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    • 72. 发明授权
    • Thiazole containing coumarin compounds
    • 噻唑含香豆素化合物
    • US4404389A
    • 1983-09-13
    • US403118
    • 1982-07-29
    • Christos VamvakarisManfred PatschWolfgang Mach
    • Christos VamvakarisManfred PatschWolfgang Mach
    • C09B57/02D06P1/90D06P3/60D06P5/28C07D417/04
    • D06P1/908C09B57/02D06P3/6041D06P5/006
    • Compounds of the general formula I ##STR1## where B.sup.2 and B.sup.2 independently of one another are hydrogen, C.sub.1 -C.sub.6 -alkyl which may or may not be interrupted by oxygen or sulfur and is unsubstituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylmercapto, cyano, phenylmercapto (which is unsubstituted by chorine or methyl), unsubstituted or substituted carbamoyl or a carboxylic acid ester group, benzyl or phenylethyl which are unsubstituted or substituted in the ring by chlorine, bromine, methyl, ethyl, methoxy or ethoxy, phenyl which is unsubstituted or substituted by chlorine, bromine, hydroxyl, methoxy, ethoxy, methyl, C.sub.1 -C.sub.4 -alkylmercapto, C.sub.1 -C.sub.4 -alkanoylamino or amino, unsubstituted or substituted carbamoyl or a carboxylic acid ester group,B.sup.2 may in addition be cyano, C.sub.2 -C.sub.4 -alkanoyl, benzoyl which is unsubstituted or substituted by chlorine, methyl, methoxy or ethoxy, C.sub.1 -C.sub.6 -alkylsulfonyl, or phenylsulfonyl, which is unsubstituted or substituted by chlorine, bromine, methyl, methoxy, ethoxy, amino, C.sub.1 -C.sub.4 -alkanoylamino, C.sub.1 -C.sub.4 -alkylsulfonyl or benzoylamino,B.sup.1 and B.sup.2 together may also be a saturated 5-membered or 6-membered ring which may or may not contain oxygen or sulfur,X is oxygen or imino andthe ring A may be substituted.Such compounds are outstandingly suitable for dyeing synthetic fibers and plastics.
    • 其中B2和B2彼此独立的通式I的化合物是氢,可被或不被氧或硫中断的未被羟基取代的C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C4 - 烷基巯基,氰基,苯基巯基(未被氯或甲基取代),未取代或取代的氨基甲酰基或羧酸酯基,未被取代或被环取代的氯,溴,甲基,乙基,甲氧基 或乙氧基,未被取代或被氯,溴,羟基,甲氧基,乙氧基,甲基,C1-C4烷基巯基,C1-C4-烷酰基氨基或氨基,未取代或取代的氨基甲酰基或羧酸酯基取代的苯基,B2可以 氰基,C 2 -C 4烷酰基,未被取代或被氯,甲基,甲氧基或乙氧基取代的苯甲酰基,未被取代或被氯,溴,甲基,甲氧基,乙氧基, 氨基, C1-C4-烷酰基氨基,C1-C4-烷基磺酰基或苯甲酰基氨基,B1和B2一起也可以是饱和的5元或6元环,其可以含有或不含氧或硫,X是氧或亚氨基,环A 可以被替代。 这种化合物非常适合于染色合成纤维和塑料。
    • 73. 发明授权
    • Pyrazoline compounds
    • 吡唑啉化合物
    • US4187226A
    • 1980-02-05
    • US898630
    • 1978-04-21
    • Manfred PatschAlbert Hettche
    • Manfred PatschAlbert Hettche
    • C07D231/06C07D231/12D21H21/30C07D401/12
    • C07D231/06C07D231/12D21H21/30
    • Pyrazoline compounds of the formula (I): ##STR1## in which each of B.sup.1 to B.sup.5 is hydrogen or C.sub.1 to C.sub.4 alkyl;R.sup.1 is hydrogen, alkyl or hydroxy;R.sup.2, R.sup.3, R.sup.5, R.sup.6 and R.sup.7 independently of one another are hydrogen, chloro, bromo, fluoro, methyl, ethyl, methoxy or ethoxy;R.sup.4 is hydrogen, alkyl, benzyl, phenylethyl or also phenyl optionally bearing chloro, bromo, methyl, ethyl, methoxy, ethoxy, cyano, dialkylamino or SO.sub.3 H as a substituent;X is --O--, --S--, --NR.sup.8 --, --NR.sup.8 CO--, --NR.sup.8 --SO.sub.2 --, --OSO.sub.3 -- or --SO.sub.3 --;R.sup.8 is hydrogen, alkyl or alkyl bearing hydroxy or C.sub.1 to C.sub.4 alkoxy as a substituent;A is hydrogen, sodium, potassium, unsubstituted or substituted ammonium, unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl; and--NR.sup.8 -- and A together may be an optionally quaternized saturated or unsaturated heterocyclic ring.The compounds are eminently suitable as optical brighteners for example for acrylonitrile polymers, wool and polyamides.
    • 式(I)的吡唑啉化合物:其中B 1至B 5各自为氢或C 1至C 4烷基; R1是氢,烷基或羟基; R 2,R 3,R 5,R 6和R 7彼此独立地是氢,氯,溴,氟,甲基,乙基,甲氧基或乙氧基; R4是氢,烷基,苄基,苯基乙基,或者也可以是含有氯,溴,甲基,乙基,甲氧基,乙氧基,氰基,二烷基氨基或SO3H作为取代基的苯基; X是-O - , - S - , - NR 8 - , - NR 8 CO-, - NR 8 -SO 2 - , - SO 3 - 或-SO 3 - ; R8是氢,烷基或烷基,带有羟基或C1-C4烷氧基作为取代基; A是氢,钠,钾,未取代或取代的铵,未取代或取代的烷基,环烷基,芳烷基或芳基; 并且-NR 8 - 和A一起可以是任选季铵化的饱和或不饱和杂环。 该化合物特别适用于例如丙烯腈聚合物,羊毛和聚酰胺的荧光增白剂。