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1. 发明申请

US20120305071A1 SUBSTRATE HAVING A METAL FILM FOR PRODUCING PHOTOVOLTAIC CELLS 审中-公开
标题翻译：具有用于生产光伏电池的金属膜的基底
公开(公告)号：US20120305071A1
公开(公告)日：2012-12-06
申请号：US13511619
申请日：2010-11-02
申请人： Andreas Afseth , Volkmar Gillich , Josef Statti , Ralf Platte , Stephane Antoine
发明人： Andreas Afseth , Volkmar Gillich , Josef Statti , Ralf Platte , Stephane Antoine
IPC分类号： B32B3/26 , H01L31/0216
CPC分类号： H01L31/0392 , H01L31/0322 , H01L31/03928 , H01L31/0749 , Y02E10/541 , Y02P70/521 , Y10T428/24364 , Y10T428/24999
摘要： The invention relates to a substrate (10) having a metal film (12) for producing photovolatic cells (30), wherein a first side of the metal film (12) is intended for arranging a photovoltaic absorber layer (18). In order to improve the chemical resistance and the corrosion resistance at elevated temperature, a protective layer (16) made of a silicon-based sol-gel paint is arranged on the second side of the metal film (12).
摘要翻译：本发明涉及具有用于制造光电池（30）的金属膜（12）的基板（10），其中金属膜（12）的第一侧用于布置光伏吸收层（18）。为了提高高温下的耐化学性和耐腐蚀性，在金属膜（12）的第二面上配置由硅系溶胶 - 凝胶涂料构成的保护层（16）。

2. 发明申请

US20080008833A1 Method for Production of Formed Aluminium Metal Parts with Decorative Surface 失效
标题翻译：具有装饰面的成形铝金属零件的生产方法
公开(公告)号：US20080008833A1
公开(公告)日：2008-01-10
申请号：US11660773
申请日：2004-09-08
申请人： Walter Hotz , Volkmar Gillich , Roman Fuchs
发明人： Walter Hotz , Volkmar Gillich , Roman Fuchs
IPC分类号： B05D7/00 , B05D3/00 , B05D7/14
CPC分类号： B05D7/16 , B05D7/546 , B05D2202/25 , B05D2252/02 , B05D2701/00
摘要： A method for producing weather- and corrosion-resistant shaped sheets consisting of aluminum or an aluminum alloy with a decorative finish in a coil coating process that comprises the following sequential steps: an aluminum strip or aluminum alloy strip is provided; optional continuous degreasing of the strip; optional electrochemical, chemical or mechanical burnishing of the optionally degreased strip; the optionally degreased and/or burnished strip is continuously pre-treated to create a pre-treated layer that is suitable for use as an adhesive base for a paint layer; the optionally degreased strip is continuously pre-treated to create a strip surface that is suitable for use as an adhesive base for a paint layer; the pre-treated strip is continuously painted with a sol-gel paint consisting of a polysiloxane to create a first protect protective layer; the first protective layer is continuously dried and cured in a continuous furnace; the sheets are produced by shaping the strip that comprises the first protective layer and cutting the sheets that are optionally to be further shaped, or by cutting the sheets out of the strip that comprises the first protective layer and shaping the cut sheets; the shaped sheets are painted with a sol-gel paint consisting of a polysiloxane to create a second protective layer and the second protective layer is dried and cured in a furnace. The shaped parts that are produced by the method are characterized by excellent weather- corrosion- and abrasion resistance.
摘要翻译：一种用于在线圈涂覆工艺中由铝或铝合金制成的具有装饰漆的耐候性和耐腐蚀成形片材的方法，其包括以下顺序步骤：提供铝条或铝合金带; 可选连续脱脂条; 任选脱脂条带的电化学，化学或机械抛光; 任选脱脂和/或抛光的条带被连续地预处理以产生适合用作涂料层的粘合剂基底的预处理层; 任选脱脂条带被连续预处理以产生适于用作涂料层的粘合剂基底的条带表面; 使用由聚硅氧烷组成的溶胶 - 凝胶涂料连续涂覆预处理的带材以产生第一保护保护层; 第一保护层在连续炉中连续干燥和固化; 通过使包括第一保护层的条切割并切割可选地进一步成形的片材，或者通过将片材从包括第一保护层的条状物切割并且对切割片材成形来制造片材; 用由聚硅氧烷组成的溶胶 - 凝胶涂料成型片材以产生第二保护层，并且第二保护层在炉中干燥和固化。通过该方法制造的成形部件的特征在于优异的耐候性和耐磨性。

3. 发明授权

US06709119B2 Resistant surface reflector 有权
标题翻译：抗反射面
公开(公告)号：US06709119B2
公开(公告)日：2004-03-23
申请号：US10231155
申请日：2002-08-30
申请人： Volkmar Gillich , Renato Kirin , Roman Fuchs
发明人： Volkmar Gillich , Renato Kirin , Roman Fuchs
IPC分类号： G02B508
CPC分类号： G02B5/0866 , G02B1/105 , G02B1/111 , G02B1/14 , G02B5/08 , G02B5/0858
摘要： A reflector with high total reflection which is resistant to mechanical stresses. The reflector includes a reflector body and superimposed thereon (a) a functional coating such as a varnish, (b) a reflecting layer structure composed of a reflecting metallic layer and optionally arranged thereon one or several transparent ceramic layers, for example, layers having an optical depth of &lgr;/2. The reflecting layer structure contains, as its surface layer, a protective layer. The protective layer is a silicon oxide of general formula SiOx, wherein x is a number from 1.1 to 2.0, or it is aluminum oxide of formula Al2O3, in a thickness of 3 nm or more. The protective layer protects the underlying layers from mechanical damages. In the DIN 58196 abrasion test the protected surface does not show any damages after 50 test cycles with 100 abrasion strokes.
摘要翻译：具有高机械应力抗反射能力的反射器。反射器包括反射体，并叠置在其上（a）诸如清漆的功能涂层，（b）由反射金属层构成的反射层结构，并且可选地在其上布置有一个或多个透明陶瓷层，例如具有 λ/ 2的光学深度。反射层结构包含作为其表面层的保护层。保护层是通式为SiO x的氧化硅，其中x为1.1〜2.0的数，或者为Al 2 O 3的氧化铝，厚度为3nm以上。保护层保护下层免受机械损坏。在DIN 58196磨损试验中，经过100次磨损行程的50次试验循环后，受保护的表面不会发生任何损坏。

4. 发明授权

US06848797B1 Reflector with a resistant surface 有权
标题翻译：反光板带有耐磨面
公开(公告)号：US06848797B1
公开(公告)日：2005-02-01
申请号：US09830410
申请日：1998-11-12
申请人： Volkmar Gillich , Renato Kirin , Roman Fuchs
发明人： Volkmar Gillich , Renato Kirin , Roman Fuchs
IPC分类号： F21V7/22 , G02B5/08 , G02B1/10
CPC分类号： G02B5/0858 , F21V7/22
摘要： A reflector with high total reflection which is resistant to mechanical stresses. The reflector comprises a reflector body and superimposed thereon (a) a functional coating such as a varnish, (b) a reflecting layer structure composed of a reflecting metallic layer and optionally arranged thereon one or several transparent ceramic layers, for example, layers having an optical depth of λ/2. The reflecting layer structure contains, as its surface layer, a protective layer. The protective layer is a silicon oxide of general formula SiOx, wherein x is a number from 1.1 to 2.0, or it is aluminum oxide of formula Al2O3, in a thickness of 3 nm or more. The protective layer protects the underlying layers from mechanical damages. In the DIN 58196 abrasion test the protected surface does not show any damages after 50 test cycles with 100 abrasion strokes.
摘要翻译：具有高机械应力抗反射能力的反射器。反射器包括反射体，并叠置在其上（a）诸如清漆的功能涂层，（b）由反射金属层构成的反射层结构，并且可选地在其上布置有一个或多个透明陶瓷层，例如具有 λ/ 2的光学深度。反射层结构包含作为其表面层的保护层。保护层是通式为SiO x的氧化硅，其中x为1.1〜2.0的数，或者为Al 2 O 3的氧化铝，厚度为3nm以上。保护层保护下层免受机械损坏。在DIN 58196磨损试验中，经过100次磨损行程的50次试验循环后，受保护的表面不会发生任何损坏。

5. 发明授权

US5904989A Aluminum surface with interference colors 失效
标题翻译：铝表面具有干涉色
公开(公告)号：US5904989A
公开(公告)日：1999-05-18
申请号：US832295
申请日：1997-04-03
申请人： Paul Hanggi , Walter Hotz , Roman Fuchs , Volkmar Gillich
发明人： Paul Hanggi , Walter Hotz , Roman Fuchs , Volkmar Gillich
IPC分类号： C25D11/04 , C25D11/18 , B32B15/04
CPC分类号： C25D11/04 , C25D11/18 , Y10T428/31678
摘要： Interference layer which acts as a coloring surface layer on aluminum items, said layer containing an aluminum oxide layer and, deposited on this, a partially transparent layer. The aluminum oxide layer is a transparent, pore-free barrier layer produced by anodizing, of predetermined thickness d corresponding to the desired surface color of the interference layer; the thickness d of the barrier layer lies between 20 and 900 nm, and the partially transparent layer exhibits a wavelength dependent transmission .tau.(.lambda.) which is greater than 0.01 and smaller than 1. The side of the partially transparent layer facing away from the barrier layer is preferably protected from mechanical and chemical effects by an additional, transparent protective layer.
摘要翻译：作为铝物品上的着色表面层的干涉层，所述层含有氧化铝层，并在其上沉积有部分透明的层。氧化铝层是通过对与干涉层的期望表面颜色相对应的预定厚度d的阳极氧化而产生的透明的无孔阻挡层; 阻挡层的厚度d位于20和900nm之间，并且部分透明层表现出大于0.01且小于1的波长相关传输tau（λ）。部分透明层的背离屏障的一侧优选通过附加的透明保护层来保护层免受机械和化学作用。

6. 发明授权

US5582863A Process for forming a reflective surface 失效
标题翻译：用于形成反射表面的工艺
公开(公告)号：US5582863A
公开(公告)日：1996-12-10
申请号：US351719
申请日：1994-12-08
申请人： Marcus Textor , Roman Fuchs , Volkmar Gillich , Erich Simon
发明人： Marcus Textor , Roman Fuchs , Volkmar Gillich , Erich Simon
IPC分类号： B21B3/00 , C22C21/12 , C22F1/04 , C23C14/00 , C23C14/02 , C23C14/06 , C23C16/00 , C23C16/02 , G02B1/10 , B05D5/06
CPC分类号： C23C16/0254 , C22F1/04 , C23C14/021 , C23C14/028 , G02B1/105 , G02B5/0808 , G02B5/0858 , Y10T428/24975 , Y10T428/265 , Y10T428/31678
摘要： A process for forming a reflective surface, comprises the steps of: providing at least a part of at least one unanodized surface which has a peak-to-valley height Ra of equal to or less than 1 micron. The unanodized surface is selected from the group consisting of (1) refined aluminum with a degree of purity equal to or greater than 98.3% by weight aluminum and (2) aluminum alloys with at least one element selected from the group consisting of Si, Mg, Mn, Cu, Zn, Fe. The unanodized surface is in a form selected from the group consisting of rolled foil, rolled sheets, and rolled strips and said unanodized surface is used as a substrate. The process further includes depositing at least two layers from the gas phase on the unanodized surface, wherein the two layers include a ceramic adhesive layer from the gas phase and at least one reflecting layer from the gas phase on said adhesive layer for the reflection of radiation with wavelengths in the optical range. The reflecting layer is selected from the group consisting of aluminum, silver, gold, copper and alloys containing at least one of aluminum, silver, gold and copper.
摘要翻译：一种用于形成反射表面的方法，包括以下步骤：提供具有等于或小于1微米的峰 - 谷高度Ra的至少一个未阳光化表面的至少一部分。未阳极化表面选自（1）纯度等于或大于98.3重量％的铝的精制铝和（2）具有选自Si，Mg中的至少一种元素的铝合金，Mn，Cu，Zn，Fe。未标记的表面是选自轧制箔，轧制板和轧制带的形式，并且所述未阳模化表面用作基板。该方法还包括在未阳光化表面上从气相沉积至少两层，其中两层包括来自气相的陶瓷粘合剂层和在所述粘合剂层上的来自气相的至少一个反射层，用于反射辐射波长在光学范围内。反射层选自铝，银，金，铜和含有铝，银，金和铜中的至少一种的合金。

7. 发明授权

US5760981A Aluminum reflector with a composite reflectivity-enhancing surface layer 失效
标题翻译：具有复合反射增强表面层的铝反射器
公开(公告)号：US5760981A
公开(公告)日：1998-06-02
申请号：US701313
申请日：1996-08-21
申请人： Volkmar Gillich
发明人： Volkmar Gillich
IPC分类号： G02B5/08 , B32B7/02 , B32B9/00 , C03C17/36 , C25D11/04 , F21V7/22 , G02B1/10 , C23C28/00
CPC分类号： C03C17/36 , C03C17/3615 , C03C17/3649 , C03C17/3689 , G02B5/0833 , G02B5/0858 , C03C2217/734
摘要： Reflector having a composite reflectivity enhancing layer as reflecting surface layer on a reflector body where the said composite has a sandwich structure with an aluminum layer facing the reflector body, an outer layer, the HI-layer, with a refractive index n.sub.2 facing the radiation to be reflected, and an intermediate aluminum oxide layer, the LI-layer, with a refractive index n.sub.1 which is smaller than n.sub.2. The LI-layer is a transparent and pore-free barrier layer produced by anodic oxidation of the aluminum layer and having a dielectric constant .epsilon..sub.1 of 6 to 10.5 at 20.degree. C. and the optical layer thickness d.sub.opt.1 of the LI-layer and d.sub.opt.2 of the HI-layer are such that d.sub.opt,i =d.sub.i.n.sub.i =l.sub.i..lambda./4.+-.10 nm, i=1, 2 where d.sub.1 represents the thickness of the LI-layer in nm, d.sub.2 the thickness of the HI-layer in nm, .lambda. the average wave length in nm of the light striking the reflector surface and l.sub.1, l.sub.2, uneven natural numbers. The reflectors are particularly suitable as reflectors for infrared radiation or for lamps for technical lighting purposes, especially for daylight lighting purposes.
摘要翻译：反射器具有复合反射增强层作为反射体层上的反射表面层，其中所述复合体具有铝层对准反射体的夹层结构，外层为HI层，折射率n2面向辐射至被反射，中间氧化铝层LI层，折射率n1小于n2。 LI层是通过铝层的阳极氧化产生的透明且无孔的阻挡层，其在20℃下的介电常数ε1为6至10.5，并且LI层的光学层厚度dopt.1 并且HI层的dopt.2使得dopt，i = di.ni = li。 λ/ 4 +/- 10nm，i = 1,2，其中d1表示LI层的厚度，以nm为单位，d2为HI层的厚度，以nm为单位，λ为入射到其中的光的平均波长反射面和l1，l2，自然数不均匀。反射器特别适用于红外辐射的反射器或用于技术照明目的的灯，特别是用于日光照明目的。

8. 发明授权

US07182475B2 Reflector 有权
标题翻译：反射器
公开(公告)号：US07182475B2
公开(公告)日：2007-02-27
申请号：US10275264
申请日：2001-04-27
申请人： Tomas Kramer , Volkmar Gillich , Roman Fuchs
发明人： Tomas Kramer , Volkmar Gillich , Roman Fuchs
IPC分类号： G02B5/124
CPC分类号： G02B5/0858 , F21S41/37 , F21V7/22 , G02B1/105 , G02B1/14 , G02B5/0808 , H01L31/02327 , H01L31/0547 , Y02E10/52
摘要： A weather and corrosion-resistant reflector with high overall reflection in the visible and infrared wavelength ranges. The reflector contains a reflector body with a reflection surface of an aluminum or aluminum alloy or a reflector body with a reflection coating of an aluminum or aluminum alloy. The reflector also contains an outer, final transparent protective layer of a sol-gel coating which is thicker than 1 μm. The transparent sol-gel coating is a polymer of cross-linked inorganic siloxanes with alcohol groups that are bonded to the silicon with a carbon bond. The sol-gel coating is produced in a sol-gel process and, after having been applied to the reflector body, is dried and hardened using heat. The protective layer has excellent resistance to weather, corrosion and abrasion.
摘要翻译：耐候和耐腐蚀的反射器，在可见光和红外波长范围内具有高整体反射。反射器包括具有铝或铝合金的反射表面的反射体，或具有铝或铝合金反射涂层的反射体。反射器还包含比1um厚的溶胶 - 凝胶涂层的外部最终的透明保护层。透明溶胶 - 凝胶涂层是具有与碳键结合到硅上的醇基的交联无机硅氧烷的聚合物。溶胶 - 凝胶涂层以溶胶 - 凝胶法生产，并且在涂布到反射体之后，用热量干燥和硬化。保护层具有优异的耐候性，耐腐蚀性和耐磨性。

9. 发明授权

US06670045B1 Reflector with a resistant surface 有权
标题翻译：反光板带有耐磨面
公开(公告)号：US06670045B1
公开(公告)日：2003-12-30
申请号：US09554165
申请日：2000-05-10
申请人： Volkmar Gillich , Renato Kirin , Roman Fuchs
发明人： Volkmar Gillich , Renato Kirin , Roman Fuchs
IPC分类号： B32B1504
CPC分类号： G02B5/0833 , G02B1/105 , G02B1/14 , Y10T428/12736 , Y10T428/12764 , Y10T428/31681
摘要： A reflector, with high total reflection, resisting mechanical stress, and having a reflector body on which the following components are superimposed (a) a functional coating, e.g., a varnish, (b) a reflection layer structure composed of a reflecting metallic layer and, optionally, one or more transparent ceramic layers, having for instance an optical depth of &lgr;/2, applied on the top of the metallic layer. The reflection layer structure is a protection layer as a surface layer. The protection layer is a silicon oxide of general formula SiOx where x is a number from 1.1 to 2.0, or is an aluminum oxide of formula Al2O3, with a thickness of 3nm or more. The protection layer protects the underlying layers from mechanical stresses. In the DIN 58196 wipe test, the protected layer shows no damage after 50 test cycles, each with 100 wiping strokes. These reflectors are useful in the field of lighting and illumination where they can be used for lighting of display units with screens, primary lighting, secondary lighting, raster lighting, light ceilings or light deflector lamella.
摘要翻译：具有高全反射，抗机械应力的反射器，并且具有反射体，其上叠加以下组分（a）功能性涂层，例如清漆，（b）由反射金属层和，可选地，一个或多个透明陶瓷层，其具有例如λ/ 2的光学深度，施加在金属层的顶部。反射层结构是作为表面层的保护层。保护层是通式为SiO x的氧化硅，其中x为1.1至2.0的数，或者为Al 2 O 3的氧化铝，其厚度为3nm或更大。保护层保护下层免受机械应力。在DIN 58196擦拭测试中，受保护层在50次测试循环后没有显示损伤，每次都有100次擦拭冲程。这些反射器在照明和照明领域是有用的，其中它们可以用于具有屏幕，初级照明，二次照明，光栅照明，轻型天花板或导光板的显示单元的照明。

10. 发明授权

US06310737B1 Reflector with a resistant surface 失效
标题翻译：反光板带有耐磨面
公开(公告)号：US06310737B1
公开(公告)日：2001-10-30
申请号：US09554147
申请日：2000-05-10
申请人： Volkmar Gillich , Renato Kirin , Roman Fuchs
发明人： Volkmar Gillich , Renato Kirin , Roman Fuchs
IPC分类号： G02B508
CPC分类号： G02B5/0833 , G02B1/105 , G02B1/14 , Y10T428/12736 , Y10T428/12764 , Y10T428/31681
摘要： A reflector, with high total reflection, resisting mechanical stress and having a reflector body on which the following components are superimposed (a) a functional coating, e.g., a varnish, (b) a reflection layer structure composed of a reflecting metallic layer and a transparent ceramic layer, having for instance a geometric thickness of 3 nm or more or an optical depth of &lgr;2, applied on the top of the metallic layer. The layer arranged on the surface of the reflection layer structure is formed by the transparent layer which acts simultaneously as a protection layer. The protection layer is a silicon oxide of general formula SiOx, where x is a number from 1.1 to 2.0, or is an aluminum oxide of formula Al2O3. The protection layer protects the underlying layers from mechanical stresses. In the DIN 58196 wipe test, the protected layer shows no damage after 50 test cycles, each with 100 wiping strokes. These reflectors are useful in the field of lighting and illumination where they can be used for lighting of display units with screens, primary lighting, secondary lighting, raster lighting, light ceilings or light deflector lamella.
摘要翻译：具有高全反射，抗机械应力的反射器，并具有反射体，其上叠加以下组分（a）功能性涂层，例如清漆，（b）由反射金属层和透明陶瓷层，其具有例如3nm以上的几何厚度或lambd2的光学深度，施加在金属层的顶部。布置在反射层结构的表面上的层由同时作为保护层的透明层形成。保护层是通式为SiO x的氧化硅，其中x为1.1至2.0的数，或为Al 2 O 3的氧化铝。保护层保护下层免受机械应力。在DIN 58196擦拭测试中，受保护层在50次测试循环后没有显示损伤，每次都有100次擦拭冲程。这些反射器在照明和照明领域是有用的，其中它们可以用于具有屏幕，初级照明，二次照明，光栅照明，轻型天花板或导光板的显示单元的照明。

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