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1. 发明授权

US5861192A Method of improving adhesive property of polyimide film and polymidefilm having improved adhesive property 失效
标题翻译：提高聚酰亚胺膜粘合性能和改善粘合性能的聚酰亚胺膜的方法
公开(公告)号：US5861192A
公开(公告)日：1999-01-19
申请号：US690975
申请日：1996-08-01
申请人： Masao Nakata , Kosuke Kataoka , Hirosaku Nagano
发明人： Masao Nakata , Kosuke Kataoka , Hirosaku Nagano
IPC分类号： C08J7/00 , B05D3/08 , B05D3/10 , B05D3/12 , B29C59/00 , B29C59/02 , B29C59/08 , B29C71/00 , C08J7/02 , C08J7/12 , H05K1/03 , H05K3/38 , B05D3/00
CPC分类号： C08J7/12 , B05D3/08 , B05D3/101 , B05D3/12 , B29C59/005 , B29C59/02 , B29C59/08 , B29C71/0009 , H05K3/381 , B29C2059/027 , B29C2791/001 , B29K2079/08 , C08J2379/08 , H05K1/0346
摘要： The invention solves a problem of that sufficient adhesive intensity to satisfy recent demand for high adhesive property cannot be obtained by conventional surface treatment, and provides a method of improving adhesive property of polyimide film and achieving distinctly improved effect of adhesive property. The invention further provides novel polyimide film having improved adhesive property.A method for improving adhesive property of polyimide film according to the present invention comprises a combination of steps of;execution of a liquid applying process for treating polyimide film surface by exerting physical mechanical force on said film surface under the condition of that said film surface remains wet with water or organic solvent, or solution of organic solvent or aqueous solution; and execution of a surface treatment process for treating polyimide film surface by performing selected treatment among flame treatment, alkaline treatment, coupling agent treatment or surface treatment by way of projecting grinding material of fine grading onto film surface at high velocity, and said steps are performed in an arbitrary order. For example, using a surface treating device 10 shown in FIG. 1, consecutive execution of a surface treatment process for treating film surface, a liquid applying process and a drying process is realized by that polyimide film 22 is run from a feeding device 18 to a winding device 20.
摘要翻译：本发明解决了通过常规的表面处理不能获得足够的粘合强度以满足最近对高粘合性能的要求的问题，并且提供了改进聚酰亚胺膜的粘合性能并且显着提高粘合性能的效果的方法。本发明还提供了具有改进的粘合性能的新型聚酰亚胺膜。根据本发明的改进聚酰亚胺薄膜的粘合性的方法包括以下步骤的组合：执行用于在所述膜表面保持用水或有机溶剂润湿的条件下或在有机溶剂或水溶液的溶液的条件下在所述膜表面上施加物理机械力来处理聚酰亚胺膜表面的液体施加过程; 并且通过在火焰处理，碱处理，偶联剂处理或表面处理中进行选择的处理，通过以高速投影细微分级的研磨材料到薄膜表面上来执行用于处理聚酰亚胺膜表面的表面处理工艺，并且执行所述步骤以任意顺序。例如，使用图1所示的表面处理装置10，如图1所示，通过聚酰亚胺膜22从供给装置18向卷绕装置20运行，连续执行用于处理膜表面的表面处理工艺，液体施加处理和干燥处理。

2. 发明授权

US07101455B1 Method and device for manufacturing laminated plate 有权
标题翻译：层压板的制造方法和装置
公开(公告)号：US07101455B1
公开(公告)日：2006-09-05
申请号：US10129037
申请日：2000-10-30
申请人： Naoki Hase , Kosuke Kataoka , Hiroyuki Furutani , Yasuo Fushiki
发明人： Naoki Hase , Kosuke Kataoka , Hiroyuki Furutani , Yasuo Fushiki
IPC分类号： B32B37/04 , B32B37/06 , B32B37/08 , B32B37/12 , B32B37/20 , B32B38/10
CPC分类号： B32B37/0015 , B32B37/26 , B32B2309/02 , B32B2309/14 , H05K3/022
摘要： The present invention provides a method for producing a laminate suitable for a flexible circuit board which is free from visual defects such as wrinkles and curls that appear when a plurality of laminating materials containing a thermally fusible laminating material are formed by thermally laminating these materials each other using a thermal-press forming device, which comprises the steps of: arranging a heat resistant protective material between a pressing surface and the laminating materials, laminating the materials by thermal pressure at not lower than 200° C., wherein the bonded laminating materials are in contact with the protective material, cooling the bonded laminating materials, and peeling off the protective material from the bonded laminating materials, whereby the laminate with less nonuniformity in pressurization, a uniform surface, and a good inter-layer adhesion, and the method and device for producing the laminate can be provided, more particularly, the thermal pressure and forming is performed by a thermal-press forming device having at least a pair of metal rolls.
摘要翻译：本发明提供了一种适用于柔性电路板的层叠方法，该柔性电路板在没有视觉缺陷的情况下，例如当通过将这些材料彼此热层叠形成多个包含热熔性层压材料的层压材料时，出现褶皱和卷曲使用热压成型装置，其包括以下步骤：在挤压表面和层压材料之间布置耐热保护材料，通过热压不低于200℃层压材料，其中粘合层压材料为与保护材料接触，冷却接合的层压材料，并从保护层压材料剥离保护材料，由此加压不均匀性，均匀表面和良好的层间粘合性的层压体，以及该方法和可以提供用于制造层压体的装置，更具体地，提供热压通过具有至少一对金属辊的热压成形装置进行确定和成形。

3. 发明授权

US6106949A Reformed polyimide fluorocarbon resin laminated film 失效
标题翻译：改性聚酰亚胺氟碳树脂层压膜
公开(公告)号：US6106949A
公开(公告)日：2000-08-22
申请号：US759682
申请日：1996-12-06
申请人： Kosuke Kataoka , Eiichiro Kuribayashi , Yoshihide Ohnari
发明人： Kosuke Kataoka , Eiichiro Kuribayashi , Yoshihide Ohnari
IPC分类号： B32B27/08
CPC分类号： B32B27/08
摘要： The present invention provides a reformed polyimide fluorocarbon resin laminated film having superior adhesive property with metals.The reformed polyimide fluorocarbon resin laminated film according to the present invention is constructed by that a surface of fluorocarbon resin of polyimide fluorocarbon resin laminated film having fluorocarbon resin being laminated on a single surface or both surfaces of a polyimide film is coated with a coupling agent, or executed with corona treatment.
摘要翻译：本发明提供了与金属具有优异粘合性的改性聚酰亚胺氟碳树脂层压膜。根据本发明的改性聚酰亚胺氟碳树脂层压膜是通过将聚碳酸酯树脂层压在聚酰亚胺膜的单面或两面的聚酰亚胺氟碳树脂层合膜的碳氟树脂的表面涂覆有偶联剂而构成的，或用电晕处理执行。

4. 发明授权

US6060158A Fluoro-carbon resinous laminate having a crack-resistant surface and method of producing said laminate 失效
标题翻译：具有耐裂纹表面的氟碳树脂层压板及其制造方法
公开(公告)号：US6060158A
公开(公告)日：2000-05-09
申请号：US725898
申请日：1996-10-04
申请人： Kazuhiro Ono , Eiichiro Kuribayashi , Kosuke Kataoka , Kiyokazu Akahori
发明人： Kazuhiro Ono , Eiichiro Kuribayashi , Kosuke Kataoka , Kiyokazu Akahori
IPC分类号： C08J7/04 , B32B27/06 , B32B27/08 , B32B31/12 , B32B31/26
CPC分类号： C08J7/047 , C08J2379/08 , C08J2427/00 , Y10T428/269 , Y10T428/3154 , Y10T428/31544 , Y10T428/31721
摘要： A fluoro-carbon resinous laminate has a crack-resistant surface on a fluoro-carbon resinous layer thereof produced by coating a single surface or both surfaces of a plastic film with a single layer of a fluoro-carbon resinous dispersion, and a method of producing the laminate. To produce the fluoro-carbon resinous laminate, which is a minimum of 10 .mu.m in thickness, a single surface or both surfaces of a plastic film are coating with a single layer of concentration-adjusted fluoro-carbon resinous dispersion and then dried, followed by curing the resinous dispersion in a thermal treating furnace with heated atmospheric air or by adding organic solvent to the resinous dispersion, the enabling production of a fluoro-carbon resinous laminate having a surface appearance in which cracks cannot visually be identified.
摘要翻译：氟碳树脂层叠体通过用单层氟碳树脂分散体涂覆塑料膜的单面或两面而在其氟碳树脂层上具有抗裂性表面，以及制造方法层压板。为了生产厚度最小为10μm的氟碳树脂层压板，塑料薄膜的单面或两面用单层浓度调节氟碳树脂分散体涂布，然后干燥通过在具有加热的大气空气的热处理炉中固化树脂分散体或通过向树脂分散体中加入有机溶剂，能够生产具有无法在视觉上识别裂纹的表面外观的氟碳树脂层压体。

5. 发明授权

US5637382A Flexible copper-coated laminate and flexible printed circuit board 失效
标题翻译：柔性铜涂层压板和柔性印刷电路板
公开(公告)号：US5637382A
公开(公告)日：1997-06-10
申请号：US592480
申请日：1996-01-26
申请人： Kosuke Kataoka , Eiichiro Kuribayashi , Yoshihide Ohnari
发明人： Kosuke Kataoka , Eiichiro Kuribayashi , Yoshihide Ohnari
IPC分类号： B32B15/08 , B32B15/088 , B32B15/20 , H05K1/03 , B32B9/00
CPC分类号： H05K1/0346 , Y10S428/901 , Y10T428/24917 , Y10T428/31721
摘要： The object of the invention is to embody further thinning of a double layer flexible printed circuit board (FPC) and provide a flexible copper-coated laminate capable of producing such a novel flexible printed circuit board distinguished in bending characteristic and heat-resistant property and provide a printed circuit board using the novel flexible copper-coated laminate. To achieve the above object, novel flexible copper-coated laminates 10 and 12 according to the present invention are respectively composed by directly forming a copper layer 16 having a thickness of 10 .mu.m or less than 10 .mu.m on a single surface or both surfaces of polyimide film 14 which is composed of polyimide polymer containing modulus of initial tensile elasticity of 400 kg/mm.sup.2 or more than 400 kg/mm.sup.2, and which has a thickness of 10 .mu.m or less than 10 .mu.m.
摘要翻译：本发明的目的是体现双层柔性印刷电路板（FPC）的进一步减薄，并提供一种柔性的铜涂层压板，其能够制造出具有弯曲特性和耐热性能的区别的新型柔性印刷电路板，并提供使用新型柔性铜包覆层压板的印刷电路板。为了实现上述目的，根据本发明的新型柔性铜包覆层压板10和12分别通过在单个表面或两个表面上直接形成厚度为10μm或小于10μm的铜层16 由聚酰亚胺聚合物构成的聚酰亚胺膜14，该聚酰亚胺聚合物的初始拉伸弹性模量为400kg / mm2以上400kg / mm2以下，厚度为10μm以下，10μm以下。

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