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1. 发明授权

US08987489B2 Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether and the use thereof 有权
标题翻译：使用乙烯基醚制备单羧基官能化二烷基次膦酸，酯和盐的方法及其用途
公开(公告)号：US08987489B2
公开(公告)日：2015-03-24
申请号：US13132196
申请日：2009-10-06
申请人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
发明人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
IPC分类号： C07F9/32 , C07F9/30 , C07F9/48 , C08K5/5313 , C09K21/12 , C08L21/00
CPC分类号： C07F9/30 , C07F9/301 , C07F9/32 , C07F9/4816 , C07F9/4866 , C08K5/5313 , C08L21/00 , C09K21/12
摘要： A method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, the salt or the ester (II) thereof, b) reacting the alkylphosphonous acid so obtained, the salt or the ester (II) thereof with a vinyl ether of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting this derivative (VI) with an oxidant or in the presence of a catalyst C to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III), wherein the catalysts A and C are transition metals and/or transition metal compounds, and the catalyst B is a peroxide-forming compound and/or a peroxo compound and/or an azo compound.
摘要翻译：使用乙烯基醚制备单羧基官能化的二烷基次膦酸，酯和盐的方法。该方法的特征在于以下步骤：a）在催化剂A存在下使次膦酸源（I）与烯烃（IV）反应，得到烷基亚磷酸，其盐或其酯（II），b）使所得的烷基亚磷酸，其盐或其酯（II）与式（V）的乙烯基醚在催化剂B的存在下反应，得到单官能化的二烷基次膦酸衍生物（VI），和c）使该衍生物 VI）与氧化剂或催化剂C的存在下反应，得到单羧基官能化的二烷基次膦酸衍生物（III），其中催化剂A和C为过渡金属和/或过渡金属化合物，催化剂B为过氧化物形成化合物和/或过氧化合物和/或偶氮化合物。

2. 发明授权

US08735476B2 Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid and the use thereof 有权
标题翻译：使用羧酸的乙烯基酯制备单羧基官能化的二烷基次膦酸，酯和盐的方法及其用途
公开(公告)号：US08735476B2
公开(公告)日：2014-05-27
申请号：US13132153
申请日：2009-10-06
申请人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
发明人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313
CPC分类号： C09K21/12 , C07F9/301 , C07F9/4816 , C07F9/4866 , C08K5/5313
摘要： The invention relates to a method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphinic acid, the salt or the ester (II) thereof, b) reacting the alkylphosphinic acid so obtained, the salt or the ester (II) thereof with a vinyl ester of a carboxylic acid of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting the mono-functionalized dialkylphosphinic acid derivative (VI) so obtained in the presence of a catalyst C to give a mono-functionalized dialkylphosphinic acid derivative (VII) and d) reacting the mono-functionalized dialkylphosphinic acid derivative (VII); with an oxidant or in the presence of a catalyst D to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III).
摘要翻译：本发明涉及使用羧酸的乙烯基酯制备单羧基官能化的二烷基次膦酸，酯和盐的方法。该方法的特征在于以下步骤：a）在催化剂A存在下使次膦酸源（I）与烯烃（IV）反应，得到烷基次膦酸，其盐或其酯（II），b）使如此获得的烷基次膦酸，其盐或其酯（II）与式（V）的羧酸的乙烯基酯在催化剂B的存在下反应，得到单官能化的二烷基次膦酸衍生物（Ⅵ）和c）使在催化剂C存在下得到的单官能化二烷基次膦酸衍生物（Ⅵ）反应，得到单官能化二烷基次膦酸衍生物（Ⅶ），和d）使单官能化二烷基次膦酸衍生物（Ⅶ）反应; 与氧化剂或在催化剂D存在下反应，得到单羧基官能化的二烷基次膦酸衍生物（III）。

3. 发明申请

US20110245385A1 Process for Preparing Mono-Carboxy-Functionalized Dialkylphosphinic Acids, Esters and Salts by Means of Alkylene Oxides and Use Thereof 有权
标题翻译：通过氧化亚烷基制备单羧基官能化二烷基膦酸，酯和盐的方法及用途
公开(公告)号：US20110245385A1
公开(公告)日：2011-10-06
申请号：US13140126
申请日：2009-10-06
申请人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
发明人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/30 , C07F9/32
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a process for preparing mono-carboxy-functionalized dialkylphosphinic acids, dialkylphosphinic esters and dialkylphosphinic salts by means of alkylene oxides, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to form an alkylphosphonous acid, its salt or ester (II), b) the resultant alkylphosphonous acid, its salt or ester (II) is reacted with alkylene oxides of the formula (V) in the presence of a catalyst B, to give a mono-functionalized dialkylphosphinic acid derivative (VI), and c) the resultant mono-functionalized dialkylphosphinic acid derivative (VI) is reacted in the presence a catalyst C to give the mono-carboxy-functionalized dialkylphosphinic acid derivative (III), where R1,R2,R3,R4,R5, and R6 are identical or different and independently of one another are inter alia H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl or C6-C18-alkylaryl, and X and Y are identical or different and independently of one another are H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogen base, and the catalysts A and C are transition metals and/or transition-metal compounds and/or catalyst systems which are composed of a transition metal and/or a transition-metal compound and at least one ligand, and the catalyst B is a Lewis acid.
摘要翻译：本发明涉及一种通过烯化氧制备单羧基官能化二烷基次膦酸，二烷基次膦酸酯和二烷基次膦酸盐的方法，其特征在于a）一种次膦酸源（I）与烯烃（Ⅳ）在形成烷基亚磷酸，其盐或酯（II）的催化剂A，b）在催化剂B存在下，使得到的烷基亚磷酸，其盐或酯（II）与式（V）的烯化氧反应，得到单官能化二烷基次膦酸衍生物（Ⅵ），和c）所得到的单官能化二烷基次膦酸衍生物（Ⅵ）在催化剂C存在下反应，得到单羧基官能化二烷基次膦酸衍生物（Ⅲ）其中R 1，R 2，R 3，R 4，R 5和R 6相同或不同并且彼此独立地尤其是H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 芳烷基或C 6 -C 18烷基芳基，X和Y相同或不同，独立一个是H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn ，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化的氮碱，催化剂A和C是组成的过渡金属和/或过渡金属化合物和/或催化剂体系的过渡金属和/或过渡金属化合物和至少一种配体，催化剂B是路易斯酸。

4. 发明申请

US20110237721A1 Method for Producing Mono-Carboxy-Functionalized Dialkylphosphinic Acids, Esters and Salts Using a Vinyl Ester of a Carboxylic Acid and the Use Thereof 有权
公开(公告)号：US20110237721A1
公开(公告)日：2011-09-29
申请号：US13132153
申请日：2009-10-06
申请人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
发明人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/30 , C07F9/32
CPC分类号： C09K21/12 , C07F9/301 , C07F9/4816 , C07F9/4866 , C08K5/5313
摘要： The invention relates to a method for producing mono-carboxy-functionalized dialkyiphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphinic acid, the salt or the ester (II) thereof, b) reacting the alkylphosphinic acid so obtained, the salt or the ester (II) thereof with a vinyl ester of a carboxylic acid of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting the mono-functionalized dialkyiphosphinic acid derivative (VI) so obtained in the presence of a catalyst C to give a mono-functionalized dialkylphosphinic acid derivative (VII) and d) reacting the mono-functionalized dialkyiphosphinic acid derivative (VII); with an oxidant or in the presence of a catalyst D to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III), wherein R1, R2, R3, R4, R5, R6 are the same or different and independently of each other inter alia represent H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X and Y are the same or different and independently of each other represent H, C1-C18 alkyl, C8-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogen base and the catalysts A and D are transition metals and/or transition metal compounds and/or catalyst systems which are composed of a transition metal and/or a transition metal compound and at least one ligand, and the catalyst B is a peroxide-forming compound and/or a peroxo compound and/or an azo compound, and the catalyst C is an acid or a base.

5. 发明授权

US09085734B2 Process for preparing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts by means of alkylene oxides and use thereof 有权
标题翻译：通过烯化氧制备单羧基官能化二烷基次膦酸，酯和盐的方法及其用途
公开(公告)号：US09085734B2
公开(公告)日：2015-07-21
申请号：US13140126
申请日：2009-10-06
申请人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
发明人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
IPC分类号： C07F9/32 , C09K21/12 , C07F9/30 , C08K5/5313
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： A process for preparing mono-carboxy-functionalized dialkylphosphinic acids, dialkylphosphinic esters and dialkylphosphinic salts by means of alkylene oxides, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to form an alkylphosphonous acid, its salt or ester (II), b) the resultant alkylphosphonous acid, its salt or ester (II) is reacted with alkylene oxides of the formula (V) in the presence of a catalyst B, to give a mono-functionalized dialkylphosphinic acid derivative (VI), and c) the resultant mono-functionalized dialkylphosphinic acid derivative (VI) is reacted in the presence of a catalyst C to give the mono-carboxy-functionalized dialkylphosphinic acid derivative (III), and the catalysts A and C are transition metals and/or transition-metal compounds and/or catalyst systems which are composed of a transition metal and/or a transition-metal compound and at least one ligand, and the catalyst B is a Lewis acid.
摘要翻译：一种通过烯化氧制备单羧基官能化二烷基次膦酸，二烷基次膦酸酯和二烷基次膦酸盐的方法，其特征在于a）一个次膦酸源（I）与烯烃（Ⅳ）在催化剂A存在下反应，形成烷基亚磷酸，其盐或酯（II），b）在催化剂B的存在下，使得到的烷基亚磷酸，其盐或酯（II）与式（V）的氧化烯反应，得到单官能化二烷基次膦酸衍生物（Ⅵ），和c）所得到的单官能化二烷基次膦酸衍生物（Ⅵ）在催化剂C存在下反应得到单羧基官能化二烷基次膦酸衍生物（Ⅲ） A和C是由过渡金属和/或过渡金属化合物和至少一种配体组成的过渡金属和/或过渡金属化合物和/或催化剂体系，催化剂B是路易斯酸。

6. 发明申请

US20110275744A1 Method for Producing Mono-Carboxy-Functionalized Dialkylphosphinic Acids, Esters and Salts Using a Vinyl Ether and the Use Thereof 有权
标题翻译：使用乙烯基醚生产单羧基官能化二烷基膦酸，酯和盐及其用途的方法
公开(公告)号：US20110275744A1
公开(公告)日：2011-11-10
申请号：US13132196
申请日：2009-10-06
申请人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
发明人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/32 , C07F9/30
CPC分类号： C07F9/30 , C07F9/301 , C07F9/32 , C07F9/4816 , C07F9/4866 , C08K5/5313 , C08L21/00 , C09K21/12
摘要： The invention relates to a method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, the salt or the ester (II) thereof, b) reacting the alkylphosphonous acid so obtained, the salt or the ester (II) thereof with a vinyl ether of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting the mono-functionalized dialkylphosphinic acid derivative (VI) so obtained with an oxidant or in the;presence of a catalyst C to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III), wherein R1, R2, R3, R4, R5, R6 are the same or different and independently of each other inter alia represent H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X and Y are the same or different and independently of each other represent H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogen base and the catalysts A and C are transition metals and/or transition metal compounds and/or catalyst systems which are composed of a transition metal and/or a transition metal compound and at least one ligand, and the catalyst B is a peroxide-forming compound and/or a peroxo compound and/or an azo compound.
摘要翻译：本发明涉及使用乙烯基醚制备单羧基官能化二烷基次膦酸，酯和盐的方法。该方法的特征在于以下步骤：a）在催化剂A存在下使次膦酸源（I）与烯烃（IV）反应，得到烷基亚磷酸，其盐或其酯（II），b）使如此获得的烷基亚磷酸，其盐或其酯（II）与式（V）的乙烯基醚在催化剂B的存在下反应，得到单官能化的二烷基次膦酸衍生物（VI），和c）官能化的二烷基次膦酸衍生物（Ⅵ），由氧化剂或催化剂C存在得到单羧基官能化的二烷基次膦酸衍生物（Ⅲ），其中R1，R2，R3，R4，R5，R6为相同或不同且彼此独立地特别表示H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X和Y相同或不同，彼此独立地表示H，C1 C18烷基，C6-C18芳基，C6-C18芳烷基，C6-C18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti， Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化的氮碱，催化剂A和C是过渡金属和/或过渡金属化合物和/ 其由过渡金属和/或过渡金属化合物和至少一种配体组成，催化剂B是形成过氧化物的化合物和/或过氧化合物和/或偶氮化合物。

7. 发明申请

US20090136440A1 Mixtures of phosphorus-containing compounds, a process for their preparation, and their use as flame retardants 审中-公开
标题翻译：含磷化合物的混合物，其制备方法及其作为阻燃剂的用途
公开(公告)号：US20090136440A1
公开(公告)日：2009-05-28
申请号：US12313542
申请日：2008-11-21
申请人： Wiebke Maas , Mathias Dietz , Martin Sicken
发明人： Wiebke Maas , Mathias Dietz , Martin Sicken
IPC分类号： A61K31/765 , C08L85/02 , C08L77/00 , C08L67/00 , H01M10/02 , A01P3/00 , A01P13/00 , C10L1/04 , A01P21/00 , A01P7/04 , H01G9/004 , C11D3/36 , C08L1/02 , A01N57/20
CPC分类号： C08K5/5317 , C08K2201/014
摘要： The invention relates to mixtures of compounds of the formulae (I), (III), (IV), and/or (V), in which n is an average chain length of from 0 to 10, A1 and A2 are identical or different and, independently of one another, are C(═O)NHR5, C(═O)R5, CH3, CH2CH3, CH2CH2CH3, CH(CH3)2, CH2(CH2)2CH3, CH2CH(CH3)2, C(CH3)3, C6H5, and/or CH2—C6H5, R1 is a moiety of the formula (II), in which k is an average chain length of from 0 to 5; R2 is CH3, CH2CH3, CH2CH2CH3, CH2(CH3)2, CH2(CH2)2CH3, CH2CH(CH3)2, C(CH3)3, C6H5, or CH2—C6H5; OCH3, OCH2CH3, O(CH2)2CH3, OCH(CH3)2, O(CH2)3CH3, OCH2CH(CH3)2, OC(CH3)3, O—C6H5, or O—CH2—C6H4, R3, R4, R5 are identical or different and, independently of one another, are CH3, CH2CH3, CH2CH2CH3, CH(CH3)2, CH2(CH2)2CH3, CH2Ch(CH3)2, C(CH3)3, C6H5, and/or CH2—C6H5 and where at least 2 compounds of the formulae (I), (III), (IV), or (V) are simultaneously present in the mixture; to a process for their preparation, and to their use as flame retardants.
摘要翻译：本发明涉及式（I），（III），（IV）和/或（V）的化合物的混合物，其中n是0至10的平均链长，A1和A2相同或不同并且彼此独立地为C（= O）NHR 5，C（-O）R 5，CH 3，CH 2 CH 3，CH 2 CH 2 CH 3，CH（CH 3）2，CH 2（CH 2）2 CH 3，CH 2 CH（CH 3）2，C（CH 3） 3，C 6 H 5和/或CH 2 -C 6 H 5，R 1是式（II）的部分，其中k是0至5的平均链长度; R 2是CH 3，CH 2 CH 3，CH 2 CH 2 CH 3，CH 2（CH 3）2，CH 2（CH 2）2 CH 3，CH 2 CH（CH 3）2，C（CH 3）3，C 6 H 5或CH 2 -C 6 H 5; OCH 3 CH 3，OCH（CH 3）2，O（CH 2）3 CH 3，OCH 2 CH（CH 3）2，OC（CH 3）3，O-C 6 H 5或O-CH 2 -C 6 H 4，是CH 3，CH 2 CH 3，CH 2 CH 2 CH 3，CH（CH 3）2，CH 2（CH 2）2 CH 3，CH 2 CH（CH 3）2，C（CH 3）3，C 6 H 5和/或CH 2 -C 6 H 5 并且其中至少2种式（I），（III），（IV）或（V）化合物同时存在于混合物中; 作为其制备方法，并用作阻燃剂。

8. 发明申请

US20080241529A1 Flameproofed adhesive and sealing materials 审中-公开
标题翻译：防火胶粘剂和密封材料
公开(公告)号：US20080241529A1
公开(公告)日：2008-10-02
申请号：US12079211
申请日：2008-03-25
申请人： Harald Bauer , Mathias Dietz , Werner Krause
发明人： Harald Bauer , Mathias Dietz , Werner Krause
IPC分类号： C09J101/00 , C08K5/5313 , C09J103/00 , C09J123/00 , C09J175/04 , C09J167/00 , C09J163/00 , B32B27/06 , C09J153/00 , C09J109/00 , C09J133/04 , C09J105/00 , C08K5/3492
CPC分类号： C09J9/00 , C08K5/5313 , C08L9/06 , C08L21/00 , C09J11/06 , Y10T428/2852
摘要： The invention relates to flameproofed adhesive and sealing materials containing 0.1-99.9% by weight of adhesive or thermoplastic polymer and 0.1-99.9% by weight of flameproofing agent, wherein the flameproofing agent contains at least one phosphinic acid salt of the formula (I) and/or one diphosphinic acid salt of the formula (II) in which R1, R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C6-C10-alkylarylene or C6-C10-arylalkylene; M is Mg, Ca, Al, Zn, Sb, Sn, Ge, Zn, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4 and x is 1 to 4, the adhesive polymers being acrylate resins, polyurethane resins, saturated and unsaturated polyester resins, styrene-butadiene copolymers, vinyl acetate copolymers, silicones, synthetic rubber and/or polyolefin resins.
摘要翻译：本发明涉及含有0.1-99.9重量％的粘合剂或热塑性聚合物和0.1-99.9重量％的防火剂的防火粘合剂和密封材料，其中该防火剂含有至少一种式（I）的次膦酸盐和 /或其中R 1，R 2，R 2相同或不同的式（II）的一种二膦酸盐是C 1 -C 直链或支链的烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - 10亚芳基，C 6 -C 10 - 亚烷基亚芳基或C 6 -C 10 - 芳基亚烷基; M是Mg，Ca，Al，Zn，Sb，Sn，Ge，Zn，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4，x为1〜4，粘合性聚合物为丙烯酸酯树脂，聚氨酯树脂，饱和和不饱和聚酯树脂，苯乙烯 - 丁二烯共聚物，乙酸乙烯酯共聚物，硅酮，合成橡胶和/或聚烯烃树脂。

9. 发明授权

US07812063B2 Flame-retardant resin formulation and its use 有权
标题翻译：阻燃树脂配方及其用途
公开(公告)号：US07812063B2
公开(公告)日：2010-10-12
申请号：US12008602
申请日：2008-01-11
申请人： Mathias Dietz , Harald Bauer , Werner Krause
发明人： Mathias Dietz , Harald Bauer , Werner Krause
IPC分类号： C08F2/50 , C08J7/18 , C08J7/04 , C09K21/00
CPC分类号： H05K3/287 , C08K5/5313 , H05K2201/012 , C08L63/10
摘要： The invention relates to a flame-retardant resin formulation comprising respectively at least one flame-retardant component, one alkali-soluble component, one polymerizable monomer, one photoinitiator, and one epoxy component, which comprises, as flame-retardant component, a phosphinic salt of the formula (I), in which R1 and R2 are identical or different and, independently of one another, are C1-C6-alkyl, linear or branched, and/or aryl; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base, and m is from 1 to 4. This novel flame-retardant resin formulation is preferably used as solder resist.
摘要翻译：本发明涉及一种阻燃树脂配方，其分别包含至少一种阻燃组分，一种碱溶性组分，一种可聚合单体，一种光引发剂和一种环氧组分，其包含作为阻燃组分的次膦酸盐式（I）的化合物，其中R 1和R 2相同或不同并且彼此独立地为C 1 -C 6 - 烷基，直链或支链和/或芳基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化的氮碱，m是1〜该新型阻燃树脂配方优选用作阻焊剂。

10. 发明申请

US20080171800A1 Flame-retardant resin formulation and its use 有权
标题翻译：阻燃树脂配方及其用途
公开(公告)号：US20080171800A1
公开(公告)日：2008-07-17
申请号：US12008602
申请日：2008-01-11
申请人： Mathias Dietz , Harald Bauer , Werner Krause
发明人： Mathias Dietz , Harald Bauer , Werner Krause
IPC分类号： C08F2/46 , C08J3/28 , C08F2/50
CPC分类号： H05K3/287 , C08K5/5313 , H05K2201/012 , C08L63/10
摘要： The invention relates to a flame-retardant resin formulation comprising respectively at least one flame-retardant component, one alkali-soluble component, one polymerizable monomer, one photoinitiator, and one epoxy component, which comprises, as flame-retardant component, a phosphinic salt of the formula (I), in which R1 and R2 are identical or different and, independently of one another, are C1-C6-alkyl, linear or branched, and/or aryl; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base, and m is from 1 to 4. This novel flame-retardant resin formulation is preferably used as solder resist.
摘要翻译：本发明涉及一种阻燃树脂配方，其包含至少一种阻燃组分，一种碱溶性组分，一种可聚合单体，一种光引发剂和一种环氧组分，其包含作为阻燃组分的次膦酸盐其中R 1和R 2各自相同或不同，并且彼此独立地为C 1〜 C 6 -C 6烷基，直链或支链和/或芳基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化的氮碱，m是1〜该新型阻燃树脂配方优选用作阻焊剂。

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