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    • 62. 发明授权
    • Polyester oligomer and high solids thermosetting coatings
    • 聚酯低聚物和高固体热固性涂料
    • US4518746A
    • 1985-05-21
    • US589728
    • 1984-03-15
    • Kazys SekmakasRaj ShahRonald J. LewarchikKevin P. Murray
    • Kazys SekmakasRaj ShahRonald J. LewarchikKevin P. Murray
    • C08G63/183C09D167/02C08L61/28
    • C08G63/183C09D167/02Y10T428/31681Y10T428/31688Y10T428/31786
    • An essentially linear polyester oligomer having hydroxyl and carboxyl terminal groups for subsequent cure and its production are disclosed. This polyester oligomer is produced by first adducting approximately equimolar amounts of diol carrying two primary hydroxyl groups and a dicarboxylic acid anhydride to form an hydroxy acid. The carboxyl groups of this hydroxy acid are then esterified by reaction with an approximately stoichiometric proportion of diol carrying one primary hydroxyl group and one secondary hydroxyl group, the stoichiometry being based on the total hydroxyl content of the diol and the carboxyl content of the hydroxy acid, to form an hydroxyl-terminated oligomer. This hydroxyl-terminated oligomer is then adducted with a polycarboxylic acid monoanhydride having a carboxyl functionality of at least 3, this monoanhydride being used in an amount of 0.01 to 0.15 equivalents of anhydride per hydroxyl equivalent in the hydroxyl-terminated oligomer. The resulting polyester oligomer is essentially linear and possesses low solution viscosity at high resin solids content combined with high reactivity enabling low temperature cure with aminoplast resins.
    • 公开了具有用于随后固化的羟基和羧基端基及其生产的基本上线性的聚酯低聚物。 该聚酯低聚物通过首先加入大约等摩尔量的带有两个伯羟基的二醇和二羧酸酐形成羟基酸来制备。 然后通过与大约化学计量比例的带有一个伯羟基和一个仲羟基的二醇反应将该羟基酸的羧基酯化,化学计量是基于二醇的总羟基含量和羟基酸的羧基含量 ,以形成羟基封端的低聚物。 然后将该羟基封端的低聚物与羧基官能度至少为3的多元羧酸单酸酐加成,该单酸酐的用量为羟基封端低聚物中羟基当量的0.01至0.15当量酐。 所得的聚酯低聚物基本上是线性的,并且在高树脂固体含量下具有低溶液粘度,并且具有高反应性,能够用氨基塑料树脂进行低温固化。
    • 63. 发明授权
    • Aminoplast curable compositions containing disulfonic acid esters as
latent acid catalysts
    • 含有二磺酸酯作为潜酸催化剂的氨基塑料可固化组合物
    • US4501854A
    • 1985-02-26
    • US551388
    • 1983-11-14
    • Debra L. SingerGregory J. McCollumRostyslaw Dowbenko
    • Debra L. SingerGregory J. McCollumRostyslaw Dowbenko
    • C08F4/00C08K5/42C09D133/00C08L61/28
    • C07C309/00C08K5/42
    • An improved curable composition capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent and a sulfonate as latent acid catalyst. The catalyst is represented by the following structural formula: ##STR1## wherein: Z is a radical independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, C.sub.6 to C.sub.18 aryl, halogen, alkoxy, hydroxyl, and aryloxy;R is independently selected from hydrogen, C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, and C.sub.6 to C.sub.18 aryl;R.sup.1 is independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, hydroxyalkyl, and hydroxycycloalkyl;y is an integer from 0 to 4,w is an integer from 0 to 2, andx is an integer from 1 to 3, with the proviso that when w is 0, y is an integer from 1 to 4 and x is an integer from 2 to 3 and when y is 0, w is an integer from 1 to 2 and x is an integer from 1 to 3.
    • 能够进行酸催化交联的改进的可固化组合物由含活性氢的树脂,固化剂和作为潜酸催化剂的磺酸盐组成。 催化剂由以下结构式表示:其中:Z是独立地选自C 1至C 20烷基,C 3至C 20环烷基,C 6至C 18芳基,卤素,烷氧基,羟基和芳氧基的基团; R独立地选自氢,C1至C20烷基,C3至C20环烷基和C6至C18芳基; R 1独立地选自C 1至C 20烷基,C 3至C 20环烷基,羟基烷基和羟基环烷基; y是0至4的整数,w是0至2的整数,x是1至3的整数,条件是当w为0时,y为1至4的整数,x为整数 2〜3,y为0时,w为1〜2的整数,x为1〜3的整数。
    • 70. 发明授权
    • Paint composition comprising hydroxy functional film former and
crosslinked dispersion flow control additive
    • 涂料组合物包含羟基官能成膜剂和交联的分散体流动控制添加剂
    • US4415697A
    • 1983-11-15
    • US292858
    • 1981-08-14
    • Stephen C. PengJohn D. Nordstrom
    • Stephen C. PengJohn D. Nordstrom
    • C08F2/08C08F2/14C08F291/00C08G18/62C08L33/06C08L61/20C08L61/32C09D133/06C08G12/32C08F220/10C08L61/28
    • C08G18/6229C08F2/08C08F291/00C09D133/066C08L33/062C08L61/20C08L61/32
    • Coating compositions comprising hydroxy functional film formers and a novel flow control additive comprising a stable crosslinked dispersion prepared by addition polymerization of (a) first and second ethylenically unsaturated monomers each bearing functionality capable of crosslinking with the other and (b) at least one other monoethylenically unsaturated monomer, in the presence of (I) organic liquid which is a solvent for the polymerizable monomers, but a non-solvent for the resultant polymer and (II) a novel polymeric dispersion stabilizer. The stabilizer bears pendent ethylenic unsaturation capable of reacting with monomers employed in the addition polymerization and comprises a random copolymer segment of ethylenically unsaturated monomers, some of which are characterized in that homopolymers thereof would be substantially insoluble in the organic liquid used to form the stable dispersion and some of which are characterized in that homopolymers thereof would be substantially soluble in the organic liquid used to form the stable dispersion.
    • 包含羟基官能成膜剂的涂料组合物和新的流动控制添加剂,其包含通过(a)第一和第二烯属不饱和单体的加成聚合制备的稳定的交联分散体,所述第一和第二烯属不饱和单体各自承载能够与另一个交联的官能团,和(b)至少一种其它单烯属 在(I)作为可聚合单体的溶剂的有机液体的存在下,使用所得聚合物的非溶剂和(II)新的聚合物分散体稳定剂。 稳定剂具有能够与加成聚合中使用的单体反应的侧链烯属不饱和基团,并且包含烯键式不饱和单体的无规共聚物链段,其中一些特征在于其均聚物基本上不溶于用于形成稳定分散体的有机液体 其中的一些特征在于其均聚物将基本上溶于用于形成稳定分散体的有机液体中。