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1. 发明授权

US5543267A Photo-induced optically anisotropic amorphous film materials from side group polymers 失效
标题翻译：来自侧基聚合物的光诱导光学各向异性非晶膜材料
公开(公告)号：US5543267A
公开(公告)日：1996-08-06
申请号：US210425
申请日：1994-03-21
申请人： Joachim Stumpe , Valery Shibaev , Sergei Kostromin , Sergei Ivanov , Thomas Fischer , Lutz L asker , Ralf Ruhmann , Uwe Claussen
发明人： Joachim Stumpe , Valery Shibaev , Sergei Kostromin , Sergei Ivanov , Thomas Fischer , Lutz L asker , Ralf Ruhmann , Uwe Claussen
IPC分类号： C08F220/36 , C08F20/26 , C08F20/34 , C08F246/00 , C08G65/329 , C09K19/38 , G03G5/07 , G11B7/244 , G11B7/245 , C08F220/34
CPC分类号： C08G65/329 , C08F246/00 , C09K19/38 , C09K19/3852 , G11B7/245
摘要： Flat materials made from a polymer with a backbone and side groups branching off the backbone (side group polymer), which polymer has the following structural features (1) to (3):(1) the side group polymer contains at least one photoinducibly configuration-changing side group;(2) the side group polymer contains at least one permanently conformationally anisotropic side group with high anisotropy of molecular polarisability which differs from (1);(3) the side group polymer contains flexible spacer groups between the backbone and the side groups (1) and (2);wherein the flat material in the glassy state of the side group polymers is optically isotropic, transparent, non-scattering and amorphous before irradiation and, after irradiation, is transparent and durably birefringent and dichroic due to a reversible, photoinduced alignment of the side groups (1) and (2) in the glassy state, may be purposefully modified in terms of their optical properties by the action of light.
摘要翻译：由具有骨架的聚合物制成的扁平材料和从骨架（侧基聚合物）分支的侧基，该聚合物具有以下结构特征（1）至（3）：（1）侧基聚合物含有至少一种光诱导构型交换组（2）侧基聚合物含有至少一个与（1）不同的具有高各向异性的分子极化性的永久构象异构侧基; （3）侧基聚合物在主链和侧基（1）和（2）之间包含柔性间隔基; 其中所述侧基聚合物的玻璃状态的平坦材料是光学各向同性的，透明的，非散射的和在照射之前的无定形的，并且在照射之后，由于侧基的可逆的光诱导取向而是透明和耐久的双折射和二色性（ 1）和（2）在玻璃状态下，可以通过光的作用在其光学性质方面有目的地改变。

2. 发明申请

US20090233014A1 Photoactive Film, Its Preparation And Use, And Preparation Of Surface Relief And Optically Anisotropic Structures By Irradiating Said Film 审中-公开
标题翻译：光活性膜，其制备和使用，以及通过辐射所述膜的表面浮雕和光学各向异性结构的制备
公开(公告)号：US20090233014A1
公开(公告)日：2009-09-17
申请号：US11721407
申请日：2005-12-08
申请人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
发明人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
IPC分类号： G03F7/00 , B29C41/00 , G03F7/004 , H01G9/022 , B29C39/00 , B29C35/00
CPC分类号： G11B7/245 , G03C1/733 , G11B7/246 , G11B7/2467 , G11B7/2475 , G11B7/249 , G11B7/25 , G11B7/2531 , G11B7/257 , Y10T428/24479 , Y10T428/24802
摘要： The present invention relates to a homogeneous, photoactive film consisting of or comprising a polyelectrolyte carrying residues which may undergo a photoreaction, the polyelectrolyte mainly comprising at least one structure according to any of formulae (I) to (IV), namely [Pol(R*—P—R′)]oon+n/xAx− (I), n/xAx+[Pol(R*—P—R′)]oon− (II), [Pol(R1*-Q-R1′)]oon+n/xΛx− (III), n/xΛx+[Pol(R1*-Q-R1′)]oon− (IV), wherein Pol means a repeating unit of a linear or branched polymer chain, o indicates the number of the repeating unit of the polymer chain, and (R*—P—R′) and (R1*-Q-R1′) are n-fold positively or negatively charged side chains of the repeating unit Pol, wherein P is a group which is capable of photo-induced E/Z isomerization, Q is a group capable of participating in a photocycloaddition, or capable of participating in a photoinduced rearrangement, or the so called Photo-Fries reaction, A is a cation or anion which is oppositely charged, n is preferably 1 or 2, x is 1 or 2, and o is at least 2, with the proviso that in one polyelectrolyte, groups [R—P—R′] and/or [R1-Q-R1′] all have the same sign. The invention is further directed to the preparation of the film, its use and a method for the preparation of a replica of a film of the invention having a surface relief structure.
摘要翻译：本发明涉及一种均匀的光活性膜，其由携带可能经历光反应的残余物的聚电解质组成或包含，该聚电解质主要包含至少一种根据式（I）至（IV）中任一项的结构，即[Pol *（P-R'）] oon + n / xAx-（I），n / xAx + [Pol（R * -P-R'）] oon-（II），[Pol（R1 * -Q-R1' ]其中Pol表示直链或支链聚合物链的重复单元，o表示数字（n），n / xLambdax-（III），n / xLambdax + [Pol（R1 * -Q-R1' 的聚合物链的重复单元，（R * -P-R'）和（R 1 * -Q-R 1'）是重复单元Pol的n倍带正电荷或带负电荷的侧链，其中P是基团能够进行光诱导的E / Z异构化，Q是能够参与光环加成，或能够参与光诱导重排的基团或所谓的Photo-Fries反应，A是相反的阳离子或阴离子充电，n优选为1或2，x为1或2，o为至少2，条件是在一个聚电解质中，[R-P-R']和/或[R1-Q-R1']基团都具有相同的符号。本发明进一步涉及膜的制备，其用途和制备本发明的具有表面浮雕结构的膜的复制品的方法。

3. 发明申请

US20110086420A1 POLYMER SUBSTRATE WITH FLUORESCENT STRUCTURE, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF 有权
标题翻译：具有荧光结构的聚合物基材，其生产方法及其用途
公开(公告)号：US20110086420A1
公开(公告)日：2011-04-14
申请号：US12876881
申请日：2010-09-07
申请人： Thomas Fischer , Joachim Stumpe , Valentin Kahl
发明人： Thomas Fischer , Joachim Stumpe , Valentin Kahl
IPC分类号： C12M1/26 , G03F7/20 , C08F232/00 , B65D73/00
CPC分类号： B01L3/545
摘要： The invention relates to polymer substrates which are provided with fluorescence features and in which photochemical fluorescence features, i.e. fluorescent structures, are produced by UV irradiation. Thus, fluorophores can be produced in polymer substrates with a low inherent fluorescence by means of suitable UV radiation, which fluorophores display a marked and detectable emission upon being excited with light of a suitable wavelength. If such an irradiation is implemented in a structured manner, emission patterns can be produced in this way in polymer substrates, which emission patterns can be applied for example as recovery grids in fluorescence microscopy. A further application field relates to product authentication which is made possible by the polymer substrates according to the invention provided with fluorescence features.
摘要翻译：本发明涉及具有荧光特征的聚合物基质，其中通过UV照射产生光化学荧光特征，即荧光结构。因此，荧光团可以通过合适的UV辐射在具有低固有荧光的聚合物基底中产生，该荧光团在用合适波长的光激发时显示出标记和可检测的发射。如果以结构化方式实施这种照射，则可以以这种方式在聚合物基底中产生发射图案，该发射图案可以在荧光显微镜中应用于例如回收网格。进一步的应用领域涉及通过提供有荧光特征的根据本发明的聚合物基底使得产品认证。

4. 发明申请

US20080063808A1 Method for the Preparation of High-Efficient, Tuneable and Switchable Optical Elements Based on Polymer-Liquid Crystal Composites 审中-公开
标题翻译：基于聚合物 - 液晶复合材料制备高效，可调和可切换的光学元件的方法
公开(公告)号：US20080063808A1
公开(公告)日：2008-03-13
申请号：US11571426
申请日：2005-06-28
申请人： Joachim Stumpe , Sergej Slussarenko , Oksana Sakhno
发明人： Joachim Stumpe , Sergej Slussarenko , Oksana Sakhno
IPC分类号： B05D5/06 , B05D3/06
CPC分类号： G02F1/13342
摘要： A homogeneous isotropic mixture of photocurable monomers and/or oligomers, one or more liquid crystals or a liquid crystal mixture, and optionally a photoinitiator is provided that is homogeneous and optically clear within a temperature range of between 15 and 25° C. An optically transparent film of the homogenous isotropic mixture on a substrate or in a space between two substrates is prepared. The optically transparent film is irradiated with an inhomogeneous light field of actinic light such that areas of the film are irradiated while others are not. The intensity is sufficiently low that first areas solely, substantially or mainly composed of photocured polymer are formed, while the liquid crystals or liquid crystal mixture completely, substantially or mainly escapes into second areas that are not or substantially not irradiated. The substrates are removed depending on whether the rigid or flexible film is to be prepared alone or on a substrate.
摘要翻译：提供可光固化单体和/或低聚物，一种或多种液晶或液晶混合物以及任选的光引发剂的均匀各向同性混合物，其在15至25℃的温度范围内是均匀的和光学透明的。光学透明准备在基板上或两个基板之间的空间中均匀各向同性混合物的膜。光学透明膜用光化不均匀的光场照射，使得膜的面积不被照射。强度足够低，仅形成基本上或主要由光固化聚合物构成的第一区域，而液晶或液晶混合物完全，基本上或主要逸出到不被或基本上不被照射的第二区域。取决于刚性或柔性膜是单独制备还是在基材上制备基材。

5. 发明申请

US20050244718A1 Polymerizable, luminescent compounds and mixtures, luminescent polymer materials and their use 审中-公开
标题翻译：可聚合的发光化合物和混合物，发光聚合物材料及其用途
公开(公告)号：US20050244718A1
公开(公告)日：2005-11-03
申请号：US10519712
申请日：2003-06-18
申请人： Eike Poetsch , Thomas Jacob , Jose Serrano , Milagros Pinol , Raquel Gimenez , Joachim Stumpe , Thomas Fischer , Regina Rosenhauer
发明人： Eike Poetsch , Thomas Jacob , Jose Serrano , Milagros Pinol , Raquel Gimenez , Joachim Stumpe , Thomas Fischer , Regina Rosenhauer
IPC分类号： H01L51/50 , C07D263/56 , C07D263/57 , C07D307/79 , C07D413/04 , C07D413/10 , C08F20/34 , C08G61/12 , C08G65/22 , C08G73/08 , C08G73/22 , C09K11/06 , C09K19/04 , C09K19/34 , H01L51/30 , H05B33/14 , H01M6/14
CPC分类号： H05B33/14 , C07D263/57 , C07D307/79 , C08G61/12 , C08G61/125 , C08G73/08 , C08G73/22 , C09K11/06 , C09K19/0403 , C09K2019/0444 , C09K2019/3425 , C09K2211/1475 , H01L51/0035 , H01L51/5012
摘要： The invention relates to new polymerizable, luminescent compounds of formula I wherein R1, R2, A1, A2, A3, Z1, W and Q have the meanings given in claim 1. Furthermore the invention relates to polymerizable mixtures containing compounds according to the invention and pleferably at least one polymerizable mesogenic compound. Polymer materials obtainable by polymerizing such mixtures are also described. These compounds, mixtures and materials show advantageous photoluminescent and/or electroluminescent properties and may be used in light emitting devices and optical- or electrooptical display elements.
摘要翻译：本发明涉及式I的新的可聚合的发光化合物，其中R 1，R 2，A 1，A 2， W，Q，W和Q具有权利要求1中给出的含义。此外，本发明涉及含有根据本发明的化合物的可聚合混合物，并且适用于至少一种可聚合的介晶化合物。还描述了通过聚合这种混合物获得的聚合物材料。这些化合物，混合物和材料显示出有利的光致发光和/或电致发光性质，并且可以用于发光器件和光学或电光显示元件中。

6. 发明授权

US09597688B2 Polymer substrate with fluorescent structure, method for the production thereof and the use thereof 有权
公开(公告)号：US09597688B2
公开(公告)日：2017-03-21
申请号：US12876881
申请日：2010-09-07
申请人： Thomas Fischer , Joachim Stumpe , Valentin Kahl
发明人： Thomas Fischer , Joachim Stumpe , Valentin Kahl
IPC分类号： C12M1/26 , C12M3/00 , C12M1/24 , B01L3/00
CPC分类号： B01L3/545
摘要： The invention relates to polymer substrates which are provided with fluorescence features and in which photochemical fluorescence features, i.e. fluorescent structures, are produced by UV irradiation. Thus, fluorophores can be produced in polymer substrates with a low inherent fluorescence by means of suitable UV radiation, which fluorophores display a marked and detectable emission upon being excited with light of a suitable wavelength. If such an irradiation is implemented in a structured manner, emission patterns can be produced in this way in polymer substrates, which emission patterns can be applied for example as recovery grids in fluorescence microscopy. A further application field relates to product authentication which is made possible by the polymer substrates according to the invention provided with fluorescence features.

7. 发明授权

US07612879B2 Method and device for three-dimensionally determining the refractive index of transparent or partially transparent layers 失效
$Method and device for three-dimensionally determining the refractive index of transparent or partially transparent layers$
标题翻译：用于三维地确定透明或部分透明层的折射率的方法和装置
公开(公告)号：US07612879B2
公开(公告)日：2009-11-03
申请号：US10559650
申请日：2004-06-01
申请人： Joachim Stumpe , Christoph Jung , Olga Kulikovska
发明人： Joachim Stumpe , Christoph Jung , Olga Kulikovska
IPC分类号： G01J4/00
CPC分类号： G01N21/8422 , G01N21/211 , G01N21/41 , G01N2021/214 , G01N2021/4126
摘要： The present invention relates to a method and a device for three-dimensionally determining the refractive index and, if necessary, the layer thickness of transparent or partially transparent layers in which the layer (1) is irradiated at different angles of incidence (5) with polarised light, and variations in the polarisation of the light are measured and evaluated as the light passes through the layer (1). The method is characterized in that the measurement is carried out through an immersion medium (3) between which the layer (1) is inserted. A highly accurate determination of the refractive index of anisotropic thin layers in all three spatial directions is made possible by this method.
摘要翻译：本发明涉及一种用于三维地确定折射率的方法和装置，并且如果需要，可以以不同的入射角（5）照射层（1）的透明或部分透明层的层厚度，当光通过层（1）时，测量并评估光的偏振变化。该方法的特征在于，通过插入层（1）的浸渍介质（3）进行测量。通过这种方法可以高精度地确定各向异性薄层在所有三个空间方向上的折射率。

8. 发明申请

US20090001632A1 Film Forming Material and Preparation of Surface Relief and Optically Anisotropic Structures by Irradiating a Film of the Said Material 失效
标题翻译：成膜材料和通过照射所述材料的膜来制备表面浮雕和光学各向异性结构
公开(公告)号：US20090001632A1
公开(公告)日：2009-01-01
申请号：US11574672
申请日：2005-08-30
申请人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
发明人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
IPC分类号： B29C41/42 , B05D3/12 , B05D3/06 , B32B3/10 , C08J3/28 , B05D5/06
CPC分类号： G03F7/001 , C08K5/23 , C08K5/45 , C08L79/00 , C08L79/02 , C08L101/02 , Y10S430/146 , Y10T428/24802 , C08L2666/36
摘要： The present invention is directed to a film forming, photoactive, homogeneously mixed material comprising a complex prepared from (a) at least one ionic photosensitive compound which may undergo a photoreaction, selected from photoiso-iso polyelectrolyte”) carrying residues which may undergo said photoreaction, and (b) at least one (“first”) polyelectrolyte carrying charges which are opposite to those of the active groups of the photosensitive material. This material has unique photochemical properties in that non-scattering, optically clear films may prepared therefrom which allow light-induced generation of optical anisotropy and of topological surface structures, e.g. such as surface relief gratings (SRG).
摘要翻译：本发明涉及一种成膜，光活性均匀混合的材料，其包含由（a）至少一种可能经历光反应的离子光敏化合物制备的络合物，所述络合物可以进行所述光反应的残余物，所述复合物选自光异性聚电解质“），和（b）至少一个（“第一”）聚电解质携带与感光材料的活性基团相反的电荷，该材料具有独特的光化学性质，因为可以制备非散射的光学透明膜，其允许光诱导产生光学各向异性和拓扑表面结构，例如表面浮雕光栅（SRG）。

9. 发明申请

US20060166033A1 Polymerizable, luminescent compounds and mixtures, luminescent polymer materials and their use 审中-公开
标题翻译：可聚合的发光化合物和混合物，发光聚合物材料及其用途
公开(公告)号：US20060166033A1
公开(公告)日：2006-07-27
申请号：US10519707
申请日：2003-06-18
申请人： Eike Poetsch , Thomas Jacob , Jose Serrano , Milagros Pinol , Raquel Gimenez , Joachim Stumpe , Thomas Fischer , Regina Rosenhauer , Burkhard Schulz
发明人： Eike Poetsch , Thomas Jacob , Jose Serrano , Milagros Pinol , Raquel Gimenez , Joachim Stumpe , Thomas Fischer , Regina Rosenhauer , Burkhard Schulz
IPC分类号： B32B19/00
CPC分类号： H01L51/004 , C07D213/06 , C07D271/107 , C08G73/0616 , C08G73/08 , C09K11/06 , C09K19/0403 , C09K2019/0444 , C09K2211/1007 , C09K2211/1044 , C09K2211/1048 , C09K2211/1408 , C09K2211/1416 , C09K2211/1425 , C09K2211/1466 , C09K2211/1475 , H01L51/0035 , H01L51/0038 , H01L51/0052 , H01L51/007 , H01L51/5012 , H05B33/14
摘要： The invention relates to new polymerizable, luminescent compounds of formula I wherein R1, R2, Q and L1 have the meanings given in claim 1. Furthermore the invention relates to polymerizable mixtures containing compounds according to the invention and preferably at least one polymerizable mesogenic compound. Polymer materials obtainable by polymerizing such mixtures are also described. These compounds, mixtures and materials show advantageous photoluminescent and/or electroluminescent properties and may be used in light emitting devices and optical- or electrooptical display elements.
摘要翻译：本发明涉及式I的新的可聚合发光化合物，其中R 1，R 2，Q和L 1具有权利要求中给出的含义此外，本发明涉及含有根据本发明的化合物的可聚合混合物，优选至少一种可聚合的介晶化合物。还描述了通过聚合这种混合物获得的聚合物材料。这些化合物，混合物和材料显示出有利的光致发光和/或电致发光性质，并且可以用于发光器件和光学或电光显示元件中。

10. 发明授权

US5858585A Process for intensifying information in photo-addressable side-chain polymers 失效
标题翻译：在光寻址侧链聚合物中增强信息的方法
公开(公告)号：US5858585A
公开(公告)日：1999-01-12
申请号：US793559
申请日：1997-02-28
申请人： Dietrich Haarer , Thomas Bieringer , Claus Dieter Eisenbach , Karl Fischer , Ralf Ruhmann , Roland Wuttke , Joachim Stumpe , Thomas Fischer , Lutz Laser , Michael Rutloh , Uwe Claussen
发明人： Dietrich Haarer , Thomas Bieringer , Claus Dieter Eisenbach , Karl Fischer , Ralf Ruhmann , Roland Wuttke , Joachim Stumpe , Thomas Fischer , Lutz Laser , Michael Rutloh , Uwe Claussen
IPC分类号： G02F1/13 , B41M5/26 , C08F20/30 , C08F20/36 , C08G77/04 , G02F1/1333 , G11B7/00 , G11B7/004 , G11B7/0045 , G11B7/244 , G11B7/245 , G11C13/04 , G03C5/56
CPC分类号： G11B7/0045 , G11B7/245
摘要： The light-induced modification in a side-chain polymer containing at least one side group whose configuration can be modified induced by light and at least one permanently shape-anisotropic side group can be amplified by warming to a temperature between the glass transition temperature and the clearing point. This effect opens up new aspects for optical data storage.
摘要翻译： PCT No.PCT / EP95 / 03431 Sec。 371日期1997年2月28日 102（e）日期1997年2月28日PCT提交1995年9月1日PCT公布。公开号WO96 / 08007 日期：1996年3月14日含有至少一个侧链聚合物的光诱导改性，其可以通过升温至至少一个侧基，其构型可由光诱导并且至少一个永久形状 - 各向异性侧基玻璃化转变温度和清除点。这种效应为光学数据存储开辟了新的方面。

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