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71. 发明授权

US4301215A Process for the preparation of impregnated wood 失效
标题翻译：浸渍木材的制备方法
公开(公告)号：US4301215A
公开(公告)日：1981-11-17
申请号：US116125
申请日：1980-01-28
申请人： Bernward Deubzer , Erich Brunner , Herman Wilhelm , Konrad Sallersbeck
发明人： Bernward Deubzer , Erich Brunner , Herman Wilhelm , Konrad Sallersbeck
IPC分类号： B27K3/15 , B32B9/04
CPC分类号： B27K3/15 , C08L97/02 , C08L83/04 , Y10T428/31663
摘要： A process for preparing plastic wood which comprises impregnating wood with a mixture containing (1) an organopolysiloxane having groups which are capable of condensation and/or containing SiC-bonded alkenyl group having an average molecular weight of at least 500 when the organopolysiloxane contains from 0.5 to 1.89 SiC-bonded organic radicals for each silicon atom and when the organopolysiloxane (1) contains from 1.90 to 2 SiC-bonded organic radicals for each silicon atom, then the average molecular weight is at least 20,000 and (2) an organic silicon compound having at least three groups which are capable of condensation and/or atoms capable of condensation and a maximum of 10 silicon atoms per molecule; and other substances if desired; and thereafter crosslinking the organopolysiloxane (1) having groups capable of condensation and/or containing SiC-bonded alkenyl groups, which is present in the wood.
摘要翻译：一种制备塑料木材的方法，其包括用混合物浸渍木材，所述混合物含有（1）具有基团的有机聚硅氧烷，所述有机聚硅氧烷当所述有机基聚硅氧烷含有0.5时，能够缩合和/或含有平均分子量至少为500的碳键合烯基对于每个硅原子为1.89个SiC键合的有机基团，并且当有机聚硅氧烷（1）每个硅原子含有1.90至2个与SiC键合的有机基团时，则平均分子量为至少20,000，（2）有机硅化合物具有至少三个能够缩合的基团和/或能够缩合的原子，每个分子最多具有10个硅原子; 和其他物质; 然后交联存在于木材中的具有能够缩合和/或含有SiC键合的烯基的基团的有机聚硅氧烷（1）。

72. 发明授权

US06182759B2 Process for treating water-containing natural gas wells and natural gas storage wells 失效
标题翻译：含水天然气井和天然气储存井的处理工艺
公开(公告)号：US06182759B2
公开(公告)日：2001-02-06
申请号：US09169543
申请日：1998-10-09
申请人： Willibald Burger , Hans Mayer , Robert Schröck , Holger Wöltje , Bernward Deubzer , Hans Lautenschlager
发明人： Willibald Burger , Hans Mayer , Robert Schröck , Holger Wöltje , Bernward Deubzer , Hans Lautenschlager
IPC分类号： E21B4325
CPC分类号： C09K8/885 , C09K8/5086
摘要： The gas flow in water-containing natural gas wells and natural gas storage wells is improved if a homogeneous phase comprising a water-repellent, solvolysis-resistant active compound is injected into the water-bearing rock.
摘要翻译：如果将包含拒水溶剂分解的活性化合物的均相注入含水岩石，则含水天然气井和天然气储存井中的气体流量得到改善。

73. 发明授权

US6099964A Metal deposits on mesoscopic organopolysiloxane particles 失效
标题翻译：介观有机聚硅氧烷颗粒上的金属沉积物
公开(公告)号：US6099964A
公开(公告)日：2000-08-08
申请号：US17638
申请日：1998-02-02
申请人： Frank Baumann , Bernward Deubzer , Manfred Schmidt
发明人： Frank Baumann , Bernward Deubzer , Manfred Schmidt
IPC分类号： C08G77/22 , C08G77/398 , C08J3/12 , B32B15/02 , B32B17/02 , B32B19/00 , B32B21/02 , B32B23/02
CPC分类号： C08J3/12 , C08G77/22 , C08G77/398 , C08J2383/04 , Y10T428/2982
摘要： Organopolysiloxane particles consist of a single molecule, are crosslinked, and contain metal atoms in the zero valent oxidation state, the metal atoms in each case being in intermetallic interaction with at least one further metal atom in the zero valent oxidation state, have an average diameter of 5 to 200 nm and are soluble to the extent of at least 0.1% by weight in at least one organic solvent chosen from the group consisting of methylene chloride, pentane, acetone, toluene and ethanol, at least 80% of the particles having a diameter which deviates from the average diameter by not more than 30%.
摘要翻译：有机聚硅氧烷颗粒由单一分子组成，交联并含有零价氧化态的金属原子，每种情况下的金属原子与零价氧化态的至少一个其它金属原子在金属间相互作用中具有平均直径在至少一种选自二氯甲烷，戊烷，丙酮，甲苯和乙醇的有机溶剂中可溶于至少0.1重量％的程度，至少80％的颗粒具有直径偏离平均直径不大于30％。

74. 发明授权

US5981659A Precross-linked silicone elastomer particles with organopolymer shell as formulation constituent in powder coating materials 失效
标题翻译：具有有机聚合物壳的预交联硅氧烷弹性体颗粒作为粉末涂料中的配制成分
公开(公告)号：US5981659A
公开(公告)日：1999-11-09
申请号：US29552
申请日：1998-03-06
申请人： Michael Geck , Walter Goeblmeier , Bernward Deubzer , Ekkehard Patrick
发明人： Michael Geck , Walter Goeblmeier , Bernward Deubzer , Ekkehard Patrick
IPC分类号： C08F283/12 , C09D5/03 , C09D5/46 , C09D151/08 , C09J151/08 , C08L83/00
CPC分类号： C08F283/12 , C09D5/037 , Y10S525/902
摘要： The invention relates to the use of precrosslinked silicone elastomer particles with an organopolymer shell as the formulation constituent in powder coating material compositions based on thermoplastic or thermosetting binding agents, the silicone elastomer particles containing (a) 5 to 95% by weight, in relation the total weight of the copolymerisate, of a nucleus polymer of the general formula (R.sub.w SiO.sub.2/2).sub.x.(RSiO.sub.3/2).sub.y.(SiO.sub.4/2).sub.z with x=5 to 99.5 mol %, y=0.5 to 95 mol %, z=0 to 30 mol %, and (b) 5 to 95% by weight, in relation to the total weight of the copolymer, of a shell made of an organopolymer of ethylenically mono or multi-unsaturated monomers, R standing for identical or different monovalent C.sub.1 -C.sub.6 alkyl or alkenyl residues or substituted hydrocarbon residues.
摘要翻译： PCT No.PCT / EP96 / 04208 Sec。 371日期1998年3月6日 102（e）1998年3月6日PCT PCT 1996年9月26日PCT公布。公开号WO97 / 12005 日期1997年4月3日本发明涉及在基于热塑性或热固性粘合剂的粉末涂料组合物中使用具有有机聚合物壳的预交联的有机硅弹性体颗粒作为配制成分，所述硅氧烷弹性体颗粒含有（a）5至95％重量，相对于共聚物的总重量，具有通式（RwSiO 2/2）x。（RSiO 3/2）y。（SiO 4/2）z的x = 5至99.5mol％的核聚合物，y = 0.5至95摩尔％，z = 0至30摩尔％，和（b）相对于共聚物的总重量为5至95重量％的由烯键式单或多不饱和单体的有机聚合物制成的壳 R代表相同或不同的一价C1-C6烷基或烯基残基或取代的烃残基。

75. 发明授权

US5621057A Alkenyl ether-siloxane compositions which can be crosslinked by free radicals 失效
标题翻译：可以通过自由基交联的烯基醚 - 硅氧烷组合物
公开(公告)号：US5621057A
公开(公告)日：1997-04-15
申请号：US455489
申请日：1995-05-31
申请人： Christian Herzig , Bernward Deubzer , Martina Bloechl , David Huettner , Walter Magee
发明人： Christian Herzig , Bernward Deubzer , Martina Bloechl , David Huettner , Walter Magee
IPC分类号： C08F283/12 , C08F290/00 , C08L83/04 , C08L83/07 , C09D4/00 , C08F26/00
CPC分类号： C08F283/124
摘要： Alkenyl ether-siloxane compositions comprising(A) an oligomeric or polymeric organosilicon compound having on average more than one alkenyloxy group of the formulaR.sup.2 --CH.dbd.CH--O-- (VI)(B) a monomeric maleic and/or fumaric acid compound of the formula ##STR1## in which R.sup.2 is a hydrogen atom or the methyl radical,R.sup.3 is identical or different and is a hydrogen atom, a hydrocarbon radical having 1 to 16 carbon atoms, which can be interrupted by oxygen, sulfur or oxygen- or silicon-containing units, a substituted hydrocarbon radical having 1 to 6 carbon atoms, a silyl radical or a siloxanyl radical,R.sup.4 is identical or different and is a hydrogen atom, chlorine, bromine, fluorine or an optionally substituted alkyl radical andZ is an oxygen atom or a radical --NR.sup.5 --, where R.sup.5 has one of the meanings given for R.sup.3,optionally(C) initiators which form free radicals and optionally(D) inhibitors for regulating the pot life.
摘要翻译：烯基醚 - 硅氧烷组合物，其包含（A）具有平均多于一个式R 2 -CH = CH-O-（VI）的烯氧基的低聚或聚合有机硅化合物（B）（B）单体马来酸和/或富马酸化合物该式为氢原子或甲基，R3相同或不同，为氢原子，可被氧，硫或含氧或含硅单元中断的碳原子数为1〜16的烃基，具有1至6个碳原子的取代烃基，甲硅烷基或硅氧烷基，R4相同或不同，为氢原子，氯，溴，氟或任选取代的烷基，Z为氧原子或基团 - NR5-，其中R5具有R3给出的含义之一，任选的（C）引发剂，其形成自由基和任选的（D）抑制剂以调节适用期。

76. 发明授权

US5162452A Thermocurable compositions 失效
标题翻译：耐热组合物
公开(公告)号：US5162452A
公开(公告)日：1992-11-10
申请号：US530388
申请日：1990-05-30
申请人： Christian Herzig , Bernward Deubzer , Josef Esterbauer
发明人： Christian Herzig , Bernward Deubzer , Josef Esterbauer
IPC分类号： C08K5/10 , C08K5/17 , C08L83/04 , C08L83/08 , C08L101/00 , C08L101/06 , C09D183/04 , C09D183/08
CPC分类号： C09D183/08 , C08L83/08
摘要： The Thermocurable compositions which contain(A) at least one mercaptoalkyl-containing compound which contains at least two SiC-bonded radicals per molecule of the general formulaHS--R.sup.2 -- (I) where R.sup.2 represents a divalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical, selected from the group consisting mercaptoalkyl-containing organopolysiloxanes and cocondensates of mercaptoalkyl-containing organosilicon compounds containing groups capable of condensation, and hydroxyl-containing organic compounds,(B) at least one vinyl-containing compound which is compatible with constituent (A) and contains at least two groups per molecule of the general formulaR.sup.4 CH.dbd.CR.sup.3 C(O)O-- (II) where R.sup.3 represents a hydrogen atom or a methyl radical, and R.sup.4 represents a hydrogen atom or an alkyl radical having from 1 to 3 carbon atom(s) per radical, and(C) a mixture of a strong organic base selected from the group consisting of quaternary ammonium hydroxides, quaternary ammonium alkoxides, tertiary, secondary and primary amines, and a weak protonic acid.
摘要翻译：含有（A）至少一种含巯基烷基的化合物的热固性组合物，其每分子具有通式HS-R2-（I）中至少两个SiC键合的基团，其中R2表示具有1至8个碳原子的二价烃基每个基团的原子选自含巯基烷基的有机聚硅氧烷和含有缩合基团的含巯基烷基的有机硅化合物的缩聚物和含羟基的有机化合物，（B）至少一种含乙烯基的化合物，其相容与组分（A）组成，每分子含有至少两个通式为R 4 CH = CR 3 C（O）O-（II）的基团，其中R 3表示氢原子或甲基，R 4表示氢原子或具有每个基团具有1至3个碳原子，和（C）选自下列的强有机碱的混合物：季铵氢氧化物，季铵醇盐，te 仲胺和伯胺，以及弱质子酸。

77. 发明授权

US4661551A Transparent aqueous organopolysiloxane compositions 失效
标题翻译：透明的有机聚硅氧烷组合物
公开(公告)号：US4661551A
公开(公告)日：1987-04-28
申请号：US787841
申请日：1985-10-16
申请人： Hans Mayer , Bernward Deubzer , Petra Iretzberger , Rudolf Muhlhofer , Hermann Wilhelm
发明人： Hans Mayer , Bernward Deubzer , Petra Iretzberger , Rudolf Muhlhofer , Hermann Wilhelm
IPC分类号： C08G77/00 , C04B24/42 , C04B41/49 , C04B41/64 , C08G77/12 , C08G77/26 , C08G77/28 , C08G77/38 , C08K5/544 , C08L83/00 , C08L83/04 , C08L83/08 , C09D7/12 , C09K3/18 , D21H19/10 , D21H19/32 , C08K5/05
CPC分类号： C04B41/009 , C04B24/42 , C04B41/4905 , C04B41/4961 , C04B41/64 , C08G77/12 , C08G77/26 , C08K5/544 , C08L83/08
摘要： Transparent aqueous organopolysiloxane compositions comprising (A) a salt of a water-soluble organic or inorganic acid and a polysiloxane, which contains in addition to the other siloxane units siloxane units containing SiC-bonded monovalent radicals having basic nitrogen atoms in an amount of at least 0.5 percent by weight, based on the weight of the polysiloxane; and (B) an organic silicon compound having basic nitrogen atoms in an amount of from 0 to 0.5 percent by weight, based on the weight of the organic silicon compound; and when constituent (B) does not contain at least one organic silicon compound having a molecular weight greater than 600 g/mol in an amount of at least 0.1 part per part by weight of contituent (A), then an organic solvent (C) is present in an amount up to about 5 percent by weight based on the weight of constituent (A), in which the organic solvent is soluble in water up to about 1 part by weight per 100 parts by weight of water at 20.degree. C. and 1020 hPa (abs.) and is free of halogen atoms.The organopolysiloxanes may contain Si-bonded hydrogen as well as at least one SiC-bonded radical having a basic nitrogen atom in one and the same molecule.
摘要翻译：透明含水有机基聚硅氧烷组合物，其包含（A）水溶性有机酸或无机酸的盐和聚硅氧烷，其除了含有其它硅氧烷单元的硅氧烷单元外，所述硅氧烷单元含有至少具有碱性氮原子的具有至少 0.5重量％，基于聚硅氧烷的重量; 和（B）基于有机硅化合物的重量，碱性氮原子的量为0至0.5重量％的有机硅化合物; 当组分（B）不含有至少一种分子量大于600g / mol的至少一种有机硅化合物，其量为每份重量的（A）成分为至少0.1份时，则有机溶剂（C）基于组分（A）的重量，其含量高达约5重量％，其中有机溶剂在水中可溶于高达约1重量份/ 100重量份的20℃的水。和1020hPa（绝对），并且不含卤素原子。有机聚硅氧烷可以含有与Si键合的氢，以及至少一个在一个和相同分子中具有碱性氮原子的与SiC键合的基团。

78. 发明授权

US4368294A Process for preparing organopolysiloxane modified organic polymers 失效
标题翻译：制备有机聚硅氧烷改性有机聚合物的方法
公开(公告)号：US4368294A
公开(公告)日：1983-01-11
申请号：US239226
申请日：1981-02-27
申请人： Bernward Deubzer , Josef Esterbauer , Christian Solbrig , Volker Frey
发明人： Bernward Deubzer , Josef Esterbauer , Christian Solbrig , Volker Frey
IPC分类号： C08G77/00 , C08G63/695 , C08G63/91 , C08G77/42 , C08G81/00 , C08L67/00 , C08L83/06
CPC分类号： C08G77/42 , C08G63/6954 , C08G63/914 , C08L67/00
摘要： Organopolysiloxane modified organic polymers are prepared by reacting organic polymers containing C-bonded hydroxyl groups with organopolysiloxanes containing Si-bonded hydroxyl groups and/or alkyl groups which are bonded to silicon via oxygen in the presence of water in excess of any formed during the reaction.
摘要翻译：有机聚硅氧烷改性的有机聚合物通过使含C-键羟基的有机聚合物与含有Si键合的羟基和/或烷基的有机聚硅氧烷通过氧在超过反应中形成的任何水的存在下通过氧键与硅键合而制备。

79. 发明授权

US4322473A Organosiloxanes with SiC-bonded groups and a process for preparing the same 失效
标题翻译：具有SiC键合基团的有机硅氧烷及其制备方法
公开(公告)号：US4322473A
公开(公告)日：1982-03-30
申请号：US68114
申请日：1979-08-20
申请人： Walter Hafner , Erich Markl , Ludwig Eibel , Gerhard Kreis , Dietrich Samrowski , Manfred Wick , Bernward Deubzer , Wilhelm Friedrich
发明人： Walter Hafner , Erich Markl , Ludwig Eibel , Gerhard Kreis , Dietrich Samrowski , Manfred Wick , Bernward Deubzer , Wilhelm Friedrich
IPC分类号： C07F7/08 , C08G77/04 , C08G77/14 , C08G77/38 , C10M105/76 , C10M107/50 , C10N40/08 , D02G3/00
CPC分类号： C08G77/38 , C08G77/045 , C08G77/14 , C10M107/50 , C10M2201/102 , C10M2201/103 , C10M2201/105 , C10M2203/006 , C10M2207/106 , C10M2207/1206 , C10M2207/125 , C10M2207/129 , C10M2207/1406 , C10M2207/2613 , C10M2207/2626 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2211/06 , C10M2213/02 , C10M2213/062 , C10M2215/227 , C10M2217/044 , C10M2217/045 , C10M2227/006 , C10M2229/025 , C10M2229/0405 , C10M2229/0415 , C10M2229/0425 , C10M2229/0435 , C10M2229/0445 , C10M2229/045 , C10M2229/0455 , C10M2229/046 , C10M2229/0465 , C10M2229/047 , C10M2229/0475 , C10M2229/048 , C10M2229/0485 , C10M2229/0505 , C10M2229/051 , C10M2229/0515 , C10M2229/0525 , C10M2229/0535 , C10M2229/0545 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2240/08 , C10N2240/40 , C10N2240/62 , Y10T428/2962 , Y10T428/2964 , Y10T428/2965 , Y10T428/2967 , Y10T428/2969
摘要： This invention relates to organosiloxanes which have SiC-bonded ester groups and contain at least one unit of the general formula: ##EQU1## in which R represents the same or different monovalent hydrocarbon radicals having from 1 to 12 carbon atoms, which are free of aliphatic unsaturation and which may contain one ether oxygen atom; R' represents hydrogen or a methyl group (CH.sub.3) and a is 0, 1 or 2. These organosiloxanes can be prepared by hydrolyzing or co-hydrolyzing silanes of the general formula:ROOCCH.sub.2 CH(COOR)CH.sub.2 CHR'CH.sub.2 Si(CH.sub.3).sub.a X.sub.3-a,where R, R' and a are the same as above and X represents the same or different hydrolyzable atoms or groups. Also, they may be prepared by the addition of a diester of allyl succinic acid and/or methallyl succinic acid to an organosiloxane containing Si-bonded hydrogen. These new organosiloxanes may be used as lubricants for inorganic and organic fibers, metal surfaces and as hydraulic fluids.
摘要翻译：本发明涉及具有SiC键合的酯基并含有至少一个下列通式的单元的有机硅氧烷：其中R代表具有1至12个碳原子的相同或不同的一价烃基，其不含脂族并且可以含有一个醚氧原子; R'表示氢或甲基（CH 3），a是0,1或2.这些有机硅氧烷可以通过水解或共水解通式如下的硅烷来制备：ROOCCH2CH（COOR）CH2CHR'CH2Si（CH3）aX3-a 其中R，R'和a与上述相同，X表示相同或不同的可水解原子或基团。此外，它们可以通过将烯丙基琥珀酸和/或甲代烯丙基琥珀酸的二酯加入到含有Si键合氢的有机硅氧烷中来制备。这些新的有机硅氧烷可用作无机和有机纤维，金属表面和液压油的润滑剂。

80. 发明授权

US4207246A Organosiloxanes with SiC-bonded groups and a process for preparing the same 失效
标题翻译：具有SiC键合基团的有机硅氧烷及其制备方法
公开(公告)号：US4207246A
公开(公告)日：1980-06-10
申请号：US15551
申请日：1979-02-26
申请人： Walter Hafner , Erich Markl , Ludwig Eibel , Gerhard Kreis , Dietrich Samrowski , Manfred Wick , Bernward Deubzer , Wilhelm Friedrich
发明人： Walter Hafner , Erich Markl , Ludwig Eibel , Gerhard Kreis , Dietrich Samrowski , Manfred Wick , Bernward Deubzer , Wilhelm Friedrich
IPC分类号： C07F7/08 , C08G77/04 , C08G77/14 , C08G77/38 , C10M105/76 , C10M107/50 , C10N40/08
CPC分类号： C08G77/38 , C08G77/045 , C08G77/14 , C10M107/50 , C10M2201/102 , C10M2201/103 , C10M2201/105 , C10M2203/006 , C10M2207/106 , C10M2207/1206 , C10M2207/125 , C10M2207/129 , C10M2207/1406 , C10M2207/2613 , C10M2207/2626 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2211/06 , C10M2213/02 , C10M2213/062 , C10M2215/227 , C10M2217/044 , C10M2217/045 , C10M2227/006 , C10M2229/025 , C10M2229/0405 , C10M2229/0415 , C10M2229/0425 , C10M2229/0435 , C10M2229/0445 , C10M2229/045 , C10M2229/0455 , C10M2229/046 , C10M2229/0465 , C10M2229/047 , C10M2229/0475 , C10M2229/048 , C10M2229/0485 , C10M2229/0505 , C10M2229/051 , C10M2229/0515 , C10M2229/0525 , C10M2229/0535 , C10M2229/0545 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2240/08 , C10N2240/40 , C10N2240/62 , Y10T428/2962 , Y10T428/2964 , Y10T428/2965 , Y10T428/2967 , Y10T428/2969
摘要： This invention relates to organosiloxanes which have SiC-bonded ester groups and contain at least one unit of the general formula:ROOCCH.sub.2 CH(COOR)CH.sub.2 CHR'CH.sub.2 Si(CH.sub.3).sub.a O.sub.3-a/2in which R represents the same or different monovalent hydrocarbon radicals having from 1 to 12 carbon atoms, which are free of aliphatic unsaturation and which may contain one ether oxygen atom; R' represents hydrogen or a methyl group (CH.sub.3) and a is 0, 1 or 2. These organosiloxanes can be prepared by hydrolyzing or co-hydrolyzing silanes of the general formula:ROOCCH.sub.2 CH(COOR)CH.sub.2 CHR'CH.sub.2 Si(CH.sub.3).sub.a X.sub.3-a,where R, R' and a are the same as above and X represents the same or different hydrolyzable atoms or groups. Also, they may be prepared by the addition of a diester of allyl succinic acid and/or methallyl succinic acid to an organosiloxane containing Si-bonded hydrogen. These new organosiloxanes may be used as lubricants for inorganic and organic fibers, metal surfaces and as hydraulic fluids.
摘要翻译：本发明涉及具有SiC键合的酯基并且含有至少一个通式为：ROOCCH 2 CH（COOR）CH 2 CHR'CH 2 Si（CH 3）a O 3-a / 2的单元的有机硅氧烷，其中R表示相同或不同的具有 1至12个碳原子，其不含脂族不饱和基团并且可以含有一个醚氧原子; R'表示氢或甲基（CH 3），a是0,1或2.这些有机硅氧烷可以通过水解或共水解通式如下的硅烷来制备：ROOCCH2CH（COOR）CH2CHR'CH2Si（CH3）aX3-a 其中R，R'和a与上述相同，X表示相同或不同的可水解原子或基团。此外，它们可以通过将烯丙基琥珀酸和/或甲代烯丙基琥珀酸的二酯加入到含有Si键合氢的有机硅氧烷中来制备。这些新的有机硅氧烷可用作无机和有机纤维，金属表面和液压油的润滑剂。

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