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1. 发明授权

US09873978B2 Hybrid-type polyester resin, resin composition for formation of film, and polyester film and textile 有权
公开(公告)号：US09873978B2
公开(公告)日：2018-01-23
申请号：US13505277
申请日：2010-10-28
申请人： Koji Maeda , Yusuke Numamoto
发明人： Koji Maeda , Yusuke Numamoto
IPC分类号： C08G63/91 , D06M15/507 , C08G63/695 , C09D5/18 , C08G77/04
CPC分类号： D06M15/507 , C08G63/6954 , C08G63/914 , C08G77/04 , C09D5/18 , D06M2200/30
摘要： Provided is a hybrid-type polyester resin which, when used in processing a base material such as textile or PET film, can impart excellent flame retardance to the base material. The hybrid-type polyester resin can be inhibited from scattering high-temperature drips, even if the hybrid-type polyester resin burns. The hybrid-type polyester resin comprises both a polyester resin and a siloxane prepared from silica and an alkoxysilane. Therefore, the hybrid-type polyester resin retains the excellent properties inherent in polyester resin and exhibits extremely excellent flame retardance by virtue of hybridization with the siloxane. Even if the hybrid-type polyester resin burns, the hybrid-type polyester resin is less susceptible to deformation, and is therefore inhibited from scattering high-temperature drips.

2. 发明授权

US08674049B1 Silicone containing aromatic film forming polymers 失效
标题翻译：含有硅酮的芳香族成膜聚合物
公开(公告)号：US08674049B1
公开(公告)日：2014-03-18
申请号：US13507580
申请日：2012-07-12
申请人： Thomas G. O'Lenick
发明人： Thomas G. O'Lenick
IPC分类号： C08G77/04
CPC分类号： A61K8/892 , A61Q3/02 , C08G63/6954 , C08G77/445
摘要： The present invention is directed to polymers that are useful in nail polish applications. The specific film forming polyester polymers that are liquids in solvents like butyl acetate, form a uniform film upon application when in a solvent (most commonly butyl acetate), evaporates under atmospheric conditions and at the same time can be removed easily and thoroughly by application of a solvent like acetone. The polymers of the present invention having a silicone portion contained therein provide improved flexibility, tear resistance and superior aesthetics.
摘要翻译：本发明涉及可用于指甲油应用的聚合物。在溶剂（最常见的是乙酸丁酯）中在溶剂（最常见的是乙酸丁酯）中，在溶剂如乙酸丁酯中溶解时形成均匀的膜的特定成膜聚酯聚合物在大气条件下蒸发，同时可以通过应用溶剂如丙酮。本发明的含有硅氧烷部分的聚合物提供了改进的柔韧性，抗撕裂性和优异的美观性。

3. 发明授权

US08623969B2 Terminal silicone capped regiospecific glycerin polyesters 有权
标题翻译：端子硅胶封端区域特异性甘油聚酯
公开(公告)号：US08623969B2
公开(公告)日：2014-01-07
申请号：US13815935
申请日：2013-03-18
申请人： Thomas George O'Lenick
发明人： Thomas George O'Lenick
IPC分类号： C08G63/02 , C08G77/14 , C08G63/12 , C08G77/04 , C08G77/00 , C08G63/91 , C08G63/695
CPC分类号： A61K8/85 , A61Q5/12 , A61Q19/00 , A61Q19/007 , C07F7/0838 , C08G63/12 , C08G63/52 , C08G63/6954 , C08G63/6958
摘要： The present invention is directed to a series of glycerin based polymers that have been designed to have very specific substitution patterns, herein referred to as regiospecific substitution (RSS). The attachment of terminal mono-functional silicone polymers engineered polyesters of glycerin results in heretofore unrecognized products. The unique properties include lower surface tension, better spreadability and a dry skin feel, all of which cannot be attained without the use of a terminal silicone. Incorporation of silicone into the terminal position requires a very specific synthesis regime to establish the sought after regiospecificity.
摘要翻译：本发明涉及一系列甘油基聚合物，其被设计为具有非常特定的取代模式，在本文中称为区域特异性取代（RSS）。末端单官能硅氧烷聚合物工程聚甘油的附着导致迄今未被认识的产品。独特的性质包括较低的表面张力，更好的铺展性和干燥的皮肤感觉，所有这些都不能在不使用终端硅酮的情况下实现。将硅胶结合到终端位置需要非常具体的合成方式来建立追求的区域特异性。

4. 发明授权

US07396893B2 Solid siliconized polyester resin for powder coating 失效
标题翻译：固体硅化聚酯树脂粉末涂料
公开(公告)号：US07396893B2
公开(公告)日：2008-07-08
申请号：US11534752
申请日：2006-09-25
申请人： James D. Greene , Mohammed Khalid Yousuf
发明人： James D. Greene , Mohammed Khalid Yousuf
IPC分类号： C08G77/12
CPC分类号： C08G77/445 , C08G63/6954 , C08G63/914 , C08K3/011 , C08K5/0025 , C09D183/10 , Y10S525/934 , Y10T428/31663
摘要： The present invention pertains to a siliconized polyester resin that has a sufficiently high Tg that the siliconized polyester is a solid at room temperature. The silicone polyester preferably has a Tg of 30° C. or greater. The silicone polyester can be produced as a particulate and remain stable at room temperature. The particulate silicone polyester is suitable for use in coating compositions, including powder coating compositions. The coating can be clear or pigmented, and thus optionally can include pigment. The coating composition also includes a crosslinker. The coating composition can be ground into a powder. The powder is stable at room temperature. The powder is then capable of being coated on a suitable substrate and then baked to form a coated metal object.
摘要翻译：本发明涉及具有足够高Tg的硅化聚酯树脂，其中硅化聚酯在室温下为固体。硅氧烷聚酯的Tg优选为30℃以上。硅氧烷聚酯可以作为颗粒生产并在室温下保持稳定。颗粒状硅氧烷聚酯适用于涂料组合物，包括粉末涂料组合物。涂层可以是透明的或着色的，因此任选地可以包括颜料。涂料组合物还包括交联剂。涂料组合物可以研磨成粉末。粉末在室温下稳定。然后将粉末涂覆在合适的基材上，然后烘焙以形成涂覆的金属物体。

5. 发明授权

US07129310B2 Solid siliconized polyester resins for powder coatings 失效
标题翻译：用于粉末涂料的固体硅化聚酯树脂
公开(公告)号：US07129310B2
公开(公告)日：2006-10-31
申请号：US10745181
申请日：2003-12-23
申请人： James A. Greene , Mohammed Khalid Yousuf
发明人： James A. Greene , Mohammed Khalid Yousuf
IPC分类号： C08G77/14
CPC分类号： C08G77/445 , C08G63/6954 , C08G63/914 , C08K3/011 , C08K5/0025 , C09D183/10 , Y10S525/934 , Y10T428/31663
摘要： The present invention pertains to a siliconized polyester resin that has a sufficiently high Tg that the siliconized polyester is a solid at room temperature. The silicone polyester preferably has a Tg of 30° C. or greater. The silicone polyester can be produced as a particulate and remain stable at room temperature. The particulate silicone polyester is suitable for use in coating compositions, including powder coating compositions. The coating can be clear or pigmented, and thus optionally can include pigment. The coating composition also includes a crosslinker. The coating composition can be ground into a powder. The powder is stable at room temperature. The powder is then capable of being coated on a suitable substrate and then baked to form a coated metal object.
摘要翻译：本发明涉及具有足够高Tg的硅化聚酯树脂，其中硅化聚酯在室温下为固体。硅氧烷聚酯的Tg优选为30℃以上。硅氧烷聚酯可以作为颗粒生产并在室温下保持稳定。颗粒状硅氧烷聚酯适用于涂料组合物，包括粉末涂料组合物。涂层可以是透明的或着色的，因此任选地可以包括颜料。涂料组合物还包括交联剂。涂料组合物可以研磨成粉末。粉末在室温下稳定。然后将粉末涂覆在合适的基材上，然后烘焙以形成涂覆的金属物体。

6. 发明申请

US20060084726A1 Cathodic electrocoating compositions containing an anti-crater agent 有权
标题翻译：含有抗火山口剂的阴极电涂组合物
公开(公告)号：US20060084726A1
公开(公告)日：2006-04-20
申请号：US10967491
申请日：2004-10-18
申请人： Allisa Gam , Thomas Grawe , Joachim Ruerup , Andreas Fieberg
发明人： Allisa Gam , Thomas Grawe , Joachim Ruerup , Andreas Fieberg
IPC分类号： C08L63/00 , B32B27/38
CPC分类号： C08G18/44 , C08G18/0823 , C08G18/581 , C08G18/8064 , C08G63/42 , C08G63/64 , C08G63/6854 , C08G63/6954 , C09D5/4492 , C09D175/04
摘要： An improved aqueous cathodic electrocoating composition that contains an anti-crater agent which is a water-reducible polyester resin having an acid value less than 40 mg KOH/g. The water-reducible polyester is the reaction product of (1) a hydroxy cyclic carbonate; (2) a polycarboxylic acid anhydride; (3) optional monofunctional epoxy resin; (4) a polyfunctional epoxy resin; and, (5) a polyamine compound containing tertiary amine and either primary or secondary functionality. The reaction product is neutralized in the presence of acid and water to convert the tertiary amine groups to water-dilutable groups. Hydrolyzable silane groups can also be incorporated into the reaction product to further enhance its crater resistance property. The electrocoat composition produces coatings having a smoother appearance with fewer craters without adversely affecting intercoat adhesion of the cured film to subsequent coating layers applied thereover.
摘要翻译：一种改进的含水阴极电泳涂料组合物，其含有抗发泡剂，其是酸值小于40mg KOH / g的水可稀释聚酯树脂。水可稀释聚酯是（1）羟基环状碳酸酯的反应产物; （2）聚羧酸酐; （3）可选单官能环氧树脂; （4）多官能环氧树脂; 和（5）含有叔胺的聚胺化合物和主要或次要官能团。将反应产物在酸和水的存在下中和以将叔胺基团转化为水可稀释基团。可水解的硅烷基也可以加入到反应产物中以进一步提高其耐火山口性。电泳涂料组合物产生具有更平滑外观的涂层，具有更少的孔口，而不会不利地影响固化膜的涂层附着力到施加到其上的后续涂层。

7. 发明授权

US5457166A Process for preparing a polyester-modified silicone resin and a curable composition comprising the polyester-modified silicone resin 失效
标题翻译：制备聚酯改性有机硅树脂的方法和包含聚酯改性的有机硅树脂的可固化组合物
公开(公告)号：US5457166A
公开(公告)日：1995-10-10
申请号：US278193
申请日：1994-07-21
申请人： Yuji Yoshikawa , Tadashi Takahashi , Mitsuhiro Takarada
发明人： Yuji Yoshikawa , Tadashi Takahashi , Mitsuhiro Takarada
IPC分类号： C08G63/695 , C08G77/445 , C09D183/10 , C08F20/00
CPC分类号： C09D183/10 , C08G63/6954 , C08G77/445
摘要： A process for preparing a polyester-modified silicone resin comprises mixing an alkoxysilane and/or its hydrolyzate, i.e. an alkoxysiloxane, and a polyester resin having at least two hydroxyl groups in the molecule, and subjecting the mixture to hydrolysis and polycondensation reactions in the presence of an acid catalyst. This process is performed by a continuous one-stage reaction sequence including hydrolysis, polycondensation and modification and is simplified. A composition comprising the polyester-modified silicone resin is also described. The composition comprising organozinc compounds along with the modified silicone resin is significantly improved in heat resistance and color-difference.
摘要翻译：制备聚酯改性有机硅树脂的方法包括在分子中混合烷氧基硅烷和/或其水解产物，即烷氧基硅氧烷和具有至少两个羟基的聚酯树脂，并在该存在下使混合物进行水解和缩聚反应的酸催化剂。该方法通过包括水解，缩聚和改性的连续一步反应顺序进行，并被简化。还描述了包含聚酯改性的有机硅树脂的组合物。包含有机锌化合物以及改性有机硅树脂的组合物的耐热性和色差显着提高。

8. 发明授权

US5417867A Fiber treatment agent 失效
标题翻译：纤维处理剂
公开(公告)号：US5417867A
公开(公告)日：1995-05-23
申请号：US131166
申请日：1993-10-04
申请人： Ryuzo Mikami , Isao Ona
发明人： Ryuzo Mikami , Isao Ona
IPC分类号： C08G63/91 , C08G63/695 , C08G77/445 , C08G81/00 , C08K5/00 , C08L67/00 , C08L67/02 , D06M15/507 , D06M15/643 , D06M15/647 , D06M14/00 , C08G77/04 , C08G77/12
CPC分类号： D06M15/507 , C08G63/6954 , C08G77/445 , C08G81/00 , D06M15/6436 , D06M15/647
摘要： A fiber treating agent which is a silicone modified polyester in which a polyester has a polyoganosiloxane grafted thereto. The grafted polyester is the reaction product of an allyl ether containing polyester and a polyorganosiloxane wherein at least one of the silicon atoms of the polyorganosiloxane has a hydrogen atom attached thereto. Preferably, the hydrogen atom is attached to one terminal end of the polyorganosiloxane. The reaction product is modified by reacting the reaction product with a polycarboxylic anhydride, and the amine salt of the modified reaction product may be formed by reacting the modified reaction product with an aminoalkylalkoxysilane. Methods of treating fibrous materials are also described.
摘要翻译：一种纤维处理剂，其是其中聚酯具有接枝到其上的聚羟基硅氧烷的硅氧烷改性聚酯。接枝聚酯是含烯丙基醚的聚酯与聚有机硅氧烷的反应产物，其中聚有机硅氧烷的至少一个硅原子具有附着氢原子。优选地，氢原子连接到聚有机硅氧烷的一个末端。反应产物通过使反应产物与多元羧酸酐反应而改性，改性反应产物的胺盐可以通过使改性反应产物与氨基烷基烷氧基硅烷反应形成。还描述了处理纤维材料的方法。

9. 发明授权

US5082916A Organopolysiloxane graft polyester and its manufacturing method 失效
标题翻译：有机硅氧烷聚酰胺及其制造方法
公开(公告)号：US5082916A
公开(公告)日：1992-01-21
申请号：US522753
申请日：1990-05-11
申请人： Ryuzo Mikami , Makoto Yoshitake , Tadashi Okawa
发明人： Ryuzo Mikami , Makoto Yoshitake , Tadashi Okawa
IPC分类号： C08G63/68 , C08G63/695 , C08G63/91 , C08G77/42 , C08G77/445 , C08G81/00
CPC分类号： C08G63/6954 , C08G77/445
摘要： An organopolysiloxane graft-type polyester is prepared by reacting, in the presence of an effective amount of a hydrosilylation catalyst, a polyester containing at least one alkenyl group and having no unsaturated terminal groups, said polyester having a number average molecular weight of about 500 to about 5,000, and an organopolysiloxane containing one hydrosilyl group. The organopolysiloxane graft-type polyester has excellent compatibility with polyesters and can improve the surface smoothness and hydrophobic property of the polyester when modified therewith.

10. 发明授权

US4310640A Curable composition 失效
标题翻译：可固化组合物
公开(公告)号：US4310640A
公开(公告)日：1982-01-12
申请号：US150638
申请日：1980-05-16
申请人： Yasushi Kato , Hisao Furukawa , Shoichi Matsumura , Saori Nakatsuka
发明人： Yasushi Kato , Hisao Furukawa , Shoichi Matsumura , Saori Nakatsuka
IPC分类号： C08K5/00 , C08F8/00 , C08F8/42 , C08G63/00 , C08G63/68 , C08G63/695 , C08G63/91 , C08K3/22 , C08K5/17 , C08K5/54 , C08L33/00 , C08L33/02 , C08L43/04 , C08L67/00 , C08L77/00 , C08L101/00 , C08L101/02 , C08L101/10 , C09D167/00 , C09D183/04 , C09D201/00 , C09D201/02 , C09J167/00 , C09K3/10 , C08C19/00
CPC分类号： C08L101/02 , C08F8/00 , C08F8/42 , C08G63/695 , C08G63/6954 , C08G63/91 , C08K3/20 , C08K3/22 , C08K5/17 , C08K5/54 , C08L43/04 , C09D167/00 , C09K3/10
摘要： A composition comprising (a) an organic compound having at least one hydrolyzable silyl group and (b) an organic amine and/or an alkali metal hydroxide. The composition is curable upon exposure to moisture, and has superior properties, such as hardness, toughness and stain resistance, when used for example as a coating. The composition can be utilized as a coating material.
摘要翻译：一种组合物，其包含（a）具有至少一个可水解甲硅烷基的有机化合物和（b）有机胺和/或碱金属氢氧化物。该组合物在暴露于水分时可固化，并且当用作例如涂层时具有优异的性能，例如硬度，韧性和耐污渍性。组合物可以用作涂料。

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