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1. 发明授权

US07485161B2 Dehydrogenation of liquid fuel in microchannel catalytic reactor 有权
标题翻译：微通道催化反应器中液体燃料的脱氢
公开(公告)号：US07485161B2
公开(公告)日：2009-02-03
申请号：US11029059
申请日：2005-01-04
申请人： Bernard Allen Toseland , Guido Peter Pez , Pushpinder Singh Puri
发明人： Bernard Allen Toseland , Guido Peter Pez , Pushpinder Singh Puri
IPC分类号： B01J7/00 , B01J8/04 , B01J19/00 , C01B6/00
CPC分类号： H01M8/065 , B01J19/0093 , B01J2219/00783 , B01J2219/00835 , B01J2219/0086 , B01J2219/00867 , B01J2219/00873 , B01J2219/00891 , B01J2219/00905 , B01J2219/00997 , C01B3/0015 , C07C5/32 , C07C5/327 , Y02E60/328 , Y02P20/129
摘要： The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.
摘要翻译：本发明是通过可逆氢化/脱氢有机化合物的储存和输送氢的改进方法，其中有机化合物最初处于其氢化状态。生成氢气的途径的改进是脱氢步骤，脱氢有机化合物的回收步骤如下：将氢化有机化合物引入到包含脱氢催化剂的微通道反应器中; 所述氢化有机化合物在所述氢化有机化合物作为液相存在的条件下进行脱氢; 产生由液相脱氢有机化合物和气态氢组成的反应产物; 将液相脱氢有机化合物与气态氢分离; 并回收氢和液相脱氢的有机化合物。

2. 发明申请

US20090019768A1 Dehydrogenation of Liquid Fuel in Microchannel Catalytic Reactor 有权
标题翻译：液态燃料在微通道催化反应器中脱氢
公开(公告)号：US20090019768A1
公开(公告)日：2009-01-22
申请号：US12211585
申请日：2008-09-16
申请人： Bernard Allen Toseland , Guido Peter Pez , Pushpinder Singh Puri
发明人： Bernard Allen Toseland , Guido Peter Pez , Pushpinder Singh Puri
IPC分类号： C01B3/16
CPC分类号： H01M8/065 , B01J19/0093 , B01J2219/00783 , B01J2219/00835 , B01J2219/0086 , B01J2219/00867 , B01J2219/00873 , B01J2219/00891 , B01J2219/00905 , B01J2219/00997 , C01B3/0015 , C07C5/32 , C07C5/327 , Y02E60/328 , Y02P20/129
摘要： The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.
摘要翻译：本发明是通过可逆氢化/脱氢有机化合物的储存和输送氢的改进方法，其中有机化合物最初处于其氢化状态。生成氢气的途径的改善是在脱氢步骤中，脱氢有机化合物的回收步骤如下：将氢化有机化合物引入到包含脱氢催化剂的微通道反应器中; 所述氢化有机化合物在所述氢化有机化合物作为液相存在的条件下进行脱氢; 产生由液相脱氢有机化合物和气态氢组成的反应产物; 将液相脱氢有机化合物与气态氢分离; 并回收氢和液相脱氢的有机化合物。

3. 发明授权

US07438889B2 Use of complex metal oxides in the autothermal generation of hydrogen 有权
标题翻译：在自发生成氢气中使用复合金属氧化物
公开(公告)号：US07438889B2
公开(公告)日：2008-10-21
申请号：US11165720
申请日：2005-06-24
申请人： Guido Peter Pez , Baolong Zhang , Hans-Conrad zur Loye
发明人： Guido Peter Pez , Baolong Zhang , Hans-Conrad zur Loye
IPC分类号： C01B3/26
CPC分类号： C01B3/38 , C01B3/56 , C01B2203/0244 , C01B2203/0425 , C01B2203/0475
摘要： A process for producing hydrogen comprising reacting at least one hydrocarbon and steam in the presence of a complex metal oxide and a steam-hydrocarbon reforming catalyst in a production step under reaction conditions sufficient to form hydrogen and a spent complex metal oxide, wherein the complex metal oxide is represented by the formula (A′xCax′Mgx″)x(B′yMny′Fey″)yOn where A′ represents at least one element selected from the group consisting of Sr, Ba, a Group 1 element, and an element of the Lanthanide series according to the IUPAC Periodic Table of the Elements; B′ represents at least one element selected from the group consisting of Cu, Ni, Co, Cr, and V; 0≦x≦1, 0≦x′≦1, 0≦x″≦1 wherein x+x′+x″=x; 0≦y≦1, 0≦y′≦1, 0≦y″≦1 wherein y+y′+y″=y; 1≦x≦10; 1≦y≦10; and n represents a value such that the complex metal oxide is rendered electrically neutral.
摘要翻译：一种生产氢的方法，包括在复合金属氧化物和蒸汽 - 烃重整催化剂存在下，在足以形成氢的复合金属氧化物的反应条件下，在制备步骤中使至少一种烃和蒸汽反应，其中复合金属氧化物由公式<？in-line-formula description =“In-line Formulas”end =“lead”？>（A' Ca x' x“x”x“”“”“”“Y”“”“”“” ＆lt;＆lt;＆lt;＆lt; /＆gt;＆lt;＆lt;＆lt;＆lt;＆lt;＆lt; 来自由Sr，Ba，第1族元素组成的组和根据元素IUPAC周期表的镧系元素的元素; B'表示选自Cu，Ni，Co，Cr和V中的至少一种元素; 0 <= x <= 1，0 <= x'<= 1，0 <= x“<= 1其中x + x'+ x”= x; 0 <= y <= 1，0 <= y'<= 1，0 <= y“<= 1其中y + y'+ y”= y; 1 <= x <= 10; 1 <= y <= 10; n表示使复合金属氧化物呈电中性的值。

4. 发明授权

US07419623B2 Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same 有权
标题翻译：用于电化学装置的质子传导介质和包括其的电化学装置
公开(公告)号：US07419623B2
公开(公告)日：2008-09-02
申请号：US10910529
申请日：2004-08-03
申请人： Sergei Vladimirovich Ivanov , William Jack Casteel, Jr. , Guido Peter Pez
发明人： Sergei Vladimirovich Ivanov , William Jack Casteel, Jr. , Guido Peter Pez
IPC分类号： H01B1/00 , H01M10/40
CPC分类号： C25B13/04 , C07F5/022 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/106 , H01M8/124 , H01M8/144 , H01M2300/0005 , Y02P70/56
摘要： An electrochemical device and a proton conducting medium for use in an electrochemical device having a proton conducting electrolyte comprising the formula: HaMbQ.nH2O where H is a proton, M is a cation, Q is the fluoroborate or fluoroheteroborate anion, n ranges from 0.01 to 1000, a ranges from 0.01 to 2 and b ranges from 0 to 2, a and b are chosen to render the formula electrically neutral, and when b is greater than 0, the ratio of b to a is less than 100 to 1.
摘要翻译：一种用于具有质子传导电解质的电化学装置的电化学装置和质子传导介质，其包含下式：<？in-line-formula description =“In-line formula”end =“lead”？> H＆其中H是在线公式描述=“在线公式”end =“tail”？>其中H是质子，M是阳离子，Q是氟硼酸根或氟代硼酸根阴离子，n在0.01至1000的范围内，a在0.01至2的范围内，b的范围为0至2，a和b被选择以使配方电中性，以及当b大于0时，b与a的比例小于100比1。

5. 发明授权

US07030283B2 Process for producing 1,1-difluorovinyl cycloaliphatic compounds 有权
标题翻译：制备1,1-二氟乙烯基脂环族化合物的方法
公开(公告)号：US07030283B2
公开(公告)日：2006-04-18
申请号：US10763366
申请日：2004-01-23
申请人： Gauri Sankar Lal , Kathryn Sue Hayes , Guido Peter Pez
发明人： Gauri Sankar Lal , Kathryn Sue Hayes , Guido Peter Pez
IPC分类号： C07C17/25 , C07C17/23
CPC分类号： C07C17/25 , C07C22/00
摘要： This invention relates to a process for the preparation of 1,1-difluoroolefins, e.g., difluorovinyl cycloaliphatic compounds such as difluorovinylcyclohexane and derivatives by the dehydrofluorination of a trifluoromethyl-substituted cycloaliphatic compound and the resulting compositions. This method utilizes a “sterically hindered super-base” system represented by the formula M+−NRR−; where M is Na or K and R is a secondary, or tertiary alkyl or cycloalkyl group of amines for effecting dehydrofluorination of the trifluoromethyl group leading to the difluorovinyl based cycloaliphatic compounds. The sterically hindered super base can be formed by the, in situ, reaction of a sodium or potassium alkoxide, e.g., KtBuO with a lithium dialkylamide where the lithium is bonded to nitrogen atom of an amine bearing secondary or tertiary aliphatic groups.
摘要翻译：本发明涉及一种制备1,1-二氟烯烃的方法，例如二氟乙烯基脂环族化合物如二氟乙烯基环己烷和通过三氟甲基取代的脂环族化合物的脱氟化氢的衍生物和所得组合物。该方法利用由式M + - NRR - SUP表示的“空间位阻超基”系统。其中M是Na或K，R是仲烷基或烷基或环烷基的胺，用于实现导致二氟乙烯基的脂环族化合物的三氟甲基的脱氟化氢。空间位阻的超级碱可以通过钾或钾醇钾例如KtBuO与二烷基氨基锂的原位反应形成，其中锂与带有仲或叔脂族基团的胺的氮原子键合。

6. 发明授权

US07025901B2 Alkyl and aryl trifluoromethoxytetrafluorosulfuranes 失效
标题翻译：烷基和芳基三氟甲氧基四氟硫烷
公开(公告)号：US07025901B2
公开(公告)日：2006-04-11
申请号：US10620237
申请日：2003-07-15
申请人： Wade H. Bailey, III , Reno Joseph Pesaresi, Jr. , William Jack Casteel, Jr. , Guido Peter Pez
发明人： Wade H. Bailey, III , Reno Joseph Pesaresi, Jr. , William Jack Casteel, Jr. , Guido Peter Pez
IPC分类号： C09K19/06 , C01B3/04 , C07C69/76 , C07C317/00
CPC分类号： C09K19/0403 , C07C381/00 , C09K19/12 , C09K19/3068 , C09K19/3402 , C09K2019/0444 , C09K2019/3422 , Y02E60/364
摘要： Novel compositions containing SF4—O—CF3 bonded to an organic group are disclosed. Aryl trifluoromethoxytetrafluorosulfuranes (or Ar—SF4—O—CF3), have been synthesized via the reaction of an aryl disulfide or thiol with fluoroxytrifluoromethane (F3COF). The compositions are useful synthons, which may be derivatized to yield highly electrically polar molecules, particularly novel liquid crystal compositions having high dielectric anisotropies. Cycloalkyl trifluoromethoxytetrafluorosulfuranes have similar utility.
摘要翻译：公开了与有机基团键合的含有SF 4 -OR-CF 3 3 N的新型组合物。已经通过芳基二硫化物或硫醇与氟氧基三氟甲烷的反应合成了三氟甲氧基四氟硫烷（或Ar-SF 4 -O-CF 3 N）（F 3， / SUB> COF）。组合物是有用的合成物，其可以被衍生化以产生高电极性分子，特别是具有高介电各向异性的新型液晶组合物。环烷基三氟甲氧基四氟硫烷具有相似的用途。

7. 发明授权

US07024869B2 Addition of odorants to hydrogen by incorporating odorants with hydrogen storage materials 失效
标题翻译：通过将气味剂与储氢材料混合，将气味剂添加到氢气中
公开(公告)号：US07024869B2
公开(公告)日：2006-04-11
申请号：US10321326
申请日：2002-12-16
申请人： Pushpinder Singh Puri , Guido Peter Pez
发明人： Pushpinder Singh Puri , Guido Peter Pez
IPC分类号： F17C11/00
CPC分类号： G01M3/20
摘要： An apparatus for dispensing an odorant to a hydrogen gas includes at least one container, each container having an interior volume. At least one odorant material is disposed in the interior volume of a first container, the odorant material having at least one detectable odor. At least one hydrogen storage material is disposed in the interior volume of the first container or the interior volume of a second container.
摘要翻译：用于将气味剂分配到氢气的装置包括至少一个容器，每个容器具有内部容积。至少一种加臭剂材料设置在第一容器的内部容积中，该加臭剂材料具有至少一种可检测的气味。至少一个储氢材料设置在第一容器的内部容积或第二容器的内部容积中。

8. 发明授权

US06222064B1 Fluorination with aminosulfur trifluorides 有权
标题翻译：用氨基三氟化硫氟化
公开(公告)号：US06222064B1
公开(公告)日：2001-04-24
申请号：US09483751
申请日：2000-01-14
申请人： Gauri Sankar Lal , Guido Peter Pez
发明人： Gauri Sankar Lal , Guido Peter Pez
IPC分类号： C07C17013
CPC分类号： C07C319/14 , C07B39/00 , C07C17/093 , C07C17/16 , C07C17/18 , C07C17/38 , C07C45/63 , C07C51/60 , C07C67/307 , C07C253/30 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C23/10 , C07C22/08 , C07C23/16 , C07C49/457 , C07C69/63 , C07C323/03 , C07C255/10
摘要： A fluorination method of oxygen and halogen sites with diaryl-, dialkoxyalkyl-, alkylalkoxyalkyl-, arylalkoxyalkyl- and cyclic aminosulfur trifluorides fluorinating reagents is disclosed.
摘要翻译：公开了具有二芳基 - ，二烷氧基烷基 - 烷基烷氧基烷基 - ，芳基烷氧基烷基 - 和环状氨基三氟化硫氟化试剂的氧和卤素位点的氟化方法。

9. 发明授权

US07429373B2 Process for autothermal generation of hydrogen 失效
标题翻译：氢热自发生成工艺
公开(公告)号：US07429373B2
公开(公告)日：2008-09-30
申请号：US11165731
申请日：2005-06-24
申请人： Guido Peter Pez , Robert Quinn , Shankar Nataraj
发明人： Guido Peter Pez , Robert Quinn , Shankar Nataraj
IPC分类号： C01B3/26
CPC分类号： C01B3/56 , C01B3/38 , C01B2203/0244 , C01B2203/0425 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/86 , Y02P20/52 , Y02P30/30
摘要： Process for producing hydrogen comprising reacting at least one hydrocarbon and steam in the presence of a complex metal oxide and a steam-hydrocarbon reforming catalyst in a production step under reaction conditions sufficient to form hydrogen gas and a spent complex metal oxide, wherein the complex metal oxide is represented by the formula AxByOn wherein A represents at least one metallic element having an oxidation state ranging from +1 to +3, inclusive, wherein the metallic element is capable of forming a metal carbonate; x is a number from 1 to 10, inclusive; B represents at least one metallic element having an oxidation state ranging from +1 to +7, inclusive; y is a number from 1 to 10, inclusive; and n represents a value such that the complex metal oxide is rendered electrically neutral.
摘要翻译：包括在生产步骤中在复合金属氧化物和蒸汽 - 烃重整催化剂存在下使至少一种烃和蒸汽与足以形成氢气的反应条件和废复合金属氧化物反应的方法，其中复合金属氧化物由公式<？in-line-formula description =“In-line Formulas”end =“lead”？> A B 其中A表示至少一种具有+1至+3的氧化态的金属元素，包括端值在内，其中，金属元素能够形成金属碳酸盐; x是1到10的数字，包括1和10; B表示至少一种具有+1至+7的氧化态的金属元素，包括端值; y是从1到10的数字，包括; n表示使复合金属氧化物呈电中性的值。

10. 发明授权

US07429372B2 Hydrogen storage by reversible hydrogenation of pi-conjugated substrates 有权
标题翻译：通过π-共轭底物的可逆氢化来储存氢
公开(公告)号：US07429372B2
公开(公告)日：2008-09-30
申请号：US10833484
申请日：2004-04-27
申请人： Guido Peter Pez , Aaron Raymond Scott , Alan Charles Cooper , Hansong Cheng
发明人： Guido Peter Pez , Aaron Raymond Scott , Alan Charles Cooper , Hansong Cheng
IPC分类号： C01B3/00 , F17C11/00
CPC分类号： C01B3/0015 , Y02E60/328
摘要： Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, nitrile, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.
摘要翻译：提供了通过扩展的π-共轭底物的基本可逆的催化氢化来提供氢的方法，其包括大的多环芳烃，具有氮杂原子的多环芳烃，具有氧杂原子的多环芳烃，具有烷基的多环芳烃烷氧基，腈，酮，醚或聚醚取代基，包含5元环的π-共轭分子，包含具有氮或氧杂原子的六元和五元环的π-共轭分子和延伸的π-共轭有机聚合物。包含在延伸的π-共轭体系的至少部分氢化形式中的氢可以通过在脱氢催化剂的存在下通过催化脱氢来容易地释放使用，所述脱氢催化剂可以通过降低氢气压力来实现，通常压力大于0.1巴或将温度升高到小于250℃或更低，或通过这两个工艺参数的组合。

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