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1. 发明授权

US4098834A Optically active 3-substituted cyclooctene bicyclo-[6.0.3.]-undecene-3 and exo-2-vinyl norbornane 失效
标题翻译：光学活性3-取代的环己基双酚 - （6.0.3。） - 未反应-3和外-2-乙烯基异腈
公开(公告)号：US4098834A
公开(公告)日：1978-07-04
申请号：US649164
申请日：1976-01-14
申请人： Gunther Wilke , Borislav Bogdanovic , Horst Pauling
发明人： Gunther Wilke , Borislav Bogdanovic , Horst Pauling
IPC分类号： B01J31/24 , C07C2/04 , C07C2/36 , C07C11/113 , C07C13/263 , C07C13/32 , C07C13/40 , C07C3/00
CPC分类号： B01J31/2404 , B01J31/143 , B01J31/24 , C07C11/113 , C07C13/263 , C07C13/32 , C07C13/40 , C07C2/04 , C07C2/36 , B01J2231/20 , B01J2231/323 , B01J2531/847 , B01J31/2291 , C07B2200/07 , C07C2101/18 , C07C2102/32 , C07C2102/42 , C07C2527/125 , C07C2527/128 , C07C2531/02 , C07C2531/04 , C07C2531/14 , C07C2531/24 , Y10S585/952
摘要： Optically active compounds are prepared from optically inactive unsaturated hydrocarbons by reacting at least one unsaturated hydrocarbon in the presence of a catalyst prepared by combining a nickel compound, a Lewis acid and an optically active phosphine of the general formulaPR'R"R'"in which R', R" and R'" are hydrocarbon radicals, thereby forming optically active compounds having chiral centers formed by the carbon-to-carbon linkages. The optically active compounds can be polymerized to provide optically active polymers.

2. 发明授权

US4080388A Phenyl substituted-hexene-(3)-diol-(1,6) 失效
标题翻译：苯基取代的己烯 - （3） - 二醇 - （1,6）
公开(公告)号：US4080388A
公开(公告)日：1978-03-21
申请号：US621187
申请日：1975-10-09
申请人： Gunther Wilke , Paul Heimbach
发明人： Gunther Wilke , Paul Heimbach
IPC分类号： B01J31/22 , C07C29/68 , C07C33/02 , C07C33/14 , C07C33/26 , C07C33/28 , C07C33/30 , C07D307/42 , C07F15/04 , C07C43/20
CPC分类号： C07F15/04 , B01J31/2213 , B01J31/2291 , B01J31/2295 , C07C29/68 , C07C33/02 , C07C33/14 , C07C33/26 , C07C33/28 , C07C33/30 , C07D307/42 , B01J2531/847 , C07C2101/16
摘要： Process of producing nickel alcoholates by reacting .pi.-allyl nickel compounds with carbonyl compounds. The nickel alcoholates so produced can be hydrolyzed to their corresponding alcohols and these alcohols can in part be dehydrated to their corresponding olefins. The nickel alcoholate products are useful for the production of their corresponding alcohols and these alcohols are useful for the production of their corresponding olefins.
摘要翻译：通过使pi烯丙基镍化合物与羰基化合物反应生产镍醇化物的方法。如此生产的镍醇盐可以水解成其相应的醇，这些醇可以部分脱水成相应的烯烃。镍醇化物产品可用于生产其相应的醇，这些醇可用于生产其相应的烯烃。

3. 发明授权

US4070406A 1-Phenyl-cyclooctadiene (1,5) 失效
标题翻译： 1-苯基 - 环辛二烯（1,5）
公开(公告)号：US4070406A
公开(公告)日：1978-01-24
申请号：US737765
申请日：1976-11-01
申请人： Gunther Wilke , Paul Heimbach
发明人： Gunther Wilke , Paul Heimbach
IPC分类号： C07C2/02 , C07C2/42 , C07C13/00 , C07C13/20 , C07C13/263 , C07C13/271 , C07C13/277 , C07C13/28 , C07C13/32 , C07C13/605 , C07C43/188 , C07C15/00 , C07C3/035
CPC分类号： C07C43/188 , C07C13/00 , C07C13/20 , C07C13/263 , C07C13/271 , C07C13/277 , C07C13/28 , C07C13/32 , C07C13/605 , C07C2/02 , C07C2/42 , C07C2101/14 , C07C2101/16 , C07C2101/18 , C07C2101/20 , C07C2103/84
摘要： A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.
摘要翻译：一系列单环，双和三环化合物，其中大多数在环中具有烯属不饱和键，其可以具有或不具有取代基。虽然双环和三环可以是未取代的，但是具有烯属不饱和键，特别是多个烯属不饱和键的这些化合物在已知的聚合体系中是可聚合的和可共聚的。它们是特别好的交联剂。这些化合物在它们可以被氧化裂解的意义上可进一步用于在增塑剂和洗涤剂领域已知有用的相应的羧酸，醛和/或醇。不具有烯属不饱和键的化合物也可被氧化裂解以产生氧化的，例如酸，醇或醛，已知有用的化合物。

4. 发明授权

US4056552A Ethyl 3,7-cyclodecadiene-1-carboxylate 失效
标题翻译： 3,7-环癸二烯-1-羧酸乙酯
公开(公告)号：US4056552A
公开(公告)日：1977-11-01
申请号：US565282
申请日：1975-04-04
申请人： Gunther Wilke , Paul Heimbach
发明人： Gunther Wilke , Paul Heimbach
IPC分类号： C07C69/74
CPC分类号： C07C2102/32 , C07C2103/84
摘要： A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.
摘要翻译：一系列单环，双和三环化合物，其中大多数在环中具有烯属不饱和键，其可以具有或不具有取代基。虽然双环和三环可以是未取代的，但是具有烯属不饱和键，特别是多个烯属不饱和键的这些化合物在已知的聚合体系中是可聚合的和可共聚的。它们是特别好的交联剂。这些化合物在它们可以被氧化裂解的意义上可进一步用于在增塑剂和洗涤剂领域已知有用的相应的羧酸，醛和/或醇。不具有烯属不饱和键的化合物也可被氧化裂解以产生氧化的，例如酸，醇或醛，已知有用的化合物。

5. 发明授权

US3978147A Process for the preparation of optically active carbon compounds 失效
标题翻译：制备光活性炭化合物的方法
公开(公告)号：US3978147A
公开(公告)日：1976-08-31
申请号：US413722
申请日：1973-11-07
申请人： Gunther Wilke , Borislav Bogdanovic , Horst Pauling
发明人： Gunther Wilke , Borislav Bogdanovic , Horst Pauling
IPC分类号： B01J31/24 , C07C2/04 , C07C2/36 , C07C11/113 , C07C13/263 , C07C13/32 , C07C13/40 , C07C3/00
CPC分类号： B01J31/2404 , B01J31/143 , B01J31/24 , C07C11/113 , C07C13/263 , C07C13/32 , C07C13/40 , C07C2/04 , C07C2/36 , B01J2231/20 , B01J2231/323 , B01J2531/847 , B01J31/2291 , C07B2200/07 , C07C2101/18 , C07C2102/32 , C07C2102/42 , C07C2527/125 , C07C2527/128 , C07C2531/02 , C07C2531/04 , C07C2531/14 , C07C2531/24 , Y10S585/952
摘要： Optically active compounds are prepared from optically inactive unsaturated hydrocarbons by reacting at least one unsaturated hydrocarbon in the presence of a catalyst prepared by combining a nickel compound, a Lewis acid and an optically active phosphine of the general formulaPR'R"R'"in which R', R" and R' " are hydrocarbon radicals, thereby forming optically active compounds having chiral centers formed by the carbon-to-carbon linkages. The optically active compounds can be polymerized to provide optically active polymers.

6. 发明授权

US3964983A Process for the electrochemical synthesis of organic metal compounds 失效
标题翻译：电化学合成有机金属化合物的方法
公开(公告)号：US3964983A
公开(公告)日：1976-06-22
申请号：US403239
申请日：1973-10-03
申请人： Wilhelm Eisenbach , Herbert Lehmkuhl , Gunther Wilke
发明人： Wilhelm Eisenbach , Herbert Lehmkuhl , Gunther Wilke
IPC分类号： C25B3/12 , C25B3/00 , B01K3/00
CPC分类号： C25B3/12 , C25B3/00
摘要： Process for reacting an H-acidic organic compound, in which the acidic H-atom is bonded to the organic radical by an oxygen or a sulphur atom, e.g. an alcohol, with a metal having a standard potential which is more positive than -1.66 volts and which at most reacts with the H-acidic compound under current-free conditions, e.g. Ni, Co, Fe, Mn, Sb, Cu, or Au. The H-acidic compound or a solution thereof is a polar solvent is made conducting by addition of a soluble salt of chlorine, bromine or iodine, and is electrolysed at a temperature of up to 150.degree.C, using said metal as the anode, for production of the alcoholate.
摘要翻译：使酸性H原子通过氧或硫原子键合到有机基团上的H酸性有机化合物反应的方法，例如醇，其具有比-1.66伏特更正的标准电位的金属，并且其在无电流条件下至多与H-酸性化合物反应，例如在无电流条件下。 Ni，Co，Fe，Mn，Sb，Cu或Au。通过加入氯，溴或碘的可溶性盐使H酸性化合物或其溶液是极性溶剂进行导电，并使用所述金属作为阳极，在高达150℃的温度下电解，得到生产醇酸盐。

7. 发明授权

US4827067A Azaphospholenes and use thereof 失效
标题翻译： Azaphospholenes及其用途
公开(公告)号：US4827067A
公开(公告)日：1989-05-02
申请号：US246577
申请日：1988-09-19
申请人： Gunther Wilke , Jaroslaw Monkiewicz , Herbert Kuhn
发明人： Gunther Wilke , Jaroslaw Monkiewicz , Herbert Kuhn
IPC分类号： B01J31/14 , B01J31/00 , B01J31/22 , B01J31/24 , C07B61/00 , C07C2/04 , C07C2/32 , C07C5/29 , C07C5/31 , C07C13/12 , C07C13/40 , C07C15/44 , C07F9/6564 , C07F9/6584 , C07C2/42
CPC分类号： C07F9/6584 , C07C2/04 , C07C5/31 , C07C2101/10 , C07C2102/42 , C07C2531/02 , C07C2531/14 , C07C2531/22
摘要： The invention relates to azaphospholene of the type ##STR1## wherein R.sub.1 and R.sub.2 may be alkyl, aryl and aralkyl groups, processes for preparing same and the use thereof.
摘要翻译：本发明涉及类型“IMAGE”的氮杂磷脂，其中R 1和R 2可以是烷基，芳基和芳烷基，其制备方法及其用途。

8. 发明授权

US4594447A Process for catalytic dimerization of acrylic acid derivatives 失效
标题翻译：丙烯酸衍生物的催化二聚方法
公开(公告)号：US4594447A
公开(公告)日：1986-06-10
申请号：US657292
申请日：1984-10-03
申请人： Gunther Wilke , Karin Sperling , Ludwig Stehling
发明人： Gunther Wilke , Karin Sperling , Ludwig Stehling
IPC分类号： B01J31/00 , B01J31/24 , C07B61/00 , C07C67/347 , C07C67/465 , C07C69/593 , C07C67/343
CPC分类号： C07C67/347
摘要： The invention relates to a process for the dimerization of derivatives of acrylic acid in the homogeneous phase which process is characterized in that a compound having the general formula H.sub.2 C.dbd.CR.sup.1 -COOR.sup.2, wherein R.sup.1 represents H or a linear alkyl group having from 1 to 3 carbon atoms and R.sup.2 represents a linear alkyl group having from 1 to 3 carbon atoms, is reacted in a solvent at a temperature of from -50.degree. C. to +50.degree. C. in the presence of nickel compounds as catalysts which contain complex anions X in a molar ratio Ni:X=1:1 and organic or hydride ligands and are modifed with phosphanes having the general formula PR.sub.2 R', wherein R and R' may be same or different and represent alkyl residues having from 1 to 8 carbon atoms or phenyl residues, as well as the use of the dimers formed in the dimerization.
摘要翻译：本发明涉及在均相中使丙烯酸衍生物二聚的方法，该方法的特征在于具有通式H 2 C = CR 1 -COOR 2的化合物，其中R 1表示H或具有1至3个直链烷基碳原子和R 2表示具有1至3个碳原子的直链烷基，在溶剂中在-50℃至+ 50℃的温度下在镍化合物作为催化剂存在下反应，所述催化剂含有复合阴离子 X与Ni：X = 1：1的摩尔比和有机或氢化物配体，并用具有通式PR2R'的磷烷改性，其中R和R'可以相同或不同，代表具有1至8个碳原子的烷基或苯基残基，以及二聚体中形成的二聚体的用途。

9. 发明授权

US4120882A Metal complexes 失效
标题翻译：金属配合物
公开(公告)号：US4120882A
公开(公告)日：1978-10-17
申请号：US798199
申请日：1977-05-18
申请人： Gunther Wilke , Ernst Willi Muller
发明人： Gunther Wilke , Ernst Willi Muller
IPC分类号： B01J31/22 , C07C2/46 , C07C2/52 , C07F9/02 , C07F15/04 , C07F15/06
CPC分类号： C07F15/06 , B01J31/122 , B01J31/143 , B01J31/185 , B01J31/1855 , B01J31/1895 , B01J31/2234 , B01J31/2295 , B01J31/2404 , C07C2/465 , C07C2/52 , C07F15/04 , C07F9/02 , B01J2231/324 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2101/16 , C07C2101/18 , C07C2101/20 , C07C2531/02 , C07C2531/12 , C07C2531/22 , C07C2531/24
摘要： Complexes of nickel or cobalt with phosphine, phosphite, stilbene or arsine ligands, especially nickel-phosphine complexes, useful as catalysts.
摘要翻译：镍或钴与膦，亚磷酸酯，二苯乙烯或胂配体的配合物，特别是可用作催化剂的镍 - 膦配合物。

10. 发明授权

US4076757A 3-Methoxycyclooctadiene-(1,5) 失效
标题翻译： 3-甲氧基环辛二烯 - （1,5）
公开(公告)号：US4076757A
公开(公告)日：1978-02-28
申请号：US737766
申请日：1976-11-01
申请人： Gunther Wilke , Paul Heimbach
发明人： Gunther Wilke , Paul Heimbach
IPC分类号： C07C2/02 , C07C2/42 , C07C13/00 , C07C13/20 , C07C13/263 , C07C13/271 , C07C13/277 , C07C13/28 , C07C13/32 , C07C13/605 , C07C43/188 , C07C43/18
CPC分类号： C07C43/188 , C07C13/00 , C07C13/20 , C07C13/263 , C07C13/271 , C07C13/277 , C07C13/28 , C07C13/32 , C07C13/605 , C07C2/02 , C07C2/42 , C07C2101/14 , C07C2101/16 , C07C2101/18 , C07C2101/20 , C07C2103/84
摘要： A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.
摘要翻译：一系列单环，双和三环化合物，其中大多数在环中具有烯属不饱和键，其可以具有或不具有取代基。虽然双环和三环可以是未取代的，但是具有烯属不饱和键，特别是多个烯属不饱和键的这些化合物在已知的聚合体系中是可聚合的和可共聚的。它们是特别好的交联剂。这些化合物在它们可以被氧化裂解的意义上可进一步用于在增塑剂和洗涤剂领域已知有用的相应的羧酸，醛和/或醇。不具有烯属不饱和键的化合物也可被氧化裂解以产生氧化的，例如酸，醇或醛，已知有用的化合物。

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