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1. 发明授权

US4778929A Continuous hydroformylation of olefinically unsaturated compounds 失效
标题翻译：烯属不饱和化合物的连续加氢甲酰化
公开(公告)号：US4778929A
公开(公告)日：1988-10-18
申请号：US70963
申请日：1987-07-08
申请人： Peter Zehner , Herwig Hoffmann , Wolfgang Richter , Dieter Stuetzer , Max Strohmeyer , Helmut Walz , Erich Weippert
发明人： Peter Zehner , Herwig Hoffmann , Wolfgang Richter , Dieter Stuetzer , Max Strohmeyer , Helmut Walz , Erich Weippert
IPC分类号： C07B61/00 , B01J31/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C67/00
CPC分类号： C07C45/50
摘要： Olefinically unsaturated compounds are hydroformylated continuously, the olefin being passed into the lower region of the reactor, under from 1 to 40 bar and at from 50.degree. to 140.degree. C. with the aid of a rhodium complex as a catalyst in a hydroformylation reactor having a liquid reaction zone which occupies about 60-85% of the reactor volume, the gaseous products and reactants being removed from the hydroformylation reactor, the products being isolated and the major part of the remaining gas being recycled to the reactor by the cycle gas method, by a process in which from 20 to 80% by volume of the cycle gas is fed into the hydroformylation reactor above the liquid reaction zone and/or below the liquid surface in the top fourth of the liquid reaction zone.
摘要翻译：烯化不饱和化合物连续加氢甲酰化，在加氢甲酰化反应器中借助于铑络合物作为催化剂，将烯烃在1至40巴和50至140℃下进入反应器的下部区域，占反应器体积约60-85％的液体反应区，气态产物和反应物从加氢甲酰化反应器中除去，产物被分离，剩余气体的主要部分通过循环气体法再循环到反应器，其中循环气体的20至80体积％被输入到液体反应区上方的加氢甲酰化反应器和/或液体反应区顶部第四个液体表面下方的流程。

2. 发明授权

US4659866A Continuous preparation of furmamide 失效
标题翻译：连续制备呋喃胺
公开(公告)号：US4659866A
公开(公告)日：1987-04-21
申请号：US347578
申请日：1982-02-10
申请人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Rudolf Irnich , Otto Kratzer
发明人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Rudolf Irnich , Otto Kratzer
IPC分类号： C07C231/02 , C07C20060101 , C07C67/00 , C07C231/00 , C07C233/03 , C07C102/06
CPC分类号： C07C231/02
摘要： Formamide is prepared continuously from methyl formate and ammonia, pure methanol being recovered, by a process wherein(a) the reaction of methyl formate and ammonia is carried out predominantly in the liquid phase in the upper region of a reaction column R having a total of from 15 to 30 theoretical plates,(b) the methanol formed in this reaction is removed, together with small amounts of formamide, from the column or the evaporator in vaporus form at the level of plates 1-5 (counted from the bottom),(c) the formamide is removed from this methanol/formamide mixture, together with small amounts of methanol, in a distillation column D1 and recycled to R, and(d) the small amounts of methanol contained in the bottom product from R, which substantially consists of formamide and in this column should be at from 110.degree. to 130.degree. C., are separated off in a distillation column D2.
摘要翻译：甲酸甲酯由甲酸甲酯和氨，回收的纯甲醇连续制备，其中（a）甲酸甲酯和氨的反应主要在反应塔R的上部区域的液相中进行，其总共具有从15到30个理论塔板，（b）将该反应中形成的甲醇与少量甲酰胺一起从塔或蒸发器以蒸汽形式在板1-5的水平（从底部计数）中除去，（c）将甲酰胺与蒸馏塔D1中的少量甲醇一起从该甲醇/甲酰胺混合物中除去并再循环至R，和（d）从R中的底部产物中含有的少量甲醇，其基本上由甲酰胺组成，该柱应在110℃至130℃，在蒸馏塔D2中分离。

3. 发明授权

US4067914A Manufacture of butynediol 失效
标题翻译：丁炔二醇的制造
公开(公告)号：US4067914A
公开(公告)日：1978-01-10
申请号：US671384
申请日：1976-03-29
申请人： Wolfgang Reiss , Siegfried Winderl , Wolfgang Schroeder , Herwig Hoffmann
发明人： Wolfgang Reiss , Siegfried Winderl , Wolfgang Schroeder , Herwig Hoffmann
IPC分类号： C07C29/42 , B01J31/00 , C07B61/00 , C07C27/00 , C07C33/046 , C07C67/00 , C07C29/00
CPC分类号： C07C33/046
摘要： In a process for the manufacture of butynediol by the reaction of formaldehyde and acetylene in aqueous solution, in which a catalyst is used which is produced by the action of acetylene and formaldehyde on copper (II) compounds, the catalyst becomes inactive when it is treated for a relatively long period with formaldehyde at elevated temperature in the absence of acetylene so that it must constantly remain in contact with acetylene-containing solution if its temperature is above 70.degree. C.
摘要翻译：在通过甲醛和乙炔在水溶液中反应制造丁炔二醇的方法中，其中使用通过乙炔和甲醛作用于铜（II）化合物而产生的催化剂，当处理时催化剂变得不活动在不存在乙炔的情况下，甲醛在高温下持续相当长的时间，如果其温度高于70℃，则必须与乙炔溶液一直保持接触。

4. 发明授权

US4062899A Butynediol manufacture 失效
标题翻译：丁炔二醇制造
公开(公告)号：US4062899A
公开(公告)日：1977-12-13
申请号：US712701
申请日：1976-08-09
申请人： Peter Rudolf Laurer , Wolfgang Schroeder , Herwig Hoffmann , Heinz Lingk
发明人： Peter Rudolf Laurer , Wolfgang Schroeder , Herwig Hoffmann , Heinz Lingk
IPC分类号： B01J23/00 , B01J23/72 , B01J27/232 , C01G3/00 , C07C29/00
CPC分类号： B01J27/232 , B01J23/007 , B01J23/72 , C01G3/00
摘要： Basic carbonate which contains copper and aluminum and is suitable for the manufacture of copper-containing catalysts and which has the general formula Cu.sub.m Al.sub.6 (CO.sub.3).sub.0.5m O.sub.3 (OH).sub.m+12, where m may be an integer or non-integer between 2 and 6.
摘要翻译：含铜和铝的碱性碳酸盐，适用于制造含铜催化剂，具有通式CumAl6（CO3）0.5mO3（OH）m + 12，其中m可以是2和2之间的整数或非整数， 6。

5. 发明授权

US4048116A Catalyst for the hydrogenation of acetylene alcohols 失效
标题翻译：用于氢化乙炔醇的催化剂
公开(公告)号：US4048116A
公开(公告)日：1977-09-13
申请号：US706471
申请日：1976-07-19
申请人： Dieter Voges , Karl Baer , Juergen Boudier , Siegfried Winderl , Herwig Hoffmann
发明人： Dieter Voges , Karl Baer , Juergen Boudier , Siegfried Winderl , Herwig Hoffmann
IPC分类号： B01J23/88 , C07B61/00 , C07C27/00 , C07C29/17 , C07C31/02 , C07C67/00 , C07C209/00 , C07C209/70 , C07C213/00 , C07C213/08 , C07C215/08 , B01J23/72 , B01J23/84
CPC分类号： B01J23/8898 , C07C29/172
摘要： An improved catalyst for the complete hydrogenation of acetylenically unsaturated alcohols and based on nickel, copper and manganese. The catalyst is used without a support and molybdenum is additionally included in an amount approximately equal to the content of manganese.
摘要翻译：用于炔属不饱和醇的完全氢化并基于镍，铜和锰的改进的催化剂。催化剂不需要载体就可以使用，钼的含量大约等于锰的含量。

6. 发明授权

US3691205A Production of 6-alkoxy-5,6-dihydro-4h-pyrans 失效
标题翻译： 6-烷基-5,6-二氢-4H-吡啶的生产
公开(公告)号：US3691205A
公开(公告)日：1972-09-12
申请号：US3691205D
申请日：1971-02-09
申请人： HERWIG HOFFMANN , GERHARD JESCHEK , ALFRED KUERZINGER , ERWIN SCHMIDT , WILLIBALD SCHOENLEBEN , DIETER VOGES , SIEGFRIED WINDERL
发明人： HOFFMANN HERWIG , JESCHEK GERHARD , KUERZINGER ALFRED , SCHMIDT ERWIN , SCHOENLEBEN WILLIBALD , VOGES DIETER , WINDERL SIEGFRIED
IPC分类号： C07D309/30 , C07D7/10
CPC分类号： C07D309/30
摘要： A process for the production of 6-alkoxy-5,6-dihydro-4H-pyrans by reaction of Alpha , Beta -unsaturated aldehydes with vinyl ethers. The products are valuable intermediates, for example for the production of glutaraldehyde or substituted glutaraldehydes which may be used for example as tanning agents for leather.

7. 发明授权

US5191044A Preparation of polyisobutene 失效
标题翻译：聚氨酯的制备
公开(公告)号：US5191044A
公开(公告)日：1993-03-02
申请号：US772804
申请日：1991-10-08
申请人： Hans P. Rath , Herwig Hoffmann , Peter Reuter , Helmut Mach
发明人： Hans P. Rath , Herwig Hoffmann , Peter Reuter , Helmut Mach
IPC分类号： C08F4/12 , C08F2/00 , C08F4/06 , C08F4/14 , C08F10/00 , C08F10/10
CPC分类号： C08F10/10
摘要： A process for the preparation of polyisobutene from isobutene and/or hydrocarbons containing isobutene in the presence of a complex of BF.sub.3 and an alcohol, wherein the free BF.sub.3 is substantially removed from the complex solution and/or from the reaction chamber.
摘要翻译：在BF 3和醇的配合物存在下，从异丁烯和/或含有异丁烯的烃制备聚异丁烯的方法，其中游离BF 3基本上从复合溶液和/或从反应室除去。

8. 发明授权

US4996324A Preparation of alkanols which are substituted in the 1 position by aromatic or heterocyclic radicals 失效
标题翻译：通过芳族或杂环基团在1位上被取代的烷醇的制备
公开(公告)号：US4996324A
公开(公告)日：1991-02-26
申请号：US266270
申请日：1988-10-26
申请人： Kaspar Bott , Herwig Hoffmann , Walter Scheidmeir , Horst Trapp
发明人： Kaspar Bott , Herwig Hoffmann , Walter Scheidmeir , Horst Trapp
IPC分类号： C07C29/34 , C07C33/20 , C07D213/30
CPC分类号： C07C29/34
摘要： ##STR1## where R
1 is an aromatic or heterocyclic radical, R
2 is a straight-chain or branched alkyl raical and R
3 is hydrogen, methyl or ethyl, are prepared by reacting a secondary alcohol of the formula ##STR2## with a primary alcohol of the formula R
2 OH (III) in the presence of an alkali metal hydroxide at from 150° to 300° C.
摘要翻译：其中R 1是芳族或杂环基，R 2是直链或支链烷基，R 3是氢，甲基或乙基，是通过使式II的仲醇与伯醇的式R 2 OH（III）在碱金属氢氧化物存在下在150-300℃下反应。

9. 发明授权

US4262140A Production of anhydrous or substantially anhydrous formic acid 失效
标题翻译：生产无水或基本无水的甲酸
公开(公告)号：US4262140A
公开(公告)日：1981-04-14
申请号：US99760
申请日：1979-12-03
申请人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Otto Kratzer , Rudolf Irnich
发明人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Otto Kratzer , Rudolf Irnich
IPC分类号： C07C53/02 , C07C51/00 , C07C51/09 , C07C51/44 , C07C51/48 , C07C67/00 , B01D3/34
CPC分类号： C07C51/44 , C07C51/09 , C07C51/48
摘要： A process for the production of anhydrous or substantially anhydrous formic acid by hydrolysis of methyl formate which is carried out in a column having an upper fractionating section, a middle hydrolysis section and a lower extraction section and in which(a) the hydrolysis is carried out in the middle section of the columm, with water and methyl formate in countercurrent,(b) the resulting formic acid is extracted, in the lower section of the column, by means of a carboxylic acid amide which is fed into the lower end of the middle section of the column,(c) the extract phase, consisting in the main of formic acid and the carboxylic acid amide, is distillatively dehydrated, or substantially dehydrated, in the lower section of the column,(d) the methanol and uncovered methyl formate are removed by fractional distillation in the upper section of the column and(e) the pure formic acid or concentrated aqueous formic acid is distilled from the anhydrous or substantially anhydrous extract phase in a second column, leaving the carboxylic acid amide.
摘要翻译：一种通过水解甲酸甲酯生产无水或基本上无水的甲酸的方法，该甲酸甲酯在具有上部分馏段，中间水解段和下部萃取段的塔中进行，其中（a）进行水解在水的中间部分，与水和甲酸甲酯逆流，（b）所得甲酸在柱的下部通过羧酸酰胺萃取，该羧酸酰胺进料到塔的中间部分，（c）主要由甲酸和羧酸酰胺组成的提取相在塔的下部进行蒸馏脱水或基本上脱水，（d）甲醇和未被覆盖的甲基甲酸盐在塔的上部通过分馏除去，（e）从无水或基本上无水的提取物中蒸馏出纯甲酸或浓缩的甲酸水溶液相在第二塔中，留下羧酸酰胺。

10. 发明授权

US4197258A Manufacture of 1-disubstituted aminoalk-2-yn-4-ols 失效
标题翻译： 1-二取代的氨基亚烷基-2-炔-4-醇的制备
公开(公告)号：US4197258A
公开(公告)日：1980-04-08
申请号：US969663
申请日：1978-12-15
申请人： Herwig Hoffmann , Heinz Graefje , Wolfgang Koernig , Siegfried Winderl
发明人： Herwig Hoffmann , Heinz Graefje , Wolfgang Koernig , Siegfried Winderl
IPC分类号： C07D295/084 , C07D207/04
CPC分类号： C07D295/084
摘要： The manufacture of N-disubstituted 1-aminoalk-2-yn-4-ols by reacting a secondary amine, e.g. a dialkylamine, formaldehyde and an acetylene-alcohol by a Mannich reaction, using a copper catalyst, takes place with better yield and at a higher rate if carried out in the presence of iodine or of a bromide or iodide.
摘要翻译： N-二取代的1-氨基
碳-2-炔-4-醇的制备通过使仲胺例如通过Mannich反应使用铜催化剂，以更好的产率发生二烷基胺，甲醛和乙炔醇，并且如果在碘或溴或碘的存在下进行，则以更高的速率进行。

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