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1. 发明授权

US07429372B2 Hydrogen storage by reversible hydrogenation of pi-conjugated substrates 有权
标题翻译：通过π-共轭底物的可逆氢化来储存氢
公开(公告)号：US07429372B2
公开(公告)日：2008-09-30
申请号：US10833484
申请日：2004-04-27
申请人： Guido Peter Pez , Aaron Raymond Scott , Alan Charles Cooper , Hansong Cheng
发明人： Guido Peter Pez , Aaron Raymond Scott , Alan Charles Cooper , Hansong Cheng
IPC分类号： C01B3/00 , F17C11/00
CPC分类号： C01B3/0015 , Y02E60/328
摘要： Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, nitrile, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.
摘要翻译：提供了通过扩展的π-共轭底物的基本可逆的催化氢化来提供氢的方法，其包括大的多环芳烃，具有氮杂原子的多环芳烃，具有氧杂原子的多环芳烃，具有烷基的多环芳烃烷氧基，腈，酮，醚或聚醚取代基，包含5元环的π-共轭分子，包含具有氮或氧杂原子的六元和五元环的π-共轭分子和延伸的π-共轭有机聚合物。包含在延伸的π-共轭体系的至少部分氢化形式中的氢可以通过在脱氢催化剂的存在下通过催化脱氢来容易地释放使用，所述脱氢催化剂可以通过降低氢气压力来实现，通常压力大于0.1巴或将温度升高到小于250℃或更低，或通过这两个工艺参数的组合。

2. 发明授权

US07351395B1 Hydrogen storage by reversible hydrogenation of pi-conjugated substrates 有权
公开(公告)号：US07351395B1
公开(公告)日：2008-04-01
申请号：US11266803
申请日：2005-11-04
申请人： Guido Peter Pez , Aaron Raymond Scott , Alan Charles Cooper , Hansong Cheng , Frederick Carl Wilhelm , Atteye Houssein Abdourazak
发明人： Guido Peter Pez , Aaron Raymond Scott , Alan Charles Cooper , Hansong Cheng , Frederick Carl Wilhelm , Atteye Houssein Abdourazak
IPC分类号： C01B3/00 , F17C11/00
CPC分类号： C01B3/0015 , C01B3/26 , C01B2203/1252 , F17C11/005 , Y02E60/321 , Y02E60/328
摘要： Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, nitrile, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.

3. 发明授权

US06596055B2 Hydrogen storage using carbon-metal hybrid compositions 失效
公开(公告)号：US06596055B2
公开(公告)日：2003-07-22
申请号：US09988084
申请日：2001-11-19
申请人： Alan Charles Cooper , Guido Peter Pez
发明人： Alan Charles Cooper , Guido Peter Pez
IPC分类号： B01D53047
CPC分类号： B82Y30/00 , C01B3/001 , C01B3/0021 , C01B3/0078 , Y02E60/321 , Y02E60/325 , Y02E60/327 , Y10S420/90 , Y10S977/742 , Y10S977/748 , Y10S977/842 , Y10S977/948
摘要： A process is provided for the transport and storage of hydrogen by reversible sorption and containment within carbon-metal hybrid materials. The process comprises contacting a carbon-metal hybrid composition with a hydrogen-containing gas at conditions of temperature and pressure whereby the carbon-metal hybrid composition sorbs the hydrogen gas. The hydrogen that is sorbed in the carbon-metal composition is subsequently released by lowering the H2 pressure and/or increasing the temperature to levels which cause desorption of the hydrogen gas.

4. 发明申请

US20110268651A1 METHOD AND APPARATUS FOR STORING AND DELIVERING HYDROGEN 审中-公开
标题翻译：用于储存和输送氢的方法和装置
公开(公告)号：US20110268651A1
公开(公告)日：2011-11-03
申请号：US12772860
申请日：2010-05-03
申请人： Alan Charles Cooper , Robert Gregory Wolf
发明人： Alan Charles Cooper , Robert Gregory Wolf
IPC分类号： C01B3/02 , H01M8/06 , B01J19/00
CPC分类号： B01J7/00 , B01J2208/00141 , B01J2219/00083 , C01B3/0026 , C01B3/0031 , C01B3/02 , C01B3/26 , C01B3/501 , C01B3/508 , C01B3/56 , C01B2203/0277 , C01B2203/0405 , C01B2203/042 , C01B2203/0495 , C01B2203/066 , C01B2203/0822 , C01B2203/085 , C01B2203/1252 , H01M8/0606 , Y02E60/327 , Y02P20/128
摘要： An apparatus and method for storing and releasing hydrogen is disclosed. In one embodiment, the apparatus includes a reactor, a heater having a first portion that is located in the reactor; a dehydrogenation catalyst that is affixed to the first portion of the heater; a hydrogen release conduit in communication with the reactor; a chamber containing a hydrogenated carrier; and an energy source coupled to the heater.
摘要翻译：公开了用于储存和释放氢的装置和方法。在一个实施例中，该装置包括反应器，具有位于反应器中的第一部分的加热器; 固定在加热器的第一部分上的脱氢催化剂; 与反应器连通的氢气释放导管; 包含氢化载体的室; 以及耦合到加热器的能量源。

5. 发明授权

US08003073B2 Autothermal hydrogen storage and delivery systems 有权
标题翻译：自热氢储存和输送系统
公开(公告)号：US08003073B2
公开(公告)日：2011-08-23
申请号：US12103205
申请日：2008-04-15
申请人： Guido Peter Pez , Alan Charles Cooper , Aaron Raymond Scott
发明人： Guido Peter Pez , Alan Charles Cooper , Aaron Raymond Scott
IPC分类号： C01B3/26 , C01B6/24
CPC分类号： C01B3/22 , C01B3/26 , C01B2203/0277 , C01B2203/0405 , C01B2203/0838 , C01B2203/1064 , C01B2203/1211 , C01B2203/1252
摘要： Processes are provided for the storage and release of hydrogen by means of dehydrogenation of hydrogen carrier compositions where at least part of the heat of dehydrogenation is provided by a hydrogen-reversible selective oxidation of the carrier. Autothermal generation of hydrogen is achieved wherein sufficient heat is provided to sustain the at least partial endothermic dehydrogenation of the carrier at reaction temperature. The at least partially dehydrogenated and at least partially selectively oxidized liquid carrier is regenerated in a catalytic hydrogenation process where apart from an incidental employment of process heat, gaseous hydrogen is the primary source of reversibly contained hydrogen and the necessary reaction energy.
摘要翻译：提供了通过氢载体组合物的脱氢来储存和释放氢的方法，其中至少部分脱氢热由载体的氢可逆选择性氧化提供。实现氢的自热发生，其中提供足够的热量以在反应温度下维持载体的至少部分吸热脱氢。至少部分脱氢和至少部分选择性氧化的液体载体在催化氢化过程中再生，除了偶然使用工艺热之外，气态氢是可逆地包含氢的主要来源和必需的反应能。

6. 发明申请

US20080175780A1 HYDROGEN STORAGE WITH GRAPHITE ANION INTERCALATION COMPOUNDS 审中-公开
标题翻译：具有石墨阴离子介质化合物的氢存储
公开(公告)号：US20080175780A1
公开(公告)日：2008-07-24
申请号：US12015712
申请日：2008-01-17
申请人： Guido Peter Pez , Hansong Cheng , Alan Charles Cooper , Maw Lin Foo
发明人： Guido Peter Pez , Hansong Cheng , Alan Charles Cooper , Maw Lin Foo
IPC分类号： C01B31/04 , C01B21/00 , C07C49/12 , C07C261/04 , C01B35/14
CPC分类号： C01B21/068 , B82Y30/00 , B82Y40/00 , C01B3/0021 , C01B32/15 , C01B32/22 , C01P2002/08 , Y02E60/325
摘要： The disclosure relates to a material for reversibly storing and releasing hydrogen comprising graphite or a graphitic structure, for example, comprising an ordered graphite structure of carbon and nitrogen atoms wherein the interlayer and/or interstitial volume is occupied with at least one intercalated anionic species. While any suitable anionic species can be employed, examples of suitable species are at least one of: F− (fluoride), (C≡C)2− (diacetylide), and (N═C═N)2−. Desirable anionic species typically have a relatively high charge to volume ratio. The disclosure also relates to a material for reversibly storing and releasing hydrogen comprising ordered graphitic structures comprising at least one member selected from the group of graphite, single walled carbon nanotubes, multiwalled carbon nanotubes, graphite nanofibers, carbon nanohorns, and boron nitride. The carbon materials may incorporate substitutional nitrogen atoms in the graphite lattice at a level ranging from about 1 to about 40 atomic percent.
摘要翻译：本公开涉及用于可逆地储存和释放包含石墨或石墨结构的氢的材料，例如包括碳和氮原子的有序石墨结构，其中中间层和/或间隙体积被至少一个插层的阴离子物质占据。尽管可以使用任何合适的阴离子种类，但合适的物质的实例是以下至少一种：氟化物（氟化物），（C≡C）2 - （二乙酰基），和（NCN）2 - 。理想的阴离子物质通常具有相对高的电荷与体积比。本公开还涉及用于可逆地储存和释放氢的材料，其包含选自石墨，单壁碳纳米管，多壁碳纳米管，石墨纳米纤维，碳纳米角和氮化硼中的至少一种的有序石墨结构。碳材料可以在约1至约40原子百分比的范围内在石墨晶格中引入取代的氮原子。

7. 发明申请

US20080260630A1 Autothermal Hydrogen Storage and Delivery Systems 有权
标题翻译：自热氢储存和输送系统
公开(公告)号：US20080260630A1
公开(公告)日：2008-10-23
申请号：US12103205
申请日：2008-04-15
申请人： Guido Peter Pez , Alan Charles Cooper , Aaron Raymond Scott
发明人： Guido Peter Pez , Alan Charles Cooper , Aaron Raymond Scott
IPC分类号： C01B3/26
CPC分类号： C01B3/22 , C01B3/26 , C01B2203/0277 , C01B2203/0405 , C01B2203/0838 , C01B2203/1064 , C01B2203/1211 , C01B2203/1252
摘要： Processes are provided for the storage and release of hydrogen by means of dehydrogenation of hydrogen carrier compositions where at least part of the heat of dehydrogenation is provided by a hydrogen-reversible selective oxidation of the carrier. Autothermal generation of hydrogen is achieved wherein sufficient heat is provided to sustain the at least partial endothermic dehydrogenation of the carrier at reaction temperature. The at least partially dehydrogenated and at least partially selectively oxidized liquid carrier is regenerated in a catalytic hydrogenation process where apart from an incidental employment of process heat, gaseous hydrogen is the primary source of reversibly contained hydrogen and the necessary reaction energy.
摘要翻译：提供了通过氢载体组合物的脱氢来储存和释放氢的方法，其中至少部分脱氢热由载体的氢可逆选择性氧化提供。实现氢的自热发生，其中提供足够的热量以在反应温度下维持载体的至少部分吸热脱氢。至少部分脱氢和至少部分选择性氧化的液体载体在催化氢化过程中再生，除了偶然使用工艺热之外，气态氢是可逆地包含氢的主要来源和必需的反应能。

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