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1. 发明申请

US20090233014A1 Photoactive Film, Its Preparation And Use, And Preparation Of Surface Relief And Optically Anisotropic Structures By Irradiating Said Film 审中-公开
标题翻译：光活性膜，其制备和使用，以及通过辐射所述膜的表面浮雕和光学各向异性结构的制备
公开(公告)号：US20090233014A1
公开(公告)日：2009-09-17
申请号：US11721407
申请日：2005-12-08
申请人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
发明人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
IPC分类号： G03F7/00 , B29C41/00 , G03F7/004 , H01G9/022 , B29C39/00 , B29C35/00
CPC分类号： G11B7/245 , G03C1/733 , G11B7/246 , G11B7/2467 , G11B7/2475 , G11B7/249 , G11B7/25 , G11B7/2531 , G11B7/257 , Y10T428/24479 , Y10T428/24802
摘要： The present invention relates to a homogeneous, photoactive film consisting of or comprising a polyelectrolyte carrying residues which may undergo a photoreaction, the polyelectrolyte mainly comprising at least one structure according to any of formulae (I) to (IV), namely [Pol(R*—P—R′)]oon+n/xAx− (I), n/xAx+[Pol(R*—P—R′)]oon− (II), [Pol(R1*-Q-R1′)]oon+n/xΛx− (III), n/xΛx+[Pol(R1*-Q-R1′)]oon− (IV), wherein Pol means a repeating unit of a linear or branched polymer chain, o indicates the number of the repeating unit of the polymer chain, and (R*—P—R′) and (R1*-Q-R1′) are n-fold positively or negatively charged side chains of the repeating unit Pol, wherein P is a group which is capable of photo-induced E/Z isomerization, Q is a group capable of participating in a photocycloaddition, or capable of participating in a photoinduced rearrangement, or the so called Photo-Fries reaction, A is a cation or anion which is oppositely charged, n is preferably 1 or 2, x is 1 or 2, and o is at least 2, with the proviso that in one polyelectrolyte, groups [R—P—R′] and/or [R1-Q-R1′] all have the same sign. The invention is further directed to the preparation of the film, its use and a method for the preparation of a replica of a film of the invention having a surface relief structure.
摘要翻译：本发明涉及一种均匀的光活性膜，其由携带可能经历光反应的残余物的聚电解质组成或包含，该聚电解质主要包含至少一种根据式（I）至（IV）中任一项的结构，即[Pol *（P-R'）] oon + n / xAx-（I），n / xAx + [Pol（R * -P-R'）] oon-（II），[Pol（R1 * -Q-R1' ]其中Pol表示直链或支链聚合物链的重复单元，o表示数字（n），n / xLambdax-（III），n / xLambdax + [Pol（R1 * -Q-R1' 的聚合物链的重复单元，（R * -P-R'）和（R 1 * -Q-R 1'）是重复单元Pol的n倍带正电荷或带负电荷的侧链，其中P是基团能够进行光诱导的E / Z异构化，Q是能够参与光环加成，或能够参与光诱导重排的基团或所谓的Photo-Fries反应，A是相反的阳离子或阴离子充电，n优选为1或2，x为1或2，o为至少2，条件是在一个聚电解质中，[R-P-R']和/或[R1-Q-R1']基团都具有相同的符号。本发明进一步涉及膜的制备，其用途和制备本发明的具有表面浮雕结构的膜的复制品的方法。

2. 发明申请

US20090001632A1 Film Forming Material and Preparation of Surface Relief and Optically Anisotropic Structures by Irradiating a Film of the Said Material 失效
标题翻译：成膜材料和通过照射所述材料的膜来制备表面浮雕和光学各向异性结构
公开(公告)号：US20090001632A1
公开(公告)日：2009-01-01
申请号：US11574672
申请日：2005-08-30
申请人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
发明人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
IPC分类号： B29C41/42 , B05D3/12 , B05D3/06 , B32B3/10 , C08J3/28 , B05D5/06
CPC分类号： G03F7/001 , C08K5/23 , C08K5/45 , C08L79/00 , C08L79/02 , C08L101/02 , Y10S430/146 , Y10T428/24802 , C08L2666/36
摘要： The present invention is directed to a film forming, photoactive, homogeneously mixed material comprising a complex prepared from (a) at least one ionic photosensitive compound which may undergo a photoreaction, selected from photoiso-iso polyelectrolyte”) carrying residues which may undergo said photoreaction, and (b) at least one (“first”) polyelectrolyte carrying charges which are opposite to those of the active groups of the photosensitive material. This material has unique photochemical properties in that non-scattering, optically clear films may prepared therefrom which allow light-induced generation of optical anisotropy and of topological surface structures, e.g. such as surface relief gratings (SRG).
摘要翻译：本发明涉及一种成膜，光活性均匀混合的材料，其包含由（a）至少一种可能经历光反应的离子光敏化合物制备的络合物，所述络合物可以进行所述光反应的残余物，所述复合物选自光异性聚电解质“），和（b）至少一个（“第一”）聚电解质携带与感光材料的活性基团相反的电荷，该材料具有独特的光化学性质，因为可以制备非散射的光学透明膜，其允许光诱导产生光学各向异性和拓扑表面结构，例如表面浮雕光栅（SRG）。

3. 发明授权

US08026021B2 Film forming material and preparation of surface relief and optically anisotropic structures by irradiating a film of the said material 失效
标题翻译：成膜材料，并通过照射所述材料的膜制备表面浮雕和光学各向异性结构
公开(公告)号：US08026021B2
公开(公告)日：2011-09-27
申请号：US11574672
申请日：2005-08-30
申请人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
发明人： Joachim Stumpe , Leonid Goldenberg , Olga Kulikovska
IPC分类号： G11B7/24 , G03H1/02
CPC分类号： G03F7/001 , C08K5/23 , C08K5/45 , C08L79/00 , C08L79/02 , C08L101/02 , Y10S430/146 , Y10T428/24802 , C08L2666/36
摘要： The present invention is directed to a film forming, photoactive, homogeneously mixed material comprising a complex prepared from (a) at least one ionic photosensitive compound which may undergo a photoreaction, selected from photoisomerizations, photocycloadditions and photoinduced rearrangements, and/or (a′) at least one photosensitive polyelectrolyte (“second polyelectrolyte”) carrying residues which may undergo said photoreaction, and (b) at least one (“first”) polyelectrolyte carrying charges which are opposite to those of the active groups of the photosensitive material. This material has unique photochemical properties in that non-scattering, optically clear films may prepared therefrom which allow light-induced generation of optical anisotropy and of topological surface structures, e.g. such as surface relief gratings (SRG).
摘要翻译：本发明涉及一种成膜，光活性，均匀混合的材料，其包含由（a）至少一种可经历光反应的离子光敏化合物制备的络合物，其选自光异构化，光环加成和光诱导重排，和/或（a' ）至少一种携带可能经历所述光反应的残余物的光敏聚电解质（“第二聚电解质”），和（b）携带与感光材料的活性基团相反的电荷的至少一种（“第一”）聚电解质。该材料具有独特的光化学性质，因为可由其制备的非散射的光学透明膜，其允许光诱导产生光学各向异性和拓扑表面结构，例如，例如表面浮雕光栅（SRG）。

4. 发明授权

US07612879B2 Method and device for three-dimensionally determining the refractive index of transparent or partially transparent layers 失效
$Method and device for three-dimensionally determining the refractive index of transparent or partially transparent layers$
标题翻译：用于三维地确定透明或部分透明层的折射率的方法和装置
公开(公告)号：US07612879B2
公开(公告)日：2009-11-03
申请号：US10559650
申请日：2004-06-01
申请人： Joachim Stumpe , Christoph Jung , Olga Kulikovska
发明人： Joachim Stumpe , Christoph Jung , Olga Kulikovska
IPC分类号： G01J4/00
CPC分类号： G01N21/8422 , G01N21/211 , G01N21/41 , G01N2021/214 , G01N2021/4126
摘要： The present invention relates to a method and a device for three-dimensionally determining the refractive index and, if necessary, the layer thickness of transparent or partially transparent layers in which the layer (1) is irradiated at different angles of incidence (5) with polarised light, and variations in the polarisation of the light are measured and evaluated as the light passes through the layer (1). The method is characterized in that the measurement is carried out through an immersion medium (3) between which the layer (1) is inserted. A highly accurate determination of the refractive index of anisotropic thin layers in all three spatial directions is made possible by this method.
摘要翻译：本发明涉及一种用于三维地确定折射率的方法和装置，并且如果需要，可以以不同的入射角（5）照射层（1）的透明或部分透明层的层厚度，当光通过层（1）时，测量并评估光的偏振变化。该方法的特征在于，通过插入层（1）的浸渍介质（3）进行测量。通过这种方法可以高精度地确定各向异性薄层在所有三个空间方向上的折射率。

5. 发明申请

US20070097356A1 Method and device for three-dimensionally determining the refractive index of transparent or partially transparent layers 失效
$Method and device for three-dimensionally determining the refractive index of transparent or partially transparent layers$
标题翻译：用于三维地确定透明或部分透明层的折射率的方法和装置
公开(公告)号：US20070097356A1
公开(公告)日：2007-05-03
申请号：US10559650
申请日：2004-06-01
申请人： Joachim Stumpe , Christoph Jung , Olga Kulikovska
发明人： Joachim Stumpe , Christoph Jung , Olga Kulikovska
IPC分类号： G01N21/41
CPC分类号： G01N21/8422 , G01N21/211 , G01N21/41 , G01N2021/214 , G01N2021/4126
摘要： The present invention relates to a method and a device for three-dimensionally determining the refractive index and, if necessary, the layer thickness of transparent or partially transparent layers in which the layer (1) is irradiated at different angles of incidence (5) with polarised light, and variations in the polarisation of the light are measured and evaluated as the light passes through the layer (1). The method is characterised in that the measurement is carried out through an immersion medium (3) between which the layer (1) is inserted. A highly accurate determination of the refractive index of anisotropic thin layers in all three spatial directions is made possible by this method.
摘要翻译：本发明涉及一种用于三维地确定折射率的方法和装置，并且如果需要，可以以不同的入射角（5）照射层（1）的透明或部分透明层的层厚度，当光通过层（1）时，测量并评估光的偏振变化。该方法的特征在于，通过插入层（1）的浸渍介质（3）进行测量。通过这种方法可以高精度地确定各向异性薄层在所有三个空间方向上的折射率。

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