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    • 6. 发明授权
    • Method for producing epoxides
    • 环氧化物生产方法
    • US5486627A
    • 1996-01-23
    • US348639
    • 1994-12-02
    • George J. Quarderer, Jr.Curtis N. SwisherDavid L. Trent
    • George J. Quarderer, Jr.Curtis N. SwisherDavid L. Trent
    • C07D301/26C07D303/04C07D303/08C07D303/14
    • C07D301/26
    • Described herein is a method for producing epoxides which is continuous, inhibits formation of chlorinated byproducts, and eliminates or substantially reduces waste water discharge. The method includes:(a) forming a low chlorides aqueous hypochlorous acid solution;(b) contacting the low chlorides aqueous hypochlorous acid solution with at least one unsaturated organic compound to form an aqueous organic product comprising at least olefin chlorohydrin;(c) contacting at least the olefin chlorohydrin with an aqueous alkali metal hydroxide to form an aqueous salt solution product containing at least epoxide; and(d) isolating the epoxide from the aqueous salt solution;wherein water is recovered from the product of at least Step (b) and recycled into Step (a) for use in forming the low chlorides aqueous hypochlorous acid solution. In this process, not only is the water internally recycled after Step (b), but a concentrated brine solution is generated in both Steps (a) and (d) which is useful in other processes such as electrochemical production of chlorine and caustic. The chlorine and caustic, in turn, may then be recycled back to the method of this invention.
    • 本文描述了一种连续生产环氧化物的方法,抑制氯化副产物的形成,并且消除或显着减少废水排放。 该方法包括:(a)形成低氯化物次氯酸水溶液; (b)将低氯化物次氯酸水溶液与至少一种不饱和有机化合物接触以形成至少含有氯代醇的含水有机产物; (c)至少使烯丙基氯醇与碱金属氢氧化物水溶液接触以形成至少含有环氧化物的盐水溶液产物; 和(d)从盐水溶液中分离环氧化物; 其中从至少步骤(b)的产物中回收水并再循环到步骤(a)中,以用于形成低氯酸盐次氯酸水溶液。 在这个过程中,不仅在步骤(b)之后内部循环的水,而且在步骤(a)和(d)中产生浓缩的盐水溶液,其可用于其它方法如氯和苛性碱的电化学生产。 然后将氯和苛性碱又可循环回本发明的方法。