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1. 发明授权

US09320686B2 Dental materials based on compounds having debonding-on-demand properties 有权
公开(公告)号：US09320686B2
公开(公告)日：2016-04-26
申请号：US14343300
申请日：2012-09-10
申请人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
发明人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
IPC分类号： A61K6/083 , A61C7/00 , A61K6/00 , C07D239/47 , C07F3/06 , C08F122/22
CPC分类号： A61K6/0835 , A61K6/0002 , A61K6/0023 , A61K6/083 , C07D239/47 , C07F3/06 , C08F122/22 , C08L33/00
摘要： The invention relates to a dental restorative material which comprises a thermolabile compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l Formula I, in which T represents a thermolabile unit which contains at least one thermolabile group based on non-covalent interactions, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3— or —NR3—CO—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical, k and l in each case independently are 0, 1, 2 or 3 and m and n in each case independently are 1, 2 or 3.

2. 发明授权

US08367748B2 Surface-modified fillers 有权
标题翻译：表面改性填料
公开(公告)号：US08367748B2
公开(公告)日：2013-02-05
申请号：US11292578
申请日：2005-12-02
申请人： Norbert Moszner , Simone Klapdohr , Ulrich Salz , Jorg Zimmermann , Volker M. Rheinberger
发明人： Norbert Moszner , Simone Klapdohr , Ulrich Salz , Jorg Zimmermann , Volker M. Rheinberger
IPC分类号： A61K6/083 , C08K9/06 , A61C5/00
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , A61K6/0073 , A61K6/093 , Y10T428/29 , C08L33/14 , C08L43/02 , C08L83/06
摘要： A filler which is surface-modified with a compound of the formula [(PG)-R1—Z]n—SP—[Y—R2-(AG)]m is particularly suitable for use in dental materials, for the preparation of adhesives, coatings and composites.
摘要翻译：用[（PG）-R1-Z] n-SP- [Y-R2-（AG）] m的化合物进行表面改性的填料特别适用于牙科材料，用于制备粘合剂，涂料和复合材料。

3. 发明申请

US20120208917A1 Dental restorative material based on an antimicrobially active compound 有权
标题翻译：基于抗微生物活性化合物的牙齿修复材料
公开(公告)号：US20120208917A1
公开(公告)日：2012-08-16
申请号：US13368998
申请日：2012-02-08
申请人： Ulrich SALZ , Thorsten BOCK , Christoph Peter FIK , Jörg TILLER , Volker RHEINBERGER
发明人： Ulrich SALZ , Thorsten BOCK , Christoph Peter FIK , Jörg TILLER , Volker RHEINBERGER
IPC分类号： A61K6/087 , C07F9/40 , C07D209/48 , A61K6/00 , C07D491/048
CPC分类号： A61K6/0023 , A61K6/0008 , A61K6/0017 , A61K6/0067 , A61K6/083 , A61K6/093
摘要： The invention relates to a dental restorative material which comprises (a) at least one antimicrobially active compound of Formula (I) [AG]m-R1—Z—SP—Y—R2—[WG]p (I), or a filler that is surface-modified with at least one compound of Formula (I), (b) at least one radically polymerizable monomer and (c) at least one initiator for the radical polymerization. The invention also relates to a use of such dental restorative material for the preparation of an adhesive, primer, cement, coating material or filling material.The invention also relates to a dental material which comprises at least one compound of Formula (I), as well as a use of a compound of Formula (I) for modifying the surface of a substrate selected from ceramic materials, noble and non-noble metals, hard tooth structure, tooth enamel, dentine, collagen, soft tissue, mucous membrane and leather.
摘要翻译：本发明涉及一种牙科修复材料，其包含（a）至少一种式（I）[AG] m-R1-Z-SP-Y-R2- [WG] p（I）的抗微生物活性化合物或填充剂其用至少一种式（I）的化合物，（b）至少一种可自由基聚合的单体和（c）至少一种用于自由基聚合的引发剂进行表面改性。本发明还涉及这种牙科修复材料用于制备粘合剂，底漆，水泥，涂料或填充材料的用途。本发明还涉及包含至少一种式（I）化合物的牙科材料，以及式（I）化合物用于改性选自陶瓷材料，贵金属和非贵金属的基材表面的用途的牙科材料金属，硬齿结构，牙釉质，牙质，胶原，软组织，粘膜和皮革。

4. 发明授权

US07851515B2 Hydrolysis-stable self-etching single-component dental adhesive 有权
标题翻译：水解稳定自腐蚀单组份牙科粘合剂
公开(公告)号：US07851515B2
公开(公告)日：2010-12-14
申请号：US11212065
申请日：2005-08-25
申请人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
发明人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
IPC分类号： C07F9/06 , C07F9/113 , C07F9/143 , A61K6/083 , A61K6/08 , A61K6/00 , A61C5/00 , C08F20/58 , C08F220/54
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , A61K6/0835 , C08L33/00
摘要： Dental composition containing (i) at least one acid (meth)acrylamide monomer which has two or more polymerizable groups, (ii) at least one acid monomer which has only one polymerizable group and (iii) at least one polymerization initiator.
摘要翻译：含有（i）至少一种具有两个或多个可聚合基团的酸（甲基）丙烯酰胺单体，（ii）至少一种仅具有一个可聚合基团的酸单体和（iii）至少一种聚合引发剂）的牙科组合物。

5. 发明授权

US07553881B2 Dental materials based on radically polymerizable macromers with antimicrobial effect 有权
标题翻译：基于可自由基聚合的大分子单体的牙科材料具有抗菌作用
公开(公告)号：US07553881B2
公开(公告)日：2009-06-30
申请号：US11502420
申请日：2006-08-11
申请人： Ulrich Salz , Jörg Zimmermann , Dirk Poppe , Volker Rheinberger , Jörg Tiller , Christian Waschinski
发明人： Ulrich Salz , Jörg Zimmermann , Dirk Poppe , Volker Rheinberger , Jörg Tiller , Christian Waschinski
IPC分类号： A61K6/083 , C08F26/06
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/083 , A61K6/09 , C08L33/00 , C08L75/16
摘要： Dental material which contains at least one compound of the formula [PG]m—R1—Z—SP—Y—R2—[WG]p, in which m=1, 2 or 3; p=1, 2 or 3; R1=is absent, a linear or branched C1 to C20 alkylene radical which can be interrupted one or more times by O, S, NH, SiR′, CONH CONR′, COO and/or OCONH, a substituted or unsubstituted, aromatic C6 to C14 radical or a combination thereof R2=is absent, a linear or branched C1 to C20 alkylene radical which can be interrupted one or more times by O, S, NH, SiR′, CONH CONR′, COO and/or OCONH, a substituted or unsubstituted, aromatic C6 to C14 radical or a combination thereof; PG=a radically polymerizable group; SP=a polymeric spacer which is selected from polyethylene glycol, polypropylene glycol, polyglycerol, polyalkyloxazoline, polyethyleneimine, polyacrylic acid, polymethacrylic acid, polyvinyl alcohol, polyvinyl acetate, poly-(2-hydroxyethyl)acrylate, poly-(2-hydroxyethyl)methacrylate groups, hydrophilic polypeptide groups and copolymers of the corresponding monomers; WG=antimicrobially active group; Z=is absent, O, S, an ester, amide or urethane group; Y=is absent, O, S, an ester, amide or urethane group, and which has a molecular weight of at least 1,000.
摘要翻译：含有至少一种式[PG] m -R1-Z-SP-Y-R2- [WG] p化合物的牙科材料，其中m = 1,2或3; p = 1,2或3; R 1 =不存在，可被O，S，NH，SiR'，CONH CONR'，COO和/或OCONH间隔一次或多次的直链或支链C1至C20亚烷基，取代或未取代的芳族C6至 C 14基团或其组合，R 2 =不存在，可被O，S，NH，SiR'，CONH CONR'，COO和/或OCONH间隔一次或多次的直链或支链C 1至C 20亚烷基，或未取代的芳族C 6至C 14基团或其组合; PG =自由基聚合性基团; SP =选自聚乙二醇，聚丙二醇，聚甘油，聚烷基恶唑啉，聚乙烯亚胺，聚丙烯酸，聚甲基丙烯酸，聚乙烯醇，聚乙酸乙烯酯，聚（2-羟乙基）丙烯酸酯，聚（2-羟乙基）甲基丙烯酸酯基团，亲水性多肽基团和相应单体的共聚物; WG =抗微生物活性组; Z =不存在，O，S，酯，酰胺或氨基甲酸酯基; Y =不存在，O，S，酯，酰胺或氨基甲酸酯基，其分子量至少为1,000。

6. 发明申请

US20060135719A1 Self-etching dental materials based on (METH) acrylamide phosphates 有权
标题翻译：基于（METH）丙烯酰胺磷酸盐的自蚀牙科材料
公开(公告)号：US20060135719A1
公开(公告)日：2006-06-22
申请号：US11211938
申请日：2005-08-25
申请人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker Rheinberger
发明人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker Rheinberger
IPC分类号： C08F120/54
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/0029 , A61K6/083 , A61K6/09 , C08L33/26 , C08L33/04 , C08L75/04
摘要： Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-C10 aralkyl or a bicylic C4-C12 radical; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.
摘要翻译：可聚合的牙科材料，其特征在于它含有至少一种下列通式（I）的（甲基）丙烯酰胺磷酸酯：其中R 1是H或CH 3; R 2是H或C 1 -C 4烷基，或与其键合的氮原子一起形成一个或多个属于R 3或R 3'杂原子的杂原子; R 3，R 3，R 3'彼此独立地是直链或支链的脂族C 1 -C 50 - 基团具有m + n或p + n的化合价，m + n或p + n的芳族C 6 -C 18 - 基团，或脂环族基团，芳烷基或杂环C 3 -C 18 - 基团，其价态为m + n或p + n，其中基团或基团的碳链可以被O， S，CONR 4，OCONH，或与一个或多个属于R 2的原子和氮原子一起形成，R 2 O 2 >键合杂环，如果p = 0，则R 3'为H，R 4为H，C 1 -C 3 C 10 -C 12烷基，C 6 -C 12芳基，C 6 -C 10芳烷基或C 6 -C 12烷基二元C 4 -C 12 - 基团; 如果p = 0，则n为1,2,3或4，如果p <0，则为1或2; m为1,2,3或4; p是0，1，2，3或4; x是0或S.

7. 发明授权

US06900251B2 Dental materials based on acrylic-ester phosphonic acids 有权
标题翻译：基于丙烯酸酯膦酸的牙科材料
公开(公告)号：US06900251B2
公开(公告)日：2005-05-31
申请号：US10606142
申请日：2003-06-25
申请人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
发明人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
IPC分类号： A61C13/087 , A61K6/00 , A61K6/083 , C07F9/38 , C08F30/02 , C08F220/54 , C08F230/02 , C09J4/00 , C09J4/02 , C09J11/04 , C09J11/06 , A61K8/00 , C07F9/09 , C08F2/46
CPC分类号： A61K6/0023 , A61K6/083 , C07F9/3808 , C08F30/02 , C08L33/00 , C08L43/02 , C08L39/06
摘要： Acrylic ester phosphonic acids of general formula (I), stereoisomers thereof and mixtures of these, wherein n is 1 or 2, on the condition that for n=1 R1 has the meaning and for n=2 R1 has the meaning R2 is a C1 to C12 alkylene radical, C4-C8 cycloalkylene radical or C7 to C15 alkylene phenylene radical; R3 is hydrogen, a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical; and R4, R5, independently of each other, each stand for a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical.
摘要翻译：在通式（I）的丙烯酸酯膦酸，其立体异构体和它们的混合物，其中n为1或2，条件是对于n = 1的R 1具有含义，n = 2 R 1具有R 2是C 1至C 12亚烷基的C 1至C 4亚烷基，C 4 C 1 -C 8亚环烷基或C 7至C 15亚烷基亚苯基; R 3是氢，C 1至C 5烷基或C 1至C 6烷基， 5 O - 烷基; 和R 4，R 5，R 5彼此独立地代表C 1至C 5烷基自由基或C 1至C 5 - O-烷基。

8. 发明授权

US06450717B1 Applicator and method of applying 有权
标题翻译：申请人和申请方法
公开(公告)号：US06450717B1
公开(公告)日：2002-09-17
申请号：US09695029
申请日：2000-10-24
申请人： Ulrich Salz , Andre Rumphorst , Alexandros Gianasmidis , Frank Muller , Volker Rheinberger
发明人： Ulrich Salz , Andre Rumphorst , Alexandros Gianasmidis , Frank Muller , Volker Rheinberger
IPC分类号： A46B1100
CPC分类号： A61C3/005 , A61C5/60 , A61J1/2031 , A61J1/2041 , A61J1/2093
摘要： An applicator kit, for dental purposes. has an application element with a grip area for handling, and also has a shaft, on a tip of which is disposed an application member, preferably in the form of a micro-brush that is provided with a reaction substance. A cup shaped sealing mechanism surrounds the shaft and the application member. The cup shaped sealing mechanism is slidably received within a housing which also receives a low velocity fluid initially spaced away from the cup-shaped sealing mechanism. The reaction substance on the application member is activated by pressing the sealing mechanism and application member into the fluid within the housing which causes the fluid to wet the application member.
摘要翻译：用于牙科用途的涂抹器套件。具有用于处理的抓握区域的应用元件，并且还具有轴，其尖端设置在施加构件上，优选地为具有反应物质的微型刷形式。杯形密封机构围绕轴和施加构件。杯形密封机构可滑动地容纳在壳体内，该壳体还容纳最初与杯状密封机构间隔开的低速流体。施加构件上的反应物质通过将密封机构和施加构件压入壳体内的流体而使流体润湿施加构件而被致动。

9. 发明授权

US06353039B1 Polymerizable composite material 有权
标题翻译：可聚合复合材料
公开(公告)号：US06353039B1
公开(公告)日：2002-03-05
申请号：US09209905
申请日：1998-12-11
申请人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
发明人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/0276 , A61K6/083 , A61K6/09 , C08F2/44 , C08K3/40 , C08K9/08 , C08L33/00 , C08L75/16
摘要： A composite material is described which contains polymerizable monomers plus a special transparent glass having high release of calcium ions and fluorine ions and, because of this release property and in particular of its optical properties, can be used as a restoration material in dentistry.
摘要翻译：描述了一种复合材料，其包含可聚合单体加上具有高释放的钙离子和氟离子的特殊透明玻璃，并且由于该释放性质，特别是其光学性质，可用作牙科中的修复材料。

10. 发明授权

US5703249A Bicycloaliphatic 2-methylene-1,3-dioxepanes 失效
标题翻译：双环脂族2-亚甲基-1,3-二氧杂环庚烷
公开(公告)号：US5703249A
公开(公告)日：1997-12-30
申请号：US548104
申请日：1995-10-25
申请人： Volker Rheinberger , Norbert Moszner , Ulrich Salz , Thomas Voelkel
发明人： Volker Rheinberger , Norbert Moszner , Ulrich Salz , Thomas Voelkel
IPC分类号： C07D321/06 , A61C13/00 , A61C13/23 , A61K6/00 , A61K6/08 , A61K6/087 , C07D321/10 , C07D493/04 , C07D493/10 , C07D493/20 , C08G63/00 , C08L67/00 , C07D317/44 , C07D317/72
CPC分类号： C07D493/04 , A61K6/0023 , A61K6/087 , C07D493/10
摘要： The present invention relates to novel bicycloaliphatic 2-methylene-1,3-dioxepanes, which are suitable as starting materials for the preparation of polymers and copolymers, preferably of composite and dental materials. The 2-methylene-1,3-dioxepanes according to the invention, which can undergo radical polymerisation with ring opening with only very little volume shrinkage, can be prepared in a simple manner, are easy to purify and to modify chemically, and are characterised by lack of odour and advantageous physical properties.
摘要翻译：本发明涉及新的双环脂族2-亚甲基-1,3-二氧杂环庚烯，它们适合作为制备聚合物和共聚物的起始材料，优选为复合材料和牙科材料。根据本发明的2-亚甲基-1,3-二氧杂环庚烯可以以简单的方式制备，其可以以仅具有非常小的体积收缩率的开环进行自由基聚合，易于化学纯化和修饰，并且被表征缺乏气味和有利的物理特性。

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