤剂和清洁剂的粉末和/或颗粒添加剂由（a）80至20重量％的一种或多种共聚物组成，所述共聚物包含40至90重量％的（甲基）丙烯酸和60至10重量％的马来酸和/或一种或多种共聚物，其包含10至45重量％的（甲基）丙烯酸，10至45重量％的马来酸和10至60重量％的一种或多种羟烷基（甲基）丙烯酸酯，其中羟基烷基为2至6个碳原子，如果合适的话以部分或完全中和的水溶性盐的形式，（b）20至80重量％的次氮基三乙酸或其单 - 或三钠或单，二或三钾盐和（c）0至20重量％的常规用于洗涤剂和清洁剂配方的一种或多种添加剂，使用这些粉状和/或颗粒状混合物作为粉末状添加剂和/或颗粒状洗涤剂和清洁剂，以及制备方法 n的所述添加剂。

7. 发明授权

US4670524A Preparation of water-soluble polymer powders and their use 失效
标题翻译：制备水溶性聚合物粉末及其用途
公开(公告)号：US4670524A
公开(公告)日：1987-06-02
申请号：US857134
申请日：1986-04-29
申请人： Karlheinz Messmer , Karl Hennig , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Hans-Juergen Raubenheimer
发明人： Karlheinz Messmer , Karl Hennig , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Hans-Juergen Raubenheimer
IPC分类号： C08F2/00 , C08F2/10 , C08F2/36 , C08F4/00 , C08F4/04 , C08F4/28 , C08F4/32
CPC分类号： C08F2/10 , Y10S526/909
摘要： Water-soluble polymer powders are prepared by polymerizing water-soluble ethylenically unsaturated monomers in a powder bed in the presence of polymerization initiators and water while maintaining the powder state, removing the heat of polymerization by distilling off water and circulating the reaction mixture, by a process in which water-insoluble organic peroxides which are liquid at 20.degree. C. are used alone or as a mixture with up to 50% by weight, based on the initiator mixture, of water-soluble, organic azo initiators and/or water-insoluble solid peroxy-containing compounds, as polymerization initiators.
摘要翻译：通过在聚合引发剂和水的存在下在粉末床中聚合水溶性烯键式不饱和单体，同时保持粉末状态，通过蒸馏除去水并使反应混合物循环除去聚合热，制备水溶性聚合物粉末其中在20℃下为液体的不溶于水的有机过氧化物单独或基于引发剂混合物使用至多50重量％的水溶性有机偶氮引发剂和/或水溶性有机过氧化物的方法，作为聚合引发剂的不溶性固体过氧化合物。

8. 发明授权

US4647396A Copolymers for detergents and cleaning agents 失效
标题翻译：用于洗涤剂和清洁剂的共聚物
公开(公告)号：US4647396A
公开(公告)日：1987-03-03
申请号：US703614
申请日：1985-02-21
申请人： Walter Denzinger , Heinrich Hartmann , Albert Hettche , Ulrich Kaluza , Johannes Perner , Christos Vamvakaris
发明人： Walter Denzinger , Heinrich Hartmann , Albert Hettche , Ulrich Kaluza , Johannes Perner , Christos Vamvakaris
IPC分类号： C08F20/00 , C08F20/26 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/28 , C08F222/02 , C11D3/37 , C08F22/04 , C08F22/20
CPC分类号： C11D3/3757 , C08F220/28
摘要： The invention relates to copolymers as ingredients for detergents and cleaning agents, which contain monoethylenically unsaturated mono- and dicarboxylic acids, their hydroxyalkyl esters and, if appropriate, other ethylenically unsaturated compounds as monomer units, and are distinguished by a particular calicum-binding and magnesium-binding capacity, detergents and cleaning agents containing these copolymers, and their use in detergents and cleaning agents, in particular as sequestering agents and anti-redeposition agents.
摘要翻译：本发明涉及作为洗涤剂和清洁剂的成分的共聚物，其含有单烯键式不饱和单羧酸和二羧酸，它们的羟烷基酯和（如果合适的话）其它烯键式不饱和化合物作为单体单元，并且由特定的孔隙结合和镁包含这些共聚物的结合能力，洗涤剂和清洁剂，以及它们在洗涤剂和清洁剂中的用途，特别是作为螯合剂和抗再沉积剂。

9. 发明授权

US4914167A Polymeric organic acids, their preparation and their use in detergents and cleansers 失效
标题翻译：聚合有机酸，它们的制备及其在洗涤剂和清洁剂中的应用
公开(公告)号：US4914167A
公开(公告)日：1990-04-03
申请号：US752013
申请日：1985-07-08
申请人： Juergen Hambrecht , Heinrich Hartmann , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Rolf Schneider
发明人： Juergen Hambrecht , Heinrich Hartmann , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Rolf Schneider
IPC分类号： C08F2/02 , C08F220/04 , C11D3/37
CPC分类号： C11D3/3761 , C08F220/04
摘要： Organic polyacids are prepared from monomeric monofunctional acids, such as acrylic acid or methacrylic acid and monomers without an acid group, with or without dicarboxylic acids or their anhydrides, by continuous free radical mass copolymerization under superatmospheric pressure at from 200.degree. to 400.degree. C., followed, if desired, by neutralization of the polyacids obtained. The polyacids obtained by the novel process are useful as phosphate substitutes and scale inhibitors in detergents and cleansers.
摘要翻译：有机多元酸通过在200-400℃的超大气压下连续自由基基团共聚，由单体单官能酸例如丙烯酸或甲基丙烯酸和无酸基的单体制备，含或不含二羧酸或其酸酐。，如果需要，通过中和获得的多元酸。通过该方法获得的多酸可用作洗涤剂和清洁剂中的磷酸盐替代物和防垢剂。

10. 发明授权

US06171583B2 Powdery iodine complexes 失效
标题翻译：粉状碘络合物
公开(公告)号：US06171583B2
公开(公告)日：2001-01-09
申请号：US09068305
申请日：1998-05-07
申请人： Jörg Breitenbach , Axel Sanner , Walter Denzinger , Siegfried Lang
发明人： Jörg Breitenbach , Axel Sanner , Walter Denzinger , Siegfried Lang
IPC分类号： A61K3318
CPC分类号： C08F226/06 , C08F8/22 , C08F26/06
摘要： Complexes in powder form of iodine and a crosslinked polymer based on N-vinyl compounds are obtainable by dry heating of iodine and a polymer which is obtained by polymerization of monovinyl compounds (monomers A) whose vinyl group is bonded to a nitrogen atom of a nitrogen-containing heterocycle, in the presence of from 0.5 to 10% by weight, based on the monomers (A), of a compound (B) of the formula I; where A is —CH— or a nitrogen atom, and n is 2 or 3. The complexes are suitable for producing antidiarrheals.
摘要翻译：可以通过干燥加热碘和聚合物获得碘粉末形式和基于N-乙烯基化合物的交联聚合物的复合物，该聚合物是通过乙烯基结合在氮的氮原子上的单乙烯基化合物（单体A）基于单体（A），在式I化合物（B）为0.5〜10重量％的存在下，其中A为-CH-或氮原子，n为2 或3.该配合物适于产生止泻药。

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