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1. 发明授权

US4968760A Paintable organopolysiloxane compositions which crosslink at room temperature to form elastomers 失效
标题翻译：可室外有机聚硅氧烷组合物，其在室温下交联以形成弹性体
公开(公告)号：US4968760A
公开(公告)日：1990-11-06
申请号：US318993
申请日：1989-03-06
申请人： August Schiller , Norman Dorsch , Werner Graf , Karl Braunsperger
发明人： August Schiller , Norman Dorsch , Werner Graf , Karl Braunsperger
IPC分类号： C08J3/24 , C08G77/14 , C08G77/26 , C08G77/38 , C08K5/5419 , C08K5/544 , C08K5/5465 , C08L83/04 , C08L83/06 , C08L83/08 , C09D183/04 , C09D183/06 , C09J183/00 , C09J183/06 , C09K3/10
CPC分类号： C08L83/04 , C08G77/045 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/26 , C08G77/28 , Y10S528/901
摘要： Organopolysiloxane compositions which crosslink at room temperature to form paintable elastomers containing (3) an organopolysiloxane having SiC-bonded radicals with a basic nitrogen and/or (4) a branched organopolysiloxane.
摘要翻译：在室温下交联以形成可涂覆的弹性体的有机聚硅氧烷组合物，其包含（3）具有与SiC键合的基团与/或（4）支化的有机聚硅氧烷的有机聚硅氧烷。

2. 发明授权

US5597882A Tin compound-containing compositions as one of the two components of two component systems which crosslink at room temperature to give organopolysiloxane elastomers 失效
标题翻译：含锡化合物的组合物作为双组分体系的两种组分之一，其在室温下交联以得到有机聚硅氧烷弹性体
公开(公告)号：US5597882A
公开(公告)日：1997-01-28
申请号：US240742
申请日：1994-09-06
申请人： August Schiller , Norman Dorsch , Werner Graf , Alois Strasser
发明人： August Schiller , Norman Dorsch , Werner Graf , Alois Strasser
IPC分类号： C07F7/22 , C08K5/544 , C08K5/57 , C08L83/04 , C08L83/14 , C08G77/06
CPC分类号： C08K5/57 , C07F7/2252 , C08L83/04 , C08G77/18 , C08G77/20 , C08G77/24
摘要： The compositions proposed contain, as their main constituents,(a) a diorganopolysiloxane with triorganosiloxy groups as terminal groups, the organic groups being hydrocarbon groups which may be halogenated,(b) the reaction product of a diacylated diorganotin compound with a disilaalkane containing, per molecule, at least two monovalent hydrocarbon groups which are bonded to silicon via oxygen and may optionally be substituted by an alkoxy group, or with an oligomer of such a disilaalkane,(c) an organosilicon compound containing, per molecule, at least one amino or amino group bonded to silicon via carbon,(d) optionally, a filler and(e) optionally, a disilaalkane and/or silane containing, per molecule, at least three monovalent hydrocarbon groups which are bonded to silicon via oxygen and may optionally be substituted by an alkoxy group, or an oligomer of such a disilaalkane and/or silane.
摘要翻译：所提出的组合物作为其主要成分包含（a）具有三有机甲硅烷氧基作为端基的二有机聚硅氧烷，有机基团可以被卤化的烃基，（b）二酰基二有机锡化合物与二硫代烷烃的反应产物分子，至少两个通过氧连接到硅上并可任选地被烷氧基取代的单价烃基，或与二恶烷的低聚物结合的（c）每分子含有至少一个氨基或氨基通过碳与硅键合，（d）任选的填料和（e）任选的二烷基和/或硅烷，每分子含有至少三个一价烃基，其通过氧连接到硅上，并且可以任选被取代通过烷氧基，或这种二吡烷和/或硅烷的低聚物。

3. 发明授权

US4503210A Oxime containing compositions which crosslink in the presence of moisture to form elastomers at room temperature 失效
标题翻译：含肟的组合物在水分存在下交联以在室温下形成弹性体
公开(公告)号：US4503210A
公开(公告)日：1985-03-05
申请号：US573735
申请日：1984-01-25
申请人： G/u/ nter Von Au , Karl-Heinrich Wegehaupt , August Schiller , Karl Braunsperger
发明人： G/u/ nter Von Au , Karl-Heinrich Wegehaupt , August Schiller , Karl Braunsperger
IPC分类号： C08L83/00 , C08K5/5465 , C08L83/04 , C08G77/04
CPC分类号： C08L83/04 , C08G77/14 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/70 , Y10S528/901
摘要： Compositions which are stable in the absence of moisture, but crosslink to form elastomers in the presence of moisture at room temperature comprising a diorganopolysiloxane having terminal condensable groups and a silicon compound having at least three oxime groups per molecule bonded to silicon via oxygen, in which a mixture containing a silane having four oxime groups bonded to a silicon atom via oxygen, and a silane having a hydrocarbon radical bonded to a silicon atom via a SiC-bonding and having three oxime groups bonded to the silicon atom via oxygen, or an oligomer of the silane mixture is substituted for at least a portion of the silicon compound having at least three oxime groups per molecule bonded to silicon via oxygen.
摘要翻译：在不存在水分的情况下稳定但在室温下存在水分时形成弹性体的组合物包含具有末端可缩合基团的二有机聚硅氧烷和每分子具有至少三个肟基团的硅化合物通过氧与硅键合，其中含有具有通过氧连接到硅原子的具有四个肟基的硅烷的混合物，以及具有通过SiC键合键合到硅原子的烃基并具有通过氧连接到硅原子上的三个肟基的硅烷或低聚物的硅烷混合物的至少一部分取代至少一部分每分子具有至少三个肟基团的硅化合物，其通过氧与硅键合。

4. 发明授权

US4191817A Curable compositions and elastomers prepared therefrom 失效
标题翻译：可固化组合物和由其制备的弹性体
公开(公告)号：US4191817A
公开(公告)日：1980-03-04
申请号：US925909
申请日：1978-07-19
申请人： August Schiller , Eckhart Louis , Erhard Bosch , Karl Braunsperger
发明人： August Schiller , Eckhart Louis , Erhard Bosch , Karl Braunsperger
IPC分类号： C08L83/00 , C08L83/04 , C08G77/26
CPC分类号： C08L83/04 , C08G77/045 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/26 , C08G77/46 , Y10S528/901 , Y10T428/31612 , Y10T428/31663 , Y10T428/31678
摘要： Curable compositions which can be stored under anhydrous conditions, but when exposed to atmospheric moisture cross-link to form elastomers, which consists of (1) a diorganopolysiloxane having terminal condensable groups, (2) a silicon compound containing at least three hydrolyzable groups per molecule in which the hydrolyzable groups are amino groups bonded to silicon via nitrogen and/or oxime groups bonded to silicon via oxygen and (3) at least one additional component which improves adhesion of the elastomers obtained from said compositions to substrates, in which the additional component (3) is an organosilicon compound containing at least one siloxane-oxygen atom and at least one amino group which is bonded to silicon by carbon.
摘要翻译：可固化的组合物可以在无水条件下储存，但当暴露于大气中的水分交联形成弹性体时，其由（1）具有末端可缩合基团的二有机聚硅氧烷，（2）每分子含有至少三个可水解基团的硅化合物其中所述可水解基团是通过经由氧键接到硅上的氮和/或肟基团与硅结合的氨基，和（3）至少一种另外的组分，其改善了由所述组合物获得的弹性体对底物的粘合性，其中附加组分（3）是含有至少一个硅氧烷 - 氧原子和至少一个与碳键合的氨基的有机硅化合物。

5. 发明授权

US4460761A Organopolysiloxane compositions which are stable under anhydrous conditions and elastomers formed therefrom 失效
标题翻译：在无水条件下稳定的有机聚硅氧烷组合物和由其形成的弹性体
公开(公告)号：US4460761A
公开(公告)日：1984-07-17
申请号：US466255
申请日：1983-02-14
申请人： August Schiller , Norman Dorsch
发明人： August Schiller , Norman Dorsch
IPC分类号： C09K3/10 , C08G77/38 , C08K5/57 , C08L83/00 , C08L83/04 , C08L101/10 , C08G77/06
CPC分类号： C08K5/57
摘要： Compositions which are stable when stored under anhydrous conditions, but which crosslink to form elastomers when exposed to moisture at room temperature are prepared by mixing (1) a diorganopolysiloxane having terminal condensable groups, with (2) a silicon compound containing at least three groups per molecule selected from amino groups which are bonded to silicon via nitrogen, oxime groups which are bonded to silicon via oxygen or mixtures thereof and (3) a product which is obtained from the reaction of (a) a silane containing as hydrolyzable groups at least two monovalent hydrocarbon radicals per molecule which are bonded to silicon via oxygen in which the monovalent hydrocarbon radicals may be interrupted by at least one ether-oxygen, or an oligomer thereof, with (b) a diorganotin diacylate, in which all the valences of the tin atom in the reaction product are saturated by SnC-bonded monovalent radicals or by oxygen atoms of the .tbd.SiOSn.tbd. group.
摘要翻译：通过将（1）具有末端可缩合基团的二有机基聚硅氧烷与（2）含有至少三个基团的硅化合物混合，制备在室温下暴露于水分时交联形成弹性体时稳定的组合物选自经由氮键合到硅的氨基的分子，通过氧或其混合物与硅键合的肟基和（3）从（a）含有至少两个可水解基团的硅烷的反应得到的产物通过氧，其中单价烃基可以被至少一个醚 - 氧或其低聚物与（b）二有机锡二酰化物中间体的氧连接到硅上，每分子中的单价烃基，其中锡的全部化合价反应产物中的原子被SnC键合的一价基团或3BOND SiOSn 3BOND基团的氧原子饱和。

6. 发明授权

US4426474A Organopolysiloxane compositions and elastomers formed therefrom 失效
标题翻译：有机聚硅氧烷组合物和由其形成的弹性体
公开(公告)号：US4426474A
公开(公告)日：1984-01-17
申请号：US372905
申请日：1982-04-29
申请人： Oswin Sommer , Norman Dorsch , Erhard Bosch , August Schiller , Alois Strasser
发明人： Oswin Sommer , Norman Dorsch , Erhard Bosch , August Schiller , Alois Strasser
IPC分类号： C08L83/00 , C08K5/00 , C08K5/17 , C08K5/54 , C08L83/04 , C08L83/06
CPC分类号： C08K5/17 , C08L83/04 , C08G77/26 , Y10S528/901
摘要： Compositions which can be stored under anhydrous conditions but when exposed to moisture crosslink at room temperature to form elastomers, comprising a diorganopolysiloxane having terminal condensable groups, a silicon compound containing at least three hydrolyzable groups per molecule which are bonded to silicon, and an alkylenediamine in which at least one hydrogen atom that is bonded to a nitrogen atom of the alkylenediamine is substituted with a polyalkylene oxide.
摘要翻译：可以在无水条件下存储但暴露于水分时在室温下交联以形成弹性体的组合物，其包含具有末端可缩合基团的二有机聚硅氧烷，每分子中含有至少三个可水解基团的硅化合物，其与硅键合，其中与亚烷基二胺的氮原子键合的至少一个氢原子被聚环氧烷取代。

7. 发明授权

US4399267A Organopolysiloxanes having retarded skin formation 失效
标题翻译：有机聚硅氧烷延缓皮肤形成
公开(公告)号：US4399267A
公开(公告)日：1983-08-16
申请号：US401809
申请日：1982-07-26
申请人： Erhard Bosch , Ingo Craubner , Norman Dorsch , August Schiller , Oswin Sommer
发明人： Erhard Bosch , Ingo Craubner , Norman Dorsch , August Schiller , Oswin Sommer
IPC分类号： C09K3/10 , C08K5/5415 , C08K5/544 , C08L83/00 , C08L83/04 , C08G77/22
CPC分类号： C08K5/54 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/26 , C08G77/28 , Y10S528/901
摘要： The invention relates to organopolysiloxane compositions which are stable when stored under anhydrous conditions, but when exposed to moisture cure to an elastomer containing (a) a diorganopolysiloxane having terminal condensable groups, (b) a silicon compound having 3 amino groups bonded to silicon via nitrogen and/or oxime groups bonded to silicon via oxygen per molecule and (c) a silicon compound having at least one thiol group selected from mercapto-functional silanes or siloxanes. The presence of the mercapto-functional silanes or siloxanes substantially retards the formation of skin but does not substantially extend the cure time of the organopolysiloxanes compositions. These compositions are useful in, for example, screen printing, where a long skin-over time is desired.
摘要翻译：本发明涉及有机聚硅氧烷组合物，其在无水条件下储存时是稳定的，但当暴露于水分固化至含有（a）具有末端可缩合基团的二有机聚硅氧烷的弹性体时，（b）具有3个氨基的硅化合物通过氮键接到硅上，和/或每分子通过氧键连接至硅的肟基团和（c）具有至少一个选自巯基官能硅烷或硅氧烷的硫醇基团的硅化合物。巯基官能硅烷或硅氧烷的存在基本上延缓了皮肤的形成，但基本上延长了有机聚硅氧烷组合物的固化时间。这些组合物可用于例如期望丝网印刷长时间的丝网印刷。

8. 发明授权

US4230826A Organopolysiloxane compositions and elastomers formed therefrom 失效
标题翻译：有机聚硅氧烷组合物和由其形成的弹性体
公开(公告)号：US4230826A
公开(公告)日：1980-10-28
申请号：US33280
申请日：1979-04-25
申请人： Oswin Sommer , August Schiller , Norman Dorsch , Alois Strasser
发明人： Oswin Sommer , August Schiller , Norman Dorsch , Alois Strasser
IPC分类号： C08L83/00 , C08L1/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L83/04 , C08L83/06 , C08L33/20
CPC分类号： C08L83/04 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/70
摘要： Compositions which are stable when stored under anhydrous conditions, but when exposed to atmospheric moisture cross-link to form elastomers comprising (1) an organopolysiloxane having terminal condensable groups, (2) a silicon compound having at least 3 Si-bonded hydrolyzable groups per molecule and (3) from 30 to 100 percent by weight, based on the weight of the organopolysiloxane (1), of a powder obtained from the homopolymerization or copolymerization of an acrylonitrile in an aqueous medium.
摘要翻译：当在无水条件下储存时，但当暴露于大气中的水分交联以形成弹性体时，它们是稳定的组合物，其包含（1）具有末端可缩合基团的有机聚硅氧烷，（2）每个分子具有至少3个Si键合的可水解基团的硅化合物和（3）基于有机基聚硅氧烷（1）的重量，30至100重量％的由在水性介质中丙烯腈的均聚或共聚获得的粉末。

9. 发明授权

US4147855A Organopolysiloxane compositions and elastomers obtained therefrom 失效
标题翻译：有机聚硅氧烷组合物和由其获得的弹性体
公开(公告)号：US4147855A
公开(公告)日：1979-04-03
申请号：US846281
申请日：1977-10-28
申请人： August Schiller , Norman Dorsch , Owsin Sommer
发明人： August Schiller , Norman Dorsch , Owsin Sommer
IPC分类号： C08L83/00 , C08K5/521 , C08L83/04 , C09D5/25 , C08G77/04
CPC分类号： C08K5/521 , C08K3/22 , C08K3/36 , C08K5/52 , C08K5/54 , C08G77/16 , Y10S528/901
摘要： This invention relates to compositions which can be stored under anhydrous conditions, but when exposed to atmospheric moisture cure at room temperature to form elastomers. These compositions contain a diorganopolysiloxane having terminal condensable groups, a silicon compound having at least one nitrogen atom and at least three hydrolyzable groups per molecule, a reinforcing filler and a phosphoric acid ester. These compositions have improved stability and improved flow properties. Elastomers prepared from these compositions when compared with known compositions, have lower modulus values at 100 percent elongation.
摘要翻译：本发明涉及可以在无水条件下储存的组合物，但当暴露于大气湿度下在室温下固化形成弹性体时。这些组合物含有具有末端可缩合基团的二有机聚硅氧烷，每分子具有至少一个氮原子和至少三个可水解基团的硅化合物，增强填料和磷酸酯。这些组合物具有改进的稳定性和改善的流动性能。与已知组合物相比，由这些组合物制备的弹性体在100％伸长率下具有较低的模量值。

10. 发明授权

US4296228A Room temperature curable compositions 失效
标题翻译：室温固化组合物
公开(公告)号：US4296228A
公开(公告)日：1981-10-20
申请号：US126230
申请日：1980-03-03
申请人： Ernst Innertsberger , Oswin Sommer , Erhard Bosch , Johann Muller , August Schiller
发明人： Ernst Innertsberger , Oswin Sommer , Erhard Bosch , Johann Muller , August Schiller
IPC分类号： C08L83/04 , C08G77/04
CPC分类号： C08K5/54 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/44 , C08G77/70 , Y10S528/901
摘要： Room temperature curable compositions, which can be stored under anhydrous conditions, but when exposed to atmospheric moisture at room temperature cure to an elastomer comprising a diorganopolysiloxane having terminal condensable groups, a silicon compound containing acetoxy, tert-butoxy and SiC-bonded alkyl groups and a condensation catalyst, if desired, in which at least a portion of the silicon compound containing acetoxy, tert-butoxy and SiC-bonded alkyl groups is obtained from the reaction of an alkyltriacetoxysilane and tert-butanol in aqueous acetic acid.
摘要翻译：室温可固化组合物，其可以在无水条件下储存，但是当暴露于常温水分时在室温下固化到包含具有末端可缩合基团的二有机聚硅氧烷，含有乙酰氧基，叔丁氧基和与SiC键合的烷基的硅化合物的弹性体，以及如果需要，缩合催化剂，其中至少一部分含有乙酰氧基，叔丁氧基和与SiC键合的烷基的硅化合物是由烷基三乙酰氧基硅烷和叔丁醇在乙酸水溶液中的反应得到的。

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