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1. 发明授权

US08066977B2 Agent for permanent hair waving containing heterocyclic mercapto compound 有权
标题翻译：含有杂环巯基化合物的永久性头发挥发剂
公开(公告)号：US08066977B2
公开(公告)日：2011-11-29
申请号：US11884413
申请日：2006-05-25
申请人： Akira Shibuya , Shinichi Yorozuya , Makoto Saito
发明人： Akira Shibuya , Shinichi Yorozuya , Makoto Saito
IPC分类号： A61Q5/04
CPC分类号： A61Q5/04 , A61K8/4933
摘要： Disclosed is an agent for permanent hair waving that can realize permanent hair waving even in the neutral to weakly acidic pH range in which irritation particularly to the skin is not significant. The agent for permanent hair waving includes at least one heterocyclic mercapto compound represented by formula (1): wherein R1 and R2 each independently represent a hydrogen atom or an optionally substituted alkyl group having 1 to 5 carbon atoms; X represents —O—, —S—, —NH—, or —NR3—; R3 represents an alkyl group having 1 to 5 carbon atoms; n is an integer of 0 to 2; and, when n is 2, group SH may be attached to any carbon atom of an alkylene group having 2 carbon atoms.
摘要翻译：公开了即使在特别是对皮肤的刺激不显着的中性至弱酸性pH范围内也能实现永久性头发挥发的药剂。永久性头发挥发剂包括至少一种由式（1）表示的杂环巯基化合物：其中R 1和R 2各自独立地表示氢原子或任选取代的具有1至5个碳原子的烷基; X表示-O - ， - S - ， - NH-或-NR 3 - ; R3表示碳原子数1〜5的烷基。 n为0〜2的整数，并且当n为2时，基团SH可以连接到具有2个碳原子的亚烷基的任何碳原子上。

2. 发明申请

US20090208439A1 Agent for Permanent Hair Waving Containing Heterocyclic Mercapto Compound 有权
标题翻译：含有杂环巯基化合物的永久性头发挥发剂
公开(公告)号：US20090208439A1
公开(公告)日：2009-08-20
申请号：US11884413
申请日：2006-05-25
申请人： Akira Shibuya , Shinichi Yorozuya , Makoto Saito
发明人： Akira Shibuya , Shinichi Yorozuya , Makoto Saito
IPC分类号： A61K8/49 , C07D233/40 , A61Q5/04
CPC分类号： A61Q5/04 , A61K8/4933
摘要： Disclosed is an agent for permanent hair waving that can realize permanent hair waving even in the neutral to weakly acidic pH range in which irritation particularly to the skin is not significant. The agent for permanent hair waving includes at least one heterocyclic mercapto compound represented by formula (1): wherein R1 and R2 each independently represent a hydrogen atom or an optionally substituted alkyl group having 1 to 5 carbon atoms; X represents —O—, —S—, —NH—, or —NR3—; R3 represents an alkyl group having 1 to 5 carbon atoms; n is an integer of 0 to 2; and, when n is 2, group SH may be attached to any carbon atom of an alkylene group having 2 carbon atoms.
摘要翻译：公开了即使在特别是对皮肤的刺激不显着的中性至弱酸性pH范围内也能实现永久性头发挥发的药剂。永久性头发挥发剂包括至少一种由式（1）表示的杂环巯基化合物：其中R 1和R 2各自独立地表示氢原子或任选取代的具有1至5个碳原子的烷基; X表示-O - ， - S - ， - NH-或-NR 3 - ; R3表示碳原子数1〜5的烷基。 n为0〜2的整数，并且当n为2时，基团SH可以连接到具有2个碳原子的亚烷基的任何碳原子上。

3. 发明申请

US20080085251A1 Hair Processing Agent And Method For Permanent Waving Hair 有权
标题翻译：头发处理剂及烫发方法
公开(公告)号：US20080085251A1
公开(公告)日：2008-04-10
申请号：US11792828
申请日：2005-12-20
申请人： Akira Shibuya , Hidemasa Aoki , Makoto Saito , Motoaki Kamachi , Atsushi Tsuchiya , Akio Okamura
发明人： Akira Shibuya , Hidemasa Aoki , Makoto Saito , Motoaki Kamachi , Atsushi Tsuchiya , Akio Okamura
IPC分类号： A61K8/46 , A61Q5/04
CPC分类号： A61K8/4933 , A61Q5/04
摘要： Provided are hair processing agents capable of permanent waving hair even at a neutral to weakly acidic pH range that causes less irritation to the skin, and hair processing agents in which an unpleasant odor is masked. Hair processing agents contain at least one compound represented by the formula (2). Hair processing agents contain a compound of the formula (2) and at least one compound (ii) selected from thioglycolic acid, thiolactic acid, cysteine, acetylcysteine, cysteamine, acylcysteamine, salts thereof and ester derivatives thereof. Hair processing agents contain a compound of the formula (2), a surfactant and water, and are emulsified. Hair processing agents contain a compound of the formula (2) and a specific perfume. wherein X is a structure selected from —O—, —S—, —NH— and —NR1—; R1 is an alkyl group of 1 to 6 carbon atoms; Y is an oxygen atom or a sulfur atom; in the formula (1), Z is a divalent organic residue having at least one mercapto group; in the formula (2), R is a divalent organic residue optionally having a mercapto group; and R2 is a hydrogen atom or an alkyl group of 1 to 6 carbon atoms.
摘要翻译：提供即使在对皮肤刺激较少的中性至弱酸性pH范围也能永久挥发头发的头发加工剂，以及掩盖有令人不愉快的气味的毛发加工剂。头发处理剂含有至少一种式（2）表示的化合物。头发处理剂含有式（2）化合物和至少一种选自巯基乙酸，硫代乳酸，半胱氨酸，乙酰半胱氨酸，半胱胺，酰基半胱胺，其盐和其酯衍生物的化合物（ii）。头发处理剂含有式（2）的化合物，表面活性剂和水，并被乳化。头发处理剂含有式（2）的化合物和特定的香料。其中X是选自-O - ， - S - ， - NH-和-NR 1 - 的结构。 R 1是1至6个碳原子的烷基; Y是氧原子或硫原子; 在式（1）中，Z是具有至少一个巯基的二价有机残基; 在式（2）中，R是任选具有巯基的二价有机残基; R 2是氢原子或1〜6个碳原子的烷基。

4. 发明授权

US06953859B2 Production process for 5-alkyl-oxazolidin-2,4-dione 失效
标题翻译： 5-烷基 - 恶唑烷-2,4-二酮的制备方法
公开(公告)号：US06953859B2
公开(公告)日：2005-10-11
申请号：US10343607
申请日：2002-06-04
申请人： Akira Shibuya , Yoshio Fujiwara , Yoshiaki Miyota , Norihito Nishimura , Makoto Saito
发明人： Akira Shibuya , Yoshio Fujiwara , Yoshiaki Miyota , Norihito Nishimura , Makoto Saito
IPC分类号： C07D263/44
CPC分类号： C07D263/44
摘要： The object of the present invention is to produce a 5-alkyl-oxazolidin-2,4-dione by an industrially advantageous method. The invention relates to novel process for producing a high-purity 5-alkyl-oxazolidin-2,4-dione comprising the steps of reacting a 2-hydroxycarboxylic acid amide with a carbonic acid ester in the presence of a metal alcoholate, thereby completing the reaction in one step, and then isolating the reaction product by a neutralization crystallization method.
摘要翻译：本发明的目的是通过工业上有利的方法制备5-烷基 - 恶唑烷-2,4-二酮。本发明涉及生产高纯度5-烷基 - 恶唑烷-2,4-二酮的新方法，包括在金属醇化物存在下使2-羟基羧酸酰胺与碳酸酯反应的步骤，从而完成一步反应，然后用中和结晶法分离反应产物。

5. 发明授权

US08961946B2 Hair processing agent and method for permanent waving hair 有权
标题翻译：头发处理剂及烫发方法
公开(公告)号：US08961946B2
公开(公告)日：2015-02-24
申请号：US11792828
申请日：2005-12-20
申请人： Akira Shibuya , Hidemasa Aoki , Makoto Saito , Motoaki Kamachi , Atsushi Tsuchiya , Akio Okamura
发明人： Akira Shibuya , Hidemasa Aoki , Makoto Saito , Motoaki Kamachi , Atsushi Tsuchiya , Akio Okamura
IPC分类号： A61K8/46 , A61Q5/04 , A61K8/49
CPC分类号： A61K8/4933 , A61Q5/04
摘要： Provided are hair processing agents capable of permanent waving hair even at a neutral to weakly acidic pH range that causes less irritation to the skin, and hair processing agents in which an unpleasant odor is masked. Hair processing agents contain at least one compound represented by the formula (2). Hair processing agents contain a compound of the formula (2) and at least one compound (ii) selected from thioglycolic acid, thiolactic acid, cysteine, acetylcysteine, cysteamine, acylcysteamine, salts thereof and ester derivatives thereof. Hair processing agents contain a compound of the formula (2), a surfactant and water, and are emulsified. Hair processing agents contain a compound of the formula (2) and a specific perfume. wherein X is a structure selected from —O—, —S—, —NH— and —NR1—; R1 is an alkyl group of 1 to 6 carbon atoms; Y is an oxygen atom or a sulfur atom; in the formula (1), Z is a divalent organic residue having at least one mercapto group; in the formula (2), R is a divalent organic residue optionally having a mercapto group; and R2 is a hydrogen atom or an alkyl group of 1 to 6 carbon atoms.
摘要翻译：提供即使在对皮肤刺激较少的中性至弱酸性pH范围也能永久挥发头发的头发加工剂，以及掩盖有令人不愉快的气味的毛发加工剂。头发处理剂含有至少一种式（2）表示的化合物。头发处理剂含有式（2）化合物和至少一种选自巯基乙酸，硫代乳酸，半胱氨酸，乙酰半胱氨酸，半胱胺，酰基半胱胺，其盐和其酯衍生物的化合物（ii）。头发处理剂含有式（2）的化合物，表面活性剂和水，并被乳化。头发处理剂含有式（2）的化合物和特定的香料。其中X是选自-O - ， - S - ， - NH-和-NR 1 - 的结构。 R1是1-6个碳原子的烷基; Y是氧原子或硫原子; 在式（1）中，Z是具有至少一个巯基的二价有机残基; 在式（2）中，R是任选具有巯基的二价有机残基; R2为氢原子或碳原子数1〜6的烷基。

6. 发明申请

US20080131389A1 Hair Relaxer 审中-公开
标题翻译：头发放松
公开(公告)号：US20080131389A1
公开(公告)日：2008-06-05
申请号：US11793798
申请日：2006-02-03
申请人： Akira Shibuya , Makoto Saito
发明人： Akira Shibuya , Makoto Saito
IPC分类号： A61K8/46 , A61Q5/04
CPC分类号： A61K8/46 , A61Q5/04
摘要： A hair relaxer includes at least one specific mercapto compound such as 2-methoxyethyl 3-mercaptopropionate, 2-mercapto-4-butanolide and 2-mercapto-4-butyrolactam. The hair relaxer can achieve an excellent effect of shaping and relaxing hair over a wide range of pH values from weak acidity to weak alkalinity. In particular, the hair relaxer displays a more superior hair shaping and relaxing performance in a weakly acidic to neutral pH range. Consequently, the hair relaxer can drastically reduce the damage to the hair and skin and can reliably perform straightening, uncurling, curling and other hair processing.
摘要翻译：头发松弛剂包括至少一种特定的巯基化合物，例如3-巯基丙酸2-甲氧基乙酯，2-巯基-4-丁醇酯和2-巯基-4-丁内酰胺。头发松弛剂可以在从弱酸性到弱碱性的广泛pH值范围内实现成型和松弛头发的优异效果。特别地，头发松弛剂在弱酸性至中性pH范围内显示出更优异的头发成型和松弛性能。因此，头发松弛剂可以大大降低对头发和皮肤的损伤，并可以可靠地进行矫直，卷曲，卷曲和其它头发处理。

7. 发明申请

US20080031839A1 Agent For Prermanent Hair Processing 审中-公开
标题翻译：头发处理代理
公开(公告)号：US20080031839A1
公开(公告)日：2008-02-07
申请号：US11631027
申请日：2005-06-28
申请人： Akira Shibuya , Makoto Saito , Hiroshi Ishit
发明人： Akira Shibuya , Makoto Saito , Hiroshi Ishit
IPC分类号： A61K8/37 , A61K8/23 , A61Q5/04
CPC分类号： A61K8/46 , A61Q5/04
摘要： An agent for permanent hair processing is disclosed that can shape the hair even in a neutral to slightly acidic pH region. The agent contains one or more compounds represented by the following formula (1) and/or formula (2): wherein R1 is a hydrogen atom or an alkyl group of 1 to 5 carbon atoms, R2 is an alkoxyalkyl group having a total of 3 to 15 carbon atoms, and the alkylene portion of R2 may contain an ether bond(s); wherein R3 is an alkoxyalkyl group having a total of 3 to 15 carbon atoms, and the alkylene portion of R3 may contain an ether bond(s).
摘要翻译：公开了一种用于永久性毛发加工的试剂，即使在中性至微酸性pH区域中也能使头发成型。该试剂含有一种或多种由下式（1）和/或式（2）表示的化合物：其中R 1是氢原子或1至5个碳原子的烷基， SUP> 2是总共3至15个碳原子的烷氧基烷基，R 2的亚烷基部分可以含有醚键; 其中R 3是总共3至15个碳原子的烷氧基烷基，R 3的亚烷基部分可以含有醚键。

8. 发明授权

US06372921B1 Process for producing isochromanones and intermediates thereof 失效
标题翻译：异色满酮的制造方法及其中间体
公开(公告)号：US06372921B1
公开(公告)日：2002-04-16
申请号：US09444309
申请日：1999-11-22
申请人： Yoshiaki Miyota , Akira Shibuya , Masaru Yasuda , Kimitaka Ohshiro , Makoto Saito
发明人： Yoshiaki Miyota , Akira Shibuya , Masaru Yasuda , Kimitaka Ohshiro , Makoto Saito
IPC分类号： C07D31176
CPC分类号： C07D311/76 , C07C17/14 , C07C29/124 , C07C253/14 , C07C253/30 , C07C22/04 , C07C255/35 , C07C255/36 , C07C33/26 , C07C33/46
摘要： (1) Methods for producing isochromanone compounds from o-xylene compounds as starting compounds through &agr;-halogeno-o-xylene derivatives, &agr;-cyano-o-xylene derivatives, and &agr;-halogeno-&agr;′-cyano-o-xylene derivatives, and (2) methods for producing isochromanone compounds from o-xylene compounds as starting compounds through &agr;,&agr;′-dihalogeno-o-xylene derivatives, &agr;,&agr;′-dihydroxy-o-xylene derivatives, &agr;-halogeno-&agr;′-hydroxy-o-xylene derivatives and &agr;-cyano-&agr;′-hydroxy-o-xylene derivatives, and methods for producing these intermediate compounds.
摘要翻译：（1）通过α-卤代邻 - 二甲苯衍生物，α-氰基邻二甲苯衍生物和α-卤代-α'-氰基邻二甲苯衍生物从邻二甲苯化合物作为起始化合物生产异色酮化合物的方法，和（2）通过α，α'-二卤代邻二甲苯衍生物，α，α'-二羟基邻二甲苯衍生物，α-卤代-α-羟基，邻二甲苯衍生物，由邻二甲苯化合物作为起始化合物生产异色酮化合物的方法 α-二甲苯衍生物和α-氰基-α'-羟基邻二甲苯衍生物，以及制备这些中间体化合物的方法。

9. 发明授权

US09829231B2 Refrigeration cycle apparatus 有权
公开(公告)号：US09829231B2
公开(公告)日：2017-11-28
申请号：US13822726
申请日：2011-10-04
申请人： Koji Fukui , Fumitake Unezaki , Makoto Saito
发明人： Koji Fukui , Fumitake Unezaki , Makoto Saito
IPC分类号： F25B49/00 , F25B49/02 , F24F11/00 , F25B25/00
CPC分类号： F25B49/02 , F24F11/83 , F24F2140/20 , F25B25/005 , F25B49/005 , F25B2500/19 , F25B2600/21 , F25B2700/171 , F25B2700/1933 , F25B2700/21151 , F25B2700/21172 , F25B2700/21173 , F25B2700/21174 , F25D2500/04
摘要： A refrigeration cycle apparatus includes low-pressure side pressure detecting means for detecting the pressure of a refrigerant being sucked by a compressor, suction refrigerant temperature detecting means for detecting the temperature of the refrigerant being sucked by the compressor, frequency detecting means for detecting the operation frequency of the compressor, cooling target fluid inflow temperature detecting means for detecting the temperature of a cooling target fluid flowing in an evaporator, cooling target fluid outflow temperature detecting means for detecting the temperature of the cooling target fluid flowing out of the evaporator, and flow rate calculating means (measuring unit, computing unit, and storage unit) for calculating the absolute quantity of the flow rate of the cooling target fluid flowing in the evaporator using a value detected by each detecting means.

10. 发明授权

US09651267B2 Cooling and hot water supply system and cooling and hot water supply method 有权
公开(公告)号：US09651267B2
公开(公告)日：2017-05-16
申请号：US13817914
申请日：2011-03-08
申请人： Shogo Tamaki , Makoto Saito
发明人： Shogo Tamaki , Makoto Saito
IPC分类号： F25B1/00 , F25B49/00 , F24D19/10 , F25B13/00 , F24F5/00 , F24F11/00 , F25B29/00 , F24F11/06
CPC分类号： F24D19/1051 , F24D19/1054 , F24D2220/042 , F24D2240/26 , F24F5/0096 , F24F11/30 , F24F11/83 , F24F2110/10 , F25B13/00 , F25B29/003 , F25B2313/003 , F25B2313/0231 , F25B2313/02731 , F25B2313/02741
摘要： A combined air-conditioning and hot water supply system simultaneously executes the cooling operation of a use unit and the hot water supply operation of a hot water supply unit, wherein the combined air-conditioning and hot water supply system operates in a cooling priority mode when the temperature differential ΔTwm between a set hot water supply temperature Twset and the inlet water temperature Twi of a plate water-heat exchanger is smaller than a priority operation determination threshold M that is set in advance, and operates in a hot water supply priority mode when the temperature differential ΔTwm becomes equal to or higher than the priority operation determination threshold M. This simultaneous execution of cooling and hot water supply operations prevents hot water from running out.

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