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71. 发明授权

US4514613A Method of an apparatus for welding together metal components 失效
标题翻译：金属部件焊接在一起的装置的方法
公开(公告)号：US4514613A
公开(公告)日：1985-04-30
申请号：US377157
申请日：1982-05-11
申请人： Michael Hill , John H. P. C. Megaw , Howard Harvey
发明人： Michael Hill , John H. P. C. Megaw , Howard Harvey
IPC分类号： B23K26/00 , B23K15/00 , B23K26/08 , B23K26/20 , B23K26/28 , B23K11/10
CPC分类号： B23K26/0823 , B23K26/28
摘要： In having a method of welding together metal components (A,B) a high restraint geometry (as defined in the Specification) the components are urged into abutment and a high energy density weld is effected at a location in said abutment by means such as a focussed laser beam (L). In order to compensate for the high restraint geometry of the components which prevents them from deformation such as to accommodate welding stresses, an additional force (J) is applied, for example by a roller (K), to urge the components together adjacent to the position at which the weld is effected. The method is advantageously employed to form a continuous elongate weld between a plateform and web of a brake shoe.
摘要翻译：在具有将金属部件（A，B）焊接在一起的高度约束几何形状（如本说明书中所定义））的方法中，部件被推进邻接，并且在所述邻接部分的位置处实现高能量密度焊接，例如聚焦激光束（L）。为了补偿组件的高约束几何形状，防止它们变形以适应焊接应力，例如通过辊（K）施加额外的力（J），以将部件压在邻近的部件进行焊接的位置。该方法有利地用于在制动蹄板的平板和腹板之间形成连续的细长焊缝。

72. 发明申请

US20160275765A1 Portable Security System 审中-公开
标题翻译：便携式安全系统
公开(公告)号：US20160275765A1
公开(公告)日：2016-09-22
申请号：US15071193
申请日：2016-03-15
申请人： Bryan Ulrich McClain , Demetrius Madrigal , Daniel Nicholas Peknik , Michael Hill
发明人： Bryan Ulrich McClain , Demetrius Madrigal , Daniel Nicholas Peknik , Michael Hill
IPC分类号： G08B13/14 , G08B25/10
CPC分类号： G08B13/1445 , G08B5/36 , G08B25/10
摘要： An apparatus embodiment includes a security module having a guard frame, a dome slidably engaged with the guard frame, and an alarm system inside the dome. The alarm system includes a controller and a radio frequency transceiver. The security module further includes a suction cup coupled to the dome, a valve in fluid communication with the suction cup and electrically connected to the controller, and a suction cup in fluid communication with the valve. An embodiment may further include a client application including software instructions for arming the alarm system, disarming the alarm system, and opening the valve. The security module may autonomously seek and/or link with another security module, thereby forming an ad hoc communications network to protect an object tethered to the security module by a wireless communications link and/or a security cable.
摘要翻译：设备实施例包括具有防护框架，与防护框架可滑动地接合的拱顶以及穹顶内的报警系统的安全模块。报警系统包括控制器和射频收发器。安全模块还包括联接到圆顶的吸盘，与吸盘流体连通并与控制器电连接的阀以及与阀流体连通的吸盘。实施例还可以包括客户端应用，其包括用于布防报警系统的软件指令，撤防报警系统和打开阀门。安全模块可以自主地寻找和/或链接到另一个安全模块，从而形成一个自组织通信网络，以通过无线通信链路和/或安全电缆来保护拴在安全模块上的对象。

73. 发明授权

US09139714B2 Method for producing dialkylphosphinic acids and esters and salts thereof by means of allyl alcohols-acroleins and use thereof 有权
标题翻译：通过烯丙醇 - 丙烯醛制备二烷基次膦酸及其酯及其盐的方法及其用途
公开(公告)号：US09139714B2
公开(公告)日：2015-09-22
申请号：US13121870
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C07C69/02 , C07F9/32 , C08K5/5313 , C07F9/30 , C07F9/48 , C09K21/12
CPC分类号： C08K5/5313 , C07C69/02 , C07F9/301 , C07F9/32 , C07F9/3211 , C07F9/3264 , C07F9/4816 , C07F9/4866 , C09K21/12
摘要： The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkyl phosphonic acid, salt, salt or ester (II) thereof is reacted with compounds of formula (V) and/or (VI′) to yield mono-functionalized dialkylphosphinic acid derivatives (VI) and/or (VI′) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivatives (VI) and/or (VI′) are reacted to yield a mono-carboxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst C, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H1 C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X and Y are the same or different and stand independently of each other for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalysts A and C are formed by transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides and/or peroxo compounds and/or azo compounds and/or alkali metals and/or alkaline earth metals, alkali hydrides, alkaline earth hydrides and/or alkali alcoholates and alkaline earth alcoholates.
摘要翻译：本发明涉及一种用于制备单羧基官能化二烷基次膦酸及其酯和盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸，盐或酯（II）在催化剂A存在下，b）将由此得到的烷基膦酸，其盐，盐或酯（II）与式（Ⅴ）和/或（Ⅵ'）化合物反应，得到单官能化二烷基次膦酸衍生物（VI）和/或（VI'）在催化剂B的存在下反应，和c）将如此获得的单官能化二烷基次膦酸衍生物（VI）和/或（Ⅵ'）反应，得到单羧基官能化二烷基次膦基酸衍生物（III）在催化剂C存在下，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7相同或不同，并且彼此独立地表示H1 C1-C18烷基， C6-C18芳基，C6-C18芳烷基，C6-C18烷基芳基，X和Y相同或不同 H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn， Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化的氮碱，催化剂A和C由过渡金属和/或过渡金属化合物和/或催化剂体系形成，过渡金属和/或过渡金属化合物和至少一种配体，催化剂B由形成过氧化物和/或过氧化合物和/或偶氮化合物和/或碱金属和/或碱土金属的化合物，碱金属氢化物，碱碱土金属盐和/或碱金属醇盐和碱土金属盐。

74. 发明授权

US09085734B2 Process for preparing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts by means of alkylene oxides and use thereof 有权
标题翻译：通过烯化氧制备单羧基官能化二烷基次膦酸，酯和盐的方法及其用途
公开(公告)号：US09085734B2
公开(公告)日：2015-07-21
申请号：US13140126
申请日：2009-10-06
申请人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
发明人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
IPC分类号： C07F9/32 , C09K21/12 , C07F9/30 , C08K5/5313
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： A process for preparing mono-carboxy-functionalized dialkylphosphinic acids, dialkylphosphinic esters and dialkylphosphinic salts by means of alkylene oxides, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to form an alkylphosphonous acid, its salt or ester (II), b) the resultant alkylphosphonous acid, its salt or ester (II) is reacted with alkylene oxides of the formula (V) in the presence of a catalyst B, to give a mono-functionalized dialkylphosphinic acid derivative (VI), and c) the resultant mono-functionalized dialkylphosphinic acid derivative (VI) is reacted in the presence of a catalyst C to give the mono-carboxy-functionalized dialkylphosphinic acid derivative (III), and the catalysts A and C are transition metals and/or transition-metal compounds and/or catalyst systems which are composed of a transition metal and/or a transition-metal compound and at least one ligand, and the catalyst B is a Lewis acid.
摘要翻译：一种通过烯化氧制备单羧基官能化二烷基次膦酸，二烷基次膦酸酯和二烷基次膦酸盐的方法，其特征在于a）一个次膦酸源（I）与烯烃（Ⅳ）在催化剂A存在下反应，形成烷基亚磷酸，其盐或酯（II），b）在催化剂B的存在下，使得到的烷基亚磷酸，其盐或酯（II）与式（V）的氧化烯反应，得到单官能化二烷基次膦酸衍生物（Ⅵ），和c）所得到的单官能化二烷基次膦酸衍生物（Ⅵ）在催化剂C存在下反应得到单羧基官能化二烷基次膦酸衍生物（Ⅲ） A和C是由过渡金属和/或过渡金属化合物和至少一种配体组成的过渡金属和/或过渡金属化合物和/或催化剂体系，催化剂B是路易斯酸。

75. 发明授权

US09018413B2 Method for the production of alkylphosphonic acids, esters, and salts by oxidizing alkylphosphonous acids, and use thereof 有权
标题翻译：通过氧化烷基亚磷酸生产烷基膦酸，酯和盐的方法及其用途
公开(公告)号：US09018413B2
公开(公告)日：2015-04-28
申请号：US13140225
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C07F9/22 , C09K21/12 , C07F9/38 , C07F9/40 , C07F9/48 , C08K5/5317
CPC分类号： C09K21/12 , C07F9/3808 , C07F9/4006 , C07F9/4816 , C07F9/4866 , C08K5/5317
摘要： The invention relates to a method for producing monocarboxy-functionalized dialkylphosphinic acids, esters, and salts, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester (II) thereof, and b) the obtained alkylphosphonous acid, the salt or ester (II) thereof is reacted with an oxidizing agent or with an oxidizing agent and water or with oxygen and water in the presence of a catalyst B to obtain the alkylphosphonic acid derivative (III), wherein R1, R2, R3, R4 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, X and Y are identical or different from each other and independently represent H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogenous base, and catalysts A and B are transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand.
摘要翻译：本发明涉及一种用于制备单羧基官能化二烷基次膦酸，酯和盐的方法，其特征在于a）在催化剂A存在下，使次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或酯（II），和b）得到的烷基亚磷酸，其盐或酯（II）与氧化剂或氧化剂和水或者在氧化和水中在催化剂存在下反应 B获得烷基膦酸衍生物（III），其中R 1，R 2，R 3，R 4彼此相同或不同，并且独立地表示H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 芳烷基，C 6 -C 18烷基芳基，X和Y彼此相同或不同，独立地表示H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基， Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化的含氮碱，催化剂A 和B是由过渡金属和/或过渡金属化合物和至少一种配体组成的过渡金属和/或过渡金属化合物和/或催化剂体系。

76. 发明授权

US08664418B2 Method for producing dialkylphosphinic acids and esters and salts thereof by means of acrylic acid derivatives and use thereof 有权
标题翻译：通过丙烯酸衍生物及其用途制备二烷基次膦酸及其酯及其盐的方法
公开(公告)号：US08664418B2
公开(公告)日：2014-03-04
申请号：US13127102
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C07F9/32 , C07F9/30 , C07F5/06
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the alkylphosphonic acid thus obtained, salt or ester (II) thereof is reacted with an α,β-unsaturated carboxylic acid derivative (V) to yield a mono-carboxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst B, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X and Y are the same or different and stand independently of each other for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalyst A is formed by transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides and/or peroxo compounds and/or azo compounds and/or alkali metals and/or alkaline earth metals, alkali hydrides, alkaline earth hydrides and/or alkali alcoholates and alkaline earth alcoholates.
摘要翻译：本发明涉及一种用于制备单羧基官能化二烷基次膦酸及其酯和盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸，盐或酯（II）在催化剂A存在下，b）将由此得到的烷基膦酸，其盐或酯（II）与α，β-不饱和羧酸衍生物（V）反应，得到单羧基官能化的二烷基次膦酸衍生物（III ），其中R 1，R 2，R 3，R 4，R 5，R 6，R 7相同或不同并且彼此独立地表示，其中，H，C 1 -C 18烷基，C 6 -C 18 芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X和Y相同或不同并且独立地为H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基， Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化氮碱，并且催化剂A由过渡金属和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系形成，催化剂B由形成过氧化物和/或过氧化合物和/或偶氮化合物和/或碱金属和/或碱土金属，碱金属氢化物，碱土金属氢化物和/或碱金属醇盐和碱土金属盐。

77. 发明申请

US20140031960A1 SYSTEM AND METHOD FOR PRESENTING ADVERTISEMENTS IN ASSOCIATION WITH MEDIA STREAMS 审中-公开
标题翻译：用于介绍与媒体流相关的广告的系统和方法
公开(公告)号：US20140031960A1
公开(公告)日：2014-01-30
申请号：US13559503
申请日：2012-07-26
申请人： Michael Hill
发明人： Michael Hill
IPC分类号： G06F3/16
CPC分类号： G06F3/165 , H04H20/103
摘要： A system and related method are provided for presenting advertisements in association with a media stream in a network environment, without interrupting the media stream. The advertisements are provided in a real-time and targeted manner to maximize advertisement revenue. The advertisements replace advertisements otherwise provided within the media stream.
摘要翻译：提供了一种用于在网络环境中与媒体流相关联地呈现广告而不中断媒体流的系统和相关方法。广告以实时和有针对性的方式提供，以最大化广告收入。广告替代媒体流中否则提供的广告。

78. 发明授权

US08614267B2 Method for producing mono-hydroxyfunctionalized dialkylphosphinic acids and esters and salts thereof by means of allyl alcohols and use thereof 有权
标题翻译：通过烯丙醇制备单羟基官能化二烷基次膦酸及其酯和盐的方法及其用途
公开(公告)号：US08614267B2
公开(公告)日：2013-12-24
申请号：US13121889
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313
CPC分类号： C09K21/12 , C07F9/301 , C07F9/4816 , C07F9/4866 , C08K5/5313 , C08L21/00
摘要： The invention relates to a method for producing mono-hydroxyfunctionalized dialkylphosphinic acids and esters and salts thereof by means of allyl alcohols, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with compounds of formula (V) to yield a mono-hydroxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst B, wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X stands for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalyst A is formed by transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides and/or peroxo compounds and/or azo compounds.
摘要翻译：本发明涉及通过烯丙醇制备单羟基官能化二烷基次膦酸及其酯及其盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸盐或其酯（II），b）将如此得到的烷基膦酸，其盐或酯（II）与式（V）化合物反应，得到单羟基官能化二烷基次膦酸衍生物（III）在催化剂B的存在下，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，相同或不同，，C6-C18芳基，C6-C18芳烷基，C6-C18烷基芳基，X代表H，C1-C18烷基，C6-C18芳基，C6-C18芳烷基，C6-C18烷基芳基，Mg，Ca，Al， Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化的氮碱，催化剂A由过渡金属和/或t 由过渡金属和/或过渡金属化合物和至少一种配体组成的过渡金属化合物和/或催化剂体系和催化剂B由形成过氧化物和/或过氧化合物和/或偶氮化合物的化合物形成。

79. 发明申请

US20130131239A1 Method for Producing Mixtures of Alkylphosphonous Acid Salts And Dialkylphosphinic Acid Salts 有权
标题翻译：制备烷基膦酸盐和二烷基次膦酸盐的混合物的方法
公开(公告)号：US20130131239A1
公开(公告)日：2013-05-23
申请号：US13643899
申请日：2011-04-20
申请人： Michael Hill , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Michael Hill , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C09K21/12
CPC分类号： C09K21/12 , C07F9/3808 , C07F9/4816
摘要： The invention relates to a method for producing mixtures of alkylphosphonous acid and dialkylphosphinic acid salts, characterised in that a) a phosphinic acid source (I) is reacted with olefins (II) in the presence of a catalyst A to obtain a mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or salts or esters thereof, and b) the thus obtained mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or the salts or esters thereof is reacted with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base to obtain the corresponding mixtures of alkylphosphonous acid salt (V) and dialkylphosphinic acid salt (VI) of said metals and/or a nitrogen compound, (V) (VI), wherein Y represents Mg, Ca, AI, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na; K and/or a nitrogen compound and n represents ¼, ⅓, ½, 1.
摘要翻译：本发明涉及烷基磷酸和二烷基次膦酸盐的混合物的制备方法，其特征在于a）在催化剂A存在下，使次膦酸源（I）与烯烃（II）反应，得到烷基亚磷酸（III）和二烷基次膦酸（IV）或其盐或酯，和b）由此得到的烷基亚磷酸（III）和二烷基次膦酸（IV）或其盐或酯的混合物与Mg，Ca， Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化的氮碱，得到烷基亚磷酸盐（V）和二烷基次膦酸所述金属的酸性盐（VI）和/或氮化合物（V）（VI），其中Y表示Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr ，Mn，Li，Na; K和/或氮化合物，n表示¼，1/3，½，1。

80. 发明申请

US20120205306A1 MULTI-LAYERED BLOOD COMPONENT EXCHANGE DEVICES, SYSTEMS, AND METHODS 审中-公开
标题翻译：多层血液成分交换装置，系统和方法
公开(公告)号：US20120205306A1
公开(公告)日：2012-08-16
申请号：US13392519
申请日：2010-08-27
申请人： Ilan K. Reich , Edward F. Leonard , Michael Hill , John Howard
发明人： Ilan K. Reich , Edward F. Leonard , Michael Hill , John Howard
IPC分类号： B01D17/00
CPC分类号： B01D61/18 , A61M1/3472 , A61M2205/0244 , B01D63/081 , B01D2313/12
摘要： A microfluidic separation device suitable for high throughput applications such as medical treatments, and associated methods and systems, are described. Embodiments are suitable for treatment of end stage renal disease.
摘要翻译：描述了适用于诸如医疗处理和相关方法和系统的高通量应用的微流体分离装置。实施方案适用于治疗终末期肾病。

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