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    • 1. 发明授权
    • Photographic elements with tetra-nuclear merocyanine sensitizers
    • 摄影元素与四核花菁敏化剂
    • US5563021A
    • 1996-10-08
    • US479581
    • 1995-06-07
    • Julia PichJohn M. HigginsJohn D. Mee
    • Julia PichJohn M. HigginsJohn D. Mee
    • G03C5/29A01M31/00G03C1/06G03C1/22G03C1/26G03C1/295G03C1/08
    • G03C1/26A01M31/002G03C1/061
    • A photographic element comprising a light sensitive silver halide emulsion sensitized with a dye of formula (I) and a nucleating agent or amine booster associated with the silver halide emulsion: ##STR1## wherein: R.sub.3 is an alkyl group, alkenyl group, or aryl groupR.sub.4 and R.sub.5 are each hydrogen, an alkyl group, alkenyl or aryl group;R.sub.6, R.sub.7 and R.sub.8 are, independently, an alkyl group, alkenyl group, aryl group, or H;the dye has at least three acid or acid salt substituents; andeach L independently represents a methine group;p is 0 or 1;Z.sub.1 represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring group;(X).sub.n represents counterions as needed to balance the charge on the molecule.The present invention also provides a process for forming a high contrast photographic image on a photographic element having a light sensitive silver halide emulsion sensitized with a dye of formula (I). The process comprises developing such a photographic element in the presence of a hydrazine compound and an amine booster.
    • 包含用式(I)的染料敏化的感光卤化银乳剂和与卤化银乳剂相关的成核剂或胺促进剂的照相元件:其中:R 3是烷基,烯基, 或芳基R 4和R 5各自为氢,烷基,烯基或芳基; R6,R7和R8独立地为烷基,烯基,芳基或H; 该染料具有至少三个酸或酸盐取代基; 并且每个L独立地表示次甲基; p为0或1; Z1表示完成5-或6-元杂环基团所必需的原子; (X)n表示在分子上平衡电荷所需的抗衡离子。 本发明还提供了在具有用式(I)的染料敏化的感光卤化银乳剂的照相材料上形成高对比度摄影图像的方法。 该方法包括在肼化合物和胺助剂的存在下开发这种照相元件。
    • 6. 发明授权
    • Photographic element
    • 摄影元素
    • US06312884B1
    • 2001-11-06
    • US09533573
    • 2000-03-23
    • Steven G. LinkJohn D. Mee
    • Steven G. LinkJohn D. Mee
    • G03C114
    • G03C1/14
    • This invention comprises a photographic element comprising a light sensitive silver halide emulsion layer which contains a sensitizing dye of the formula: wherein: n is 0 or 1; X, Y, and Z are independently O, N, S, Se, or C; X′ is O, NR13, S, or Se; R1 and R2 are acid substituted alkyl; R4 is H or alkyl, with the proviso that if X′ is N, R4 is H; each of R6, R7, R8 and R9 is independently H or a substituent or R7 and R8 or R8 and R9 together with the carbon atoms to which they are attached form a 5-membered or 6-membered ring; when X or Y or Z is O, N, S or Se then a, b or c, respectively, is 0 and when X or Y or Z is C, a, b or c, respectively is 1 and the corresponding R10, R11, or R12 substituent is independently H or a non-aromatic substituent; and R13 is alkyl or substituted alkyl.
    • 本发明包括一种含有感光卤化银乳剂层的照相元件,其含有下式的增感染料:其中:n为0或1; X,Y和Z独立地为O,N,S,Se或C; X'是O,NR 13,S或Se; R 1和R 2是酸取代的烷基; R 4是H或烷基,条件是如果X'是N,则R4是H; R6,R7,R8和R9各自是 独立地是H或取代基,或者R 7和R 8或R 8和R 9与它们所连接的碳原子一起形成5元或6元环;当X或Y或Z为O,N,S或Se时, ,b或c分别为0,当X或Y或Z为C时,a,b或c分别为1,相应的R10,R11或R12取代基独立为H或非芳香族取代基; 和R 13是烷基或取代的烷基。