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1. 发明申请

US20100089761A1 METHOD OF SURFACE TREATMENT FOR METAL GLASS PART, AND METAL GLASS PART WITH ITS SURFACE TREATED BY THE METHOD 有权
标题翻译：金属玻璃部分表面处理方法及金属玻璃部件及其表面处理方法
公开(公告)号：US20100089761A1
公开(公告)日：2010-04-15
申请号：US12530920
申请日：2007-03-13
申请人： Xin Min Wang , Naokuni Muramatsu , Junsuke Kiuchi , Hiroshi Suzuki , Tatsue Arakawa , Hisamichi Kimura , Akihisa Inoue , Eiichi Makabe
发明人： Xin Min Wang , Naokuni Muramatsu , Junsuke Kiuchi , Hiroshi Suzuki , Tatsue Arakawa , Hisamichi Kimura , Akihisa Inoue , Eiichi Makabe
IPC分类号： C23G1/02 , B05D3/10 , C25D5/34 , C23C16/44 , C23C14/16 , C23C14/34 , B05D3/12 , C23C28/00 , C25D5/38 , C23C14/02 , C25D5/40 , C25D5/36 , C23C18/18 , C23F1/16
CPC分类号： C23G1/02 , C23C18/165 , C23C18/1844 , C23C18/31 , C23G1/086 , C23G1/10 , C23G1/103 , C23G1/106 , C25D5/34 , C25D5/36 , C25D5/38 , C25D5/40 , C25D5/48 , C25D5/54
摘要： There is provided a metallic glass component with its surface layer having both durability of a film and chromatic color properties, and a method for forming the surface layer. Surface active treatment is performed wherein the surface of the metallic glass component is reacted with a mixed aqueous solution of nitric acid and hydrofluoric acid to remove an oxide film and to provide an anchor bond shape on the surface of a metallic glass component, and electroplating or electroless plating is then performed, to form a plating film on the surface of the metallic glass component. It is thereby possible to form a surface layer of a metallic glass which has both durability and a chromatic color.
摘要翻译：提供一种其表面层具有薄膜的耐久性和彩色特性的金属玻璃组分和形成表面层的方法。进行表面活性处理，其中金属玻璃组分的表面与硝酸和氢氟酸的混合水溶液反应以除去氧化物膜，并在金属玻璃组分的表面上提供锚结合形状，以及电镀或然后进行化学镀，以在金属玻璃组分的表面上形成镀膜。从而可以形成具有耐久性和有色颜色的金属玻璃的表面层。

2. 发明授权

US06481088B1 Golf club manufacturing method 失效
标题翻译：高尔夫球杆制造方法
公开(公告)号：US06481088B1
公开(公告)日：2002-11-19
申请号：US09112360
申请日：1998-07-09
申请人： Akihisa Inoue , Eiichi Makabe , Masahide Onuki
发明人： Akihisa Inoue , Eiichi Makabe , Masahide Onuki
IPC分类号： B21B146
CPC分类号： B21J1/006 , A63B53/04 , A63B53/0466 , A63B53/047 , A63B60/00 , A63B2053/0408 , A63B2053/042 , A63B2209/00 , B22D25/02 , B22D27/04 , Y10T29/49988
摘要： A golf club which has a clubface of desired shape comprising an alloy metal is provided. The golf club has excellent strength properties as well as excellent ball hitting properties. The clubface is free from casting defects such as cold shuts, and preferably, free from the crystalline phase formed from crystal nuclei through nonuniform nucleation since the club face is produced in a simple, highly reproducible, one-step process by selectively cooling the molten metal at a temperature above the melting point at a rate higher than the critical cooling rate, and the product comprises a single amorphous phase. The metallic glass face used in the golf club is produced by filling a metal material in a hearth; melting said metal material by using a high-energy heat source which is capable of melting said the metal material; pressing said the molten metal at a temperature above the melting point of said the metal material to deform the molten metal into the desired shape by at least one of compressive stress and shear stress at a temperature above the melting point, while avoiding the surfaces of the molten metal cooled to a temperature below the melting point of said the metal material from meeting with each other during the pressing; and cooling said the molten metal at a cooling rate higher than the critical cooling rate of the metal material simultaneously with or after said the deformation to produce the metallic glass face of desired form.
摘要翻译：提供具有包括合金金属的所需形状的球杆面的高尔夫球杆。高尔夫球杆具有优异的强度性能以及出色的击球性能。球杆表面没有铸造诸如冷切之类的缺陷，并且优选地，通过非均匀成核而不存在由晶核形成的结晶相，因为球杆表面通过选择性地冷却熔融金属以简单，高度可重复的一步法生产在高于临界冷却速率的熔点的温度下，产物包含单一非晶相。在高尔夫球杆中使用的金属玻璃面通过将金属材料填充在炉床中而制成; 通过使用能够熔化所述金属材料的高能热源来熔化所述金属材料; 在高于所述金属材料的熔点的温度下压制所述熔融金属，以通过在高于熔点的温度下的压应力和剪切应力中的至少一种将熔融金属变形为期望的形状，同时避免熔融金属在压制期间被冷却到低于所述金属材料的熔点的温度彼此相遇的温度; 并且在所述变形之后或之后以比金属材料的临界冷却速度高的冷却速率冷却熔融金属，以产生所需形式的金属玻璃面。

3. 发明授权

US5740854A Production methods of metallic glasses by a suction casting method 失效
标题翻译：采用吸铸法生产金属玻璃的方法
公开(公告)号：US5740854A
公开(公告)日：1998-04-21
申请号：US892181
申请日：1997-07-14
申请人： Akihisa Inoue , Tao Zhang , Eiichi Makabe
发明人： Akihisa Inoue , Tao Zhang , Eiichi Makabe
IPC分类号： B22D18/06 , B22D11/00 , B22D23/00 , B22D27/04 , C22B9/20 , C22C1/00 , C22C1/02 , B22D27/15
CPC分类号： B22D11/009 , B22D27/04
摘要： This invention provides a glassy metal-suction casting method capable of readily and conveniently producing a large-sized amorphous material with excellent properties as an amorphous material. Such an object of the invention is attained by filling a metal material in a mold cooled with water; melting said metal material by using a high-energy heat source which is capable of rapidly melting said metal material; and introducing the resulting molten metal instantaneously into a vertically extending water-cooled mold provided below said mold by using a difference in gas pressure or gravity to move the metal melt at a high speed and attain a high quenching rate to thereby enable the production of a glassy metal ingot of a large size.
摘要翻译：本发明提供了一种玻璃状金属吸入铸造方法，其能够容易且方便地制造具有优异性能的大尺寸无定形材料作为无定形材料。本发明的目的是通过将金属材料填充在用水冷却的模具中来实现; 通过使用能够快速熔化所述金属材料的高能热源来熔化所述金属材料; 并通过使用气体压力或重力的差异将所产生的熔融金属瞬时引入设置在所述模具下方的垂直延伸的水冷模具中，以高速移动金属熔体并获得高淬火速率，从而能够生产玻璃状金属锭大尺寸。

4. 发明授权

US09175406B2 Method of surface treatment for metal glass part, and metal glass part with its surface treated by the method 有权
标题翻译：金属玻璃部件表面处理方法，金属玻璃部件表面处理方法
公开(公告)号：US09175406B2
公开(公告)日：2015-11-03
申请号：US12530920
申请日：2007-03-13
申请人： Xin Min Wang , Naokuni Muramatsu , Junsuke Kiuchi , Hiroshi Suzuki , Tatsue Arakawa , Hisamichi Kimura , Akihisa Inoue , Eiichi Makabe
发明人： Xin Min Wang , Naokuni Muramatsu , Junsuke Kiuchi , Hiroshi Suzuki , Tatsue Arakawa , Hisamichi Kimura , Akihisa Inoue , Eiichi Makabe
IPC分类号： C25D5/34 , C23C28/00 , C25D5/54 , C23G1/02 , C23C18/16 , C23C18/18 , C23C18/31 , C23G1/08 , C23G1/10 , C25D5/36 , C25D5/38 , C25D5/40 , C25D5/48
CPC分类号： C23G1/02 , C23C18/165 , C23C18/1844 , C23C18/31 , C23G1/086 , C23G1/10 , C23G1/103 , C23G1/106 , C25D5/34 , C25D5/36 , C25D5/38 , C25D5/40 , C25D5/48 , C25D5/54
摘要： There is provided a metallic glass component with its surface layer having both durability of a film and chromatic color properties, and a method for forming the surface layer. Surface active treatment is performed wherein the surface of the metallic glass component is reacted with a mixed aqueous solution of nitric acid and hydrofluoric acid to remove an oxide film and to provide an anchor bond shape on the surface of a metallic glass component, and electroplating or electroless plating is then performed, to form a plating film on the surface of the metallic glass component. It is thereby possible to form a surface layer of a metallic glass which has both durability and a chromatic color.
摘要翻译：提供一种其表面层具有薄膜的耐久性和彩色特性的金属玻璃组分和形成表面层的方法。进行表面活性处理，其中金属玻璃组分的表面与硝酸和氢氟酸的混合水溶液反应以除去氧化物膜，并在金属玻璃组分的表面上提供锚结合形状，以及电镀或然后进行化学镀，以在金属玻璃组分的表面上形成镀膜。从而可以形成具有耐久性和有色颜色的金属玻璃的表面层。

5. 发明授权

US06427753B1 Process and apparatus for producing metallic glass 失效
标题翻译：用于生产金属玻璃的工艺和设备
公开(公告)号：US06427753B1
公开(公告)日：2002-08-06
申请号：US09242136
申请日：1999-02-10
申请人： Akihisa Inoue , Eiichi Makabe
发明人： Akihisa Inoue , Eiichi Makabe
IPC分类号： B22D2306
CPC分类号： C22C45/02 , B21J1/006 , B22D18/02 , B22D23/06 , B22D27/00 , B22D27/04 , C22C21/003 , C22C21/02 , C22C33/003 , C22C45/00 , C22C45/003 , C22C45/005 , C22C45/04 , C22C45/10
摘要： A process and an apparatus for producing metallic glass which are capable of producing a bulk amorphous alloy of desired shape, in particular, a bulk amorphous alloy of desired final shape are provided. In the present invention, the molten metal at a temperature above the melting point is selectively cooled at a rate higher than the critical cooling rate, and the product comprises single amorphous phase which is free from the crystalline phase formed by the development of crystal nuclei through nonuniform nucleation. The present invention is capable of producing the bulk amorphous alloy which is free from casting defects such as cold shuts and which has excellent strength properties in a simple process at a high reproducibility. Accordingly, a bulk metallic glass of desired shape is produced by filling a metal material in a hearth; melting the metal material by using a high-energy heat source which is capable of melting the metal material; pressing the molten metal at a temperature above the melting point of the metal material to deform the molten metal into the desired shape by at least one of compressive stress and shear stress at a temperature above the melting point, while avoiding the surfaces of the molten metal cooled to a temperature below the melting point of the metal material from meeting with each other during the pressing; and cooling the molten metal at a cooling rate higher than the critical cooling rate of the metal material simultaneously with or after the deformation to produce the bulk metallic glass of desired form.
摘要翻译：提供一种能够生产所需形状的块状非晶合金，特别是具有所需最终形状的块状非晶合金的金属玻璃的制造方法和装置。在本发明中，在高于熔点的温度下的熔融金属以高于临界冷却速率的速率被选择性地冷却，并且产物包含单晶非晶相，其不含晶界形成的结晶相非均匀成核。本发明能够制造不含铸造缺陷的块状非晶合金，例如冷切，并且在高再现性的简单工艺中具有优异的强度性能。因此，通过将金属材料填充在炉床中来制造所需形状的块状金属玻璃; 通过使用能够熔化金属材料的高能热源来熔化金属材料; 在高于金属材料的熔点的温度下挤压熔融金属，以在高于熔点的温度下通过压缩应力和剪切应力中的至少一种使熔融金属变形成所需形状，同时避免熔融金属的表面冷却到低于金属材料的熔点的温度，在压制过程中彼此相遇; 并且以与金属材料的临界冷却速率相比更高的冷却速率在变形之后或之后冷却熔融金属，以产生所需形式的块状金属玻璃。

6. 发明授权

US09279186B2 Metal member manufacturing method and metal member 有权
标题翻译：金属构件制造方法和金属构件
公开(公告)号：US09279186B2
公开(公告)日：2016-03-08
申请号：US13574854
申请日：2010-10-22
申请人： Hidemi Kato , Takeshi Wada , Kunio Yubuta , Akihisa Inoue
发明人： Hidemi Kato , Takeshi Wada , Kunio Yubuta , Akihisa Inoue
IPC分类号： C23F4/04 , C23C26/02 , C23F1/00 , C22B9/02 , C22B26/22
CPC分类号： C23C26/02 , B22F2998/00 , C22B9/02 , C22B26/22 , C23F1/00 , C23F4/04 , Y02P10/234 , Y10T428/12479 , C22C1/0425 , C22C1/0433 , C22C33/02
摘要： A metallic material containing both a second constituent and a third constituent having positive and negative heats of mixing relative to a first constituent, respectively, and including a compound, an alloy or a nonequilibrium alloy having a melting point that is higher than the solidifying point of a metal bath made of the first constituent is placed in the metal bath. The metal bath is controlled to a temperature lower than a minimum value of a liquidus temperature within a range of compositional variations in which the amount of the third constituent in the metallic material decreases down to a point where the metallic material becomes substantially the second constituent so that the third constituent is selectively dissolved into the metal bath.
摘要翻译：一种含有第二成分和第三成分的金属材料，分别具有相对于第一成分的正和负的混合热，并且包括熔点高于凝固点的化合物，合金或非平衡合金将由第一成分制成的金属浴放置在金属浴中。将金属浴控制在低于液相线温度的最小值的温度范围内，其中金属材料中的第三成分的量减少到金属材料基本上变成第二成分的程度第三组分选择性地溶解到金属浴中。

7. 发明授权

US08652399B2 Sputtering target for producing metallic glass membrane and manufacturing method thereof 有权
标题翻译：制造金属玻璃膜的溅射靶及其制造方法
公开(公告)号：US08652399B2
公开(公告)日：2014-02-18
申请号：US12854683
申请日：2010-08-11
申请人： Atsushi Nakamura , Masataka Yahagi , Akihisa Inoue , Hisamichi Kimura , Shin-ichi Yamaura
发明人： Atsushi Nakamura , Masataka Yahagi , Akihisa Inoue , Hisamichi Kimura , Shin-ichi Yamaura
IPC分类号： C22C1/04
CPC分类号： C23C14/3414 , B01D67/0072 , B01D71/022 , B01D2325/04 , B22F2998/10 , B22F2999/00 , C01B3/503 , C01B3/505 , C22C5/04 , C22C9/00 , C22C16/00 , C22C19/03 , C22C19/07 , C22C45/001 , C22C45/003 , C22C45/02 , C22C45/04 , C22C45/10 , B22F9/082 , B22F3/10 , B22F2201/11
摘要： A sputtering target for producing a metallic glass membrane characterized in comprising a structure obtained by sintering atomized powder having a composition of a ternary compound system or greater with at least one or more metal elements selected from Pd, Zr, Fe, Co, Cu and Ni as its main component (component of greatest atomic %), and being an average grain size of 50 μm or less. The prepared metallic glass membrane can be used as a substitute for conventional high-cost bulk metallic glass obtained by quenching of molten metal. This sputtering target for producing the metallic glass membrane is also free from problems such as defects in the metallic glass membrane and unevenness of composition, has a uniform structure, can be produced efficiently and at low cost, and does not generate many nodules or particles. Further provided is a method for manufacturing such a sputtering target for forming the metallic glass membrane.
摘要翻译：一种用于制造金属玻璃膜的溅射靶，其特征在于包括通过将选自Pd，Zr，Fe，Co，Cu和Ni中的至少一种或多种金属元素烧结成具有三元化合物体系以上的组成的雾化粉末而获得的结构作为其主要成分（原子％最大的成分），平均粒径为50μm以下。制备的金属玻璃膜可用作通过熔融金属淬火获得的常规高成本大块金属玻璃的替代物。用于制造金属玻璃膜的溅射靶也没有诸如金属玻璃膜的缺陷和组成不均匀等问题，具有均匀的结构，可有效且低成本地生产，并且不产生许多结节或颗粒。进一步提供一种用于制造用于形成金属玻璃膜的溅射靶的方法。

8. 发明授权

US08418366B2 Internal gear manufacturing method and metallic glass internal gear manufactured thereby 失效
标题翻译：由此制造内齿轮制造方法和金属玻璃内齿轮
公开(公告)号：US08418366B2
公开(公告)日：2013-04-16
申请号：US12745166
申请日：2008-11-27
申请人： Xinmin Wang , Akihisa Inoue , Yukiharu Shimizu
发明人： Xinmin Wang , Akihisa Inoue , Yukiharu Shimizu
IPC分类号： B22D27/15 , B22D29/00
CPC分类号： B22D27/15 , B22D29/001 , F16H55/06 , Y10T29/49462 , Y10T29/49467 , Y10T29/49474 , Y10T29/4998 , Y10T29/49988 , Y10T29/49989 , Y10T74/19
摘要： An internal gear manufacturing method capable of manufacturing time reduction and easy core removal, and a metallic glass internal gear manufactured thereby. A carbon core formed into a shape of an external gear is arranged in a thin, long tubular mold of a length equal thereto with a space extending longitudinally therealong. A molten metal material is pressure-injected under a temperature higher than a melting point thereof into the space between the mold and the core. The molten metal material is resolidified by rapid cooling at or above a critical cooling rate thereof together with the mold and the core. After resolidification of the molten metal material, the core is removed by pulverization or dissolution. Along internal gear formed of the resolidified metal material is cut into a plurality of segments of a prescribed length.
摘要翻译：一种能够制造时间缩短和易于除芯的内齿轮制造方法，以及由此制造的金属玻璃内齿轮。形成为外部齿轮形状的碳芯被布置在长度相当于其长度的长而长的管状模具中，沿着其纵向延伸的空间。熔融金属材料在高于其熔点的温度下被压注入模具和芯体之间的空间。熔融金属材料通过与模具和芯体一起的临界冷却速度或其上的快速冷却来重新凝固。在熔融金属材料重新固化之后，通过粉碎或溶解除去芯体。沿由固化后的金属材料形成的内齿轮切割成规定长度的多个段。

9. 发明申请

US20130068417A1 ARC MELTING FURNACE DEVICE 有权
标题翻译：电弧熔炼设备
公开(公告)号：US20130068417A1
公开(公告)日：2013-03-21
申请号：US13700335
申请日：2011-06-01
申请人： Masaki Nagata , Motohiro Kameyama , Yoshihiko Yokoyama , Akihisa Inoue
发明人： Masaki Nagata , Motohiro Kameyama , Yoshihiko Yokoyama , Akihisa Inoue
IPC分类号： F27D11/08
CPC分类号： F27D11/08 , B22C9/06 , B22D7/00 , B22D23/06 , B22D27/04 , B22D29/04 , F27B3/085 , F27B17/00
摘要： An arc melting furnace apparatus is provided which reduces an operation burden on a worker and shortens working hours. An arc melting furnace apparatus 1 includes a housing 2 having formed therein a melting chamber 2a, a hearth 4 provided within the melting chamber 2a and having a recessed portion 4a, and a heating mechanism 10 for heating and melting a metal material supplied into the recessed portion 4 to generate an alloy ingot. The apparatus comprises a turning member 23 rotatably supported on a supporting member 21 standing within the melting chamber 2a, a perimeter edge of the turning member 23 rotating and moving along the inner surface of the recessed portion 4a to lift the alloy ingot generated in the recessed portion 4a above the hearth 4 and turn it over, and a resilient turn-over assisting member 24 provided above an upper end of the recessed portion 4a. Further, the turn-over assisting member 24 is arranged to flex by a predetermined amount when the alloy ingot abuts it, and to return to its original state from the flexed state so that the alloy ingot is urged to drop into the recessed portion 4a.
摘要翻译：提供了一种电弧熔化炉装置，其减少了对工人的操作负担并缩短了工作时间。电弧熔化炉装置1包括：壳体2，其中形成有熔化室2a，设置在熔化室2a内并具有凹部4a的炉床4，以及加热和熔化被供给到凹部部分4以产生合金锭。该装置包括可旋转地支撑在站立在熔化室2a内的支撑构件21上的转动构件23，转动构件23的周边边缘沿着凹进部分4a的内表面旋转并移动，以提升在凹进部分中产生的合金块在炉床4上方的部分4a翻转，并且设置在凹部4a的上端上方的弹性翻转辅助件24。此外，转向辅助构件24被布置为当合金锭抵接时弯曲预定量，并且从弯曲状态恢复到其初始状态，使得合金锭被推入凹入部分4a中。

10. 发明授权

US08377580B2 Metallic glass, magnetic recording medium using the same, and method of manufacturing the magnetic recording medium 有权
标题翻译：金属玻璃，使用其的磁记录介质以及制造磁记录介质的方法
公开(公告)号：US08377580B2
公开(公告)日：2013-02-19
申请号：US12678291
申请日：2008-09-17
申请人： Akihiro Makino , Akihisa Inoue , Wei Zhang , Hisamichi Kimura
发明人： Akihiro Makino , Akihisa Inoue , Wei Zhang , Hisamichi Kimura
IPC分类号： G11B5/65 , G11B5/667
CPC分类号： G11B5/653 , C22C33/003 , C22C45/003 , C22C45/02 , G11B5/855 , H01F1/01 , H01F1/068 , H01F1/15333 , H01F10/131 , H01F41/34
摘要： A magnetic recording medium 1 includes a substrate 11; and a metallic glassy layer 12 that is arranged on the substrate 11 and has a plurality of convex portions 12A and concave portions 12B. The metallic glassy layer 12 has a chemical composition represented by any one of the formulae (1) to (3): FemPtnSixByPz (wherein, 20
摘要翻译：磁记录介质1包括基板11; 以及设置在基板11上并具有多个凸部12A和凹部12B的金属玻璃层12。金属玻璃层12具有由式（1）至（3）中的任一个表示的化学组成：FemPtnSixByPz（其中，20

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