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    • 5. 发明授权
    • Burn rate modification of solid propellants with bismuth trioxide
    • 固体推进剂与三氧化铋的燃烧速率改性
    • US5372070A
    • 1994-12-13
    • US834123
    • 1992-02-10
    • Jamie B. NeidertRobert E. Askins
    • Jamie B. NeidertRobert E. Askins
    • C06B23/00C06B45/00C06B29/04
    • C06B23/007
    • Propellant formulations are provided which include non-toxic burn rate modifiers. In order to produce a usable propellant formulation, it is necessary to control the burn rate of the propellant. Failure to adequately control the propellant burn rate often results in unacceptable performance of the propellant. For example, during the operation of a rocket motor, or similar device which contains a propellant, the propellant may produce operating pressures which are too high or too low for the intended purpose of the device.It has often been the practice to add lead to rocket motor propellants in order to modify the burn rate and to maintain the burn rate within acceptable parameters. Lead, however, is known to be toxic and a pollutant. Accordingly, it is desirable to replace the lead in the formulation. It has been found herein that bismuth trioxide is capable of modifying the burn rate of propellants without resorting to lead as a burn rate additive. Accordingly, the use of bismuth trioxide is taught as effective burn rate modifiers in propellants, in order provide non-toxic means for modifying the propellant burn rate.
    • 提供了包括无毒燃烧速率调节剂的推进剂配方。 为了生产可用的推进剂制剂,需要控制推进剂的燃烧速率。 不能充分控制推进剂燃烧速率通常导致推进剂的不可接受的性能。 例如,在火箭发动机或包含推进剂的类似装置的操作期间,推进剂可能产生对于装置的预期目的来说太高或太低的操作压力。 为了改变燃烧速率并将燃烧速率保持在可接受的参数范围内,通常会增加引燃火箭发动机的推进剂。 然而,铅被认为是有毒的和污染物的。 因此,期望替代制剂中的铅。 本文已经发现,三氧化二铋能够改变推进剂的燃烧速率,而不需要使用铅作为燃烧速率添加剂。 因此,使用三氧化铋作为推进剂中的有效燃烧速率调节剂被教导,以提供用于改变推进剂燃烧速率的无毒手段。
    • 6. 发明授权
    • Castable double base solid rocket propellant containing ballistic
modifier pasted in an inert polymer
    • 含有弹性改性剂的铸造双基固体火箭推进剂粘贴在惰性聚合物中
    • US6024810A
    • 2000-02-15
    • US166942
    • 1998-10-06
    • Jamie B. NeidertEdna M. Williams
    • Jamie B. NeidertEdna M. Williams
    • B64G1/40C06B23/00C06B25/18C06B25/28C06D5/00F02K9/10C06B45/10C06B25/20
    • C06B21/0025C06B23/007C06B25/18
    • Castable propellant formulations are provided including reduced toxicity ballistic modifiers that do not adversely increase the sensitivity of the propellant to shock detonation. Failure to adequately control the propellant burn rate often results in unacceptable performance of the propellant. Carbon can act as an effective ballistic, but not to the extent of metal compounds. It has been found that pasting a ballistic modifier, including ballistic modifiers containing lead, in an inert polymer modifies the burn rate of propellants while allowing the use of a reduced amount of modifier to achieve the same desired burn rate modification as the prior art, and therefore creating reduced shortcomings associated with the ballistic modifiers. Accordingly, the use of from about 1% to about 6% burn rate modifier wherein the burn rate modifier includes a ballistic modifier pasted in an inert polymer is taught as an effective burn rate modifier in a propellant, in order to provide reduced toxicity means for modifying the propellant burn rate without increasing the sensitivity of the propellant to shock detonation.
    • 提供了可铸造的推进剂配方,包括减少毒性的弹道改性剂,其不会不利地增加推进剂对休克爆炸的敏感性。 不能充分控制推进剂燃烧速率通常导致推进剂的不可接受的性能。 碳可以作为有效的弹道,但不能达到金属化合物的程度。 已经发现,将惰性聚合物中含有铅的弹道改性剂的弹道改性剂粘贴在惰性聚合物中,改变了推进剂的燃烧速率,同时允许使用减少量的改性剂来实现与现有技术相同的所需燃烧速率改性,以及 因此产生与弹道改进剂相关的减少的缺点。 因此,使用约1%至约6%的燃烧率调节剂,其中燃烧速率改进剂包括粘贴在惰性聚合物中的防弹改性剂被教导为推进剂中的有效燃烧速率改性剂,以便提供减少毒性的方法 改变推进剂燃烧速率,而不增加推进剂对冲击爆震的敏感性。