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1. 发明授权

US4072655A Organosilicon compounds as additives for curable organopolysiloxane compositions 失效
标题翻译：有机硅化合物作为可固化的有机聚硅氧烷组合物的添加剂
公开(公告)号：US4072655A
公开(公告)日：1978-02-07
申请号：US648429
申请日：1976-01-12
申请人： Eckhart Louis , Norman Dorsch , Ernst Wohlfarth
发明人： Eckhart Louis , Norman Dorsch , Ernst Wohlfarth
IPC分类号： C08L83/04 , C08G77/04
CPC分类号： C08K5/54 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/26 , C08G77/42 , C08G77/44 , C08G77/70 , Y10T428/31663
摘要： Organosilicon compounds having at least one hydrocarbon radical linked to at least 75 percent of the silicon atoms via an oxygen atom in which the hydrocarbon radical has at least one hydroxyl group and may be linked again to the same silicon atom or to another silicon atom via an oxygen atom are added to room temperature curable organopolysiloxane compositions to form compositions which are resistant to flow on vertical surfaces. When these compositions are exposed to atmospheric moisture at room temperature, they form elastomers having decreased Shore hardness and modulus on the surface in contact with the substrate as compared to the surface exposed to atmospheric moisture.
摘要翻译：具有至少一个烃基的有机硅化合物通过氧原子与至少75％的硅原子连接，其中烃基具有至少一个羟基并且可以再次通过相同的硅原子或另一个硅原子经由将氧原子加入到室温可固化的有机基聚硅氧烷组合物中以形成耐垂直表面流动的组合物。当这些组合物在室温下暴露于大气水分时，与形成暴露于大气湿度的表面相比，它们形成具有与基材接触的表面上肖氏硬度和模量降低的弹性体。

2. 发明授权

US06531621B1 Organopolysiloxane materials which can be cross-linked by cleaving alcohols into elastomers 失效
标题翻译：可通过将醇裂解成弹性体而交联的有机聚硅氧烷材料
公开(公告)号：US06531621B1
公开(公告)日：2003-03-11
申请号：US09582143
申请日：2000-07-18
申请人： Norman Dorsch , Rudolf Heinrich , Oswin Sommer , Stefan Oberneder , Wolfgang Hechtl
发明人： Norman Dorsch , Rudolf Heinrich , Oswin Sommer , Stefan Oberneder , Wolfgang Hechtl
IPC分类号： C07F708
CPC分类号： C08G77/18 , C08G77/08 , C08G77/20 , C09K3/1018
摘要： The invention relates to a method for producing organopolysiloxane terminated with alkoxy groups, wherein A) organopolysiloxane terminated with HO is reacted with B) alkoxysilane having at least three alkoxy groups and/or whose partial hydrolysate is made to react in the presence of C) acid phosphoric acid ester of general formula (I): (HO)aOP(—O—[(CR12)b—O]c[(CR22)d]e—L—M)(3−a), wherein a=1 or 2; R1 and R2=a hydrogen, methyl or hydroxyl radical; b and d=2 or 3; c=integral values from 2 to 15; e=0 or 1; L=a radical from the group —O—, —COO—, —OOC—, —CONR3—, —NR4CO— and —CO—; R3 and R4=a hydrogen or a C1-C10-alkyl radical and M=a monovalent, optionally a hydroxyl, fluorine, chlorine, bromine, C1-C10-alkoxylalkyl or cyano group substituted C1- to C20-hydrocarbon radical, provided that the radicals R1 and R2 can only be at one given time a hydroxyl radical in each hydrocarbon atom. The invention further relates to RTV-1-alkoxy masses comprising the reaction product containing organopolysiloxane terminated with alkoxy groups as the essential constituent.
摘要翻译：本发明涉及一种制备用烷氧基封端的有机聚硅氧烷的方法，其中A）用HO封端的有机聚硅氧烷与B反应，B）具有至少三个烷氧基的烷氧基硅烷和/或其部分水解产物在C）酸存在下反应（I）的磷酸酯：（HO）aOP（-O - [（CR12）bO] c [（CR22）d] eLM）（3-a），其中a = 1或2; R1和R2 =氢，甲基或羟基; b和d = 2或3; c =从2到15的积分值; e = 0或1; L =从-O - ， - O - ， - OOC - ， - CONR 3 - ， - NR 4 CO - 和-CO - 基团的基团; R 3和R 4 =氢或C 1 -C 10 - 烷基，M =单价，任选的羟基，氟，氯，溴，C 1 -C 10 - 烷氧基烷基或氰基取代的C 1 -C 20烃基，条件是基团R 1和R 2只能在一个给定时间在每个烃原子中具有羟基。本发明还涉及包含以烷氧基为终点的有机聚硅氧烷作为必要成分的反应产物的RTV-1-烷氧基团。

3. 发明授权

US6011112A Organopolysiloxane compounds cross-linkable by cleaving of alcohols to form elastomers 失效
标题翻译：有机聚硅氧烷化合物可以通过裂解醇形成弹性体而可交联
公开(公告)号：US6011112A
公开(公告)日：2000-01-04
申请号：US43399
申请日：1998-03-23
申请人： Stefan Oberneder , Michael Stepp , Erich Pilzweger , Norman Dorsch
发明人： Stefan Oberneder , Michael Stepp , Erich Pilzweger , Norman Dorsch
IPC分类号： C08K5/54 , C08K5/544 , C08K5/5455 , C08L83/04 , C08K5/34
CPC分类号： C08K5/5442 , C08K5/5455 , C08L83/04 , C08G77/12 , C08G77/18
摘要： The invention relates to organopolysiloxane compounds which can be stored subject to the exclusion of moisture, can be cross-linked by cleaving of alcohols to form elastomers when moisture gains access at room temperature and are based on (A) polydiorganosiloxanes with organyloxy groups, optionally (B) organyloxy functional cross-linkers with at least three organyloxy groups, and optionally (C) condensation catalysts, characterised in that they contain at least one (D) compound selected from the compounds (D.sub.a) to (D.sub.f) given in claim 1.
摘要翻译： PCT No.PCT / EP96 / 04210 Sec。 371日期：1998年3月23日 102（e）1998年3月23日PCT PCT 1996年9月26日PCT公布。公开号WO97 / 12939 日期1997年04月10日本发明涉及可以在不排除水分的情况下储存的有机聚硅氧烷化合物，当在室温下进入湿气时，可以通过裂解醇形成弹性体，并且基于（A）聚二有机硅氧烷与（B）具有至少三个有机氧基的有机氧基官能交联剂和任选的（C）缩合催化剂，其特征在于它们含有至少一种选自化合物（Da）至（Df）的化合物（D）如权利要求1所述。

4. 发明授权

US5412015A Sealing compositions containing polymers of ethylenically unsaturated monomers 失效
标题翻译：含有烯属不饱和单体聚合物的密封组合物
公开(公告)号：US5412015A
公开(公告)日：1995-05-02
申请号：US126592
申请日：1993-09-27
申请人： Oswin Sommer , Michel Dubois , Norman Dorsch , Alois Strasser
发明人： Oswin Sommer , Michel Dubois , Norman Dorsch , Alois Strasser
IPC分类号： C08F20/00 , C08F20/10 , C08L33/06 , C08L83/04 , C08L83/07 , C09K3/10 , C08K3/26
CPC分类号： C09K3/1018 , C08L33/06 , C08L83/04 , C09K2200/0239 , C09K2200/0615 , C09K2200/0625
摘要： Sealing compositions containing dispersions of polymers of ethylenically unsaturated monomers comprising(a) polymers of ethylenically unsaturated monomers,(b) 0.1 to 5% by weight of branched organopolysiloxanes, based on the total weight of the sealing compositions,(c) dispersing agent,(d) filler and(e) water.
摘要翻译：其包含烯属不饱和单体聚合物的分散体，其包含（a）烯属不饱和单体的聚合物，（b）基于密封组合物的总重量为0.1-5重量％的支链有机聚硅氧烷，（c）分散剂，（ d）填料和（e）水。

5. 发明授权

US4968760A Paintable organopolysiloxane compositions which crosslink at room temperature to form elastomers 失效
标题翻译：可室外有机聚硅氧烷组合物，其在室温下交联以形成弹性体
公开(公告)号：US4968760A
公开(公告)日：1990-11-06
申请号：US318993
申请日：1989-03-06
申请人： August Schiller , Norman Dorsch , Werner Graf , Karl Braunsperger
发明人： August Schiller , Norman Dorsch , Werner Graf , Karl Braunsperger
IPC分类号： C08J3/24 , C08G77/14 , C08G77/26 , C08G77/38 , C08K5/5419 , C08K5/544 , C08K5/5465 , C08L83/04 , C08L83/06 , C08L83/08 , C09D183/04 , C09D183/06 , C09J183/00 , C09J183/06 , C09K3/10
CPC分类号： C08L83/04 , C08G77/045 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/26 , C08G77/28 , Y10S528/901
摘要： Organopolysiloxane compositions which crosslink at room temperature to form paintable elastomers containing (3) an organopolysiloxane having SiC-bonded radicals with a basic nitrogen and/or (4) a branched organopolysiloxane.
摘要翻译：在室温下交联以形成可涂覆的弹性体的有机聚硅氧烷组合物，其包含（3）具有与SiC键合的基团与/或（4）支化的有机聚硅氧烷的有机聚硅氧烷。

6. 发明授权

US06303678B1 Storage-stable organopolysiloxane compositions which can be crosslinked to give elastomers with elimination of alcohols 有权
标题翻译：存储稳定的有机聚硅氧烷组合物，其可以交联以产生具有消除醇的弹性体
公开(公告)号：US06303678B1
公开(公告)日：2001-10-16
申请号：US09523861
申请日：2000-03-14
申请人： Wolfgang Ziche , Norman Dorsch , Susanne Straussberger , Wolfgang Hechtl
发明人： Wolfgang Ziche , Norman Dorsch , Susanne Straussberger , Wolfgang Hechtl
IPC分类号： C08L1900
CPC分类号： C08K5/57 , C08G77/12 , C08G77/18 , C08L83/04 , C08L2666/14 , C08L2666/52
摘要： Stable RTV-1-alkoxy compositions contain a tin catalyst and surfactants (S) which contain divalent polyether units of the general formula (I) —O—[(CR&agr;R&bgr;)u—O]v— (I) in which R&agr; and R&bgr; are hydrogen or a monovalent C1-C10-hydrocarbon radical optionally substituted by hydroxyl, fluorine, chlorine, bromine, C1-C10-alkoxyalkyl or cyano groups, u is from 1 to 6 and v is from 3 to 100. The compositions are stable despite the presence of the tin catalyst and alkoxy-functional organosilicon compounds.
摘要翻译：稳定的RTV-1-烷氧基组合物含有锡催化剂和含有通式（I）的二价聚醚单元的表面活性剂（S），其中R a和R beta是氢或任意被羟基，氟取代的一价C1-C10-烃基，氯，溴，C 1 -C 10 - 烷氧基烷基或氰基，u为1至6，v为3至100.尽管存在锡催化剂和烷氧基官能的有机硅化合物，组合物是稳定的。

7. 发明授权

US06254811B1 Organopolysilozane compositions crosslinkable with elimination of alcohols to give elastomer 失效
标题翻译：有机聚硅氮烷组合物可与消除醇反应得到弹性体
公开(公告)号：US06254811B1
公开(公告)日：2001-07-03
申请号：US09452582
申请日：1999-12-01
申请人： Christian Finger , Norman Dorsch , Wolfgang Hechtl , Christian Baumgartner , Alfred Heinrich
发明人： Christian Finger , Norman Dorsch , Wolfgang Hechtl , Christian Baumgartner , Alfred Heinrich
IPC分类号： E04B168
CPC分类号： C08K5/521 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/24 , C08G77/26 , C08L83/04 , C08L83/00 , C08L2666/28
摘要： Alkoxy RTV-1 compositions comprise the product of the reaction of (A) an HO-terminated organopolysiloxane, (B1) an alkoxysilane which has at least three alkoxy groups and/or its partial hydrolysates, and (B2) an alkoxysilane which has two alkoxy groups and/or its partial hydrolysates, in the presence of (C) an acid phosphoric ester of the general formula (I) (HO)aOP(—O—[(CR12)b—O]c[(CR22)d]e—L—M)(3−a) (I), where a is 1 or 2, R1 and R2 are a hydrogen radical, methyl radical or hydroxyl radical, b and d are 2 or 3, c is an integer from 2 to 15, e is 0 or 1 L comprises a radical —O—, —COO—, —OOC—, —CONR3—, —NR4CO— or —CO—, R3 and R4 are a hydrogen radical or C1-C10-alkyl radical, and M is a monovalent, unsubstituted or hydroxyl-, fluorine-, chlorine-, bromine-, C1-C10-alkoxyalkyl- or cyano-substituted C1-C20-hydrocarbon radical, with the proviso that on any given carbon atom not more than one radical R1 and R2 may be a hydroxyl radical.
摘要翻译：烷氧基RTV-1组合物包含（A）HO封端的有机聚硅氧烷，（B1）具有至少三个烷氧基的烷氧基硅烷和/或其部分水解产物的反应的产物和（B2）具有两个烷氧基的烷氧基硅烷基团和/或其部分水解产物在（C）通式（I）的酸式磷酸酯的存在下，其中1或2，R 1和R 2是氢基，甲基或羟基，b和d是 2或3，c为2至15的整数，e为0或1L包含-O - ， - COO - ， - OOC - ， - CONR 3 - ， - NR 4 CO-或-CO- - 基，R 3和R 4为氢或C 1 -C 10 - 烷基，M是单价，未取代或羟基，氟，氯，溴，C 1 -C 10 - 烷氧基烷基或氰基取代的C 1 -C 20烃基，条件是在任何给定的碳原子上不超过一个基团R 1和R 2可以是羟基。

8. 发明授权

US4944989A Compositions which crosslink in the presence of moisture at room temperature to form elastomers 失效
标题翻译：在室温下在水分存在下交联以形成弹性体的组合物
公开(公告)号：US4944989A
公开(公告)日：1990-07-31
申请号：US255234
申请日：1988-10-11
申请人： Norman Dorsch
发明人： Norman Dorsch
IPC分类号： C03C27/10 , C08K5/5435 , C08K5/549 , C08L83/04 , C09J183/00 , C09J183/04 , C09K3/10
CPC分类号： C08K5/549 , C09J183/04 , Y10S528/901 , Y10T428/249991 , Y10T428/249992 , Y10T428/31612 , Y10T428/31663
摘要： Compositions which can be stored in the absence of moisture, but crosslink in the presence of moisture at room temperature to form elastomers comprising a diorganopolysiloxane having terminal condensable groups, a silicon compound having at least three hydrolyzable groups bonded directly to silicon per molecule, an average of at least one acyloxy group being present as a hydrolyzable group per silicon atom in the silicon compound, and an organosilicon compound having at least one vicinal epoxy group, in which at least part of the organosilicon compound containing at least one vicinal epoxy group is a cyclic diorganopolysiloxane. These compositions are prepared by mixing under anhydrous conditions a diorganopolysiloxane having terminal condensable groups with a silicon compound having at least three hydrolyzable groups bonded directly to silicon per molecule, an average of at least one acyloxy group being present as a hydrolyzable group per silicon atom in the silicon compound and an organosilicon compound having at least one vicinal epoxy group, in which at least part of the organosilicon compound containing at least one vicinal epoxy group is a cyclic diorganopolysiloxane.
摘要翻译：组合物，其可以在没有水分的情况下储存，但在室温下存在水分时交联以形成包含具有末端可缩合基团的二有机聚硅氧烷的弹性体，具有至少三个可水解基团的硅化合物，每个分子直接与硅键合，平均存在至少一个酰氧基作为硅化合物中的每个硅原子的可水解基团存在，以及具有至少一个邻位环氧基的有机硅化合物，其中至少一部分含有至少一个邻位环氧基的有机硅化合物为环状二有机聚硅氧烷。这些组合物是通过在无水条件下混合具有末端可缩合基团的二有机聚硅氧烷与每分子具有至少三个直接键合至硅的可水解基团的硅化合物，平均每个硅原子存在至少一个酰氧基作为可水解基团硅化合物和具有至少一个邻位环氧基的有机硅化合物，其中至少一部分含有至少一个邻位环氧基的有机硅化合物是环状二有机聚硅氧烷。

9. 发明授权

US4460761A Organopolysiloxane compositions which are stable under anhydrous conditions and elastomers formed therefrom 失效
标题翻译：在无水条件下稳定的有机聚硅氧烷组合物和由其形成的弹性体
公开(公告)号：US4460761A
公开(公告)日：1984-07-17
申请号：US466255
申请日：1983-02-14
申请人： August Schiller , Norman Dorsch
发明人： August Schiller , Norman Dorsch
IPC分类号： C09K3/10 , C08G77/38 , C08K5/57 , C08L83/00 , C08L83/04 , C08L101/10 , C08G77/06
CPC分类号： C08K5/57
摘要： Compositions which are stable when stored under anhydrous conditions, but which crosslink to form elastomers when exposed to moisture at room temperature are prepared by mixing (1) a diorganopolysiloxane having terminal condensable groups, with (2) a silicon compound containing at least three groups per molecule selected from amino groups which are bonded to silicon via nitrogen, oxime groups which are bonded to silicon via oxygen or mixtures thereof and (3) a product which is obtained from the reaction of (a) a silane containing as hydrolyzable groups at least two monovalent hydrocarbon radicals per molecule which are bonded to silicon via oxygen in which the monovalent hydrocarbon radicals may be interrupted by at least one ether-oxygen, or an oligomer thereof, with (b) a diorganotin diacylate, in which all the valences of the tin atom in the reaction product are saturated by SnC-bonded monovalent radicals or by oxygen atoms of the .tbd.SiOSn.tbd. group.
摘要翻译：通过将（1）具有末端可缩合基团的二有机基聚硅氧烷与（2）含有至少三个基团的硅化合物混合，制备在室温下暴露于水分时交联形成弹性体时稳定的组合物选自经由氮键合到硅的氨基的分子，通过氧或其混合物与硅键合的肟基和（3）从（a）含有至少两个可水解基团的硅烷的反应得到的产物通过氧，其中单价烃基可以被至少一个醚 - 氧或其低聚物与（b）二有机锡二酰化物中间体的氧连接到硅上，每分子中的单价烃基，其中锡的全部化合价反应产物中的原子被SnC键合的一价基团或3BOND SiOSn 3BOND基团的氧原子饱和。

10. 发明授权

US4426474A Organopolysiloxane compositions and elastomers formed therefrom 失效
标题翻译：有机聚硅氧烷组合物和由其形成的弹性体
公开(公告)号：US4426474A
公开(公告)日：1984-01-17
申请号：US372905
申请日：1982-04-29
申请人： Oswin Sommer , Norman Dorsch , Erhard Bosch , August Schiller , Alois Strasser
发明人： Oswin Sommer , Norman Dorsch , Erhard Bosch , August Schiller , Alois Strasser
IPC分类号： C08L83/00 , C08K5/00 , C08K5/17 , C08K5/54 , C08L83/04 , C08L83/06
CPC分类号： C08K5/17 , C08L83/04 , C08G77/26 , Y10S528/901
摘要： Compositions which can be stored under anhydrous conditions but when exposed to moisture crosslink at room temperature to form elastomers, comprising a diorganopolysiloxane having terminal condensable groups, a silicon compound containing at least three hydrolyzable groups per molecule which are bonded to silicon, and an alkylenediamine in which at least one hydrogen atom that is bonded to a nitrogen atom of the alkylenediamine is substituted with a polyalkylene oxide.
摘要翻译：可以在无水条件下存储但暴露于水分时在室温下交联以形成弹性体的组合物，其包含具有末端可缩合基团的二有机聚硅氧烷，每分子中含有至少三个可水解基团的硅化合物，其与硅键合，其中与亚烷基二胺的氮原子键合的至少一个氢原子被聚环氧烷取代。

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