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    • 6. 发明授权
    • Multi-stage process and apparatus for recovering dichlorohydrins
    • 用于回收二氯丙醇的多级方法和装置
    • US08586802B2
    • 2013-11-19
    • US12935303
    • 2009-03-18
    • Bruce D. HookAndrei MerenovDan Tirtowidjojo
    • Bruce D. HookAndrei MerenovDan Tirtowidjojo
    • C07C29/78B01J8/00
    • C07C29/82B01D3/14B01D3/36C07C31/36
    • A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated-aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising water, chlorinating agents, catalysts and/or esters of catalysts is disclosed. The mixture is distilled or fractionated to separate a lower boiling fraction comprising dichlorohydrin(s) from the mixture to form a higher boiling fraction comprising the residue of the distillation or fractionation. The higher boiling fraction is distilled or fractionated to separate remaining dichlorohydrin(s) from the above mixture to form an even higher boiling fraction comprising the residue of the distillation or fractionation. At least some of the lower boiling fraction and the dichlorohydrin(s) are recovered. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, reduced capital investment in recovery equipment, and reduced energy utilization while maintaining the quality of dichlorohydrin product produced and not increasing the amount of undesired byproducts formed.
    • 一种用于从包含二氯代醇,一种或多种选自二氯丙醇,一氯代醇和/或其酯的酯,以及多羟基化脂族烃化合物和/或其酯的化合物和一种或多种包含水的物质的混合物中回收二氯代醇的方法和装置 ,公开了氯化剂,催化剂和/或催化剂的酯。 将混合物蒸馏或分馏以从混合物中分离包含二氯丙醇的低沸点馏分以形成包含蒸馏或分馏残余物的较高沸点馏分。 将较高沸点馏分蒸馏或分馏以从上述混合物中分离剩余的二氯代醇,以形成包含蒸馏或分馏残余物的更高沸点馏分。 回收至少一些较低沸点馏分和二氯代丙醇。 优点包括对于给定的蒸馏塔更有效地回收二氯代醇,由于避免了有利于形成重质副产物的条件而减少了浪费,减少了回收设备的资本投入,并降低了能源利用率,同时保持了生产的二氯丙醇产品的质量并且不增加 形成不希望的副产物的量。