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    • 1. 发明授权
    • Polymer electrolyte composition and fuel cell
    • 聚合物电解质组成和燃料电池
    • US08273500B2
    • 2012-09-25
    • US12680119
    • 2008-09-25
    • Yasuhiro YamashitaDiazaburo YashikiMitsunori Nodono
    • Yasuhiro YamashitaDiazaburo YashikiMitsunori Nodono
    • H01M8/10
    • H01M8/1044C08G2650/40C08J5/2275C08J2371/00C08J2381/06C08L71/00C08L81/06H01B1/122H01M8/1004H01M8/1025H01M8/1027H01M8/1032H01M8/1067H01M2300/0082Y02P70/56
    • A polymer electrolyte composition obtained by mixing a plurality of ion-conductive polymers, wherein if the ion-conductive polymer that is highest in ion exchange capacity among the plurality of ion-conductive polymers is termed first ion-conductive polymer, and the ion-conductive polymer that is lowest in ion exchange capacity is termed second ion-conductive polymer, then the first ion-conductive polymer and the second ion-conductive polymer are both block copolymers composed of a segment having an ion-exchange group and a segment having substantially no ion-exchange groups, and if the weight fraction of the segment having an ion-exchange group in the first ion-conductive polymer is termed Wh1, and the weight fraction of the segment having an ion-exchange group in the second ion-conductive polymer is termed Wh2, then the relations (I) and (II) listed below are satisfied: (I) Wh1>Wh2; (II) Wh1−Wh2≦0.25.
    • 通过混合多种离子传导性聚合物而获得的高分子电解质组合物,其中如果将多个离子传导性高分子中离子交换容量最高的离子导电性聚合物称为第1离子传导性高分子,则离子传导性聚合物 离子交换容量最低的聚合物被称为第二离子导电聚合物,则第一离子导电聚合物和第二离子导电聚合物都是由具有离子交换基团的链段和基本上没有离子交换基团的链段组成的嵌段共聚物 离子交换基团,并且如果在第一离子导电聚合物中具有离子交换基团的链段的重量分数称为Wh1,并且在第二离子导电聚合物中具有离子交换基团的链段的重量分数 称为Wh2,则满足以下列出的关系(I)和(II):(I)Wh1> Wh2; (II)Wh1-Wh2≦̸ 0.25。
    • 2. 发明申请
    • POLYMER ELECTROLYTE COMPOSITION AND FUEL CELL
    • 聚合物电解质组合物和燃料电池
    • US20100196792A1
    • 2010-08-05
    • US12680119
    • 2008-09-25
    • Yasuhiro YamashitaDiazaburo YashikiMitsunori Nodono
    • Yasuhiro YamashitaDiazaburo YashikiMitsunori Nodono
    • H01M8/10
    • H01M8/1044C08G2650/40C08J5/2275C08J2371/00C08J2381/06C08L71/00C08L81/06H01B1/122H01M8/1004H01M8/1025H01M8/1027H01M8/1032H01M8/1067H01M2300/0082Y02P70/56
    • A polymer electrolyte composition obtained by mixing a plurality of ion-conductive polymers, wherein if the ion-conductive polymer having that is highest in ion exchange capacity among the plurality of ion-conductive polymers is termed first ion-conductive polymer, and the ion-conductive polymer that is lowest in ion exchange capacity is termed second ion-conductive polymer, then the first ion-conductive polymer and the second ion-conductive polymer are both block copolymers composed of a segment having an ion-exchange group and a segment having substantially no ion-exchange groups, and if the weight fraction of the segment having an ion-exchange group in the first ion-conductive polymer is termed Wh1, and the weight fraction of the segment having an ion-exchange group in the second ion-conductive polymer is termed Wh2, then the relationships (I) and (II) listed below are satisfied. Wh1>Wh2  (I) Wh1−Wh2≦0.25  (II)
    • 通过混合多种离子导电聚合物得到的聚合物电解质组合物,其中如果具有离子交换能力最高的多个离子导电聚合物中的离子导电聚合物被称为第一离子导电聚合物, 离子交换能力最低的导电聚合物称为第二离子导电聚合物,则第一离子导电聚合物和第二离子导电聚合物都是由具有离子交换基团的链段和基本上具有离子交换基团的链段组成的嵌段共聚物 没有离子交换基团,并且如果在第一离子导电聚合物中具有离子交换基团的链段的重量分数称为Wh1,并且在第二离子导电聚合物中具有离子交换基团的链段的重量分数 聚合物称为Wh2,则满足下面列出的关系(I)和(II)。 Wh1> Wh2(I)Wh1-Wh2≦̸ 0.25(II)
    • 4. 发明申请
    • POLYMER ELECTROLYTE MEMBRANE, LAMINATE THEREOF, AND THEIR PRODUCTION METHODS
    • 聚合物电解质膜及其制备方法
    • US20090325028A1
    • 2009-12-31
    • US12310355
    • 2007-08-23
    • Yasuhiro YamashitaMitsunori Nodono
    • Yasuhiro YamashitaMitsunori Nodono
    • H01M8/10H01M8/00
    • B29C39/18B29K2096/005B29L2031/755H01B1/122H01M8/1025H01M8/1027H01M8/1032H01M8/1055H01M8/1058H01M8/1067H01M8/1081H01M8/1093H01M2300/0082Y02P70/56
    • Provided is a method for producing a laminate in which an ion conductive polymer electrolyte membrane is laminated on a supporting substrate in a state where any one surface of the polymer electrolyte membrane is bonded to the supporting substrate, a difference in a contact angle against water between a first surface and a second surface of the surface of the ion conductive polymer electrolyte membrane being more than 30° in a case where the first surface is the side having a small contact angle against water of a membrane surface and the second surface is the side having a large contact angle against water of the membrane surface, the method includes the steps of:preparing a polymer electrolyte solution in which a polymer electrolyte containing an ion conductive polymer having an aromatic group in the main chain and/or the side chain, and also having an ion exchange group bonded directly to the aromatic group or bonded indirectly to the aromatic group with another atom or atomic group interposed therebetween is dissolved in a solvent; andapplying the polymer electrolyte solution on the supporting substrate by flow casting thereby laminating the polymer electrolyte membrane on the supporting substrate.
    • 本发明提供一种层叠体的制造方法,其中,将离子导电性聚合物电解质膜层叠在支撑基板上,在高分子电解质膜的任一面与支撑基板接合的状态下,与水的接触角的差异 在第一表面是与膜表面的水接触角小的一侧的情况下,离子导电聚合物电解质膜的表面的第一表面和第二表面大于30°,第二表面是侧面 该方法包括以下步骤:制备其中含有在主链和/或侧链具有芳族基团的离子导电聚合物的聚合物电解质的聚合物电解质溶液,以及 也具有与芳族基团直接键合的离子交换基团或者与另一个原子或原子团间接与芳族基团键合的离子交换基团 插入其中溶解在溶剂中; 并通过流延法将聚合物电解质溶液施加在支撑基底上,从而将聚合物电解质膜层压在支撑基底上。