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1. 发明申请

US20060235191A1 Method for producing polyamides 审中-公开
标题翻译：生产聚酰胺的方法
公开(公告)号：US20060235191A1
公开(公告)日：2006-10-19
申请号：US10550491
申请日：2004-03-19
申请人： Jürgen Deininger , Jürgen Demeter , Gad Kory , Oliver Sötje , Helmut Winterling , Peter Zehner , Michael Heeger , Martin Gann , Axel Polt , Ulrich Treuling , Werner Weinle
发明人： Jürgen Deininger , Jürgen Demeter , Gad Kory , Oliver Sötje , Helmut Winterling , Peter Zehner , Michael Heeger , Martin Gann , Axel Polt , Ulrich Treuling , Werner Weinle
IPC分类号： C08G69/08
CPC分类号： C08G69/04 , C08G69/28
摘要： Polyamides, oligomers thereof or mixtures thereof, if required with further reaction products, are prepared by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine, and, if required, further polyamide-forming monomers and/oligomers with water in a reactor (1) having a vertically oriented longitudinal axis, by a process in which, in the reactor (1), the reaction product is removed from the bottom and ammonia formed and any further low molecular weight compounds formed and water are taken off via the top (2), wherein the reactor (1) has at least two chambers (4) arranged one on top of the other in the longitudinal direction, the chambers (4) being separated from one another by liquid-tight trays (5), each chamber (4) being connected by a liquid overflow (6) to the chamber (4) directly underneath and a liquid product stream being taken off by the liquid overflow (6) of the lowermost chamber (4), the gas space (7) above the liquid level in each chamber (4) being connected to the chamber (4) arranged directly above in each case by one or more conduit pipes (8) which in each case opens or open into a gas distributor (9) having orifices (11) for gas exit below the liquid level, and comprising in each case at least one baffle plate (12) which is arranged vertically around each gas distributor (9) and whose upper end terminates below the liquid level and whose lower end terminates above the liquid-tight tray (5) of the chamber (4) and which separates each chamber (4) into one or more gassed (13) and into one or more ungassed (14) spaces.
摘要翻译：如果需要，聚酰胺，其低聚物或其混合物，如果需要与其他反应产物反应，可通过氨基腈或二腈和二胺或含有氨基腈，二腈和二胺的混合物，以及如果需要，将另外的聚酰胺形成单体和/ 反应器（1）具有垂直取向的纵向轴线，其中在反应器（1）中将反应产物从底部除去并形成氨，并且形成的任何进一步的低分子量化合物和水通过所述顶部（2），其中所述反应器（1）具有在纵向方向上一个在另一个上方布置的至少两个室（4），所述室（4）通过液密盘（5）彼此分离，，每个室（4）通过液体溢流（6）直接在下面连接到室（4），并且液体产物流被最下室（4）的液体溢流（6）取出，气体空间每个腔室（4）中的液位高于每个壳体（4）的腔室（4），其通过一个或多个在每种情况下打开或打开到气体分配器（9）的导管（8）直接布置在每个壳体的上方，具有用于气体在液面以下排出的孔口（11），并且在每种情况下包括至少一个挡板（12），所述挡板（12）围绕每个气体分布器（9）垂直布置，并且其上端终止于液面以下，并且其下端在室（4）的液密盘（5）上方，并将每个室（4）分成一个或多个充气（13）并分成一个或多个无气（14）空间。

2. 发明授权

US06204325B1 Compact, transparent polyisocyanate polyaddition products 失效
标题翻译：紧凑，透明的多异氰酸酯加成产物
公开(公告)号：US06204325B1
公开(公告)日：2001-03-20
申请号：US09266217
申请日：1999-03-10
申请人： Christian Maletzko , Edwin Baumann , Ilka Renate Beuermann , Peter Roche , Ulrich Treuling , Hans-Peter Frei
发明人： Christian Maletzko , Edwin Baumann , Ilka Renate Beuermann , Peter Roche , Ulrich Treuling , Hans-Peter Frei
IPC分类号： C08J300
CPC分类号： C08G18/792 , C08G18/10 , C08G18/4018 , C08G18/755 , C08G18/40
摘要： Compact, transparent polyisocyanate polyaddition products are produced in a process by reacting (a) isocyanates with (b) compounds reactive to isocyanates, if desired in the presence of (c) catalysts and (d) auxiliaries and/or additives, which comprises using as (b) compounds reactive to isocyanates a mixture (i) which has an average functionality of >3 and an average hydroxyl number of from 300 to 950 mg KOH/g.
摘要翻译：在（c）催化剂和（d）助剂和/或添加剂的存在下，如果需要，使（a）异氰酸酯与（b）与异氰酸酯反应的化合物反应，制备紧密，透明的多异氰酸酯加聚产物，其包括使用（b）与异氰酸酯反应的化合物，其平均官能度> 3且平均羟基数为300至950mg KOH / g的混合物（i）。

3. 发明授权

US06329440B2 Preparation of polyisocyanate polyaddition products 失效
标题翻译：多异氰酸酯加成产物的制备
公开(公告)号：US06329440B2
公开(公告)日：2001-12-11
申请号：US09305946
申请日：1999-05-06
申请人： Dietrich Scherzer , Ulrich Treuling , Martin Kreyenschmidt , Anton Kappes , Klaus Pittrich
发明人： Dietrich Scherzer , Ulrich Treuling , Martin Kreyenschmidt , Anton Kappes , Klaus Pittrich
IPC分类号： C08L7500
CPC分类号： C08G18/6674 , C08G18/6696 , C08G2101/0025 , C08G2101/005 , C08G2101/0083 , C08L75/04 , C08L2666/26 , C08L23/00
摘要： In a process for preparing polyisocyanate polyaddition products by reacting isocyanates with compounds which are reactive toward isocyanates, in the presence or absence of blowing agents, catalysts, auxiliaries and/or additives, the reaction is carried out in the presence of (i) particles which have a size of
摘要翻译：在异氰酸酯与异氰酸酯反应的化合物反应制备多异氰酸酯加成产物的方法中，在存在或不存在发泡剂，催化剂，助剂和/或添加剂的情况下，反应在（i）尺寸<200μm，熔点在50-300℃范围内，或在热固性颗粒（ii）存在下或在颗粒（i）和（ii）的存在下。

4. 发明授权

US07339020B2 High-functionality polyisocyanates 有权
标题翻译：高官能度聚异氰酸酯
公开(公告)号：US07339020B2
公开(公告)日：2008-03-04
申请号：US09811987
申请日：2001-03-19
申请人： Bernd Bruchmann , Hans Renz , Rainer Königer , Ulrike Ehe , Ulrich Treuling , Rudolf Müller-Mall
发明人： Bernd Bruchmann , Hans Renz , Rainer Königer , Ulrike Ehe , Ulrich Treuling , Rudolf Müller-Mall
IPC分类号： C08G18/10 , C08G18/72 , C08J9/04 , C07C269/02 , C07C271/06
CPC分类号： C08G18/8022 , C09D175/04
摘要： High-functionality polyisocyanates are prepared by a process which comprises (i) preparation of an addition product (A) which contains one group which is reactive toward isocyanate and at least two isocyanate groups by reacting (a) a diisocyanate or polyisocyanate I with (b1) compounds having at least three groups which are reactive toward isocyanate or (b2) compounds containing two groups which are reactive toward isocyanate or mixtures of (b1) and (b2), where at least one of the components (a) or (b) has functional groups having differing reactivities toward the functional groups of the other component and the reaction ratio is selected so that the addition product (A) contains an average of one group which is reactive toward isocyanate, (ii) if desired, intermolecular addition reaction of the addition product (A) to form a polyaddition product (P) containing an average of one group which is reactive toward isocyanate and an average of more than two isocyanate groups, and (iii) reaction of the addition product (A) and/or the polyaddition product (P) with a diisocyanate or polyisocyanate II.
摘要翻译：通过以下方法制备高官能度多异氰酸酯：（i）通过使（a）二异氰酸酯或多异氰酸酯I与（b1）反应，制备含有一个对异氰酸酯和至少两个异氰酸酯基反应的基团的加成产物（A））具有至少三个对异氰酸酯反应的基团的化合物或（b2）含有对异氰酸酯或（b1）和（b2）的混合物具有反应性的两个基团的化合物，其中至少一种组分（a）或（b）具有与其他成分的官能团反应性不同的官能团，选择反应比，使加成产物（A）含有对异氰酸酯具有反应性的一个基团的平均值，（ii）如果需要，分子内加成反应加成产物（A）形成含有平均一个对异氰酸酯反应的基团和平均多于两个异氰酸酯基团的加聚产物（P），和（iii）反应加成产物（A）和/或加聚产物（P）与二异氰酸酯或多异氰酸酯II的离子。

5. 发明授权

US6031013A Production of polyurethane foams 失效
标题翻译：生产聚氨酯泡沫
公开(公告)号：US6031013A
公开(公告)日：2000-02-29
申请号：US176423
申请日：1998-10-21
申请人： Dietrich Scherzer , Ulrich Treuling , Jurgen Mertes , Rolf Illguth
发明人： Dietrich Scherzer , Ulrich Treuling , Jurgen Mertes , Rolf Illguth
IPC分类号： C08G18/16 , C08G18/48 , C08G18/78 , C08G18/79
CPC分类号： C08G18/165 , C08G18/4812 , C08G18/7831 , C08G18/792 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083
摘要： In a process for producing foams based on polyisocyanate polyaddition products by reacting isocyanates with compounds which are reactive toward isocyanates and have a molecular weight of from 400 to 8000 in the presence of blowing agents, catalysts and, if desired, chain extenders and/or crosslinkers having a molecular weight of 40.degree. C.
摘要翻译：在通过使异氰酸酯与对异氰酸酯具有反应性并且在发泡剂，催化剂和如果需要的情况下，扩链剂和/或交联剂存在下分子量为400-8000的化合物反应生产基于多异氰酸酯加聚产物的泡沫的方法具有分子量<400的助剂和/或添加剂，使用具有异氰脲酸酯和/或缩二脲结构的异氰酸酯，至少一种对异氰酸酯具有反应性的化合物，其分子量为400至8000并且至少包含 50％的伯羟基，作为催化剂的至少一种叔胺和至少一种金属盐加上0.5-5.3重量％的水，基于对异氰酸酯具有反应性且分子量为400的化合物的重量至8000℃，反应在> 40℃下进行。

6. 发明授权

US06800667B1 Mixture containing isocyanates as well as organic and/or inorganic acid anhydrides 失效
标题翻译：含有异氰酸酯的混合物以及有机和/或无机酸酐
公开(公告)号：US06800667B1
公开(公告)日：2004-10-05
申请号：US09763280
申请日：2001-02-20
申请人： Martin Kreyenschmidt , Andreas Arlt , Reinhard Lorenz , Ulrich Treuling
发明人： Martin Kreyenschmidt , Andreas Arlt , Reinhard Lorenz , Ulrich Treuling
IPC分类号： C08G1865
CPC分类号： C08K5/09 , C08G18/12 , C08G18/2027 , C08G18/34 , C08G18/4812 , C08G18/6216 , C08G2101/0008 , C08G2101/0083 , C08G2410/00 , C08K5/15 , C08G18/6692 , C08L75/04
摘要： The present invention relates to a mixture that contains (i) at least one isocyanate and (ii) at least one organic and/or inorganic acid anhydride.
摘要翻译：本发明涉及含有（i）至少一种异氰酸酯和（ii）至少一种有机和/或无机酸酐的混合物。

7. 发明授权

US06416686B2 Polyisocyanates 有权
标题翻译：聚异氰酸酯
公开(公告)号：US06416686B2
公开(公告)日：2002-07-09
申请号：US09811201
申请日：2001-03-16
申请人： Bernd Bruchmann , Hans Renz , Rainer Königer , Ulrike Ehe , Ulrich Treuling , Rudolf Müller-Mall
发明人： Bernd Bruchmann , Hans Renz , Rainer Königer , Ulrike Ehe , Ulrich Treuling , Rudolf Müller-Mall
IPC分类号： C08G1830
CPC分类号： C08G18/8016 , C08G18/79 , C08G18/8041
摘要： Polyisocyanates are prepared by a process which comprises (i) preparation of an addition product (A) which contains one group which is reactive toward isocyanate and one isocyanate group by reacting (a) a diisocyanate I with (b) compounds containing two groups which are reactive toward isocyanate, where at least one of the components (a) or (b) has functional groups having differing reactivities toward the functional groups of the other component, (ii) if desired, intermolecular addition reaction of the addition product (A) to form a polyaddition product (P) which contains one group which is reactive toward isocyanate and one isocyanate group and (iii) reaction of the addition product (A) and/or the polyaddition product (P) with a diisocyanate or polyisocyanate II which is different from diisocyanate I.
摘要翻译：聚异氰酸酯是通过以下方法制备的：（i）通过使（a）二异氰酸酯I与（b）含有两个基团的化合物反应而制备含有一个对异氰酸酯和一个异氰酸酯基反应的基团的加成产物（A）对于异氰酸酯反应，其中组分（a）或（b）中的至少一种具有与其它组分的官能团不同的反应性的官能团，（ii）如果需要，加成产物（A）的分子内加成反应与形成加成产物（P），其包含一个对异氰酸酯和一个异氰酸酯基反应的基团，和（iii）加成产物（A）和/或加聚产物（P）与不同的二异氰酸酯或多异氰酸酯II的反应来自二异氰酸酯I.

8. 发明授权

US06303833B1 Multi-metal cyanide complexes as catalysts and their use in preparing polyetherpolyols 有权
标题翻译：多金属氰化物络合物作为催化剂及其在制备聚醚多元醇中的应用
公开(公告)号：US06303833B1
公开(公告)日：2001-10-16
申请号：US09509515
申请日：2000-03-29
申请人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
发明人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
IPC分类号： C07C4311
CPC分类号： B01J27/26 , C08G65/2663
摘要： A crystalline multimetal cyanide complex of the formula (I) M1a[M2(CN)bL1c]d*e(M1fXg)*hL2′iH2O (I) where M1 is at least one element from the group consisting of Zn(II), Fe(II), Co(III), Ni(II), Mn(II), Co(II), Sn(II). Pb(II), Fe(III), Mo(IV), Mo(VI), Al(III), V(IV), V(V), Sr(II, W(IV), W(VI), Cu(II), and Cr(III), M2 is at least one element from the group consisting of Fe(II), Fe(III), Co(III), Cr(III), Mn(II), Mn(III), Ir(III), Rh(III), Ru(II), V(IV), V(V), Co(II) and Cr(II), L1 is at least one ligand from the group consisting of cyanide, carbonyl, cyanate, isocyanate, nitrile, thiocyanate and nitrosyl, X is a formate anion, an acetate anion or propionate anion, L2 is at least one water-miscible ligand from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, urea derivatives, amides, nitriles and sulfides, a, b, c, d, e, f, g, h, i are integers, with a, b, c and d being chosen so that the electrical neutrality condition is satisfied, and f and g being chosen so that the electrical neutrality condition is satisfied, the X-ray diffiactogram of which shows reflections at particular d values, can be employed as catalyst.
摘要翻译：式（I）的结晶多金属氰化物络合物，其中M 1是由Zn（II），Fe（II），Co（III），Ni（II），Mn（II），Co（II）组成的组中的至少一种元素），Sn（II）。 Pb（II），Fe（III），Mo（IV），Mo（VI），Al（III），V（IV），V（V）（II），Fe（Ⅲ），Co（Ⅲ），Cr（Ⅲ），Mn（Ⅱ），Mn（Ⅲ）等元素中的至少一种元素，，Ir（III），Rh（III），Ru（II），V（IV），V（V），Co（II）和Cr（II），L1是至少一种由氰化物，羰基，氰酸酯，异氰酸酯，腈，硫氰酸酯和亚硝酰基，X是甲酸根阴离子，乙酸根阴离子或丙酸根阴离子，L2是至少一种与醇，醛，酮，醚，聚醚，酯，尿素衍生物，酰胺，腈和硫化物，a，b，c，d，e，f，g，h，i是整数，其中选择a，b，c和d，使得满足电中性条件，被选择为使得电中性条件满足，其X射线衍射图示出特定d值的反射可用作催化剂。

9. 发明授权

US06191179B1 Preparation of polyurethane foams 失效
标题翻译：制备聚氨酯泡沫
公开(公告)号：US06191179B1
公开(公告)日：2001-02-20
申请号：US09271233
申请日：1999-03-17
申请人： Dietrich Scherzer , Ulrich Treuling , Klaus Wagner , Rolf Illguth , Sarbananda Chakrabarti
发明人： Dietrich Scherzer , Ulrich Treuling , Klaus Wagner , Rolf Illguth , Sarbananda Chakrabarti
IPC分类号： C08G1820
CPC分类号： C08G18/7831 , C08G18/165 , C08G18/2865 , C08G18/6688 , C08G18/771 , C08G18/792 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： A process for the preparation of foamed plastics materials based on polyisocyanate polyaddition products by the reaction of isocyanates with isocyanate-reactive compounds in the presence of catalysts and, optionally, auxiliaries and/or additives, wherein i) isocyanates having isocyanurate and/or biuret structures are used, the isocyanate-reactive compounds used are ii) at least one diol and/or polyol having a molecular weight of from 400 to 8000 and containing at least 50% of primary hydroxyl groups based on all of the hydroxyl groups present in the compound, iii) at least one compound having at least one primary amine group, and diols and/or triols having molecular weights of less than 400 are optionally used as chain-extending and/or crosslinking agents, the reaction being carried out in the presence of iv) at least one tertiary amine acting as catalyst and/or v) at least one metal salt acting as catalyst and vi) water.
摘要翻译：在催化剂和任选的助剂和/或添加剂的存在下通过异氰酸酯与异氰酸酯反应性化合物的反应制备基于多异氰酸酯加聚产物的泡沫塑料材料的方法，其中具有异氰脲酸酯和/或缩二脲结构的异氰酸酯是使用的异氰酸酯反应性化合物是ii）分子量为400-8000的至少一种二醇和/或多元醇，并且含有至少50％的基于化合物中存在的所有羟基的伯羟基，iii ）至少一种具有至少一个伯胺基的化合物和分子量小于400的二醇和/或三醇任选用作延伸链和/或交联剂，该反应在作为催化剂的至少一种叔胺和/或v）至少一种作为催化剂的金属盐，和vi）水。

10. 发明授权

US06913629B2 Building blocks containing isocyanate groups and their use for functionalizing or modifying compounds or surfaces 失效
标题翻译：含有异氰酸酯基团的组合物及其用于官能化或改性化合物或表面的用途
公开(公告)号：US06913629B2
公开(公告)日：2005-07-05
申请号：US09726045
申请日：2000-11-30
申请人： Bernd Bruchmann , Ulrich Treuling
发明人： Bernd Bruchmann , Ulrich Treuling
IPC分类号： C07C271/20 , C07C271/28 , C07C275/26 , C07C275/40 , C07C333/06 , C08F8/30 , C08G18/64 , C08G18/80 , C08G18/81 , C08G73/04 , C08G73/06 , D06M13/395 , D06M13/22 , C07C69/88
CPC分类号： D06M13/395 , C07C271/20 , C07C271/28 , C07C275/26 , C07C275/40 , C07C333/06 , C07C2601/14 , C08F8/30 , C08G18/6423 , C08G18/8041 , C08G18/8054 , C08G18/8064 , C08G18/808 , C08G18/8116 , C08G73/0655 , D06M2101/06 , D06M2200/12
摘要： Compounds of the formula 1 OCN—R1—NHCOX—R2—(Y)n (1), where X is a covalent bond to R2 or is O, S or NR3, Y is a hydrogen atom or a free functional group and n is an integer from 1 to 20, can be used for functionalizing or modifying compounds or solid surfaces which have at least one group which is reactive toward isocyanate.
摘要翻译：式1的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> OCN-R 1 -NHCOX-R 2 - （Y）（1），<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X是与R 2的共价键或者是O，S或NR 3，Y是氢原子或游离官能团，n是1至20的整数，可用于官能化或修饰化合物或固体具有至少一个与异氰酸酯反应的基团的表面。

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