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    • 64. 发明授权
    • Curable composition
    • 可固化组合物
    • US5376720A
    • 1994-12-27
    • US158212
    • 1993-11-29
    • Naotami Ando
    • Naotami Ando
    • C08F299/00C08F275/00C08F290/00C08F290/06C08G81/02C08L43/00C08L43/04C08L51/00C08L55/00C08L101/10C09D143/04C09D155/00C09D201/10C08L23/04
    • C09D143/04C09D155/005
    • A curable composition comprising(A) a vinyl resin having at least one hydrolyzable silyl group in one molecule wherein the main chain substantially consists of a vinyl polymer and having no segment of a resin which has polymerizable double bonds at both ends of the main chain and a glass transition temperature of not more than 0.degree. C.;(B) a modified resin having at least one hydrolyzable silyl group in one molecule which is obtained by polymerizing(a) a resin having polymerizable double bonds at both ends of the main chain and a glass transition temperature of not more than O.degree. C.,(b) a hydrolyzable silyl group-containing vinyl monomer, and(c) a vinyl monomer having no hydrolyzable silyl group; and(C) a curing catalyst. The composition of the present invention enables to prepare a top coating having the excellent physical property balance between hardness and impact resistance or that between elongation and stain resistance.
    • 一种可固化组合物,其包含(A)在一个分子中具有至少一个可水解甲硅烷基的乙烯基树脂,其中所述主链基本上由乙烯基聚合物组成,并且不具有在所述主链的两端具有可聚合双键的树脂链段, 玻璃化转变温度不超过0℃。 (B)在一分子中具有至少一个可水解甲硅烷基的改性树脂,其通过聚合(a)在主链两端具有可聚合双键的树脂和不大于0℃的玻璃化转变温度而获得。 ,(b)含水解性甲硅烷基的乙烯基单体,(c)不具有水解性甲硅烷基的乙烯基单体; 和(C)固化催化剂。 本发明的组合物能够制备在硬度和抗冲击性之间具有优异物理性能平衡的顶涂层或伸长率与耐污染性之间的表面涂层。
    • 67. 发明授权
    • Curable composition for paint
    • 油漆组合物
    • US5344879A
    • 1994-09-06
    • US5130
    • 1993-01-15
    • Masaharu InoueYoshihiko OkimuraHirotoshi KawaguchiHisao Furukawa
    • Masaharu InoueYoshihiko OkimuraHirotoshi KawaguchiHisao Furukawa
    • C08G18/71C08K5/5419C09D143/04
    • C08G18/44C08G18/4277C08G18/718C08K5/5419C09D143/04
    • A curable composition for paint including(A) 10 to 99 parts by weight of a vinyl polymer having a number average molecular weight of not less than 2,000 and at least one silicon atom to which a hydrolyzable group is bonded at an end of the main chain and/or in a side chain thereof, in one molecule, wherein the main chain is substantially a vinyl polymer chain;(B) 1 to 90 parts by weight of a compound containing a carbonyldioxy group which is at least one of(i) a compound containing a hydrolyzable silyl group, the compound having at least one carbonyldioxy group in one molecule and at least one silicon atom to which a hydrolyzable group is bonded, in one molecule, and(ii) a polycarbonate polyol compound having at least one carbonyldioxy group and at least two hydroxyl groups in one molecule; and(C) 0.001 to 10 parts by weight of a curing catalyst on the basis of 100 parts by weight of the components (A) and (B) in total.This curable composition for paint has excellent high solid content and one package storage stability as well as superior scratch resistance and acid resistance.
    • 一种涂料用固化性组合物,其含有(A)10〜99重量份数均分子量为2000以上的乙烯基聚合物和至少一个可水解基团在主链末端键合的硅原子 和/或在其侧链中,在一个分子中,其中主链基本上是乙烯基聚合物链; (B)1〜90重量份含有羰基二氧基的化合物,其为(i)含有可水解甲硅烷基的化合物,在一个分子中具有至少一个羰基二氧基的化合物和至少一个硅原子 在一个分子中可水解基团键合的聚碳酸酯多元醇化合物,和(ii)在一个分子中具有至少一个羰基二氧基和至少两个羟基的聚碳酸酯多元醇化合物; 和(C)基于100重量份的组分(A)和(B)的总量,0.001至10重量份的固化催化剂。 这种涂料用可固化组合物具有优异的高固含量和一个包装储存稳定性以及优异的抗划伤性和耐酸性。