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1. 发明申请

US20170233306A1 PROPELLANT COMPOSITIONS COMPRISING NITRAMINE OXIDANTS 审中-公开
公开(公告)号：US20170233306A1
公开(公告)日：2017-08-17
申请号：US15156394
申请日：2016-05-17
申请人： Soonkil KWON , Junsik HWANG , Jinseok KIM , Minkyu PARK
发明人： Soonkil KWON , Junsik HWANG , Jinseok KIM , Minkyu PARK
IPC分类号： C06B25/34 , C06B25/18
CPC分类号： C06B25/34 , C06B25/18
摘要： The present invention relates to a high energy-containing propellant composition and a use thereof. The propellant composition of the present invention is a propellant composition for guns, including: (a) 55 to 85 wt % of a nitrocellulose binder; (b) 10 to 35 wt % of a nitramine oxidant; (c) 1 to 4 wt % of a plasticizer having both a nitrate group and a nitramine group; and (d) 0.5 to 3 wt % of a stabilizer. The propellant composition of the present invention significantly improves a physical compatibility between the nitrocellulose binder and the oxidant using a plasticizer containing both a nitrate group and a nitramine group, leading to stable interior ballistics characteristics from low temperature to high temperature as well as improvement on the characteristics of an extrudate. Accordingly, the propellant composition of the present invention may be effectively applied to an ammunition for guns due to an excellent physical property and interior ballistic stability thereof.

2. 发明授权

US09395164B1 Methods of preparing nitrocelluse based propellants and propellants made therefrom 有权
标题翻译：制备硝基电池基推进剂和推进剂的方法
公开(公告)号：US09395164B1
公开(公告)日：2016-07-19
申请号：US14841151
申请日：2015-08-31
申请人： Orbital ATK, Inc.
发明人： William J. Worrell , Benjamin R. Vaughan , Jeffrey D. Archambault , Milca Fils-Aime
IPC分类号： F42B5/16 , C06B25/18 , F42B33/00
CPC分类号： F42B5/16 , C06B21/0016 , C06B21/0083 , C06B25/18
摘要： Methods of preparing propellant compositions for power loads and firearms that include providing pre-shaped particle sized starting material, shaped consistent with a desired final propellant product shape, and thereafter nitrating and stabilizing the pre-shaped starting material using boiling stabilization processes. The resulting nitrated propellants of the methods reliably exhibit complete stabilization, high nitrogen substitution, high shelf life and acceptable ballistic performance.
摘要翻译：制备用于动力负荷和火器的推进剂组合物的方法，其包括提供预制颗粒尺寸的起始材料，其形状与所需的最终推进剂产品形状一致，然后使用沸腾稳定化方法硝化和稳定预成型起始材料。所得到的硝化推进剂可靠地显示完全稳定，高氮替代，高保质期和可接受的弹道性能。

3. 发明申请

US20140352566A1 NITROGLYCERINE-FREE MULTI-PERFORATED HIGH-PERFORMING PROPELLANT SYSTEM 审中-公开
标题翻译：无氮多功能高性能高性能推进系统
公开(公告)号：US20140352566A1
公开(公告)日：2014-12-04
申请号：US14345037
申请日：2011-09-15
申请人： Ulrich Schaedeli , Dominik Antenen , Attila Vamos
发明人： Ulrich Schaedeli , Dominik Antenen , Attila Vamos
IPC分类号： F42B5/16 , C06B25/18 , B29C47/00
CPC分类号： F42B5/16 , B29C48/0022 , B29C48/11 , B29C2793/009 , B29K2001/18 , B29K2105/0005 , B29K2105/0038 , B29K2995/0094 , B29L2031/737 , B29L2031/777 , C06B25/18 , C06B25/34 , C06B45/00 , C06B45/105 , C06B45/12 , G06Q99/00
摘要： The propulsion system for the acceleration of projectiles is based on a multi-perforated grain propellant and is composed from nitrocellulose, a crystalline energy carrier of a nitramine type and an inert plasticizing additive. The number of perforations is 2 to 6, preferably 4. The propellant grains can have round or polygonic profiles, depending on the number of perforations. The preferred grain geometry is cubic with a rectangular grain profile. The nitramine compound contains a structural element of the general chemical structure formula R—N—NO2, where R is a residual group. The nitramine compound is present in a concentration in the range from 0 to 35% by mass, in particular in the range from 5 to 25% by mass. The nitramine compound is preferably RDX. The inert plasticizing additive is a water-insoluble polyoxo compound, if necessary in combination with a substance containing carboxyl groups. In layers near the surface an increased concentration can be present. The inert plasticizing additive is present in a concentration of 0 to 10% by mass, preferred 0 to 5% by mass.
摘要翻译：用于加速射弹的推进系统基于多孔颗粒推进剂，由硝化纤维素，硝胺型结晶能载体和惰性塑化添加剂组成。穿孔的数量为2至6，优选4.推进剂颗粒可以具有圆形或多角形轮廓，这取决于穿孔的数量。优选的晶粒几何形状是具有矩形晶粒轮廓的立方体。硝胺化合物含有一般化学结构式R-N-NO 2的结构元素，其中R是残基。硝胺化合物的浓度范围为0〜35质量％，特别是5〜25质量％。硝胺化合物优选为RDX。惰性增塑添加剂是一种不溶于水的聚氧化合物，如果需要与含有羧基的物质结合使用。在靠近表面的层中，可以存在增加的浓度。惰性增塑添加剂的浓度为0〜10质量％，优选为0〜5质量％。

4. 发明授权

US08597444B1 Foamed celluloid combustible material 有权
标题翻译：发泡赛璐id可燃材料
公开(公告)号：US08597444B1
公开(公告)日：2013-12-03
申请号：US12977374
申请日：2010-12-23
申请人： Ming-Wan Young , Costas G. Gogos , Niloufar Faridi , Linjie Zhu , Peter Bonnett , Howard Shimm , Elbert Caravaca , Joseph Palk, Jr. , Dale Conti , Mohamed Elalem , Fei Shen
发明人： Ming-Wan Young , Costas G. Gogos , Niloufar Faridi , Linjie Zhu , Peter Bonnett , Howard Shimm , Elbert Caravaca , Joseph Palk, Jr. , Dale Conti , Mohamed Elalem , Fei Shen
IPC分类号： C06B45/10 , C06B25/00 , C06B25/18 , D03D23/00 , D03D43/00
CPC分类号： F42B5/38 , C06B23/002 , C06B25/20 , F42B5/188 , F42B5/192 , F42B30/12
摘要： By using generally known chemically, physically, or a combination thereof, means to foam celluloid, a foamed celluloid material is invented with a density of less than about 1.25 gm/cm3, which material is relatively low cost, very fast burning, very low residue, easily moldable, and which material exhibits good mechanical strength, and provides a good water barrier. These characteristics make this foamed celluloid a preferred choice for military artillery propellant charge bags, military mortar and civilian fireworks increment charges, combustible cartridges, flare housings, igniter tubes, as well as, closure disks, combustible enclosures and components thereof, among other applications.
摘要翻译：通过使用通常已知的化学，物理或其组合的手段来泡沫赛璐id，发明了一种密度小于约1.25gm / cm 3的发泡赛璐id体材料，该材料成本相对较低，燃烧非常快，残渣极少，易模塑，哪种材料具有良好的机械强度，并提供良好的防水性。这些特征使得这种发泡的赛璐id是军事炮兵推进剂充电袋，军用砂浆和民用烟花增压装置，可燃筒，火炬罩，点火器管以及封闭盘，可燃外壳及其部件以及其他应用的首选。

5. 发明申请

US20090199938A1 Nitrocellulose Composition And Uses Therefor 审中-公开
标题翻译：硝酸纤维素组合物及其用途
公开(公告)号：US20090199938A1
公开(公告)日：2009-08-13
申请号：US12027440
申请日：2008-02-07
申请人： Werner Gottwald
发明人： Werner Gottwald
IPC分类号： C06B25/18 , C06B25/34
CPC分类号： C06B25/18 , C06B45/00
摘要： A nitrocellulose composition comprises an admixture comprising: from about 75 weight percent to about 85 weight percent nitrocellulose; and from about 15 weight percent to about 25 weight percent camphor, based upon the weight of the admixture; and from about 1 weight percent to about 5 weight percent of a stabilizer (based on the total weight of the composition), wherein the stabilizer is chosen from the group consisting of N,N-Diethyl-N,N′-diphenylurea, N,N′-Dimethyl-N,N′-diphenylurea, 1,1-Diphenylurea, N-methyl-N,N′-diphenylurea, 1-Ethyl-3,3′-diphenylurea, Diphenylamine, 2-Nitro-diphenylamine, 4-Nitro-diphenylamine; Triphenylamine; p-Nitro-N-methylaniline, p-Nitro-ethylaniline, soybean oil, castor oil, sodium silicate, lactic acid amide, and benzonate; and from about 1 weight percent to about 5 weight percent of azodicarbonic acid diamide, based on the total weight of the composition. The composition is heated at a temperature sufficient to cause it to polymerize, after which it is formed into sheets, from which components for munitions, such as artillery, small arms, modular artillery charge systems and mortar increments are formed. The components of the mortar increments are joined together, and after being filled with a propellant composition, one or more mortar increments is attached to a mortar shell.
摘要翻译：硝化纤维素组合物包含混合物，其包含：约75重量％至约85重量％的硝化纤维素; 和约15重量％至约25重量％的樟脑，基于该混合物的重量; 和约1重量％至约5重量％的稳定剂（基于组合物的总重量），其中稳定剂选自N，N-二乙基-N，N'-二苯基脲，N， N'-二甲基-N，N'-二苯基脲，1,1-二苯基脲，N-甲基-N，N'-二苯基脲，1-乙基-3,3'-二苯基脲，二苯胺，2-硝基 - 二苯胺，硝基二苯胺; 三苯胺; 对硝基-N-甲基苯胺，对硝基乙基苯胺，大豆油，蓖麻油，硅酸钠，乳酸酰胺和苯甲酸酯; 和约1重量％至约5重量％的偶氮二甲酸二酰胺，基于组合物的总重量。将组合物在足以使其聚合的温度下加热，之后将其形成为片材，由此形成用于弹药的组分，例如火炮，小武器，模块化火炮装料系统和砂浆增量。砂浆增量的组分连接在一起，并且在填充推进剂组合物之后，将一个或多个砂浆增量附着在砂浆壳上。

6. 发明申请

US20050000610A1 Production of water-free nitrocellulose and explosive substances that have a spheroidal shape 审中-公开
标题翻译：生产无水硝化纤维素和具有球形形状的爆炸性物质
公开(公告)号：US20050000610A1
公开(公告)日：2005-01-06
申请号：US10493367
申请日：2002-10-23
申请人： Gerhard Huber
发明人： Gerhard Huber
IPC分类号： C06B21/00 , C06B25/18 , C08L1/18 , D03D23/00
CPC分类号： C08L1/18 , C06B21/0066 , C06B25/18
摘要： The invention relates to a method for producing shaped explosive substances, in particular for a propellant charge substrate such as spheroidal propellant charge powder, for example, from a stabilized explosive substance, whereby the stabilized explosive substance is first dissolved in a solvent, the stabilizing substance is then removed from the mixture, and particles are shaped from the resulting mixture. The invention further relates to a method for producing a varnish made from a substantially water-free explosive substance.
摘要翻译：本发明涉及一种生产成形爆炸物质的方法，特别是用于诸如球形推进剂装药粉末的推进剂装料基材例如稳定的爆炸性物质，其中稳定的爆炸性物质首先溶解在溶剂中，稳定物质然后从混合物中取出，并从所得到的混合物中形成颗粒。本发明还涉及一种由基本上无水的爆炸性物质制成的清漆的方法。

7. 发明授权

US6444062B2 Perforated propellant and method of manufacturing same 有权
标题翻译：穿孔推进剂及其制造方法
公开(公告)号：US6444062B2
公开(公告)日：2002-09-03
申请号：US88240201
申请日：2001-06-16
申请人： GEN DYNAMICS ORDNANCE & TACTIC
发明人： O'MEARA WILLIAM L , HOWARD JONATHON M , GONZALEZ ANTONIO F , WILLIAMSON JOHN J
IPC分类号： C06B21/00 , C06B25/18 , D03D23/00
CPC分类号： C06B25/18 , C06B21/0066 , C06B21/0075
摘要： The present invention is directed to a propellant composition made from a lacquer, the lacquer comprising: (a) from about 15 to about 70 wt % of an organic solvent; (b) from about 0.1 to about 2.5 wt % of a stabilizer; (c) optionally, from about 0% to about 40 wt % of an energetic plasticizer; (d) optionally, from about 0 to about 10 wt % of a nonenergetic plasticizer; (e) optionally, from about 0 to about 10 wt % water; (f) optionally, from about 0 to about 15 wt % of additional additives; and balance being nitrocellulose; all weight percents based on the total weight of the composition, and wherein the lacquer has a viscosity of less than 10 million centipoise when processed. The present invention is also directed to an efficient and safe method of making perforated propellant grains using the above lacquer composition, as well as propellant grains having ellipsoidal cross sections or outwardly extending ridges.
摘要翻译：本发明涉及由漆制成的推进剂组合物，所述漆包含：（a）约15至约70重量％的有机溶剂; （b）约0.1至约2.5重量％的稳定剂; （c）任选地，约0％至约40％重量的能量增塑剂; （d）任选的约0至约10重量％的非易失性增塑剂; （e）任选地，约0至约10重量％的水; （f）任选地，约0至约15重量％的其它添加剂; 余量为硝酸纤维素; 基于组合物的总重量的所有重量百分数，并且其中所述漆在加工时具有小于1000万厘泊的粘度。本发明还涉及使用上述漆组合物制造穿孔推进剂颗粒的有效和安全的方法，以及具有椭圆形横截面或向外延伸的脊的推进剂颗粒。

8. 发明授权

US5468311A Binder system for crosslinked double base propellant 失效
标题翻译：交联双基推进剂系统
公开(公告)号：US5468311A
公开(公告)日：1995-11-21
申请号：US22123
申请日：1979-03-05
申请人： James H. Godsey , James L. Jacox , Robert F. Keller , Richard J. Legare
发明人： James H. Godsey , James L. Jacox , Robert F. Keller , Richard J. Legare
IPC分类号： C06B25/18 , C06B45/10
CPC分类号： C06B45/105 , C06B25/18
摘要： An improved crosslinked double base propellant composition is provided which has an improved binder system. The binder system is based on nitrocellulose (NC) having an intrinsic viscosity of from about 0.4 dl./gram to about 1.5 dl./gram and a polyester polyol or polyether polyol (polyol), in which the weight ratio of NC/polyol is from about 0.03/1 to about 0.8/1. The binder crosslinking agents are diisocyanates, and the ratio of NCO groups of the diisocyanates to combined OH groups of nitrocellulose and polyol is from about 0.7/1 to 1.2/1. Energetic plasticizer such as nitroglycerin comprises from about 68% to about 82% by weight of the binder. The binder contains a stabilizer and is capable of high solids loading, i.e., 70% to 77% solids.
摘要翻译：提供改进的交联双基推进剂组合物，其具有改进的粘合剂体系。粘合剂体系基于特性粘度为约0.4dl / g至约1.5dl / g的硝酸纤维素（NC）和聚酯多元醇或聚醚多元醇（多元醇），其中NC /多元醇的重量比为约0.03 / 1至约0.8 / 1。粘合剂交联剂是二异氰酸酯，二异氰酸酯的NCO基与硝基纤维素和多元醇的组合OH基的比例为约0.7 / 1-1.2 / 1。活性增塑剂如硝酸甘油包含约68％至约82％重量的粘合剂。粘合剂含有稳定剂并且能够高固含量，即70％至77％固体。

9. 发明授权

US5218166A Modified nitrocellulose based propellant composition 失效
标题翻译：改性硝基纤维素基推进剂组合物
公开(公告)号：US5218166A
公开(公告)日：1993-06-08
申请号：US763266
申请日：1991-09-20
申请人： John B. Schumacher
发明人： John B. Schumacher
IPC分类号： C06B21/00 , C06B25/18
CPC分类号： C06B21/0016 , C06B25/18
摘要： The present invention relates to modified propellant compositions of either single or multiple based type which are obtained by resolvating a conventional, previously solvated nitrocellulose-based granular propellant with a solvent such as methyl ethyl ketone followed by the addition of glycerine to replasticize the composition and create a slurry. Upon evaporation of the solvent, a waterproof and self-supporting explosive composition is produced which is extremely stable and resistant to impact, friction and static discharge.
摘要翻译：本发明涉及单一或多种类型的改性推进剂组合物，其通过用溶剂如甲基乙基甲酮溶解常规的先前溶剂化的硝酸纤维素基颗粒推进剂，然后加入甘油来重新组合并产生一种浆料溶剂蒸发后，产生了极其稳定和耐冲击，摩擦和静电放电的防水和自支撑的炸药组合物。

10. 发明授权

US5053087A Ultra high-energy azide containing gun propellants 失效
标题翻译：超高能量含氮枪
公开(公告)号：US5053087A
公开(公告)日：1991-10-01
申请号：US487472
申请日：1990-03-02
申请人： Joseph E. Flanagan , John C. Gray
发明人： Joseph E. Flanagan , John C. Gray
IPC分类号： C06B25/18 , C06B25/34 , C06D5/00 , C06D5/06
CPC分类号： C06B25/18 , C06B25/34
摘要： A family of ultra high-energy gun propellant systems based upon a nitrocellulose binder matrix, and containing a variety of azide components to provide a formulation having reduced isochoric flame temperatures and ultra-high mass impetus.

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