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    • 5. 发明申请
    • Method for producing polyamides
    • 生产聚酰胺的方法
    • US20060235191A1
    • 2006-10-19
    • US10550491
    • 2004-03-19
    • Jürgen DeiningerJürgen DemeterGad KoryOliver SötjeHelmut WinterlingPeter ZehnerMichael HeegerMartin GannAxel PoltUlrich TreulingWerner Weinle
    • Jürgen DeiningerJürgen DemeterGad KoryOliver SötjeHelmut WinterlingPeter ZehnerMichael HeegerMartin GannAxel PoltUlrich TreulingWerner Weinle
    • C08G69/08
    • C08G69/04C08G69/28
    • Polyamides, oligomers thereof or mixtures thereof, if required with further reaction products, are prepared by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine, and, if required, further polyamide-forming monomers and/oligomers with water in a reactor (1) having a vertically oriented longitudinal axis, by a process in which, in the reactor (1), the reaction product is removed from the bottom and ammonia formed and any further low molecular weight compounds formed and water are taken off via the top (2), wherein the reactor (1) has at least two chambers (4) arranged one on top of the other in the longitudinal direction, the chambers (4) being separated from one another by liquid-tight trays (5), each chamber (4) being connected by a liquid overflow (6) to the chamber (4) directly underneath and a liquid product stream being taken off by the liquid overflow (6) of the lowermost chamber (4), the gas space (7) above the liquid level in each chamber (4) being connected to the chamber (4) arranged directly above in each case by one or more conduit pipes (8) which in each case opens or open into a gas distributor (9) having orifices (11) for gas exit below the liquid level, and comprising in each case at least one baffle plate (12) which is arranged vertically around each gas distributor (9) and whose upper end terminates below the liquid level and whose lower end terminates above the liquid-tight tray (5) of the chamber (4) and which separates each chamber (4) into one or more gassed (13) and into one or more ungassed (14) spaces.
    • 如果需要,聚酰胺,其低聚物或其混合物,如果需要与其他反应产物反应,可通过氨基腈或二腈和二胺或含有氨基腈,二腈和二胺的混合物,以及如果需要,将另外的聚酰胺形成单体和/ 反应器(1)具有垂直取向的纵向轴线,其中在反应器(1)中将反应产物从底部除去并形成氨,并且形成的任何进一步的低分子量化合物和水通过 所述顶部(2),其中所述反应器(1)具有在纵向方向上一个在另一个上方布置的至少两个室(4),所述室(4)通过液密盘(5)彼此分离, ,每个室(4)通过液体溢流(6)直接在下面连接到室(4),并且液体产物流被最下室(4)的液体溢流(6)取出,气体空间 每个腔室(4)中的液位高于每个壳体(4)的腔室(4),其通过一个或多个在每种情况下打开或打开到气体分配器(9)的导管(8)直接布置在每个壳体的上方, 具有用于气体在液面以下排出的孔口(11),并且在每种情况下包括至少一个挡板(12),所述挡板(12)围绕每个气体分布器(9)垂直布置,并且其上端终止于液面以下,并且其下端 在室(4)的液密盘(5)上方,并将每个室(4)分成一个或多个充气(13)并分成一个或多个无气(14)空间。