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    • 61. 发明授权
    • Sulfur containing silica particle
    • 含硫二氧化硅颗粒
    • US08025726B1
    • 2011-09-27
    • US12756577
    • 2010-04-08
    • Bruce A. KeiserNicholas S. ErgangRichard Mimna
    • Bruce A. KeiserNicholas S. ErgangRichard Mimna
    • C01B33/00C01B33/113C09D1/00
    • C09C1/30C01G3/006C01P2002/54C01P2006/12C01P2006/14C08K3/36C09C3/00C09D7/61C09D7/69
    • A silica containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF: wherein M is at least one of the following metal or metalloid cations: boron, magnesium, aluminum, calcium, titanium, vanadium, manganese, iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, palladium, silver, cadmium, tin, platinum, gold, and bismuth; wherein S is a sulfur-based species selected from at least one of the following: sulfide salts, dithiocarbamates, polymer-based dithiocarbamates, and polysulfide salts; wherein F optionally exists and said F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of 0.01-100%; and wherein the molar ratio of y/x is equal to 0.01-0.5, the molar ratio of x/z is equal to 3-300, and the molar ratio of a/z is 1-5.
    • 公开了含二氧化硅的组合物。 该组合物包含具有下式的化合物:(SiO 2)x(OH)yMzSaF:其中M是以下金属或准金属阳离子中的至少一种:硼,镁,铝,钙,钛,钒,锰,铁,钴 ,镍,铜,锌,锆,钼,钯,银,镉,锡,铂,金和铋; 其中S是选自以下至少一种的硫基物质:硫化物盐,二硫代氨基甲酸盐,基于聚合物的二硫代氨基甲酸盐和多硫化物盐; 其中F任选存在并且所述F是以下至少一种:表面积覆盖率为0.01-100%的官能化有机硅烷,含硫有机硅烷,含胺的有机硅烷和含烷基的有机硅烷; 并且其中y / x的摩尔比等于0.01-0.5,x / z的摩尔比等于3-300,并且a / z的摩尔比为1-5。