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61. 发明授权

US07847126B2 Process for preparing tertiary phosphines 有权
标题翻译：制备叔膦的方法
公开(公告)号：US07847126B2
公开(公告)日：2010-12-07
申请号：US11810374
申请日：2007-06-05
申请人： Florian Rampf , Hans-Christian Militzer
发明人： Florian Rampf , Hans-Christian Militzer
IPC分类号： C07F9/54 , C07F5/02 , C07F7/28
CPC分类号： C07B37/04 , B01J31/24 , B01J31/2404 , B01J31/2409 , B01J31/2414 , B01J31/2447 , B01J2231/4211 , B01J2231/4233 , B01J2231/4238 , B01J2231/4255 , B01J2231/4261 , B01J2231/4266 , B01J2231/4283 , B01J2231/4288 , B01J2231/4294 , B01J2531/0205 , C07F9/5068 , C07F9/5442
摘要： The invention relates to a process for synthesizing tertiary phosphines by reacting halophosphines with organomagnesium compounds in the presence of copper compounds and optionally of salts.
摘要翻译：本发明涉及在铜化合物和任选的盐存在下使卤代膦与有机镁化合物反应合成叔膦的方法。

62. 发明申请

US20070161762A1 Metallocene-based chiral phosphine or arsine ligands 失效
标题翻译：基于茂金属的手性膦或胂配体
公开(公告)号：US20070161762A1
公开(公告)日：2007-07-12
申请号：US10586287
申请日：2005-01-14
申请人： Wei-Ping Chen , John Whittall
发明人： Wei-Ping Chen , John Whittall
IPC分类号： C07F17/00 , C08F4/44
CPC分类号： C07F17/02 , B01J31/1845 , B01J31/186 , B01J31/188 , B01J31/189 , B01J31/1895 , B01J31/2295 , B01J31/2404 , B01J31/2409 , B01J31/2452 , B01J31/2457 , B01J31/2495 , B01J2231/645 , B01J2531/0205 , B01J2531/82 , B01J2531/822 , B01J2531/842 , B01J2531/847
摘要： The present invention relates to metallocene-based phosphine ligands having chirality at phosphorus and at least one other element of chirality (planar chirality and/or chirality at carbon); and to the use of such ligands in asymmetric transformation reactions to generate high enantiomeric excesses of formed compounds. A method for the preparation of ligands according to the invention involving the conversion of the ortho-lithiated substituted metallocene to a phosphine chiral at phosphorus is also disclosed.
摘要翻译：本发明涉及在磷中具有手性和手性的至少一种其他元素（碳的手性和/或手性）的金属茂基膦配体。以及在不对称转化反应中使用这种配体以产生形成的化合物的高对映体过量。还公开了用于制备根据本发明的配体的方法，其涉及将邻位取代的金属茂转化为在磷上手性膦化合物。

63. 发明授权

US07223832B2 Double-metal cyanide catalysts which can be used to prepare polyols and the processes related thereto 有权
标题翻译：可用于制备多元醇的双金属氰化物催化剂及其相关方法
公开(公告)号：US07223832B2
公开(公告)日：2007-05-29
申请号：US10717093
申请日：2003-11-19
申请人： Bi Le-Khac , Wei Wang
发明人： Bi Le-Khac , Wei Wang
IPC分类号： C08G65/28 , C07C41/48 , B01J27/26 , B01J31/22
CPC分类号： B01J31/165 , B01J27/26 , B01J31/1805 , B01J31/2208 , B01J31/2234 , B01J31/26 , B01J31/28 , B01J2231/10 , B01J2531/0205 , B01J2531/26 , B01J2531/827 , B01J2531/84 , B01J2531/845 , C08G65/2663
摘要： The present invention is directed to polyols prepared in the presence of double metal cyanide catalysts (“DMC”) which are prepared by combining i) at least one metal salt; ii) at least one metal cyanide salt; iii) at least one organic complexing ligand; iv) at least one alkali metal salt; and, optionally, v) at least one functionalized polymer under conditions sufficient to form a catalyst; and adding a sufficient amount of the at least one alkali metal salt to the catalyst so formed in an amount such that the catalyst includes the at least one alkali metal salt in an amount of from about 0.4 to about 6 wt. % based on the total weight of the catalyst. The polyols produced by the process of the present invention have reduced levels of high molecular weight tail.
摘要翻译：本发明涉及在双金属氰化物催化剂（“DMC”）的存在下制备的多元醇，其通过将i）至少一种金属盐和 ii）至少一种金属氰化物盐; iii）至少一种有机络合配体; iv）至少一种碱金属盐; 和任选地，v）在足以形成催化剂的条件下的至少一种官能化聚合物; 并向所形成的催化剂中加入足量的至少一种碱金属盐，其量使得催化剂包含至少一种碱金属盐，其量为约0.4至约6wt。％，基于催化剂的总重量。通过本发明方法生产的多元醇具有降低的高分子量尾巴水平。

64. 发明申请

US20070004928A1 Process for preparing cationic rhodium complexes 有权
标题翻译：制备阳离子铑配合物的方法
公开(公告)号：US20070004928A1
公开(公告)日：2007-01-04
申请号：US10572632
申请日：2004-09-30
申请人： James Ramsden , Paul Moran
发明人： James Ramsden , Paul Moran
IPC分类号： C07F17/02 , C07F15/00
CPC分类号： B01J31/1845 , B01J31/0215 , B01J31/0227 , B01J31/186 , B01J31/2234 , B01J31/2295 , B01J31/24 , B01J31/2433 , B01J31/2452 , B01J31/2457 , B01J31/2476 , B01J31/26 , B01J2231/641 , B01J2531/02 , B01J2531/0205 , B01J2531/0263 , B01J2531/0266 , B01J2531/822 , B01J2531/842 , C07F15/0073 , C07F15/008
摘要： The invention comprises a process for the preparation and isolation of a non-amorphous cationic rhodium complex having the formula: [Rh(ligand)m(diolefin)]+X−, wherein the ligand is an enantiomerically enriched organic compound possessing one or two ligating phosphorus atoms.
摘要翻译：本发明包括用于制备和分离具有下式的非结晶阳离子铑配合物的方法：[Rh（配体）m（二烯烃）] + 其中配体是具有一个或两个连接的磷原子的对映异构体富集的有机化合物。

65. 发明授权

US06696383B1 Double-metal cyanide catalysts which can be used to prepare polyols and the processes related thereto 有权
标题翻译：可用于制备多元醇的双金属氰化物催化剂及其相关方法
公开(公告)号：US06696383B1
公开(公告)日：2004-02-24
申请号：US10251155
申请日：2002-09-20
申请人： Bi Le-Khac , Wei Wang
发明人： Bi Le-Khac , Wei Wang
IPC分类号： B01J2726
CPC分类号： B01J31/165 , B01J27/26 , B01J31/1805 , B01J31/2208 , B01J31/2234 , B01J31/26 , B01J31/28 , B01J2231/10 , B01J2531/0205 , B01J2531/26 , B01J2531/827 , B01J2531/84 , B01J2531/845 , C08G65/2663
摘要： The present invention is directed to double metal cyanide catalysts (“DMC”) which can be used to prepare polyols. DMC catalysts of the present invention are prepared by combining i) at least one metal salt; ii) at least one metal cyanide salt; iii) at least one organic complexing ligand; iv) at least one alkaline metal salt; and, optionally, v) at least one functionalized polymer. The present invention is also directed to a process for preparing a polyol in the presence of a DMC catalyst prepared according to the process of the present invention. Surprisingly, DMC catalysts of the present invention, which are preferably prepared with at least one alkaline metal halide, have acceptable activity and can be used to catalyze oxyalkylation reactions. Additionally, DMC catalysts produced by the process of the present invention can be used to prepare polyols which have reduced levels of high weight tail.
摘要翻译：本发明涉及可用于制备多元醇的双金属氰化物催化剂（“DMC”）。本发明的DMC催化剂通过将i）至少一种金属盐与 ii）至少一种金属氰化物盐; iii）至少一种有机络合配体; iv）至少一种碱金属盐; 和任选的v）至少一种官能化聚合物。本发明还涉及在根据本发明的方法制备的DMC催化剂存在下制备多元醇的方法。令人惊讶的是，本发明的DMC催化剂优选用至少一种碱金属卤化物具有可接受的活性，可用于催化烷氧基化反应。另外，通过本发明的方法生产的DMC催化剂可用于制备具有降低的重量尾巴水平的多元醇。

66. 发明授权

US06380416B2 Asymmetric synthesis catalyzed by transition metal complexes with rigid chiral ligands 失效
标题翻译：通过与刚性手性配体的过渡金属配合物催化不对称合成
公开(公告)号：US06380416B2
公开(公告)日：2002-04-30
申请号：US09878417
申请日：2001-06-12
申请人： Xumu Zhang
发明人： Xumu Zhang
IPC分类号： C07F906
CPC分类号： C07B53/00 , B01J31/0244 , B01J31/185 , B01J31/1875 , B01J31/2414 , B01J31/2457 , B01J31/2466 , B01J31/2476 , B01J31/248 , B01J31/2485 , B01J31/249 , B01J31/26 , B01J2231/32 , B01J2231/643 , B01J2231/645 , B01J2531/0205 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/842 , C07B2200/07 , C07C29/145 , C07C41/26 , C07C45/505 , C07C231/18 , C07F9/46 , C07F9/5027 , C07F9/572 , C07F9/59 , C07F9/6561 , C07F9/65683 , C07F9/65746 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/045 , C07C33/22 , C07C33/20 , C07C43/23 , C07C33/18 , C07C31/125 , C07C31/12 , C07C31/1355
摘要： This invention is to develop novel transition metal catalysts for the practical synthesis of important chiral molecules. The invention emphasizes asymmetric catalysis based on chiral bidentate phosphine ligands with cyclic ring structures which could be used to restrict conformational flexibility of the ligands and thus the efficiency of chiral transfer can be enhanced through the ligand rigidity.
摘要翻译：本发明是开发用于实际合成重要手性分子的新型过渡金属催化剂。本发明强调了基于具有环状环结构的手性二齿膦配体的不对称催化作用，其可用于限制配体的构象柔性，从而可以通过配体刚性增强手性转移的效率。

67. 发明授权

US06372879B1 Polyester polycondensation with catalyst and a catalyst enhancer 失效
标题翻译：与催化剂和催化剂增强剂的聚酯缩聚
公开(公告)号：US06372879B1
公开(公告)日：2002-04-16
申请号：US09895990
申请日：2001-06-29
申请人： Conor M. Dowling , Bin Chen , Sri R. Seshadri
发明人： Conor M. Dowling , Bin Chen , Sri R. Seshadri
IPC分类号： C08G6302
CPC分类号： C08G63/85 , B01J21/063 , B01J31/04 , B01J31/2239 , B01J31/26 , B01J2531/0205 , B01J2531/10 , B01J2531/20 , B01J2531/46 , B01J2531/52 , C08G63/82 , C08G63/83 , C08G63/84 , C08G63/87
摘要： The present invention is based upon the discovery that nontitanyl oxalates can enhance the catalytic functionality of titanyl oxalate catalysts. This invention provides a novel catalytic composition containing a titanyl oxalate catalyst and a metallic oxalate catalyst enhancer and optionally containing a metallic cocatalyst such as an antimony based catalyst. A synergistic relationship has been discovered between titanyl oxalate catalyst and the catalyst enhancer. A synergistic relationship has also been discovered between the titanyl oxalate catalyst, catalyst enhancer and a metallic cocatalyst such as antimony oxide or antimony triacetate. Also provided is an improved process of producing polyester by the polycondensation of polyester forming reactants in the presence of a catalytically effective amount of a polycondensation catalyst, wherein the improvement comprises utilizing, as the polycondensation catalyst, the novel catalyst composition containing a titanyl oxalate such as lithium titanyl oxalate and a catalyst enhancer such as a nontitanyl metallic oxalate like lithium oxalate and optionally containing a metallic catalyst such as antimony oxide or antimony triacetate. The improved process produces an improved polyester having lower acetaldehyde numbers and good color. The titanyl oxalate/catalyst enhancer composition can be used as a polycondensation catalyst in combination with other catalysts to achieve synergistic catalytic activity. Preferred is a combination of lithium or potassium titanyl oxalate, Li2 or K2TiO(C2O4)2, lithium or potassium oxalate, Li2 or K2(C2O4)2 with antimony oxide or antimony triacetate or antimony trisglycoxide.
摘要翻译：本发明基于以下发现，即草酸钛酸酯可以增强草酸氧钛催化剂的催化功能。本发明提供一种含有草酸氧钛催化剂和金属草酸盐催化剂增强剂并任选地含有金属助催化剂如锑基催化剂的新型催化组合物。在草酸氧钛催化剂和催化剂增强剂之间已经发现协同关系。在草酸氧钛催化剂，催化剂增强剂和金属助催化剂如氧化锑或三乙酸锑之间也发现了协同关系。还提供了通过在催化有效量的缩聚催化剂存在下，通过聚酯形成反应物的缩聚来生产聚酯的改进方法，其中改进包括利用含有草酸氧钛的新型催化剂组合物作为缩聚催化剂，草酸氧钛酸锂和催化剂增强剂如非钛酸金属草酸盐如草酸锂，并任选地含有金属催化剂如氧化锑或三乙酸锑。改进的方法产生具有较低乙醛数和良好颜色的改进的聚酯。草酸氧钛/催化剂增强剂组合物可以与其它催化剂组合用作缩聚催化剂以实现协同催化活性。优选的是草酸锂或钾钛酸盐，Li 2或K 2 TiO（C 2 O 4）2，草酸锂或钾，Li 2或K 2（C 2 O 4）2与氧化锑或三乙酸锑或三羟基氧化锑的组合。

68. 发明申请

US20010047113A1 Asymmetric synthesis catalyzed by transition metal complexes with rigid chiral ligands 失效
公开(公告)号：US20010047113A1
公开(公告)日：2001-11-29
申请号：US09878417
申请日：2001-06-12
申请人： The Penn State Research Foundation
发明人： Xumu Zhang
IPC分类号： C07F009/28
CPC分类号： C07B53/00 , B01J31/0244 , B01J31/185 , B01J31/1875 , B01J31/2414 , B01J31/2457 , B01J31/2466 , B01J31/2476 , B01J31/248 , B01J31/2485 , B01J31/249 , B01J31/26 , B01J2231/32 , B01J2231/643 , B01J2231/645 , B01J2531/0205 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/842 , C07B2200/07 , C07C29/145 , C07C41/26 , C07C45/505 , C07C231/18 , C07F9/46 , C07F9/5027 , C07F9/572 , C07F9/59 , C07F9/6561 , C07F9/65683 , C07F9/65746 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/045 , C07C33/22 , C07C33/20 , C07C43/23 , C07C33/18 , C07C31/125 , C07C31/12 , C07C31/1355
摘要： This invention is to develop novel transition metal catalysts for the practical synthesis of important chiral molecules. The invention emphasizes asymmetric catalysis based on chiral bidentate phosphine ligands with cyclic ring structures which could be used to restrict conformational flexibility of the ligands and thus the efficiency of chiral transfer can be enhanced through the ligand rigidity.

69. 发明授权

US06265601B1 Methods for using phosphine ligands in compositions for suzuki cross-coupling reactions 失效
标题翻译：在组合物中使用膦配体的Suzuki交叉偶联反应的方法
公开(公告)号：US06265601B1
公开(公告)日：2001-07-24
申请号：US09296226
申请日：1999-04-22
申请人： Anil Guram , Xiaohong Bei
发明人： Anil Guram , Xiaohong Bei
IPC分类号： C07C25552
CPC分类号： B01J31/2295 , B01J31/2404 , B01J2231/4211 , B01J2531/0205 , B01J2531/821 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/84 , C07B37/04 , C07B43/04 , C07C1/321 , C07C45/68 , C07C209/10 , C07C253/30 , C07C2531/24 , C07F9/5018 , C07F9/5022 , C07F9/65515 , C07C49/784 , C07C255/50
摘要： The present invention discloses new efficient processes for various bond forming reactions, including Suzuki reactions. Organic compounds (e.g., ligands), their metal complexes and compositions using those compounds, provide useful catalysts. The invention also relates to performing Suzuki cross coupling reactions with unreactive aryl-chlorides.
摘要翻译：本发明公开了用于形成各种键形成反应的新的有效方法，包括Suzuki反应。有机化合物（例如配体），它们的金属络合物和使用这些化合物的组合物提供有用的催化剂。本发明还涉及用非反应性芳基氯化物进行Suzuki交叉偶联反应。

70. 发明授权

US06218559B1 Hydrogenation catalyst, process for the preparation thereof and hydrogenation process 有权
标题翻译：氢化催化剂，其制备方法和氢化方法
公开(公告)号：US06218559B1
公开(公告)日：2001-04-17
申请号：US09267486
申请日：1999-03-11
申请人： Felix Spindler , Ulrich Pittelkow
发明人： Felix Spindler , Ulrich Pittelkow
IPC分类号： C07F726
CPC分类号： B01J31/1845 , B01J31/04 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J31/2419 , B01J31/2452 , B01J31/26 , B01J31/30 , B01J2231/643 , B01J2531/0205 , B01J2531/0266 , B01J2531/827 , B01J2531/842 , C07C209/52 , C07F15/004 , C07F17/02
摘要： Reaction products of an iridium(III) salt or a hydrate thereof, a diphosphine having secondary phosphine groups and a metal or ammonium chloride, bromide or iodide are excellent hydrogenation catalysts for ketimine. Using chiral diphosphines and prochiral ketimines, diastereoisomeric secondary amines are obtained in high optical yields.
摘要翻译：铱（III）盐或其水合物，具有仲膦基的二膦和金属或氯化铵，溴化物或碘化物的反应产物是用于酮亚胺的优异的氢化催化剂。使用手性二膦和前手性酮亚胺，以高光学收率获得非对映异构仲胺。

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