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    • 1. 发明授权
    • Reactor for non-isothermic reactions for the preparation of hydrocarbons
    • 用于制备碳氢化合物的非等温反应的反应器
    • US4683121A
    • 1987-07-28
    • US736908
    • 1985-05-22
    • Johan C. GoudriaanMaarten J. Van der Burgt
    • Johan C. GoudriaanMaarten J. Van der Burgt
    • B01J8/02B01J8/06B01J19/24C07C1/00C07C1/04C07C67/00C10G2/00F28F27/02
    • F28F9/0273B01J19/2465B01J8/06C07C1/042B01J2208/00212B01J2208/00221
    • A reactor having a vertically extending vessel wall (2) is provided with a plurality of staggered elongated parallel tubes (8) adapted for being filled with catalyst material and substantially vertically extending between an upper tube plate (10) and a lower tube plate (9), means (12, 13) for circulating a heat transfer medium between the tube plates (9, 10) alongside the tube walls (8), inlet means (3, 17, 18) above the parallel tubes (8) for distributing fluid in the form of one or more sprays and gas over the plurality of tubes (8) and outlet means (4, 20) situated below the plurality of tubes (8) for removal of fluids from the reactor, wherein the plurality of staggered tubes (8) are arranged in rows such that the tubes of adjacent rows are staggered, and wherein upper tube plate (10) is provided with openings (15), having a lower part in which the tubes (8) are closely fitted and having a substantially concentric upper part diverging in upward direction, the upper ends of the adjacent openings having edges in common in such a manner that the upper end of the upper tube plate (10) is formed by edges (16) arranged in a hexagonal honeycomb ribbed configuration.
    • 具有垂直延伸的容器壁(2)的反应器设置有多个交错的细长平行管(8),其适于填充催化剂材料并且基本上垂直地延伸在上管板(10)和下管板(9)之间 ),用于在管壁(8)旁边的管板(9,10)之间循环热传递介质的装置(12,13),平行管(8)上方的入口装置(3,17,18),用于分配流体 在多个管(8)和多个管(8)下方的出口装置(4,20)之间的一个或多个喷雾和气体的形式,用于从反应器中除去流体,其中多个交错管 8)布置成行,使得相邻行的管交错,并且其中上管板(10)设置有开口(15),其具有下部,管(8)紧密地配合在其中,并且具有基本上 同心上部向上发散,上端为邻接 该开口具有共同的边缘,使得上管板(10)的上端由以六边形蜂窝肋状构造布置的边缘(16)形成。
    • 8. 发明授权
    • Method of quenching synthesis gas
    • 淬灭合成气的方法
    • US5433760A
    • 1995-07-18
    • US61147
    • 1993-05-13
    • Egon L. DoeringMaarten J. van der Burgt
    • Egon L. DoeringMaarten J. van der Burgt
    • C01B3/32C10J3/84C10K3/06C10J3/46C01B3/34
    • C01B3/32C10J3/84C10K1/02C10K1/04C10K3/06C10J2300/1215
    • The invention is a process for quenching a first synthesis gas mixture containing synthesis gas, molten flyash, water, and carbon dioxide and producing additional synthesis gas consisting of (a) passing the first synthesis gas mixture into a first quench zone; (b) introducing into the quench zone a mixture of a liquid carbonaceous quenching medium in a nitrogen or carbon dioxide carrier gas; (c) endothermically reacting the liquid carbonaceous quenching medium with the water and the carbon dioxide in the synthesis gas mixture, thus producing additional synthesis gas consisting of hydrogen and carbon dioxide, and wherein the additional synthesis gas is admixed with the first synthesis gas mixture to form a second synthesis gas mixture; (d) passing the second synthesis gas mixture to a second quench zone; (e) introducing into the second quench zone a cooling gas for admixture with the second synthesis gas mixture, thus cooling the second synthesis gas mixture, where the molten flyash is solidified, and thus forms a third synthesis gas mixture; and (f) passing the third synthesis gas mixture to a solids removal stage for removing the solidified flyash.
    • 本发明是一种用于淬灭包含合成气,熔融飞灰,水和二氧化碳的第一合成气混合物并产生另外的合成气的方法,该合成气由(a)将第一合成气混合物送入第一骤冷区; (b)在淬火区中将氮气或二氧化碳载气中的液体含碳骤冷介质的混合物引入淬火区; (c)使液体含碳淬火介质与合成气混合物中的水和二氧化碳吸热反应,从而产生由氢气和二氧化碳组成的另外的合成气,并且其中所述另外的合成气与第一合成气混合物混合 形成第二合成气体混合物; (d)将第二合成气混合物通入第二骤冷区; (e)将与第二合成气混合物混合的冷却气体引入第二骤冷区,从而冷却第二合成气混合物,在该混合物中熔化的飞灰固化,从而形成第三合成气混合物; 和(f)将第三合成气混合物通入固体除去阶段以除去固化的飞灰。