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1. 发明授权

US5084487A Plastic compact or cellular moldings based on elastomers containing N-substituted urea and amide groups in bound form, and polyazomethine-containing polyoxyalkylene-polyamine mixtures 失效
标题翻译：基于含有N-取代的脲和氨基酸组合的弹性体的塑料紧密或细胞模型，以及含聚氨基甲酸酯的聚羟基亚甲基 - 多胺混合物
公开(公告)号：US5084487A
公开(公告)日：1992-01-28
申请号：US628299
申请日：1990-12-17
申请人： Johannes Becker , Guenther Matzke , Hans U. Schmidt , Willibald Schoenleben
发明人： Johannes Becker , Guenther Matzke , Hans U. Schmidt , Willibald Schoenleben
IPC分类号： C08J5/00 , C08G18/50 , C08G18/66 , C08G18/76 , C08G18/79 , C08G18/80 , C08J9/14
CPC分类号： C08G18/7671 , C08G18/503 , C08G18/6685 , C08G18/797 , C08G18/8035 , C08G2120/00
摘要： The invention relates to a process for the production of elastic, compact or cellular moldings based on elastomers containing N-substituted urea and amide groups in bound form, by reactinga) one or more organic and/or modified organic polyisocyanate withb) a polyazomethine-containing polyoxyalkylene-polyamine mixture (b) which contains:bi) one or more polyoxyalkylene-polyaldimine and/or polyketimine,bii) one or more polyoxyalkylene-polyamine containing terminal secondary amino groups, and, if desired,biii) one or more polyoxyalkylene-polyamine containing terminal primary amino groups andc) one or more alkyl-substituted aromatic polyamine having a molcular weight of up to 500, in the presence or absence ofd) catalyst, and, if appropriate,e) blowing agents,f) auxiliaries and/org) additives,to polyazomethine containing polyoxyalkylene - polyamine mixtures which can be used for this purpose and to the prepared elastomers.
摘要翻译：本发明涉及通过使a）一种或多种有机和/或改性的有机多异氰酸酯与b）多偶氮甲酰胺反应来生产基于含有结合形式的N-取代的脲和酰胺基的弹性体的弹性，紧密或多孔模制品的方法（b），其包含：bi）一种或多种聚氧化烯 - 聚醛亚胺和/或聚酮亚胺，bii）一种或多种含聚氧亚烷基 - 多胺的末端仲氨基，并且如果需要，biii）一种或多种聚氧化烯 - 含有末端伯氨基的多胺和c）在存在或不存在d）催化剂的情况下，一种或多种具有至多500摩尔重量的烷基取代的芳族多胺，以及如果合适的话，e）发泡剂，f）助剂和/或g）添加剂，可以用于可用于该目的的聚氧亚烷基 - 多胺混合物和制备的弹性体。

2. 发明授权

US3974159A Manufacture of derivatives of malondialdehyde 失效
标题翻译：丙二醛衍生物的制造
公开(公告)号：US3974159A
公开(公告)日：1976-08-10
申请号：US572135
申请日：1975-04-28
申请人： Martin Decker , Willibald Schoenleben , Herbert Toussaint , Hewig Hoffmann
发明人： Martin Decker , Willibald Schoenleben , Herbert Toussaint , Hewig Hoffmann
IPC分类号： C07C251/30 , C07C67/00 , C07C241/00 , C07D239/42 , C07C119/00 , C07C131/00
CPC分类号： C07D239/42
摘要： Compounds of the general formula ##EQU1## which may be used in place of malondialdehyde in synthesis reactions are obtained in a one-step reaction form dimethylformamide, phosgene and an alkyl vinyl ether.
摘要翻译：在合成反应中可以用来代替丙二醛的通式为+ CH3 R1O-HC-CH-CH = N ANGLE Cl - ，|| CH3 ClR2的化合物是以一步反应形式的二甲基甲酰胺，光气和烷基乙烯基醚。

3. 发明授权

US5153235A Production of elastic, compact or cellular moldings based on elastomers containing N-benzylurea groups in bound form, elastomers of this type, and N-benzylpolyoxyalkylene-polyamines which are suitable for this purpose 失效
标题翻译：基于含有结合形式的N-苄基脲的弹性体，这种类型的弹性体和适用于该目的的N-苄基聚氧化烯 - 多胺的弹性，致密或细胞模塑制品
公开(公告)号：US5153235A
公开(公告)日：1992-10-06
申请号：US824976
申请日：1992-01-24
申请人： Johannes Becker , Guenther Matzke , Hans U. Schmidt , Willibald Schoenleben
发明人： Johannes Becker , Guenther Matzke , Hans U. Schmidt , Willibald Schoenleben
IPC分类号： C08G18/10 , C08G18/50 , C08G18/66 , C08G18/76 , C08G18/79 , C08G18/80 , C08G65/331 , C08G65/338
CPC分类号： C08G65/338 , C08G18/10 , C08G18/5024 , C08G18/6685 , C08G18/7671 , C08G18/797 , C08G18/8035 , C08G65/331 , C08G2101/0008 , C08G2120/00
摘要： The present invention relates to a process for the production of elastic, compact or cellular moldings based on elastomers containing N-benzylurea groups in bound form, by reactinga) one or more organic and/or modified organic polyisocyanates withb) N-benzylpolyoxyalkylene-polyamines or mixtures of N-benzylpolyoxyalkylene-polyamines and polyoxyalkylene-polyamines containing from 2 to 4 primary amino groups andc) one or more alkyl-substituted aromatic polyamines having a molecular weight of up to 500,in the presence or absence ofd) catalystsand, if desired,e) blowing agents,f) auxiliaries and/org) additives,and to the N-benzylpolyoxyalkylene-polyamines and mixtures of N-benzylpolyoxyalkylene-polyamines and polyoxyalkylene-polyamines containing from 2 to 4 primary amino groups which can be used for this purpose, and to the elastomers prepared.
摘要翻译：本发明涉及一种通过使a）一种或多种有机和/或改性的有机多异氰酸酯与b）N-苄基聚氧化烯 - 甲基丙烯酸酯反应生产基于含有结合形式的N-苄基脲的弹性体的弹性，紧密或多孔模塑制品的方法，多胺或N-苄基聚氧化烯 - 多胺和含有2至4个伯氨基的聚氧化烯 - 多胺的混合物，以及c）一种或多种分子量高达500的烷基取代的芳族多胺，在d）催化剂存在或不存在的情况下并且如果需要，e）发泡剂，f）助剂和/或g）添加剂，以及N-苄基聚氧化烯 - 多胺和N-苄基聚氧化烯 - 多胺和含有2-4个伯氨基的聚氧化烯 - 多胺的混合物，其可以用于此目的，并用于制备的弹性体。

4. 发明授权

US4851580A Preparation of trialkylamines 失效
标题翻译：三烷基胺的制备
公开(公告)号：US4851580A
公开(公告)日：1989-07-25
申请号：US925234
申请日：1986-10-31
申请人： Herbert Mueller , Roman Fischer , Gerhard Jeschek , Willibald Schoenleben
发明人： Herbert Mueller , Roman Fischer , Gerhard Jeschek , Willibald Schoenleben
IPC分类号： C07B61/00 , B01J23/00 , B01J23/72 , B01J23/78 , C07C67/00 , C07C209/00 , C07C209/14 , C07C209/16 , C07C211/03 , C07C211/05 , C07C211/08
CPC分类号： C07C209/16
摘要： A process for the preparation of tertiary alkylamines having a total of up to 9 carbon atoms by reacting a dialkylamine with a C.sub.2 -C.sub.4 -alcohol in the presence of a hydrogenation/dehydrogenation catalyst which contains essentially only copper as the hydrogenating/dehydrogenating catalytic metal is proposed, wherein the reactants(a) are present in the liquid phase,(b) contain alkali metal and/or alkaline earth metal oxides and/or hydroxides and(c) are reacted in a molar ratio of dimethylamine to alcohol of from 1:10 to 10:1 and(d) in the presence of the water formed during the reaction.
摘要翻译：在氢化/脱氢催化剂存在下，通过使二烷基胺与C 2 -C 4醇反应来制备总共多达9个碳原子的叔烷基胺的方法，其基本上仅含有铜作为氢化/脱氢催化金属，提出，其中反应物（a）存在于液相中，（b）含有碱金属和/或碱土金属氧化物和/或氢氧化物，和（c）以二甲胺与醇的摩尔比1： 10至10：1和（d）在反应期间形成的水的存在下。

5. 发明授权

US5122547A Production of elastic, compact or cellular moldings based on elastomers containing N-benzylurea groups in bound form, elastomers of this type, and N-benzylpolyoxyalkylene-polyamines which are suitable for this purpose 失效
标题翻译：生产弹性，紧凑型或细密模型的弹性体，其包含在本体中的N-苄氧基组合的弹性体，该类型的弹性体和适用于本发明目的的N-苯甲酰基聚甲基丙烯酰胺
公开(公告)号：US5122547A
公开(公告)日：1992-06-16
申请号：US628298
申请日：1990-12-17
申请人： Johannes Becker , Guenther Matzke , Hans U. Schmidt , Willibald Schoenleben
发明人： Johannes Becker , Guenther Matzke , Hans U. Schmidt , Willibald Schoenleben
IPC分类号： C08J9/14 , C08G18/10 , C08G18/30 , C08G18/50 , C08G18/66 , C08G18/76 , C08G18/79 , C08G18/80 , C08G65/32 , C08G65/331 , C08G65/338
CPC分类号： C08G65/338 , C08G18/10 , C08G18/5024 , C08G18/6685 , C08G18/7671 , C08G18/797 , C08G18/8035 , C08G65/331 , C08G2101/0008 , C08G2120/00
摘要： The present invention relates to a process for the production of elastic, compact or cellular moldings based on elastomers containing N-benzylurea groups in bound form, by reactinga) one or more organic and/or modified organic polyisocyanates withb) N-benzylpolyoxyalkylene-polyamines or mixtures of N-benzylpolyoxyalkylene-polyamines and polyoxyalkylene-polyamines containing from 2 to 4 primary amino groups andc) one or more alkyl-substituted aromatic polyamines having a molecular weight of up to 500,in the presence or absence ofd) catalystsand, if desired,e) blowing agents,f) auxiliaries and/org) additives,and to the N-benzylpolyoxyalkylene-polyamines and mixtures of N-benzylpolyoxyalkylene-polyamines and polyoxyalkylene-polyamines containing from 2 to 4 primary amino groups which can be used for this purpose, and to the elastomers prepared.
摘要翻译：本发明涉及一种通过使a）一种或多种有机和/或改性的有机多异氰酸酯与b）N-苄基聚氧化烯 - 甲基丙烯酸酯反应生产基于含有结合形式的N-苄基脲的弹性体的弹性，紧密或多孔模塑制品的方法，多胺或N-苄基聚氧化烯 - 多胺和含有2至4个伯氨基的聚氧化烯 - 多胺的混合物，以及c）一种或多种分子量高达500的烷基取代的芳族多胺，在d）催化剂存在或不存在的情况下并且如果需要，e）发泡剂，f）助剂和/或g）添加剂，以及N-苄基聚氧化烯 - 多胺和N-苄基聚氧化烯 - 多胺和含有2-4个伯氨基的聚氧化烯 - 多胺的混合物，其可以用于此目的，并用于制备的弹性体。

6. 发明授权

US5009805A Liquid detergent with copolymer additive 失效
标题翻译：液体洗涤剂与共聚添加剂
公开(公告)号：US5009805A
公开(公告)日：1991-04-23
申请号：US424084
申请日：1989-10-19
申请人： Johannes Perner , Paul Diessel , Heinrich Hartmann , Walter Denzinger , Alfred Oftring , Willibald Schoenleben
发明人： Johannes Perner , Paul Diessel , Heinrich Hartmann , Walter Denzinger , Alfred Oftring , Willibald Schoenleben
IPC分类号： C11D3/32 , C11D3/37
CPC分类号： C11D3/3773
摘要： Liquid detergent formulations contain as essential constituents a surfactant and 0.1-20% by weight of a copolymer which contains(a) 50-99 mol % of units of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, a half ester of a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, an ester of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a C.sub.2 -C.sub.30 -olefin, styrene, a C.sub.1 -C.sub.3 -alkylstyrene, a C.sub.1 -C.sub.28 -alkyl vinyl ether, a vinyl ester of a saturated C.sub.1 -C.sub.8 -monocarboxylic acid or a mixture thereof and(b) 50-1 mol % of units of an amide of a monoethylenically unsaturated C.sub.3 -C.sub.8 -carboxylic acid where the amide groups have the structure ##STR1## where R.sup.1 is C.sub.8 -C.sub.28 -alkyl or preferably ##STR2## R.sup.3 and R.sup.4 are each H, CH.sub.3 or C.sub.2 H.sub.5, R is C.sub.1 -C.sub.28 -alkyl,n is from 2 to 100 andR.sup.2 is H or R.sup.1,and has a K value of from 8 to 200, or a salt thereof.
摘要翻译：液体洗涤剂配方含有表面活性剂和0.1-20重量％的共聚物，其含有（a）50-99摩尔％的单烯属不饱和C3-C8-单羧酸单元，单烯属不饱和C4-C8-二羧酸酸，单烯键式不饱和C4-C8-二羧酸的半酯，单烯属不饱和C3-C8-一元羧酸的酯，C2-C30-烯烃，苯乙烯，C1-C3-烷基苯乙烯，C1-C28- 烷基乙烯基醚，饱和C1-C8-一元羧酸的乙烯基酯或其混合物，和（b）50-1摩尔％的单烯属不饱和C 3 -C 8 - 羧酸的酰胺单元，其中酰胺基具有其中R 1为C 8 -C 28 - 烷基或优选R 3和R 4各自为H，CH 3或C 2 H 5，R为C 1 -C 28 - 烷基，n为2至100，R 2为H或R 1，并且的K值为8〜200，或其盐。

7. 发明授权

US3691205A Production of 6-alkoxy-5,6-dihydro-4h-pyrans 失效
标题翻译： 6-烷基-5,6-二氢-4H-吡啶的生产
公开(公告)号：US3691205A
公开(公告)日：1972-09-12
申请号：US3691205D
申请日：1971-02-09
申请人： HERWIG HOFFMANN , GERHARD JESCHEK , ALFRED KUERZINGER , ERWIN SCHMIDT , WILLIBALD SCHOENLEBEN , DIETER VOGES , SIEGFRIED WINDERL
发明人： HOFFMANN HERWIG , JESCHEK GERHARD , KUERZINGER ALFRED , SCHMIDT ERWIN , SCHOENLEBEN WILLIBALD , VOGES DIETER , WINDERL SIEGFRIED
IPC分类号： C07D309/30 , C07D7/10
CPC分类号： C07D309/30
摘要： A process for the production of 6-alkoxy-5,6-dihydro-4H-pyrans by reaction of Alpha , Beta -unsaturated aldehydes with vinyl ethers. The products are valuable intermediates, for example for the production of glutaraldehyde or substituted glutaraldehydes which may be used for example as tanning agents for leather.

8. 发明授权

US5112364A Gasoline-engine fuels containing polyetheramines or polyetheramine derivatives 失效
标题翻译：含有聚乙烯胺或聚乙烯胺衍生物的汽油发动机燃料
公开(公告)号：US5112364A
公开(公告)日：1992-05-12
申请号：US697529
申请日：1991-04-29
申请人： Hans P. Rath , Helmut Mach , Knut Oppenlaender , Willibald Schoenleben , Hans-Henning Vogel
发明人： Hans P. Rath , Helmut Mach , Knut Oppenlaender , Willibald Schoenleben , Hans-Henning Vogel
IPC分类号： C07C217/50 , C08G65/26 , C08G65/322 , C08G65/325 , C10L1/238 , C10L1/2383 , F02B1/04
CPC分类号： C10L1/238 , C07C217/50 , C08G65/2612 , C08G65/322 , C08G65/3255 , C10L1/2383 , F02B1/04
摘要： Gasolines containing polyetheramine and/or polyetheramine derivatives to improve valve cleaning properties.
摘要翻译：含有聚醚胺和/或聚醚胺衍生物的汽油提高阀清洗性能。

9. 发明授权

US4973761A Aminomono- or -di-[(poly-n-butoxy)-n-butylamino]-(poly-n-butoxy)-n-butylamines 失效
标题翻译：氨基单或 - 二 - [（聚正丁氧基） - 正丁氨基] - （聚正丁氧基） - 正丁胺
公开(公告)号：US4973761A
公开(公告)日：1990-11-27
申请号：US382906
申请日：1989-07-21
申请人： Willibald Schoenleben , Herbert Mueller
发明人： Willibald Schoenleben , Herbert Mueller
IPC分类号： B01J23/755 , C07B61/00 , C07C213/02 , C07C217/08 , C08G65/32 , C08G65/322 , C08G65/325 , C08L63/00
CPC分类号： C08G65/3255 , C08G65/322 , C08L63/00 , Y02P20/582
摘要： Aminomono- or di-[(poly-n-butoxy)-n-butylamino]-(poly-n-butoxy)-n-butylamines of the general formula IH.sub.2 N--[(CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --(CH.sub.2).sub.4 --NH].sub.y --(CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --(CH.sub.2).sub.4 --NH.sub.2 (I)where x is from 1 to 150 and y is 1 or 2, are prepared by a process in which a hydroxy-(poly-n-butoxy)-butanol of the formula IIHO--(CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 O).sub.x --(CH.sub.2).sub.4 --OH (II)where x is from 1 to 150, is reacted with from 1.01 to 300 mole equivalents of ammonia per hydroxyl group in the presence of a hydrogenation/dehydrogenation catalyst and hydrogen at from 150.degree. to 300.degree. C. and under from 20 to 400 bar.
摘要翻译：通式为H 2 N - [（CH 2 CH 2 CH 2 CH 2 O）x - （CH 2）4 -NH]的氨基 - 或二 - [（聚正丁氧基） - 正丁氨基] - （聚正丁氧基）其中x为1至150且y为1或2的Y-（CH 2 CH 2 CH 2 CH 2 O）x - （CH 2）4 -NH 2（I）通过其中羟基 - （聚正丁氧基）在加氢/脱氢催化剂存在下，其中x为1至150的式II HO-（CH 2 CH 2 CH 2 CH 2 O）x - （CH 2）4 -OH（II）与每个羟基1.01至300摩尔当量的氨反应和150至300℃的氢气和20至400巴的氢气。

10. 发明授权

US4897480A Preparation of N,N'-dialkyl substituted cyclic urea derivatives 失效
标题翻译： N，N'-二烷基取代的环状脲衍生物的制备
公开(公告)号：US4897480A
公开(公告)日：1990-01-30
申请号：US284245
申请日：1988-12-14
申请人： Willibald Schoenleben
发明人： Willibald Schoenleben
IPC分类号： C07D233/34 , B01J21/04 , B01J21/12 , C07B61/00 , C07D233/32 , C07D239/10 , C07D247/02
CPC分类号： C07D239/10 , C07D233/32 , C07D247/02
摘要： N,N'-dialkyl-substituted cyclic urea derivatives of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each alkyl of 1 to 8 carbon atoms and A is CR.sup.3 R.sup.4 -CR.sup.5 R.sup.6 - or CR.sup.3 R.sup.4 -CR.sup.5 R.sup.6 -CR.sup.7 R.sup.8, where R.sup.3 to R.sup.8 are each hydrogen or alkyl of 1 to 17 carbon atoms, are prepared by reacting a diamine of the formula II ##STR2## with carbon dioxide, by a method in which the reaction is carried out in the gas phase in the presence of an oxide of an element of main group three or four or subgroup two to six of the Periodic Table, or a mixture of these, or in the presence of an aluminum silicate or magnesium silicate.1,3,4-trimethyl-2-imidazolidinone is used as a polar solvent at low temperatures.
摘要翻译： N，N'-二烷基取代的通式I（I）的环脲衍生物，其中R 1和R 2各自是1至8个碳原子的烷基，A是CR 3 R 4 -CR 5 R 6 - 或CR 3 R 4 -CR 5 R 6 -CR 7 R 8，其中 R 3至R 8各自为氢或具有1至17个碳原子的烷基，其通过使式II（II）的二胺与二氧化碳反应的方法通过使反应在气相中进行的方法主要组分的元素的氧化物存在于元素周期表中主要为三或四元或二至六至六元的元素，或其混合物，或在硅酸铝或硅酸镁存在下。 1,3,4-三甲基-2-咪唑啉酮在低温下用作极性溶剂。

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