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    • 2. 发明授权
    • Ink jet head
    • 喷墨头
    • US5534903A
    • 1996-07-09
    • US93281
    • 1993-07-16
    • Tsuyoshi HayakawaHajime OdaTakashi KogoYukiharu ShimizuShoichi SatoToshiya TamuraHiroyuki Kojima
    • Tsuyoshi HayakawaHajime OdaTakashi KogoYukiharu ShimizuShoichi SatoToshiya TamuraHiroyuki Kojima
    • B41J2/045B41J2/055B41J2/14B41J2/16
    • B41J2/1623B41J2/14233B41J2/161B41J2002/14387
    • An ink jet head includes a nozzle plate having a nozzle through the nozzle plate in its thickness direction, a base plate laminated with the nozzle plate and having an ink supplying hole through the base plate in its thickness direction, a pressure chamber connected to the nozzle and the ink supplying hole in the substantially perpendicular manner and provided with a pressure means on the bonded surface of the nozzle plate and the base plate. The nozzle and the ink supplying hole are made narrower than the pressure chamber and the connecting channel. The plural nozzles, pressure chambers, connecting channels, and ink supplying holes are provided. A common ink chamber connecting to a plurality of the ink supplying holes are provided on the opposite surface to the nozzle plate laminated with the base plate in the perpendicular manner to the nozzle plate. A projection is formed in the nozzle plate and the nozzle is provided through the projection. The ink head enables to prevent bonding materials from flowing into the thin portions during bonding process, to eliminate variations in efficiency of ink ejection at the respective nozzles, and to improve the printing finish in quality.
    • 喷墨头包括喷嘴板,喷嘴板在其厚度方向上具有通过喷嘴板的喷嘴,与喷嘴板层叠的基板,并且在其厚度方向上具有通过基板的供墨孔,连接到喷嘴的压力室 和墨水供应孔,并且在喷嘴板和基板的接合表面上设置有压力装置。 喷嘴和供墨孔比压力室和连接通道窄。 提供多个喷嘴,压力室,连接通道和供墨孔。 连接到多个供墨孔的公共墨室设置在垂直于喷嘴板的与底板层叠的喷嘴板的相对表面上。 在喷嘴板中形成突起,并且通过突起设置喷嘴。 油墨头能够防止接合过程中接合材料流入薄壁部分,从而消除各喷嘴处的喷墨效率的变化,提高打印质量。
    • 3. 发明授权
    • Monohalo substituted triazinyl monoazo dyestuffs for
cellulose-containing fibers
    • 用于含纤维素的纤维的单卤代取代的三嗪基单偶氮染料
    • US4837309A
    • 1989-06-06
    • US583233
    • 1984-02-24
    • Toshio NiwaKiyoshi HimenoToshio HiharaYutaka KuroseYukiharu Shimizu
    • Toshio NiwaKiyoshi HimenoToshio HiharaYutaka KuroseYukiharu Shimizu
    • C09B29/085C09B62/085D06P1/382D06P3/85
    • C09B62/085
    • A monoazo dyestuff of the formula: ##STR1## wherein D represents substituted or unsubstituted phenyl, imidazolyl, pyridyl, thiazolyl, thiadiazolyl, thienyl, benzoisothiazolyl, pyridinoisothiazolyl, thienoisothiazolyl, thienothiazolyl or benzothiazolyl, R.sup.1 represents substituted or unsubstituted alkyl, cyclohexyl, alkenyl, aralkyl or aryl, R.sup.2 and R.sup.3 each represents hydrogen, alkyl optionally substituted by cyano, hydroxy, alkoxy or alkoxyalkoxy, alkenyl, cyclohexyl, aryl or aralkyl, or together represent a 5- or 6-membered nitrogen-containing heterocyclic ring formed by combining R.sup.2 and R.sup.3, A represents ##STR2## X represents fluorine or chlorine, and Y.sup.1 represents hydrogen, chlorine, methyl or acylamino. The monoazo dyestuff is especially useful in the dyeing of cellulose-containing fibers and exhibits good fastness properties including good wet color fastness and good light fastness.
    • 其中D表示取代或未取代的苯基,咪唑基,吡啶基,噻唑基,噻二唑基,噻吩基,苯并异噻唑基,吡啶并异噻唑基,噻吩并噻唑基,噻吩并噻唑基或苯并噻唑基,R1代表取代或未取代的烷基,环己基,烯基,芳烷基 或芳基,R 2和R 3各自表示氢,任选被氰基,羟基,烷氧基或烷氧基烷氧基取代的烷基,烯基,环己基,芳基或芳烷基,或一起表示通过将R 2和R 2相结合形成的5-或6-元含氮杂环, R3,A表示X表示氟或氯,Y1表示氢,氯,甲基或酰氨基。 单偶氮染料特别可用于含纤维素纤维的染色,并且具有良好的耐牢度性能,包括良好的耐湿色牢度和良好的耐光性。
    • 9. 发明授权
    • Fiber-reactive halotriazine pyridine-based monoazo colorant
    • 纤维反应性卤代三嗪吡啶类单偶氮染料
    • US4960871A
    • 1990-10-02
    • US313316
    • 1989-02-17
    • Toshio HiharaYukiharu Shimizu
    • Toshio HiharaYukiharu Shimizu
    • C09B62/085D06P1/382D06P3/66D06P3/82D06P3/85
    • C09B62/085D06P1/382D06P3/8228
    • Monoazo colorants represented by the general formula (I): ##STR1## wherein: D represents ##STR2## (wherein X represents a hydrogen atom or a halogen atom, and Y represents a nitro group, a lower alkylsulfonyl group, a thiocyanic acid group or a halogen atom), or ##STR3## (wherein P represents a nitro group or a lower alkylsulfonyl group, and Q and T each represents a hydrogen atom, a halogen atom or a cyano group);R.sup.1 and R.sup.2 each represents an ethylene group or a propylene group;R.sup.3 and R.sup.4 each represents a hydrogen atom or an alkyl group which may be substituted by a lower alkoxy group or a lower alkoxyalkoxy group; andZ represents a halogen atom.This monoazo colorants include a reactive type pyridine-based monoazo dye suitable for use in dyeing of cellulose or cellulose/polyester mixed fibers in red to orange.
    • (I)表示的单偶氮着色剂:其中:D表示(其中X表示氢原子或卤素原子,Y表示硝基,低级烷基磺酰基,硫氰酸酯 酸基或卤素原子)或(其中P表示硝基或低级烷基磺酰基,Q和T各自表示氢原子,卤素原子或氰基)。 R1和R2各自表示亚乙基或亚丙基; R3和R4各自表示氢原子或可被低级烷氧基或低级烷氧基烷氧基取代的烷基; Z表示卤素原子。 该单偶氮着色剂包括适用于染色红色至橙色的纤维素或纤维素/聚酯混合纤维的反应型吡啶类单偶氮染料。
    • 10. 发明授权
    • Reactive disperse diaminopyridine azo dyes containing a fluorostriazine
group
    • 含有氟代三嗪基团的二氨基吡啶偶氮染料的反应性分散
    • US4500455A
    • 1985-02-19
    • US400533
    • 1982-07-21
    • Toshio NiwaToshio HiharaYukiharu Shimizu
    • Toshio NiwaToshio HiharaYukiharu Shimizu
    • C09B62/085C09B62/04C09B62/08C09B62/09D06P1/382D06P3/60D06P3/66D06P3/84
    • D06P3/6041C09B62/08D06P1/382
    • Diaminopyridine dyes for dyeing cellulose-containing fibers, particularly cellulose fibers and polyester-cellulose fibers in from orange to bluish red, with excellent fastness to light. The dyes are represented by the formula (I): ##STR1## X is a hydrogen atom, or a halogen atom; Y is an alkoxy group containing from 1 to 5 carbon atoms, --O--R.sup.10 --O--R.sup.11, or a phenoxy group; andn is 2 or 3, and wherein R.sup.1 is a nitro group, a cyano group, a methylsulfonyl group, a phenylsulfonyl group, a mono- or di-lower alkylaminosulfonyl group, an acetyl group, or a benzoyl group; R.sup.2 and R.sup.3 are each a hydrogen atom, a trifluoromethyl group, a halogen atom, or a cyano group; R.sup.4 is a hydrogen atom, a lower alkyl group, a mono- or di-lower alkylaminosulfonyl group, a mono- or di-lower alkylcarbamoyl group, or an acetylamino group; R.sup.5 and R.sup.6 are each a hydrogen atom, a halogen atom, or a lower alkyl group; R.sup.7 is a lower alkyl group; R.sup.8 is a hydrogen atom or a halogen atom; R.sup.10 is an ethylene group, or a propylene group; and R.sup.11 is a methyl group, or an ethyl group.
    • 用于染色含纤维素纤维的二氨基吡啶染料,特别是从橙色到蓝红色的纤维素纤维和聚酯纤维素纤维,具有优异的耐光牢度。 染料由式(I)表示:其中X是氢原子或卤素原子;其中X是氢原子或卤素原子; Y是含有1至5个碳原子的烷氧基,-O-R10-O-R11或苯氧基; n为2或3,R 1为硝基,氰基,甲基磺酰基,苯磺酰基,一或二低级烷基氨基磺酰基,乙酰基或苯甲酰基; R2和R3各自为氢原子,三氟甲基,卤素原子或氰基; R4是氢原子,低级烷基,一或二低级烷基氨基磺酰基,一或二低级烷基氨基甲酰基或乙酰氨基; R5和R6各自为氢原子,卤素原子或低级烷基; R7是低级烷基; R8是氢原子或卤素原子; R 10是亚乙基或亚丙基; R11为甲基或乙基。