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81. 发明申请

US20060063002A1 Polymerizable organosilicon nanocapsules 失效
标题翻译：可聚合的有机硅纳米胶囊
公开(公告)号：US20060063002A1
公开(公告)日：2006-03-23
申请号：US11258025
申请日：2005-10-26
申请人： Roland Edelmann , Jaroslaw Monkiewicz
发明人： Roland Edelmann , Jaroslaw Monkiewicz
IPC分类号： B32B9/02
CPC分类号： C08K9/06 , B01J13/02 , B82Y30/00 , C01P2004/64 , C01P2006/12 , C09C1/00 , C09C1/3081 , C09C1/3684 , C09C1/407 , C09C3/12 , Y10T428/2984
摘要： The present invention provides a polymerizable organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle comprising at least one oxide or mixed oxide, KA-O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R (Ia) wherein R is a vinyl or allyl group; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA-O)—, SiO— or -Z; wherein remaining free valences of Si′ are each independently (KA-O)—, SiO—, -R, or -Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attatched thereto.
摘要翻译：本发明提供了一种可聚合的有机硅纳米胶囊，其包括：纳米级芯A，其包括：至少一种包含至少一种氧化物或混合氧化物的颗粒，KA-O，其至少一种金属或半金属选自包括主要元素周期表第2至6组，周期表第1至8族，镧系元素及其混合物; 和有机硅壳B，其包括：至少一种具有式（I）的有机硅化合物

82. 发明授权

US06830816B2 Highly filled, pasty, composition containing silicoorganic nanohybrid and/or microhybrid capsules for scratch-resistant and/or abrasion-resistant coatings 失效
标题翻译：含有硅胶有机纳米混合和/或微混合胶囊的高填充，糊状组合物，用于耐刮擦和/或耐磨涂层
公开(公告)号：US06830816B2
公开(公告)日：2004-12-14
申请号：US10112042
申请日：2002-04-01
申请人： Reiner Mehnert , Hans-Juergen Glaesel , Helmut Langguth , Jaroslaw Monkiewicz , Roland Edelmann , Bjoern Borup
发明人： Reiner Mehnert , Hans-Juergen Glaesel , Helmut Langguth , Jaroslaw Monkiewicz , Roland Edelmann , Bjoern Borup
IPC分类号： C08K320
CPC分类号： C09C1/3081 , C01P2004/88 , C08K9/06 , C09C3/12 , Y10T428/2995 , Y10T428/31551 , Y10T428/31663 , Y10T428/31786 , Y10T428/31935
摘要： The present invention relates to a composition containing silico-organic nanohybrid and/or microhybrid capsules for scratch-resistant and/or abrasion-resistant coatings, wherein the silico-organic nanohybrid and/or microhybrid system includes one or more small metal oxide cores A and a substantially complete, silico-organic shell B, and the composition can be obtained by a reaction performed in situ, in a synthetic resin or in a synthetic-resin precursor compound, between metal oxide particles (KA-O) and at least one organofunctional silicon compound which contains an organofunctional group and at least one hydrolyzable group or at least one hydroxy group. The present invention also relates to the use of such compositions as the base for lacquers for producing a scratch-resistant and abrasion-resistant coating on a substrate as well as articles provided with corresponding scratch-resistant as well as abrasion-resistant coatings.
摘要翻译：本发明涉及包含用于耐刮擦和/或耐磨涂层的硅 - 有机纳米混合和/或微混合胶囊的组合物，其中硅 - 有机纳米混合和/或微混合系统包括一个或多个小金属氧化物核心A和基本上完全的硅 - 有机壳B，并且组合物可以通过在合成树脂或合成树脂前体化合物中原位进行的金属氧化物颗粒（KA-O）与至少一种有机官能团含有有机官能团和至少一个可水解基团或至少一个羟基的硅化合物。本发明还涉及这样的组合物作为基底用于在基材上生产耐刮擦和耐磨涂层以及具有相应的耐刮擦和耐磨涂层的制品的用途。

83. 发明授权

US06695904B2 Surface coating composition comprising silicon compounds 失效
标题翻译：包含硅化合物的表面涂料组合物
公开(公告)号：US06695904B2
公开(公告)日：2004-02-24
申请号：US10227295
申请日：2002-08-26
申请人： Rosemarie Burger , Jaroslaw Monkiewicz , Roland Edelmann , Bjoern Borup
发明人： Rosemarie Burger , Jaroslaw Monkiewicz , Roland Edelmann , Bjoern Borup
IPC分类号： C09D18306
CPC分类号： C09D183/04 , C08G77/06 , C08K3/36 , C23C2222/20
摘要： A composition which retains a flash point of more than 21° C. even on storage and is obtainable by mixing and reacting (i) from 50 to 70% by weight of at least one alkyltrialkoxysilane, (ii) from 10 to 25% by weight of at least one alkoxysiloxane and/or at least one tetraalkoxysilane, (iii) from 15 to 25% by weight of at least one aqueous silica sol, (iv) from 0.1 to 5% by weight of at least one acid, and (v) from 0.1 to 60% by weight of at least one alcohol and/or glycol, the sum of the above components being not more than 100% by weight, by introducing components (i) and (ii) and also, if desired, a fraction of component (v) as an initial charge, adding component (iii), adjusting the mixture to a temperature in the range from −5 to 10° C., and subsequently adding component (iv), then allowing the mixture to continue reacting, thereafter distilling off hydrolysis alcohol under reduced pressure, and replacing it by adding component (v); which composition is useful for producing a coating on surfaces and also as a base material for paints; a process for preparing such a composition; and coatings and articles obtainable by applying such a composition.
摘要翻译：即使在储存时也保持闪点超过21℃的组合物，并且可通过混合并使（i）50至70重量％的至少一种烷基三烷氧基硅烷，（ii）10至25重量％的至少一种烷氧基硅氧烷和/或至少一种四烷氧基硅烷，（iii）15至25重量％的至少一种水性二氧化硅溶胶，（iv）0.1至5重量％的至少一种酸，和（v ）0.1至60重量％的至少一种醇和/或二醇，上述组分的总和不超过100重量％，通过引入组分（i）和（ii），并且如果需要，可以使用将组分（v）的馏分作为初始电荷，加入组分（iii），将混合物调节至-5至10℃的温度，随后加入组分（iv），然后使混合物继续反应然后在减压下蒸馏除去水解醇，并通过加入组分（v）代替; 该组合物可用于在表面上生产涂层以及用作涂料的基材; 制备这种组合物的方法; 以及通过应用这种组合物可获得的涂层和制品。

84. 发明授权

US6100408A Process for preparing 3-glycidyloxypropyltrialkoxysilanes 有权
标题翻译：制备3-缩水甘油氧基丙基三烷氧基硅烷的方法
公开(公告)号：US6100408A
公开(公告)日：2000-08-08
申请号：US246953
申请日：1999-02-09
申请人： Jaroslaw Monkiewicz , Stefan Bade , Uwe Schoen
发明人： Jaroslaw Monkiewicz , Stefan Bade , Uwe Schoen
IPC分类号： B01J23/42 , B01J35/10 , C07B61/00 , C07F7/18 , C07F7/08 , C07D303/02
CPC分类号： C07F7/1876
摘要： The invention relates to a process for preparing 3-glycidyloxypropyltrialkoxysilanes of the general formulaCH.sub.2 (O)CHCH.sub.2 --O--(CH.sub.2).sub.3 Si(OR).sub.3 (I),in which R is an alkyl radical, by reacting allyl glycidyl etherCH.sub.2 (O)CHCH.sub.2 --O--CH.sub.2 CH.dbd.CH.sub.2 (II),with a trialkoxysilane of the general formulaHSi(OR).sub.3 (III),in which R is again an alkyl radical, in a heterogeneous, platinum-catalyzed hydrosilylation reaction, where the catalyst employed is a platinum(0) catalyst on a nonmetallic support.
摘要翻译：本发明涉及一种制备通式CH 2（O）CHCH 2 -O-（CH 2）3 Si（OR）3（I）的3-缩水甘油氧基丙基三烷氧基硅烷的方法，其中R是烷基，烯丙基缩水甘油醚CH2（ O）CHCH 2 -O-CH 2 CH = CH 2（II）与通式为HSi（OR）3（III）的三烷氧基硅烷，其中R再次为烷基，在异质铂催化的氢化硅烷化反应中，其中所使用的催化剂是在非金属载体上的铂（0）催化剂。

85. 发明授权

US5442099A Bis-(thiobenzoyldisulfido)-alkanes 失效
标题翻译：双 - （硫代苯甲酰基二硫代）烷烃
公开(公告)号：US5442099A
公开(公告)日：1995-08-15
申请号：US152702
申请日：1993-11-16
申请人： Juergen Wolpers , Karl-Heinz Nordsiek , Jaroslaw Monkiewicz , Dieter Zerpner
发明人： Juergen Wolpers , Karl-Heinz Nordsiek , Jaroslaw Monkiewicz , Dieter Zerpner
IPC分类号： C07C381/00 , C07C327/36 , C08J3/24 , C08K5/36 , C08K5/38 , C08L9/00
CPC分类号： C07C327/36 , C08K5/38
摘要： Polysulfide compounds and vulcanization compositions containing the polysulfide compounds, for use in vulcanizing rubbers, are disclosed, with the polysulfide compounds being of the formula ##STR1## wherein R.sup.1 -R.sup.4 are each, independently, hydrogen or C.sub.1 -C.sub.4 alkyl and n is 2 to 10wherein the polysulfide compounds can be used alone or in a vulcanization composition containing the polysulfide compound, sulfur, one or more additional accelerators, one or more basic compounds and, optionally, conventional rubber additives, to provide vulcanized products with improved reversion stability and ageing stability.
摘要翻译：公开了用于硫化橡胶的含硫化合物的多硫化物化合物和硫化组合物，其中多硫化合物具有式“C1”或C 1 -C 4烷基，n为2至10，其中多硫化物可单独使用或在含有多硫化合物，硫，一种或多种另外的促进剂，一种或多种碱性化合物和任选的常规橡胶添加剂的硫化组合物中，以提供具有改进的逆转稳定性和老化稳定性的硫化产品。

86. 发明授权

US4827067A Azaphospholenes and use thereof 失效
标题翻译： Azaphospholenes及其用途
公开(公告)号：US4827067A
公开(公告)日：1989-05-02
申请号：US246577
申请日：1988-09-19
申请人： Gunther Wilke , Jaroslaw Monkiewicz , Herbert Kuhn
发明人： Gunther Wilke , Jaroslaw Monkiewicz , Herbert Kuhn
IPC分类号： B01J31/14 , B01J31/00 , B01J31/22 , B01J31/24 , C07B61/00 , C07C2/04 , C07C2/32 , C07C5/29 , C07C5/31 , C07C13/12 , C07C13/40 , C07C15/44 , C07F9/6564 , C07F9/6584 , C07C2/42
CPC分类号： C07F9/6584 , C07C2/04 , C07C5/31 , C07C2101/10 , C07C2102/42 , C07C2531/02 , C07C2531/14 , C07C2531/22
摘要： The invention relates to azaphospholene of the type ##STR1## wherein R.sub.1 and R.sub.2 may be alkyl, aryl and aralkyl groups, processes for preparing same and the use thereof.
摘要翻译：本发明涉及类型“IMAGE”的氮杂磷脂，其中R 1和R 2可以是烷基，芳基和芳烷基，其制备方法及其用途。

87. 发明授权

US09926451B2 Silane-modified silicic acid, method for the production and use thereof 有权
公开(公告)号：US09926451B2
公开(公告)日：2018-03-27
申请号：US15102487
申请日：2014-12-16
申请人： Anke Blume , Torsten Peterle , Jaroslaw Monkiewicz
发明人： Anke Blume , Torsten Peterle , Jaroslaw Monkiewicz
IPC分类号： C09C1/30 , B60C1/00 , C01B33/193 , C07F7/18 , C08K9/06 , C01B33/18
CPC分类号： C09C1/3081 , B60C1/0016 , C01B33/18 , C01B33/193 , C01P2004/51 , C01P2004/61 , C01P2006/12 , C07F7/1804 , C08K9/06 , C08L21/00
摘要： The invention relates to silane-modified silicas having a BET surface area of 40 to 155 m2/g, a sulphur content between 0.05% and 25% by weight and a particle size d5 of ≥4 μm, and d50 of ≥16 μm.The silane-modified silicas are used in rubber mixtures.

88. 发明授权

US09108992B2 Carboxyl-functionalized silicon-containing precursor compound of various organic carboxylic acids 有权
标题翻译：各种有机羧酸的羧基官能化含硅前体化合物
公开(公告)号：US09108992B2
公开(公告)日：2015-08-18
申请号：US13580385
申请日：2010-12-28
申请人： Kerstin Weiβenbach , Aristidis Ioannidis , Bastian Bielawski , Christian Springer , Jaroslaw Monkiewicz
发明人： Kerstin Weiβenbach , Aristidis Ioannidis , Bastian Bielawski , Christian Springer , Jaroslaw Monkiewicz
IPC分类号： C08J3/20 , C07F7/18 , C08G77/14
CPC分类号： C07F7/1896 , C07F7/1804 , C08G77/14
摘要： The invention relates to a composition of a carboxyl-functionalized silicon-containing precursor compound of at least two different organic acids, said composition having two, three, or four carboxyl groups functionalized with various hydrocarbon groups according to formula I and/or II. Said carboxyl groups can be released as carboxylic acids and can be used as silane hydrolysis catalysts and/or silane condensation catalysts. The invention further relates to methods for producing the composition, to the use of the composition for cross-linking polymers, and to a formulation of the composition in the form of a masterbatch.
摘要翻译：本发明涉及至少两种不同有机酸的羧基官能化含硅前体化合物的组合物，所述组合物具有根据式I和/或II的各种烃基官能化的两个，三个或四个羧基。所述羧基可以作为羧酸被释放，并且可以用作硅烷水解催化剂和/或硅烷缩合催化剂。本发明还涉及用于制备组合物的方法，该组合物用于交联聚合物的组合物，以及母体形式的组合物的制剂。

89. 发明授权

US08664370B2 Process for preparing silicon-containing azodicarbamides 有权
标题翻译：制备含硅偶氮二酰胺的方法
公开(公告)号：US08664370B2
公开(公告)日：2014-03-04
申请号：US13580780
申请日：2011-03-11
申请人： Karsten Korth , Julia Keck , Susann Witzsche , Oliver Klockmann , Jaroslaw Monkiewicz , Christian Springer
发明人： Karsten Korth , Julia Keck , Susann Witzsche , Oliver Klockmann , Jaroslaw Monkiewicz , Christian Springer
IPC分类号： C09B43/12 , C07F7/18
CPC分类号： C07F7/1892
摘要： The invention relates to a process for preparing silicon-containing azodicarbamides of the general formula (I) (R1)3-a(R2)aSi—RI—NH—C(O)—N═N—C(O)—NH—RI—Si(R1)3-a(R2)a (I), by reaction of azobiscarboxy compounds of the general formula II R3—X1—C(O)—N═N—C(O)—X1—R4 (II) with aminosilanes of the general formula III (R1)3-a(R2)aSi—RI—NH2 (III).
摘要翻译：本发明涉及制备通式（I）（R1）3-a（R2）aSi-RI-NH-C（O）-N = NC（O）-NH-RI- Si（R 1）3-a（R 2）a（I），通式为R 3 -X 1 -C（O）-N = NC（O）-X 1 -R 4（II）的偶氮二羧基化合物与氨基硅烷通式III（R1）3-a（R2）aSi-RI-NH2（Ⅲ）。

90. 发明申请

US20130037744A1 CARBOXYL-FUNCTIONALIZED SILICON-CONTAINING PRECURSOR COMPOUND OF VARIOUS ORGANIC CARBOXYLIC ACIDS 有权
标题翻译：各种有机碳羧酸的含羧基官能化含硅前体化合物
公开(公告)号：US20130037744A1
公开(公告)日：2013-02-14
申请号：US13580385
申请日：2010-12-28
申请人： Kerstin Weissenbach , Aristidis Ioannidis , Bastian Bielawski , Christian Springer , Jaroslaw Monkiewicz
发明人： Kerstin Weissenbach , Aristidis Ioannidis , Bastian Bielawski , Christian Springer , Jaroslaw Monkiewicz
IPC分类号： C07F7/18 , C09K3/00 , C07F7/04
CPC分类号： C07F7/1896 , C07F7/1804 , C08G77/14
摘要： The invention relates to a composition of a carboxyl-functionalized silicon-containing precursor compound of at least two different organic acids, said composition having two, three, or four carboxyl groups functionalized with various hydrocarbon groups according to formula I and/or II. Said carboxyl groups can be released as carboxylic acids and can be used as silane hydrolysis catalysts and/or silane condensation catalysts. The invention further relates to methods for producing the composition, to the use of the composition for cross-linking polymers, and to a formulation of the composition in the form of a masterbatch.
摘要翻译：本发明涉及至少两种不同有机酸的羧基官能化含硅前体化合物的组合物，所述组合物具有根据式I和/或II的各种烃基官能化的两个，三个或四个羧基。所述羧基可以作为羧酸被释放，并且可以用作硅烷水解催化剂和/或硅烷缩合催化剂。本发明还涉及用于制备组合物的方法，该组合物用于交联聚合物的组合物，以及母体形式的组合物的制剂。

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