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1. 发明申请

US20170088654A1 COPOLYMER HAVING ADJUSTABLE GLASS TRANSITION TEMPERATURE AND HAVING USEFULNESS AS ORGANIC ELECTRO-OPTIC POLYMER, AND ORGANIC ELECTRO-OPTIC ELEMENT USING THE SAME 审中-公开
公开(公告)号：US20170088654A1
公开(公告)日：2017-03-30
申请号：US15126080
申请日：2015-03-17
申请人： NATIONAL INSTITUTE OF INFORMATION AND COMMUNICATIONS TECHNOLOGY
发明人： Akira OTOMO , Isao AOKI , Toshiki YAMADA , Hideki MIKI
IPC分类号： C08F220/36 , G02F1/061 , G02F1/361 , C08F220/18
CPC分类号： C08F220/36 , C08F220/18 , C08F2810/40 , C08G18/2815 , C08G18/284 , C08G18/288 , C08G18/728 , G02F1/061 , G02F1/3617 , C08F2220/1875
摘要： An object of the present invention is to provide an organic EO polymer having a desired Tg. The present invention provides a copolymer comprising (i) a cycloalkane methacrylate and 2-isocyanatoethyl methacrylate as monomers at an adjusted blending ratio and (ii) an electro-optic molecule (EO molecule) bound to the copolymer, thereby exhibiting a desired glass transition temperature (Tg).

2. 发明申请

US20130341574A1 PHOTOREFRACTIVE COMPOSITION AND DEVICE COMPRISING THE COMPOSITION 审中-公开
标题翻译：光电组合物和包含组合物的装置
公开(公告)号：US20130341574A1
公开(公告)日：2013-12-26
申请号：US14001136
申请日：2012-02-22
申请人： Weiping Lin , Peng Wang , Tao Gu , Michiharu Yamamoto
发明人： Weiping Lin , Peng Wang , Tao Gu , Michiharu Yamamoto
IPC分类号： G02F1/361
CPC分类号： G02F1/3611 , G02F1/3612 , G02F1/3617 , G03H1/02 , G03H2001/0264 , G03H2260/54 , G11B7/24044 , G11B7/245 , G11B7/246
摘要： A photorefractive composition and a photorefractive device comprising the composition are disclosed. The composition is configured to be photorefractive upon irradiation by a laser having a wavelength in the visible light spectrum and comprises a polymer, a non linear optical chromophore, and a plasticizer. In an embodiment, the percentage of polymer recurring units that comprise a charge transport moiety is less than 30%. In an embodiment, the polymer is selected from the group consisting of polycarbonate, polyurea, polyurethane, poly(meth)acrylate, polyester, polyimide, and combinations thereof. Preferably, the composition has a diffraction efficiency of about 30% or greater upon irradiation with a visible light laser.
摘要翻译：公开了一种光折射组合物和包含该组合物的光折射装置。该组合物被配置为在具有可见光光谱波长的激光照射时具有光折射，并且包含聚合物，非线性光学发色团和增塑剂。在一个实施方案中，包含电荷转移部分的聚合物重复单元的百分比小于30％。在一个实施方案中，聚合物选自聚碳酸酯，聚脲，聚氨酯，聚（甲基）丙烯酸酯，聚酯，聚酰亚胺及其组合。优选地，组合物在用可见光激光照射时具有约30％或更大的衍射效率。

3. 发明授权

US07317058B2 (Meth)acrylate polymer and non-linear optical device material composition 失效
标题翻译：（甲基）丙烯酸酯聚合物和非线性光学器件材料组成
公开(公告)号：US07317058B2
公开(公告)日：2008-01-08
申请号：US11255735
申请日：2005-10-21
申请人： Michiharu Yamamoto
发明人： Michiharu Yamamoto
IPC分类号： C08F12/20 , C08F118/02
CPC分类号： C08F220/14 , C08F214/18 , C08F220/40 , G02F1/3615 , G02F1/3617
摘要： A non-linear optical device composition includes a trifluorovinyl group containing poly(meth)acrylate that is crosslinkable and thermally stable after crosslinking. The poly(meth)acrylate composition may provide passive or active wave-guide optical capabilities. The composition may be used for an active wave guide material, such as modulator or switching device compositions. Furthermore, the composition may include a trifluorovinyl containing chromophore and poly(meth)acrylate which provides non-linear optical ability in the matrix polymer system.
摘要翻译：非线性光学元件组合物包含交联后可交联且热稳定的聚（甲基）丙烯酸酯的三氟乙烯基。聚（甲基）丙烯酸酯组合物可以提供无源或主动的波导光学能力。组合物可用于有源波导材料，例如调制器或开关器件组合物。此外，组合物可以包括含有三氟乙烯基的发色团和在基质聚合物体系中提供非线性光学能力的聚（甲基）丙烯酸酯。

4. 发明授权

US07019453B2 Polymers having pendant nonlinear optical chromophores and electro-optic devices therefrom 有权
标题翻译：具有侧挂非线性光学发色团和电光器件的聚合物
公开(公告)号：US07019453B2
公开(公告)日：2006-03-28
申请号：US10625371
申请日：2003-07-23
申请人： Diyun Huang , Baoquan Chen
发明人： Diyun Huang , Baoquan Chen
IPC分类号： H01J1/62 , G02B26/00
CPC分类号： C07D333/38 , C07D409/06 , C07D495/04 , G02F1/3614 , G02F1/3617
摘要： A nonlinear optical chromophore having the formula D-π-A, wherein π is a π bridge including a thiophene ring having oxygen atoms bonded directly to the 3 and 4 positions of the thiophene ring, D is a donor, and A is an acceptor.
摘要翻译：具有式D-pi-A的非线性光学发色团，其中p1是包含具有氧原子的噻吩环的π桥，其直接与噻吩环的3和4位相连，D是供体，A是受体。

5. 发明申请

US20050159623A1 Electrooptic compounds and methods for making 有权
标题翻译：电光化合物和制备方法
公开(公告)号：US20050159623A1
公开(公告)日：2005-07-21
申请号：US10600901
申请日：2003-06-20
申请人： Vincent McGinniss , Steven Risser
发明人： Vincent McGinniss , Steven Risser
IPC分类号： G02B6/122 , G02F1/01 , G02F1/061 , G02F1/065 , G02F1/361 , C07C251/00 , C07C22/00
CPC分类号： G02F1/3617 , G02B6/1221 , G02F1/0147 , G02F1/061 , G02F1/065 , G02F1/3611
摘要： Functional optical materials for optical systems that are typically useful in optical waveguides, optical switching systems, optical modulators, optical computing systems and the like. Included are polymer systems and electrooptical chromophores. Polymers are thermoplastic and/or thermosetting polymers and are blended or co-polymerized with the electrooptic chromophore. The thermoplastic or thermosetting polymer selected from an acrylic/methacrylic, polyester, polyurethane, polyimide, polyamide, epoxy resin, or hybrid (organic-inorganic) or nanocomposite polyester polymer. The electrooptic chromophore is selected from a substituted aniline, substituted azobenzene, substituted stilbene, or substituted imine. Methods for improving adhesion promotion for the various novel materials are also provided.
摘要翻译：通常用于光波导，光交换系统，光调制器，光学计算系统等的用于光学系统的功能光学材料。包括聚合物体系和电光发色团。聚合物是热塑性和/或热固性聚合物，并与电光发色团共混或共聚。选自丙烯酸/甲基丙烯酸，聚酯，聚氨酯，聚酰亚胺，聚酰胺，环氧树脂或杂化（有机 - 无机）或纳米复合聚酯聚合物的热塑性或热固性聚合物。电光发色团选自取代的苯胺，取代的偶氮苯，取代的二苯乙烯或取代的亚胺。还提供了用于改善各种新型材料的附着力促进的方法。

6. 发明申请

US20050159574A1 Fluorinated sol-gel electro-optic materials, process for producing same, and devices therefrom 失效
标题翻译：氟化溶胶 - 凝胶电光材料，其制造方法及其装置
公开(公告)号：US20050159574A1
公开(公告)日：2005-07-21
申请号：US10761862
申请日：2004-01-21
申请人： Dan Jin
发明人： Dan Jin
IPC分类号： C08G77/24 , C08G77/28 , C08G77/48 , C08G77/54 , G02F1/361
CPC分类号： G02F1/3616 , C08G77/24 , C08G77/28 , C08G77/48 , C08G77/54 , G02F1/3617
摘要： A process, comprising: a) reacting a an alkoxysilane, an (epoxy)alkoxysilane, and a fluorinated alkoxysilane to form a fluorinated sol-gel polymer; and b) reacting a nonlinear optical chromophore comprising a donor, a π-bridge, an acceptor, and at least one alkoxysilyl group with the fluorinated sol-gel polymer to form a nonlinear optical fluorinated sol-gel polymer.
摘要翻译：一种方法，包括：a）使烷氧基硅烷，（环氧）烷氧基硅烷和氟化烷氧基硅烷反应以形成氟化溶胶 - 凝胶聚合物; 和b）使包含供体，π桥，受体和至少一个烷氧基甲硅烷基的非线性光学发色团与氟化溶胶 - 凝胶聚合物反应以形成非线性光学氟化溶胶 - 凝胶聚合物。

7. 发明授权

US06864347B2 Nonlinear optical chiral compounds and devices incorporating same 失效
标题翻译：非线性光学手性化合物及其结合的装置
公开(公告)号：US06864347B2
公开(公告)日：2005-03-08
申请号：US10186213
申请日：2002-06-28
申请人： Martin Kits van Heyningen , Thierry Verbiest , Andre Persoons , Celeste Samyn , Guy Koeckelberghs
发明人： Martin Kits van Heyningen , Thierry Verbiest , Andre Persoons , Celeste Samyn , Guy Koeckelberghs
IPC分类号： G02F1/361 , C08G64/00
CPC分类号： G02F1/3617 , G02F1/3615
摘要： The present disclosure is in part directed to optical devices for modulating light comprising compounds which spontaneously align. The disclosure is also directed to electro-optic compounds wherein chromophore substituents are chemically bound to a chiral polymer. In one embodiment, the chiral polymer comprises a binaphthyl monomeric unit.
摘要翻译：本公开部分地涉及用于调制光的光学装置，其包括自发对准的化合物。本公开还涉及其中发色团取代基与手性聚合物化学键合的电光化合物。在一个实施方案中，手性聚合物包含联萘单体单元。

8. 发明申请

US20040192942A1 Fluorinated pi-bridge second order nonlinear optical chromophores and electro-optic devices therefrom 失效
标题翻译：氟化pi桥二阶非线性光学发色团和电光器件
公开(公告)号：US20040192942A1
公开(公告)日：2004-09-30
申请号：US10757375
申请日：2004-01-14
发明人： Diyun Huang
IPC分类号： C07D49/02 , C07D333/34 , G02B005/02 , G02C007/10
CPC分类号： C07D409/06 , C07D333/38 , C07D495/04 , G02F1/3614 , G02F1/3617
摘要： A nonlinear optical chromophore having the formula D-null-A, wherein null is a null bridge including a thiophene ring having oxygen atoms bonded directly to the 3 and 4 positions of the thiophene ring, D is a donor, A is an acceptor, and the oxygen atoms are further substituted with a fluorinated group comprising at least three fluorines is described. Some examples of fluorinated groups comprising at least three fluorine atoms are 2,2,2-trifluoroethyl; 2,2,3,3,3-pentafluoropropyl; 2,2,3,3,4,4,4-heptafluorobutyl; 2,2,3,3,4,4,5,5,5-octafluoropentyl; 3,3,4,4,-5,5,6,6,7,7,8,8,8-tridecafluoro-1-octyl; 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8 -pentadecafluorooctyl; 1-trifluoromethyl-2,2,2-trifluoroethyl; 1-trifluoromethyl-2,2,3,3,3 -pentafluoropropyl; 2,3,4,5,6-pentafluorobenzyl; and (2,3,4,5,6-pentafluorophenyl)ethyl.
摘要翻译：具有式D-pi-A的非线性光学发色团，其中p1是包括具有氧原子的噻吩环直接连接到噻吩环的3和4位的π桥，D是供体，A是受体，和氧原子进一步被包含至少三个氟的氟化基团取代。包含至少三个氟原子的氟化基团的一些实例是2,2,2-三氟乙基; 2,2,3,3,3-五氟丙基; 2,2,3,3,4,4,4-七氟丁基; 2,2,3,3,4,4,5,5,5-八氟戊基; 3,3,4,4,5,5,6,6,7,7,8,8-十三氟-1-辛基; 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十九氟辛基; 1-三氟甲基-2,2,2-三氟乙基; 1-三氟甲基-2,2,3,3,3-五氟丙基; 2,3,4,5,6-五氟苄基; 和（2,3,4,5,6-五氟苯基）乙基。

9. 发明申请

US20030183812A1 Fluorinated crosslinked electro-optic materials and electro-optic devices therefrom 失效
标题翻译：氟化交联电光材料和电光器件
公开(公告)号：US20030183812A1
公开(公告)日：2003-10-02
申请号：US10395610
申请日：2003-03-24
发明人： Diyun Huang , Baoquan Chen
IPC分类号： G02F001/035 , C07D49/14
CPC分类号： C07D333/38 , C07D409/06 , C07D495/04 , G02F1/3614 , G02F1/3615 , G02F1/3617
摘要： A nonlinear optical chromophore having the formula D-null-A, wherein null is a null bridge including a thiophene ring having oxygen atoms bonded directly to the 3 and 4 positions of the thiophene ring, D is a donor, and A is an acceptor.
摘要翻译：具有式D-pi-A的非线性光学发色团，其中p1是包含具有氧原子的噻吩环的π桥，其直接与噻吩环的3和4位相连，D是供体，A是受体。

10. 发明授权

US06610219B2 Functional materials for use in optical systems 失效
公开(公告)号：US06610219B2
公开(公告)日：2003-08-26
申请号：US09777439
申请日：2001-02-06
申请人： Vincent D. McGinniss , Steven M. Risser
发明人： Vincent D. McGinniss , Steven M. Risser
IPC分类号： F21V914
CPC分类号： G02F1/3617 , G02B6/1221 , G02F1/0147 , G02F1/061 , G02F1/065 , G02F1/3611
摘要： Functional optical materials for optical systems that are typically useful in optical waveguides, optical switching systems, optical modulators, optical computing systems and the like. Included are polymer systems and electrooptical chromophores. Polymers are thermoplastic and/or thermosetting polymers and are blended or co-polymerized with the electrooptic chromophore. The thermoplastic or thermosetting polymer selected from an acrylic/methacrylic, polyester, polyurethane, polyimide, polyamide, epoxy resin, or hybrid (organic-inorganic) or nanocomposite polyester polymer. The electrooptic chromophore is selected from a substituted aniline, substituted azobenzene, substituted stilbene, or substituted imine. Methods for improving adhesion promotion for the various novel materials are also provided.

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