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    • 73. 发明授权
    • Semiconductor device with encapsulating material composed of silica
    • 具有由二氧化硅构成的封装材料的半导体器件
    • US06278192B1
    • 2001-08-21
    • US09354734
    • 1999-07-16
    • Yukio TakigawaEi Yano
    • Yukio TakigawaEi Yano
    • H01L2150
    • H01L23/293H01L2224/13023H01L2224/274H01L2924/01019H01L2924/01068H01L2924/10253H01L2924/12044H01L2924/00
    • A semiconductor device having enhanced reliability which is obtained by cutting a wafer encapsulated by an encapsulating material layer in such a manner that each of end faces of bumps for an external terminal is exposed, and a method of isolating a metal in an encapsulating material to allow measuring. The semiconductor device comprises a semiconductor element, bumps formed on a surface thereof for external terminals, and an encapsulating material layer, the encapsulating material layer being formed of an encapsulating material containing greater than 70% by weight and not greater than 90% by weight of fused silica, based on the total weight of the encapsulating material. The metal in the encapsulating material comprising a resin component and a fumed silica filler is isolated for measuring by adding the encapsulating material to a solvent capable of dissolving the resin component, separating solvent-insolubles from the solution in which the resin component has been dissolved, introducing the insolubles into a liquid having a specific gravity of 2.5 to 5.5 to disperse the insolubles, and then recovering the precipitate.
    • 一种具有增强的可靠性的半导体器件,其通过以这样一种方式切割由封装材料层封装的晶片而获得的,即外露端子的凸块的每个端面被暴露,以及隔离封装材料中的金属以允许 测量。 半导体器件包括半导体元件,在其外部端子的表面上形成的凸块和封装材料层,所述封装材料层由包含大于70重量%且不大于90重量% 熔融二氧化硅,基于包封材料的总重量。 通过将包封材料添加到能够溶解树脂成分的溶剂中,将溶剂不溶物从溶解有树脂成分的溶液中分离出来,分离包含树脂组分和热解法二氧化硅填料的包封材料中的金属, 将不溶物引入比重为2.5〜5.5的液体中以分散不溶物,然后回收沉淀物。
    • 74. 发明授权
    • Chemically amplified resist compositions and process for the formation of resist patterns
    • 化学扩增抗蚀剂组合物和形成抗蚀剂图案的方法
    • US06200725B1
    • 2001-03-13
    • US08969368
    • 1997-11-28
    • Satoshi TakechiAkiko KotachiKoji NozakiEi YanoKeiji WatanabeTakahisa NamikiMiwa IgarashiYoko MakinoMakoto Takahashi
    • Satoshi TakechiAkiko KotachiKoji NozakiEi YanoKeiji WatanabeTakahisa NamikiMiwa IgarashiYoko MakinoMakoto Takahashi
    • G03F7039
    • G03F7/039G03F7/0045
    • Alkali-developable, chemically amplified resist composition which comprises an alkali-insoluble compound having a structural unit containing a protected alkali-soluble group in which unit a protective moiety of said protected alkali-soluble group contains an alicyclic hydrocarbon group having bonded to a carbon atom thereof a —CH2—R1′ group wherein R1′ is methyl, ethyl, propyl or isopropyl, and said alkali-soluble group is cleaved upon action of an acid generated from a photoacid generator used in combination with said compound, thereby releasing said protective moiety from the alkali-soluble group and converting said compound to an alkali-soluble one, and a photoacid generator capable of being decomposed upon exposure to a patterning radiation to thereby produce an acid capable of causing cleavage of said protective moiety. The resist composition can exhibit a high sensitivity (not more than 5 mJ/cm2) and therefore is particularly suitable for ArF lithography and also can exhibit stable patterning properties.
    • 碱可显影的化学增幅抗蚀剂组合物,其包含具有包含受保护的碱溶性基团的结构单元的碱不溶性化合物,其中所述被保护的碱溶性基团的保护部分含有与碳原子键合的脂环族烃基 其中R 1'是甲基,乙基,丙基或异丙​​基,并且所述碱溶性基团在与所述化合物组合使用的光致酸产生剂产生的酸作用下被切割,由此释放所述保护部分 从碱溶性基团中转化为碱溶性化合物,以及光致酸发生剂,其能够在暴露于图案化辐射时分解,从而产生能够导致所述保护部分裂解的酸。 抗蚀剂组合物可以表现出高灵敏度(不大于5mJ / cm 2),因此特别适用于ArF光刻,并且还可呈现稳定的图案化性能。
    • 79. 发明申请
    • METHOD FOR FORMING RESIST PATTERN AND METHOD FOR MANUFACTURING A SEMICONDUCTOR DEVICE
    • 形成电阻图案的方法和制造半导体器件的方法
    • US20100193841A1
    • 2010-08-05
    • US12756914
    • 2010-04-08
    • Junichi KonEi Yano
    • Junichi KonEi Yano
    • H01L29/778G03F7/004
    • G03F7/0397G03F7/0045Y10S430/114Y10S430/115Y10S430/12Y10S430/121Y10S430/122Y10S430/128Y10S430/143
    • The resist material contains a photo-acid generator having an absorption peak to exposure light having a wavelength of less than 300 nm, and a second photo-acid generator having an absorption peak to exposure light having a wavelength of 300 nm or more. The method for forming a resist pattern comprises a step for selectively exposing which exposes a coating film of the resist material to an exposure light having a wavelength of less than 300 nm, and a step for selectively exposing by using an exposure light having a wavelength of 300 nm or more. The semiconductor device comprises a pattern formed by the resist pattern. The method for forming a semiconductor device comprises a step for forming a resist pattern on an underlying layer by the aforementioned manufacturing method, and a step for patterning the underlying layer by etching using the resist pattern as a mask.
    • 抗蚀剂材料包含具有对波长小于300nm的曝光光具有吸收峰的光酸产生器和具有波长为300nm或更大的曝光光的吸收峰的第二光酸产生器。 形成抗蚀剂图案的方法包括用于选择性曝光的步骤,其将抗蚀剂材料的涂膜暴露于波长小于300nm的曝光光,以及通过使用具有波长小于300nm的曝光光来选择性曝光的步骤 300nm以上。 半导体器件包括由抗蚀剂图案形成的图案。 用于形成半导体器件的方法包括通过上述制造方法在下层形成抗蚀剂图案的步骤,以及通过使用抗蚀剂图案作为掩模通过蚀刻对下层进行图案化的步骤。
    • 80. 发明授权
    • Method for forming resist pattern and method for manufacturing a semiconductor device
    • 用于形成抗蚀剂图案的方法和用于制造半导体器件的方法
    • US07723016B2
    • 2010-05-25
    • US12292170
    • 2008-11-13
    • Junichi KonEi Yano
    • Junichi KonEi Yano
    • G03F7/00G03F7/004G03F7/20
    • G03F7/0397G03F7/0045Y10S430/114Y10S430/115Y10S430/12Y10S430/121Y10S430/122Y10S430/128Y10S430/143
    • The resist material contains a photo-acid generator having an absorption peak to exposure light having a wavelength of less than 300 nm, and a second photo-acid generator having an absorption peak to exposure light having a wavelength of 300 nm or more. The method for forming a resist pattern comprises a step for selectively exposing which exposes a coating film of the resist material to an exposure light having a wavelength of less than 300 nm, and a step for selectively exposing by using an exposure light having a wavelength of 300 nm or more. The semiconductor device comprises a pattern formed by the resist pattern. The method for forming a semiconductor device comprises a step for forming a resist pattern on an underlying layer by the aforementioned manufacturing method, and a step for patterning the underlying layer by etching using the resist pattern as a mask.
    • 抗蚀剂材料包含具有对波长小于300nm的曝光光具有吸收峰的光酸产生器和具有波长为300nm或更大的曝光光的吸收峰的第二光酸产生器。 形成抗蚀剂图案的方法包括用于选择性曝光的步骤,其将抗蚀剂材料的涂膜暴露于波长小于300nm的曝光光,以及通过使用具有波长为 300nm以上。 半导体器件包括由抗蚀剂图案形成的图案。 用于形成半导体器件的方法包括通过上述制造方法在下层形成抗蚀剂图案的步骤,以及通过使用抗蚀剂图案作为掩模通过蚀刻对下层进行图案化的步骤。