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1. 发明授权

US06695993B2 Process for forming recyclable articles 失效
标题翻译：形成可回收物品的方法
公开(公告)号：US06695993B2
公开(公告)日：2004-02-24
申请号：US10056273
申请日：2002-01-25
申请人： Abdulmajid Hashemzadeh , Klaus Kohlhammer , Konrad Alfons Wierer , Herbert Pröbstl
发明人： Abdulmajid Hashemzadeh , Klaus Kohlhammer , Konrad Alfons Wierer , Herbert Pröbstl
IPC分类号： A29B1114
CPC分类号： B29B17/0042 , B29K2101/10 , B29K2105/06 , C08K9/08 , D04H1/4218 , D04H1/4266 , D04H1/435 , D04H1/587 , D04H1/64 , Y02W30/62 , C08L33/04
摘要： A process for forming particulate materials and binders into articles that are reusable after comminution, wherein the particulate materials are treated with a binder composition containing. A) one or more copolymers containing one or more comonomer units selected from the group consisting of vinyl esters of branched or unbranched alkyl carboxylic acids of 1 to 18 carbon atoms, acrylic or methacrylic esters of branched or unbranched alcohols of 1 to 15 carbon atoms, dienes, olefins, vinyl aromatics and vinyl halides, and further containing 4 to 60% by weight, based on the total weight of the copolymer, of one or more comonomer units containing polar groups, and B) one or more fillers having a polar surface capable of interaction with the polar groups of copolymer A), and formed into articles and consolidated, and, if appropriate, the formed article obtained thereby is comminuted for recycling and the material obtained thereby is reused for forming new articles.
摘要翻译：一种将颗粒材料和粘合剂形成物料的方法，其在粉碎后可重复使用，其中所述颗粒材料用含有的粘合剂组合物处理。A）一种或多种含有一种或多种共聚单体单元的共聚物，所述共聚单体选自乙烯基支链或1至18个碳原子的无支链烷基羧酸，1至15个碳原子的支链或非支链醇的丙烯酸或甲基丙烯酸酯，二烯，烯烃，乙烯基芳族化合物和乙烯基卤化物，并且还包含4至60重量％共聚物，含有极性基团的一种或多种共聚单体单元的总重量，和B）具有能与共聚物A的极性基团相互作用的极性表面的一种或多种填料），并形成制品并固化，如果合适将由此获得的成型体粉碎以进行再循环，由此得到的材料再次用于形成新的制品。

2. 发明授权

US06884837B2 Crosslinkable polymer composition 失效
标题翻译：可交联聚合物组合物
公开(公告)号：US06884837B2
公开(公告)日：2005-04-26
申请号：US09804495
申请日：2001-03-12
申请人： Klaus Kohlhammer , Abdulmajid Hashemzadeh
发明人： Klaus Kohlhammer , Abdulmajid Hashemzadeh
IPC分类号： C08J3/12 , C03C25/32 , C08F2/04 , C08F2/22 , C08G81/02 , C08L25/14 , C08L33/06 , C08L35/06 , C08L101/02 , C08L101/08 , D04H1/4218 , D04H1/593 , D04H1/60 , D04H1/64 , D04H1/68 , D06M15/227 , D06M15/233 , D06M15/244 , D06M15/263 , D06M15/273 , D06M15/327 , D06M15/347 , D06M15/356 , D06M23/08 , C08K3/20 , C08F8/30
CPC分类号： D04H1/64 , C03C25/32 , C08G81/021 , C08L25/14 , C08L33/06 , C08L33/066 , C08L35/06 , C08L2205/02 , D04H1/4218 , D04H1/593 , D04H1/60 , D04H1/68 , D06M15/227 , D06M15/233 , D06M15/244 , D06M15/263 , D06M15/273 , D06M15/327 , D06M15/347 , D06M15/3562 , D06M23/08 , C08L2666/04
摘要： The present invention provides a crosslinkable polymer composition in the form of its aqueous polymer dispersion or polymer powder, including A) a copolymer having a glass transition temperature Tg or a melting temperature of ≧30° C. and containing units derived from one or more comonomers selected from the group consisting of vinyl esters of branched or unbranched alkylcarboxylic acids of 1 to 18 carbon atoms, acrylic esters or methacrylic esters of branched or unbranched alcohols of 1 to 15 carbon atoms, dienes, olefins, vinyl aromatics and vinyl halides and from 0.1 to 50% by weight, based on the total weight of the comonomers, of one or more ethylenically unsaturated carboxyl-containing comonomers, and B) a copolymer containing units derived from one or more comonomers selected from the group consisting of vinyl esters of branched or unbranched alkylcarboxylic acids of 1 to 18 carbon atoms, acrylic esters or methacrylic esters of branched or unbranched alcohols of 1 to 15 carbon atoms, dienes, olefins, vinyl aromatics and vinyl halides and from 0.1 to 50% by weight, based on the total weight of the comonomers, of one or more ethylenically unsaturated comonomers having functional groups capable of entering a covalent bond with the carboxyl groups of said copolymer A).
摘要翻译：本发明提供其聚合物水分散体或聚合物粉末形式的可交联聚合物组合物，其包括A）具有玻璃化转变温度Tg或熔点> 30℃的共聚物，并且含有衍生自一个或多个选自由1至18个碳原子的支链或非支链烷基羧酸的乙烯基酯组成的组的共聚单体，1至15个碳原子的支链或非支链醇的丙烯酸酯或甲基丙烯酸酯，二烯，烯烃，乙烯基芳族化合物和乙烯基卤化物， 0.1至50重量％，基于共聚单体的总重量，一种或多种烯属不饱和羧酸的共聚单体，和B）含有衍生自一种或多种共聚单体的共聚物的共聚物，所述共聚单体选自由支链或1-18个碳原子的无支链烷基羧酸，1-15个碳原子的支链或非支链醇的丙烯酸酯或甲基丙烯酸酯原子，二烯，烯烃，乙烯基芳烃和乙烯基卤化物，和基于共聚单体总重量的0.1-50重量％的一种或多种具有能够与羧基共价键的官能团的烯属不饱和共聚单体所述共聚物A）。

3. 发明授权

US5977244A Powdered crosslinkable textile binder composition 失效
标题翻译：粉状可交联纺织粘合剂组合物
公开(公告)号：US5977244A
公开(公告)日：1999-11-02
申请号：US126456
申请日：1998-07-29
申请人： Klaus Kohlhammer , Richard Goetze , Reinhard Haerzschel , Abdulmajid Hashemzadeh
发明人： Klaus Kohlhammer , Richard Goetze , Reinhard Haerzschel , Abdulmajid Hashemzadeh
IPC分类号： B31F5/04 , B32B5/12 , B32B27/04 , C08F8/08 , C08F8/30 , C08G18/62 , C08G59/40 , C08J3/24 , C08J5/04 , C08J5/24 , C08L25/04 , C08L27/06 , C08L31/02 , C08L31/04 , C08L33/02 , C08L33/06 , C08L35/00 , C08L57/00 , C08L101/00 , D04H1/4209 , D04H1/4218 , D04H1/425 , D04H1/4258 , D04H1/4266 , D04H1/4291 , D04H1/4334 , D04H1/435 , D04H1/58 , D04H1/587 , D04H1/60 , D04H1/64 , D06M13/02 , D06M13/10 , D06M13/244 , D06M13/282 , D06M15/19 , D06M15/233 , D06M15/248 , D06M15/263 , D06M15/333 , D06M15/55 , D06M23/08 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/10 , D06M101/12 , D06M101/16 , D06M101/18 , D06M101/30 , D06M101/32 , D06M101/34 , C08J3/00 , C08F283/04 , C08K3/20 , C08L75/00
CPC分类号： D04H1/435 , C08F8/44 , D04H1/4209 , D04H1/4218 , D04H1/425 , D04H1/4258 , D04H1/4266 , D04H1/4291 , D04H1/4334 , D04H1/587 , D04H1/60 , D04H1/64 , D06M15/233 , D06M15/248 , D06M15/263 , D06M15/333 , D06M15/55 , D06M23/08 , C08F2800/20 , C08F2810/20 , Y10T428/24091 , Y10T428/2982
摘要： The invention provides a powdered crosslinkable textile binder composition for producing polymer bonded textile moldings or sheet materials, comprisinga) a powdered copolymer obtainable by emulsion polymerization and subsequent drying of one or more monomers selected from the group consisting of vinyl esters, acrylic esters, methacrylic esters, vinylaromatics and vinyl chloride and of 0.01 to 25% by weight, based on the total weight of the copolymer, of one or more ethylenically unsaturated carboxyl-containing monomers, the copolymer having a glass transition temperature Tg or a melting point of greater than 40.degree. C. and a molecular weight Mw of 60,000 to 300,000, andb) at least one powdered compound having two or more epoxide or isocyanate groups and a melting point of 40.degree. C. to 150.degree. C.
摘要翻译：本发明提供了一种用于生产聚合物粘合的纺织品模制品或片材的粉状可交联纺织粘合剂组合物，其包含a）通过乳液聚合和随后干燥一种或多种选自乙烯基酯，丙烯酸酯，甲基丙烯酸酯酯，乙烯基芳烃和氯乙烯，并且基于共聚物的总重量为0.01至25重量％的一种或多种烯属不饱和羧酸单体，所述共聚物具有玻璃化转变温度Tg或熔点大于 40℃，分子量Mw为60,000〜300,000，b）至少一种具有两个以上环氧化物或异氰酸酯基团，熔点为40℃〜150℃的粉末状化合物。

4. 发明授权

US06774161B2 Process for the cold molding of particulate materials 失效
标题翻译：颗粒材料冷成型工艺
公开(公告)号：US06774161B2
公开(公告)日：2004-08-10
申请号：US10354479
申请日：2003-01-30
申请人： Abdulmajid Hashemzadeh , Klaus Kohlhammer , Thomas Lehmann , Peter Weiler
发明人： Abdulmajid Hashemzadeh , Klaus Kohlhammer , Thomas Lehmann , Peter Weiler
IPC分类号： C08J300
CPC分类号： C08J5/04
摘要： Particulate materials are cold molded by preheating a binder and the material to be bound to a temperature of from 160 to 240° C., and then press molding at a temperature less than 80° C. and at a pressure of from 1 to 120 bar to give a molding, wherein the binder contains a polymer powder or aqueous polymer dispersion thereof, the polymer having a glass transition temperature Tg greater than 80° C. and a complex viscosity less than 15,000 Pa·s at 190° C., and derived from one or more comonomer units from the group of vinyl esters of optionally branched C1-18 alkylcarboxylic acids, (meth)acrylic esters of optionally branched C1-15 alcohols, dienes, olefins, vinylaromatics, and vinyl halides. The moldings exhibit excellent properties including resistance to sagging at elevated temperatures, and are recyclable.
摘要翻译：颗粒材料通过预热粘合剂和要结合到160至240℃的温度的材料进行冷成型，然后在低于80℃的温度和1至120巴的压力下进行压制成型其中粘合剂含有聚合物粉末或其聚合物水分散体，该聚合物的玻璃化转变温度Tg大于80℃，复数粘度在190℃下小于15,000Pa.s，并得到来自一个或多个共聚单体单元，任选支化的C 1-18烷基羧酸的乙烯基酯，任选支链的C 1-15醇的（甲基）丙烯酸酯，二烯，烯烃，乙烯基芳烃和卤代乙烯。模制品具有优异的性能，包括在高温下的下垂阻力，并且是可回收的。

5. 发明授权

US06472462B1 Prebinding of fiber materials 失效
标题翻译：纤维材料的预结合
公开(公告)号：US06472462B1
公开(公告)日：2002-10-29
申请号：US09707649
申请日：2000-11-06
申请人： Klaus Kohlhammer , Abdulmajid Hashemzadeh , Claudia Schmidt
发明人： Klaus Kohlhammer , Abdulmajid Hashemzadeh , Claudia Schmidt
IPC分类号： C08K334
CPC分类号： D04H1/587 , D04H1/4218 , D04H1/4242 , D04H1/4334 , D04H1/60 , D06M15/227 , D06M15/233 , D06M15/263 , D06M15/273 , D06M15/333 , D06M15/55 , D06M23/08
摘要： This invention relates to a process for prebinding fiber materials by means of a pulverulent binder composition. It further relates to the use of the prebound fiber material for producing plastics moldings from fiber-reinforced unsaturated polyester resins or epoxy resins by laying up the prebound fiber material, saturating the fiber material with the unsaturated polyester resin or epoxy resin and forming the molding.
摘要翻译：本发明涉及通过粉状粘合剂组合物预分解纤维材料的方法。本发明还涉及通过铺设预引导纤维材料，用不饱和聚酯树脂或环氧树脂使纤维材料饱和并形成模制品，从纤维增强不饱和聚酯树脂或环氧树脂生产塑料模制品的用途。

6. 发明授权

US06231921B1 Use of polymer powder for producing ballistic-resistant fiber materials 失效
标题翻译：使用聚合物粉末生产防弹纤维材料
公开(公告)号：US06231921B1
公开(公告)日：2001-05-15
申请号：US09397631
申请日：1999-09-15
申请人： Abdulmajid Hashemzadeh , Klaus Kohlhammer
发明人： Abdulmajid Hashemzadeh , Klaus Kohlhammer
IPC分类号： B05D112
CPC分类号： B32B5/26 , B32B5/022 , B32B5/024 , B32B5/026 , B32B27/12 , B32B2262/0269 , B32B2262/101 , B32B2262/106 , B32B2571/02 , D06N3/0093 , D06N3/04 , F41H5/0471 , Y10T428/2933 , Y10T428/2938 , Y10T428/294 , Y10T428/296 , Y10T428/2962 , Y10T428/2964 , Y10T428/2969
摘要： The invention discloses a method of using crosslinkable polymer powders for producing ballistic-resistant fiber materials, which comprises consolidating the textile sheet materials by means of pulverulent crosslinkable copolymers which are based on ethylenically unsaturated monomers and have a glass transition temperature Tg or a melting point of ≧40° C. and a melt viscosity of ≧2000 mPas.
摘要翻译：本发明公开了一种使用可交联聚合物粉末生产防弹纤维材料的方法，该方法包括通过基于烯键式不饱和单体的粉状可交联共聚物固化纺织片材，并具有玻璃化转变温度Tg或熔点 > 40℃，熔体粘度> 2000mPa·s。

7. 发明授权

US6117960A Water-soluble cross-linkable copolymers 失效
标题翻译：水溶性交联共聚物
公开(公告)号：US6117960A
公开(公告)日：2000-09-12
申请号：US142399
申请日：1998-09-04
申请人： Klaus Kohlhammer , Gerhard Koegler , Peter Ball , Monika Rockinger , Walter Dobler
发明人： Klaus Kohlhammer , Gerhard Koegler , Peter Ball , Monika Rockinger , Walter Dobler
IPC分类号： C08F2/10 , C08F2/20 , C08F2/22 , C08F20/36 , C08F212/08 , C08F212/14 , C08F220/36 , C08F220/38 , C08F220/58 , C08F228/02 , C08J3/12 , C08L33/26 , C09D7/45 , C09D125/18 , C09D133/14 , C09D133/24 , C09D141/00 , C09J133/14 , C09J133/26 , D06M15/227 , D06M15/233 , D06M15/263 , D06M15/285 , D06M15/29 , D06M15/327 , D06M15/333 , D06M15/356 , D06N3/04 , D21H17/34 , D21H17/37 , D21H17/41 , D21H19/20 , C08L39/00 , C08L41/00
CPC分类号： D21H17/37 , C08F220/38 , C08F220/58 , C08J3/122 , D06M15/227 , D06M15/233 , D06M15/263 , D06M15/285 , D06M15/29 , D06M15/327 , D06M15/333 , D06M15/3566 , D06M7/00 , D06M2200/40
摘要： The invention concerns water-soluble cross-linkable copolymers having a molecular weight of .ltoreq.500000 and comprising a) between 20 and 95 wt. % sulphonic-acid- or sulphonate-group-containing monomer units; b) between 4 and 80 wt. % N-methylol- or N-alkoxymethyl-group containing monomer units; and c) between 0.1 and 20 wt. % hydrophobic monomer units selected from the group comprising water-insoluble ethylenically unsaturated compounds and hydrophobic end groups of initiator radicals or regulator molecules, the portions in wt. % being relative to the total weight of the copolymer. The portion of sulphonic-acid- or sulphonate-group-containing monomer units can optionally be substituted by up to 50 wt. %, relative to the portion by weight of monomer units a), by carboxyl-group-containing monomer units d) or amide-group-containing monomer units e).
摘要翻译： PCT No.PCT / EP97 / 01137 Sec。 371日期：1998年9月4日 102（e）1998年9月4日PCT 1997年3月6日PCT公布。出版物WO97 / 32911 日期1997年9月12日本发明涉及分子量为500000的水溶性可交联共聚物，其包含a）20至95重量％含磺酸基或磺酸基的单体单元; b）4至80wt。％的N-羟甲基或N-烷氧基甲基的单体单元; 和c）0.1-20wt。选自包含不溶于水的烯键式不饱和化合物和引发剂基团或调节剂分子的疏水端基的疏水性单体单元％。％相对于共聚物的总重量。含磺酸或磺酸基的单体单元的部分可以任选地被至多50wt。％，相对于单体单元a）的重量份，含羧基的单体单元d）或含酰胺基的单体单元e）。

8. 发明授权

US5474638A Method of using aqueous polymer dispersions as lamination adhesives for glossy films 失效
标题翻译：使用聚合物水分散体作为光泽膜的层压粘合剂的方法
公开(公告)号：US5474638A
公开(公告)日：1995-12-12
申请号：US201266
申请日：1994-02-24
申请人： Klaus Kohlhammer , Wilfried Huster , Walter Dobler
发明人： Klaus Kohlhammer , Wilfried Huster , Walter Dobler
IPC分类号： B32B27/00 , B32B7/12 , C08F28/00 , C08F220/10 , C08F220/12 , C08F220/26 , C08F220/28 , C08F228/02 , C08J5/12 , C09J133/04 , C09J133/06 , C09J133/08 , C09J129/02
CPC分类号： B32B7/12 , C09J133/06
摘要： The invention relates to a method of using aqueous polymer dispersions based on acrylate-methacrylate copolymers as lamination adhesives for heat sealed glossy films, where the aqueous polymer dispersions have a solids content of from 20 to 65% by weight, the copolymer has a glass transition temperature of from -35.degree. to -10.degree. C., a K value of from 40 to 100 and a mean particle size of less than 200 nm, and the copolymer is obtainable by free-radical emulsion polymerization of:a) from 50 to 80 parts by weight of one or more comonomers from the group consisting of alkyl acrylates of alcohols having 2 to 10 carbon atoms,b) from 10 to 25 parts by weight of one or more comonomers from the group consisting of alkyl methacrylates of alcohols having 1 to 10 carbon atoms, andc1) from 0 to 10 parts by weight of one or more vinyl-aromatic comonomers,c2) from 0.1 to 4.0 parts by weight of one or more .alpha.,.beta.-unsaturated, monoolefinic carboxylic acids,c3) from 0 to 4.0 parts by weight of one or more .alpha..beta.-unsaturated, monoolefinic carboxamides,c4) from 0 to 8 parts by weight of one or more comonomers from the group consisting of hydroxyalkyl (meth)acrylates made from esters of acrylic acid or methacrylic acid and diols having 2 to 10 carbon atoms, andc5) from 0.1 to 4.0 parts by weight of one or more .alpha..beta.-unsaturated, monoolefinic compounds containing sulfonyl or sulfonate groups.
摘要翻译：本发明涉及使用基于丙烯酸酯 - 甲基丙烯酸酯共聚物的水性聚合物分散体作为热密封光泽膜的层压粘合剂的方法，其中聚合物水分散体的固体含量为20-65重量％，该共聚物具有玻璃化转变温度为-35〜-10℃，K值为40〜100，平均粒径小于200nm，共聚物可通过自由基乳液聚合得到：a）从50〜 80重量份由具有2至10个碳原子的醇的丙烯酸烷基酯组成的组中的一种或多种共聚单体，b）10至25重量份的一种或多种共聚单体，其由具有1个至少10个碳原子，和c1）0至10重量份的一种或多种乙烯基芳族共聚单体，c2）0.1至4.0份重量的一种或多种α，β-不饱和单烯烃羧酸，c3） 0〜4.0份重量 t的一种或多种αβ-不饱和单烯烃甲酰胺，c4）0至8份重量的一种或多种由丙烯酸或甲基丙烯酸的酯和二醇制成的（甲基）丙烯酸羟烷基酯的共聚单体，其具有2 至10个碳原子，和c5）0.1至4.0重量份的一种或多种含有磺酰基或磺酸酯基团的α不饱和单烯烃化合物。

9. 发明授权

US5278225A Aqueous dispersions, containing aminooxy crosslinking agents, of copolymers containing carbonyl groups 失效
标题翻译：包含含有羰基的共聚物的含氨氧基交联剂的水分散体
公开(公告)号：US5278225A
公开(公告)日：1994-01-11
申请号：US865080
申请日：1992-04-08
申请人： Klaus Kohlhammer , Wilfried Huster , Wolfgang Deinhammer
发明人： Klaus Kohlhammer , Wilfried Huster , Wolfgang Deinhammer
IPC分类号： C08J3/03 , C08F8/30 , C08J3/24 , C08K5/32 , C08L57/00 , C08L101/00 , C08K5/24
CPC分类号： C08F8/30
摘要： The invention relates to aqueous dispersions containing aminooxy crosslinking agents, of copolymers containing carbonyl groups, to processes for the preparation thereof and to the use thereof as a crosslinking system in binders, adhesives and coating agents.
摘要翻译：本发明涉及含有氨氧基交联剂，含有羰基的共聚物的水分散体，其制备方法及其作为粘合剂，粘合剂和包衣剂中的交联体系的用途。

10. 发明申请

US20060264539A1 Use of polymers for starch modification 审中-公开
标题翻译：使用聚合物进行淀粉改性
公开(公告)号：US20060264539A1
公开(公告)日：2006-11-23
申请号：US10551109
申请日：2004-03-11
申请人： Henk Mosseveld , Konrad Wierer , Klaus Kohlhammer
发明人： Henk Mosseveld , Konrad Wierer , Klaus Kohlhammer
IPC分类号： D21H19/54
CPC分类号： C08L3/02 , C08L31/04 , C08L67/04 , C08L2666/04
摘要： Polymers stabilized by protective colloids and/or emulsifiers and consisting of at least one comonomer unit from the group consisting of vinyl esters of utinbranched or branched alkyl carboxylic acids containing between 1 and 18 C atoms, acrylic acid esters or methacrylic acid esters of branched or unbranched alcohols containing between 1 and 15 C atoms, dienes, olefins, vinyl aromates and vinyl halogenides, optionally containing between 0.1 and 20 wt. % more of functional comonomer units from the group comprising carboxyl-functional, hydroxyl-functional and NH-functional, ethylenically unsaturated comonomers, are useful as additives to moldable starch compositions.
摘要翻译：由保护胶体和/或乳化剂稳定并由至少一种共聚单体单元组成的聚合物，所述共聚单体单元由含有1至18个C原子的支链或支链烷基羧酸的乙烯基酯组成，分支或未分支的丙烯酸酯或甲基丙烯酸酯含有1至15个C原子的醇，二烯，烯烃，乙烯基芳烃和乙烯基卤化物，任选地含有0.1-20重量％来自包含羧基官能，羟基官能和NH官能的烯键式不饱和共聚单体的基团的更多的官能共聚单体单元可用作可成型淀粉组合物的添加剂。

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