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1. 发明授权

US07973088B2 Polymer electrolyte membrane, method for producing the same, and proton conductivity evaluation method for polymer electrolyte membrane 有权
标题翻译：聚合物电解质膜，其制造方法，高分子电解质膜的质子传导性评价方法
公开(公告)号：US07973088B2
公开(公告)日：2011-07-05
申请号：US11843839
申请日：2007-08-23
申请人： Junichi Ikeuchi , Mitsunori Nodono , Yasuhiro Yamashita
发明人： Junichi Ikeuchi , Mitsunori Nodono , Yasuhiro Yamashita
IPC分类号： C08J5/20 , C08J3/00 , B01J39/00 , B05D1/00
CPC分类号： C08J5/2256 , C08G2261/126 , C08J2381/06 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M8/1081 , H01M2300/0082 , Y02P70/56
摘要： The present invention provides a polymer electrolyte membrane with excellent proton conductivity in its thickness direction. Preferably, the polymer electrolyte membrane containing a polymer compound comprising an ionic segment having an ionic functional group and a nonionic segment having substantially no ionic functional group, and the phase containing ionic segments as a main component and the phase containing nonionic segments as a main component are phase-separated, and in the surface region thereof, the change in the amount of the ionic segment from the surface toward the interior substantially decreases monotonically.
摘要翻译：本发明提供一种在其厚度方向上具有优异的质子传导性的聚合物电解质膜。优选的是，含有具有离子性官能团的离子性部分和基本上不具有离子性官能团的非离子部分的高分子化合物和含有离子性部分作为主要成分的相的高分子电解质膜和含有非离子性部分作为主要成分的相相分离，并且在其表面区域中，离子区段从表面朝向内部的量的变化基本上单调减小。

2. 发明授权

US06600143B2 Formed polypropylene resin container for microwave cooking 失效
标题翻译：用于微波烹饪的聚丙烯树脂容器
公开(公告)号：US06600143B2
公开(公告)日：2003-07-29
申请号：US09993679
申请日：2001-11-27
申请人： Satoshi Hanada , Mitsunori Nodono , Ryuma Kuroda
发明人： Satoshi Hanada , Mitsunori Nodono , Ryuma Kuroda
IPC分类号： H05B680
CPC分类号： B32B5/18 , A47J36/027 , A47J36/04 , B65D81/3453 , Y10S99/14
摘要： An object of the present invention is to provide a foamed polypropylene resin container for microwave cooking which is free from deformation upon cooking by a microwave oven and excellent in heat resistance. The foamed polypropylene resin container for microwave cooking of the present invention, on at least one side of a foamed polypropylene resin layer, a non-foamed layer containing 100 parts by weight of a polypropylene resin and 40 to 100 parts by weight of talc.
摘要翻译：本发明的目的是提供一种用于微波烹饪的发泡聚丙烯树脂容器，其在通过微波炉烹饪时不变形，并且耐热性优异。本发明的微波烹调用发泡聚丙烯树脂容器，在发泡聚丙烯树脂层的至少一侧，含有100重量份聚丙烯树脂的非发泡层和40〜100重量份滑石。

3. 发明申请

US20070148518A1 Polymer electrolyte and use thereof 审中-公开
标题翻译：聚合物电解质及其用途
公开(公告)号：US20070148518A1
公开(公告)日：2007-06-28
申请号：US10583606
申请日：2004-12-21
申请人： Shigeru Sasaki , Toru Onodera , Arihiro Yashiro , Mitsunori Nodono
发明人： Shigeru Sasaki , Toru Onodera , Arihiro Yashiro , Mitsunori Nodono
IPC分类号： H01M8/10 , H01M10/40
CPC分类号： C08G65/48 , C08G75/23 , C08J5/2256 , C08J2365/02 , C08J2371/12 , H01B1/122 , H01M8/04197 , H01M8/1009 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1067 , H01M2300/0082
摘要： An aromatic polymer electrolyte that when directly used in a methanol fuel cell, excels in methanol shutoff, etc. There is provided a polymer electrolyte comprising polymer main chains containing oxygen elements and/or sulfur elements and aromatic carbon rings and, directly bonded to some or all of the aromatic carbon rings of the entirety of the polymer electrolyte including side chains, ion exchange groups, wherein the ratio (R) of the number of aromatic condensed polycyclic carbon rings to the total number of aromatic carbon rings of the entirety of the polymer electrolyte including side chains (sum of the number of aromatic monocyclic carbon rings and the number of aromatic condensed polycyclic carbon rings) satisfies the formula: 1>R≧0.15.
摘要翻译：一种直接用于甲醇燃料电池中的芳族聚合物电解质，具有优异的甲醇截止等优点。提供了包含含有氧元素和/或硫元素和芳族碳环的聚合物主链的聚合物电解质，并且直接键合到一些或包括侧链的整个聚合物电解质的所有芳族碳环，离子交换基团，其中芳族稠合多环碳环数与全部聚合物的芳族碳环总数的比率（R）包括侧链的电解质（芳族单环碳环的数目和芳族稠合多环碳环的数量之和）满足下式：1> R> = 0.15。

4. 发明授权

US06805930B2 Thermoplastic resin sheet and container 失效
标题翻译：热塑性树脂板和容器
公开(公告)号：US06805930B2
公开(公告)日：2004-10-19
申请号：US09820757
申请日：2001-03-30
申请人： Satoshi Hanada , Mitsunori Nodono , Ryuma Kuroda
发明人： Satoshi Hanada , Mitsunori Nodono , Ryuma Kuroda
IPC分类号： B29D2200
CPC分类号： B29C44/06 , B29C44/0461 , Y10T428/1376 , Y10T428/1397 , Y10T428/249953 , Y10T428/249978 , Y10T428/249979 , Y10T428/249981
摘要： The present invention provides a thermoplastic resin sheet having a thermoplastic resin expanded layer of which expansion ratio is in the range of 3 to 40 times, and cell wall density ratio is in the range of 2 to 20, said thermoplastic resin sheet having excellent thermal insulation property, and a container being formed from the thermoplastic resin sheet.
摘要翻译：本发明提供一种热塑性树脂发泡层，其发泡倍率在3〜40倍的范围内，细胞壁密度比在2〜20的范围内，所述热塑性树脂片具有优异的绝热性性质和由热塑性树脂片形成的容器。

5. 发明授权

US07862921B2 Process for continuously producing polymer electrolyte membrane and producing apparatus therefor 失效
标题翻译：连续生产聚合物电解质膜的方法及其制备方法
公开(公告)号：US07862921B2
公开(公告)日：2011-01-04
申请号：US10549921
申请日：2004-03-24
申请人： Mitsunori Nodono
发明人： Mitsunori Nodono
IPC分类号： H01M8/10
CPC分类号： H01M8/1081 , B01D67/0009 , B01D69/12 , B01D2323/06 , H01M8/0289 , H01M8/106 , H01M8/1062 , H01M8/1067 , H01M8/1093 , H01M2300/0094 , Y02P70/56
摘要： The present invention provides a process for producing a polymerelectrolyte membrane comprising the steps of coating a solution of a polymerelectrolyte on at least one surface of a porous substrate and laminating the coated porous substrate and a supporting material while applying a tension F (kg/cm) in a range of the following expression (A) 0.01≦F≦10 (A) to the coated porous substrate. According to the present invention, a polymerelectrolyte composite membrane in which wrinkling and the like are suppressed and whose appearance is excellent can be continuously produced.
摘要翻译：本发明提供一种生产聚电解质膜的方法，包括以下步骤：在多孔基材的至少一个表面上涂布聚电解质溶液，并在施加张力F（kg / cm）的同时层压涂覆的多孔基材和支撑材料，在下述表达式（A）的范围内，对于涂覆的多孔基材，其含量为0.01＆nlE; F＆nlE; 10（A）。根据本发明，可以连续地制造其中皱纹等被抑制并且其外观优异的聚电解质复合膜。

6. 发明申请

US20100081030A1 METHOD FOR PRODUCING POLYMER ELECTROLYTE MEMBRANE AND POLYMER ELECTROLYTE MEMBRANE 审中-公开
标题翻译：聚合物电解质膜和聚合物电解质膜的制备方法
公开(公告)号：US20100081030A1
公开(公告)日：2010-04-01
申请号：US12516314
申请日：2007-11-26
申请人： Mitsunori Nodono
发明人： Mitsunori Nodono
IPC分类号： H01M8/10 , B05D5/12
CPC分类号： H01B1/122 , C08G65/4012 , C08G75/23 , C08J5/2256 , C08J2381/06 , C08J2387/00 , C08J2471/12 , C08L2205/05 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M8/1067 , H01M8/1088 , H01M2008/1095 , H01M2300/0082 , Y02P70/56
摘要： A method for producing a polymer electrolyte membrane including: (i) a preparation step for preparing a polymer electrolyte solution by dissolving a polymer electrolyte containing an ion conductive polymer having an ion-exchange group in an organic solvent capable of dissolving the polymer electrolyte, (ii) a coating step for obtaining a polymer electrolyte membrane intermediate containing the ion conductive polymer by a solution casting method using the polymer electrolyte solution obtained in the step (i), and (iii) a washing step for washing the polymer electrolyte membrane intermediate obtained in the step (ii) by bringing the polymer electrolyte membrane intermediate into contact with a washing solvent; wherein the concentration of the organic solvent in the washing solvent brought into contact with the polymer electrolyte membrane intermediate in the washing step (iii) is 2500 ppm by weight or lower.
摘要翻译：一种高分子电解质膜的制造方法，其特征在于，具备：（i）将含有具有离子交换基团的离子导电性聚合物的高分子电解质溶解在能够溶解高分子电解质的有机溶剂中的高分子电解质溶液的制备工序， ii）通过使用在步骤（i）中获得的聚合物电解质溶液的溶液流延法获得含有离子导电聚合物的聚合物电解质膜中间体的涂布步骤，和（iii）用于洗涤所获得的聚合物电解质膜中间体的洗涤步骤在步骤（ii）中使聚合物电解质膜中间体与洗涤溶剂接触; 其中在洗涤步骤（iii）中与所述聚合物电解质膜中间体接触的洗涤溶剂中的有机溶剂的浓度为2500ppm重量或更低。

7. 发明申请

US20100035113A1 METHOD FOR PRODUCING POLYMER ELECTROLYTE MEMBRANE AND POLYMER ELECTROLYTE MEMBRANE 审中-公开
标题翻译：聚合物电解质膜和聚合物电解质膜的制备方法
公开(公告)号：US20100035113A1
公开(公告)日：2010-02-11
申请号：US12516329
申请日：2007-11-26
申请人： Mitsunori Nodono
发明人： Mitsunori Nodono
IPC分类号： H01M8/10 , H01M8/00
CPC分类号： H01B1/122 , C08G65/40 , C08G75/23 , C08J5/2256 , C08J2365/02 , C08J2381/02 , C08J2387/00 , C08L65/02 , C08L81/06 , C08L2205/05 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1081 , H01M8/1086 , Y02P70/56 , C08L2666/22
摘要： A method for continuously producing a polymer electrolyte membrane including: (i) a preparation step for preparing a polymer electrolyte solution by dissolving a polymer electrolyte containing an ion conductive polymer having an ion-exchange group in an organic solvent capable of dissolving the polymer electrolyte, (ii) a coating step for continuously obtaining a laminate film 1 wherein a supporting substrate and a layer containing an ion conductive polymer are laminated, by casting the polymer electrolyte solution obtained in the step (i) onto the continuously fed supporting substrate, and (iii) a drying step for continuously obtaining a laminate film 2 wherein the supporting substrate and a polymer electrolyte membrane intermediate are laminated, by removing the organic solvent remaining in the layer containing an ion conductive polymer with passing the laminate film 1 obtained in the step (ii) in a drying furnace; wherein the residence time of the laminate film 1 in the drying furnace in the step (iii) is 50 minutes or shorter and the remaining organic solvent concentration in the polymer electrolyte membrane intermediate in the laminate film 2 immediately after the laminate film 2 passes through the drying furnace is 40% by weight or lower.
摘要翻译：一种连续制造聚合物电解质膜的方法，包括：（i）通过将含有离子交换基团的离子导电聚合物的聚合物电解质溶解在能够溶解聚合物电解质的有机溶剂中来制备聚合物电解质溶液的制备步骤，（ii）通过将步骤（i）中得到的高分子电解质溶液浇铸到连续供给的支撑基板上，连续地获得层叠膜1的层叠膜1，其中支撑基板和含有离子导电聚合物的层被层压，并且（ iii）干燥步骤，通过将通过步骤获得的层压膜1除去残留在含有离子导电聚合物的层中的有机溶剂，从而连续获得其中支撑基材和聚合物电解质膜中间体的叠层膜2 ii）在干燥炉中; 其中，步骤（iii）中的层压膜1在干燥炉中的停留时间为50分钟以下，层叠膜2之后立即层叠膜2中的高分子电解质膜中间的剩余有机溶剂浓度通过干燥炉为40重量％以下。

8. 发明申请

US20070009776A1 Continuous process for producing polymer electrolyte membrane and apparatus therefor 失效
标题翻译：生产聚合物电解质膜的连续工艺及其设备
公开(公告)号：US20070009776A1
公开(公告)日：2007-01-11
申请号：US10549921
申请日：2004-03-24
申请人： Mitsunori Nodono
发明人： Mitsunori Nodono
IPC分类号： H01M8/10 , C08J5/22 , B05C11/00
CPC分类号： H01M8/1081 , B01D67/0009 , B01D69/12 , B01D2323/06 , H01M8/0289 , H01M8/106 , H01M8/1062 , H01M8/1067 , H01M8/1093 , H01M2300/0094 , Y02P70/56
摘要： The present invention provides a process for producing a polymerelectrolyte membrane comprising the steps of coating a solution of a polymerelectrolyte on at least one surface of a porous substrate and laminating the coated porous substrate and a supporting material while applying a tension F (kg/cm) in a range of the following expression (A) 0.01≦F≦10 (A) to the coated porous substrate. According to the present invention, a polymerelectrolyte composite membrane in which wrinkling and the like are suppressed and whose appearance is excellent can be continuously produced.
摘要翻译：本发明提供一种生产聚电解质膜的方法，包括以下步骤：在多孔基材的至少一个表面上涂布聚电解质溶液，并在施加张力F（kg / cm）的同时层压涂覆的多孔基材和支撑材料，在以下表达式（A）的范围内<？in-line-formula description =“In-line Formulas”end =“lead”？> 0.01 <= F <= 10（A）<？ =“内联式”末端=“尾”→涂覆的多孔基材。根据本发明，可以连续地制造其中皱纹等被抑制并且其外观优异的聚电解质复合膜。

9. 发明授权

US08273500B2 Polymer electrolyte composition and fuel cell 失效
标题翻译：聚合物电解质组成和燃料电池
公开(公告)号：US08273500B2
公开(公告)日：2012-09-25
申请号：US12680119
申请日：2008-09-25
申请人： Yasuhiro Yamashita , Diazaburo Yashiki , Mitsunori Nodono
发明人： Yasuhiro Yamashita , Diazaburo Yashiki , Mitsunori Nodono
IPC分类号： H01M8/10
CPC分类号： H01M8/1044 , C08G2650/40 , C08J5/2275 , C08J2371/00 , C08J2381/06 , C08L71/00 , C08L81/06 , H01B1/122 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1067 , H01M2300/0082 , Y02P70/56
摘要： A polymer electrolyte composition obtained by mixing a plurality of ion-conductive polymers, wherein if the ion-conductive polymer that is highest in ion exchange capacity among the plurality of ion-conductive polymers is termed first ion-conductive polymer, and the ion-conductive polymer that is lowest in ion exchange capacity is termed second ion-conductive polymer, then the first ion-conductive polymer and the second ion-conductive polymer are both block copolymers composed of a segment having an ion-exchange group and a segment having substantially no ion-exchange groups, and if the weight fraction of the segment having an ion-exchange group in the first ion-conductive polymer is termed Wh1, and the weight fraction of the segment having an ion-exchange group in the second ion-conductive polymer is termed Wh2, then the relations (I) and (II) listed below are satisfied: (I) Wh1>Wh2; (II) Wh1−Wh2≦0.25.
摘要翻译：通过混合多种离子传导性聚合物而获得的高分子电解质组合物，其中如果将多个离子传导性高分子中离子交换容量最高的离子导电性聚合物称为第1离子传导性高分子，则离子传导性聚合物离子交换容量最低的聚合物被称为第二离子导电聚合物，则第一离子导电聚合物和第二离子导电聚合物都是由具有离子交换基团的链段和基本上没有离子交换基团的链段组成的嵌段共聚物离子交换基团，并且如果在第一离子导电聚合物中具有离子交换基团的链段的重量分数称为Wh1，并且在第二离子导电聚合物中具有离子交换基团的链段的重量分数称为Wh2，则满足以下列出的关系（I）和（II）：（I）Wh1> Wh2; （II）Wh1-Wh2＆nlE; 0.25。

10. 发明申请

US20090325028A1 POLYMER ELECTROLYTE MEMBRANE, LAMINATE THEREOF, AND THEIR PRODUCTION METHODS 审中-公开
标题翻译：聚合物电解质膜及其制备方法
公开(公告)号：US20090325028A1
公开(公告)日：2009-12-31
申请号：US12310355
申请日：2007-08-23
申请人： Yasuhiro Yamashita , Mitsunori Nodono
发明人： Yasuhiro Yamashita , Mitsunori Nodono
IPC分类号： H01M8/10 , H01M8/00
CPC分类号： B29C39/18 , B29K2096/005 , B29L2031/755 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1055 , H01M8/1058 , H01M8/1067 , H01M8/1081 , H01M8/1093 , H01M2300/0082 , Y02P70/56
摘要： Provided is a method for producing a laminate in which an ion conductive polymer electrolyte membrane is laminated on a supporting substrate in a state where any one surface of the polymer electrolyte membrane is bonded to the supporting substrate, a difference in a contact angle against water between a first surface and a second surface of the surface of the ion conductive polymer electrolyte membrane being more than 30° in a case where the first surface is the side having a small contact angle against water of a membrane surface and the second surface is the side having a large contact angle against water of the membrane surface, the method includes the steps of:preparing a polymer electrolyte solution in which a polymer electrolyte containing an ion conductive polymer having an aromatic group in the main chain and/or the side chain, and also having an ion exchange group bonded directly to the aromatic group or bonded indirectly to the aromatic group with another atom or atomic group interposed therebetween is dissolved in a solvent; andapplying the polymer electrolyte solution on the supporting substrate by flow casting thereby laminating the polymer electrolyte membrane on the supporting substrate.
摘要翻译：本发明提供一种层叠体的制造方法，其中，将离子导电性聚合物电解质膜层叠在支撑基板上，在高分子电解质膜的任一面与支撑基板接合的状态下，与水的接触角的差异在第一表面是与膜表面的水接触角小的一侧的情况下，离子导电聚合物电解质膜的表面的第一表面和第二表面大于30°，第二表面是侧面该方法包括以下步骤：制备其中含有在主链和/或侧链具有芳族基团的离子导电聚合物的聚合物电解质的聚合物电解质溶液，以及也具有与芳族基团直接键合的离子交换基团或者与另一个原子或原子团间接与芳族基团键合的离子交换基团插入其中溶解在溶剂中; 并通过流延法将聚合物电解质溶液施加在支撑基底上，从而将聚合物电解质膜层压在支撑基底上。

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