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    • 61. 发明申请
    • Production method of multilayer ceramic electronic device
    • 多层陶瓷电子器件的生产方法
    • US20070074806A1
    • 2007-04-05
    • US11527574
    • 2006-09-27
    • Tatsuya KojimaRaitaro MasaokaTakako Murosawa
    • Tatsuya KojimaRaitaro MasaokaTakako Murosawa
    • C03B29/00
    • C04B35/4682C04B35/638C04B2235/3206C04B2235/3208C04B2235/3225C04B2235/3236C04B2235/3239C04B2235/3241C04B2235/3418C04B2235/5445C04B2235/6562C04B2235/6565C04B2235/6567C04B2235/6582C04B2235/6584C04B2235/6588C04B2235/663H01G4/0085H01G4/12H01G4/30
    • By a production method for producing a multilayer ceramic electronic device including dielectric layers and internal electrode layers comprising the steps of forming a green sheet to be said dielectric layer after firing, forming a pre-fired electrode layer to be said internal electrode layer after firing in a predetermined pattern on said green sheet by using a conductive material paste, forming a green chip by successively stacking said green sheets and said pre-fired electrode layers, and firing said green chip: wherein the conductive material paste for forming said pre-fired electrode layer is composed at least of conductive material particles, a first common material composed of ceramic powder and a second common material composed of ceramic powder having a larger average particle diameter than that of said first common material; an average particle diameter of said first common material is 1/20 to ½ of an average particle diameter of said conductive material particles; and the average particle diameter of said second common material is 1/10 to ½ of an average thickness of said internal electrode layers after firing; a multilayer ceramic electronic device, such as a multilayer ceramic capacitor, wherein arising of cracks is effectively prevented, having a low short-circuit defect rate, a low voltage resistance defect rate and high capacitance is produced.
    • 通过制造包括电介质层和内部电极层的多层陶瓷电子器件的制造方法,包括以下步骤:在烧成后形成作为所述电介质层的生片,在烧成后形成作为所述内部电极层的预烧电极层 通过使用导电材料浆料在所述生片上的预定图案,通过连续堆叠所述生片和所述预烧电极层形成绿色芯片,并烧制所述生芯片:其中用于形成所述预烧电极的导电材料糊 至少由导电材料颗粒构成的第一普通材料,由陶瓷粉末组成的第一普通材料和平均粒径大于所述第一普通材料的陶瓷粉末的第二普通材料; 所述第一普通材料的平均粒径为所述导电材料颗粒的平均粒径的1/20至1/2; 所述第二普通材料的平均粒径为烧成后的内部电极层的平均厚度的1/10〜1/2; 可以有效地防止出现裂纹的多层陶瓷电子器件,如多层陶瓷电容器,具有低的短路缺陷率,低电压电阻缺陷率和高电容。
    • 70. 发明授权
    • Method of making laminate thin-wall ceramic tubes and said tubes with electrodes, particularly for solid oxide fuel cells
    • 制造层压薄壁陶瓷管和所述具有电极的管,特别是用于固体氧化物燃料电池的方法
    • US06974516B2
    • 2005-12-13
    • US10784445
    • 2004-02-23
    • Alan DevoeMary Trinh
    • Alan DevoeMary Trinh
    • B28B21/48B32B1/08C03B29/00H01M8/00
    • B28B21/48B32B1/08
    • A method of fabricating a ceramic tube with electrodes thereon suitable for use as a tubular reaction chamber for a fuel cell. In one embodiment, the method includes wrapping a first electrode material around a mandrel, then wrapping a green ceramic material over the first electrode material, and then wrapping a second electrode material over the green ceramic material. The wrapped layers are laminated together, and then removed from the mandrel and sintered, in either sequence, to produce the laminated ceramic tube having an inner first electrode and an outer second electrode. Alternatively, a first electrode tube is provided in place of the mandrel and around which the green ceramic material is wrapped. The outer second electrode may be produced by wrapping a second electrode material around the green ceramic material, before or after laminating, or by printing the electrode material onto the sintered ceramic tube. The present invention further provides a method of making a ceramic tube in which a sacrificial organic material is first wrapped around the mandrel to a desired thickness prior to wrapping the green ceramic material to increase the green material thickness. During sintering, the organic material is burned away leaving only a laminated ceramic tube, optionally with electrodes thereon.
    • 一种制造其上具有适合用作燃料电池的管状反应室的电极的陶瓷管的方法。 在一个实施例中,该方法包括围绕心轴缠绕第一电极材料,然后将生坯陶瓷材料缠绕在第一电极材料上,然后将第二电极材料缠绕在生陶瓷材料上。 将包裹的层层叠在一起,然后从心轴中取出并以任一顺序烧结,以制造具有内部第一电极和外部第二电极的层叠陶瓷管。 或者,提供第一电极管来代替心轴,并且围绕着该生坯陶瓷材料被包裹。 外部第二电极可以通过在层压之前或之后将绿色陶瓷材料周围缠绕第二电极材料,或通过将电极材料印刷到烧结陶瓷管上来制造。 本发明还提供一种制造陶瓷管的方法,其中在包裹生坯陶瓷材料之前首先将牺牲有机材料缠绕在心轴上至期望的厚度以增加生坯材料厚度。 在烧结期间,有机材料被烧掉,仅留下层压陶瓷管,任选地带有电极。