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61. 发明授权

US06372879B1 Polyester polycondensation with catalyst and a catalyst enhancer 失效
标题翻译：与催化剂和催化剂增强剂的聚酯缩聚
公开(公告)号：US06372879B1
公开(公告)日：2002-04-16
申请号：US09895990
申请日：2001-06-29
申请人： Conor M. Dowling , Bin Chen , Sri R. Seshadri
发明人： Conor M. Dowling , Bin Chen , Sri R. Seshadri
IPC分类号： C08G6302
CPC分类号： C08G63/85 , B01J21/063 , B01J31/04 , B01J31/2239 , B01J31/26 , B01J2531/0205 , B01J2531/10 , B01J2531/20 , B01J2531/46 , B01J2531/52 , C08G63/82 , C08G63/83 , C08G63/84 , C08G63/87
摘要： The present invention is based upon the discovery that nontitanyl oxalates can enhance the catalytic functionality of titanyl oxalate catalysts. This invention provides a novel catalytic composition containing a titanyl oxalate catalyst and a metallic oxalate catalyst enhancer and optionally containing a metallic cocatalyst such as an antimony based catalyst. A synergistic relationship has been discovered between titanyl oxalate catalyst and the catalyst enhancer. A synergistic relationship has also been discovered between the titanyl oxalate catalyst, catalyst enhancer and a metallic cocatalyst such as antimony oxide or antimony triacetate. Also provided is an improved process of producing polyester by the polycondensation of polyester forming reactants in the presence of a catalytically effective amount of a polycondensation catalyst, wherein the improvement comprises utilizing, as the polycondensation catalyst, the novel catalyst composition containing a titanyl oxalate such as lithium titanyl oxalate and a catalyst enhancer such as a nontitanyl metallic oxalate like lithium oxalate and optionally containing a metallic catalyst such as antimony oxide or antimony triacetate. The improved process produces an improved polyester having lower acetaldehyde numbers and good color. The titanyl oxalate/catalyst enhancer composition can be used as a polycondensation catalyst in combination with other catalysts to achieve synergistic catalytic activity. Preferred is a combination of lithium or potassium titanyl oxalate, Li2 or K2TiO(C2O4)2, lithium or potassium oxalate, Li2 or K2(C2O4)2 with antimony oxide or antimony triacetate or antimony trisglycoxide.
摘要翻译：本发明基于以下发现，即草酸钛酸酯可以增强草酸氧钛催化剂的催化功能。本发明提供一种含有草酸氧钛催化剂和金属草酸盐催化剂增强剂并任选地含有金属助催化剂如锑基催化剂的新型催化组合物。在草酸氧钛催化剂和催化剂增强剂之间已经发现协同关系。在草酸氧钛催化剂，催化剂增强剂和金属助催化剂如氧化锑或三乙酸锑之间也发现了协同关系。还提供了通过在催化有效量的缩聚催化剂存在下，通过聚酯形成反应物的缩聚来生产聚酯的改进方法，其中改进包括利用含有草酸氧钛的新型催化剂组合物作为缩聚催化剂，草酸氧钛酸锂和催化剂增强剂如非钛酸金属草酸盐如草酸锂，并任选地含有金属催化剂如氧化锑或三乙酸锑。改进的方法产生具有较低乙醛数和良好颜色的改进的聚酯。草酸氧钛/催化剂增强剂组合物可以与其它催化剂组合用作缩聚催化剂以实现协同催化活性。优选的是草酸锂或钾钛酸盐，Li 2或K 2 TiO（C 2 O 4）2，草酸锂或钾，Li 2或K 2（C 2 O 4）2与氧化锑或三乙酸锑或三羟基氧化锑的组合。

62. 发明申请

US20010047113A1 Asymmetric synthesis catalyzed by transition metal complexes with rigid chiral ligands 失效
公开(公告)号：US20010047113A1
公开(公告)日：2001-11-29
申请号：US09878417
申请日：2001-06-12
申请人： The Penn State Research Foundation
发明人： Xumu Zhang
IPC分类号： C07F009/28
CPC分类号： C07B53/00 , B01J31/0244 , B01J31/185 , B01J31/1875 , B01J31/2414 , B01J31/2457 , B01J31/2466 , B01J31/2476 , B01J31/248 , B01J31/2485 , B01J31/249 , B01J31/26 , B01J2231/32 , B01J2231/643 , B01J2231/645 , B01J2531/0205 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/842 , C07B2200/07 , C07C29/145 , C07C41/26 , C07C45/505 , C07C231/18 , C07F9/46 , C07F9/5027 , C07F9/572 , C07F9/59 , C07F9/6561 , C07F9/65683 , C07F9/65746 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/045 , C07C33/22 , C07C33/20 , C07C43/23 , C07C33/18 , C07C31/125 , C07C31/12 , C07C31/1355
摘要： This invention is to develop novel transition metal catalysts for the practical synthesis of important chiral molecules. The invention emphasizes asymmetric catalysis based on chiral bidentate phosphine ligands with cyclic ring structures which could be used to restrict conformational flexibility of the ligands and thus the efficiency of chiral transfer can be enhanced through the ligand rigidity.

63. 发明授权

US06265601B1 Methods for using phosphine ligands in compositions for suzuki cross-coupling reactions 失效
标题翻译：在组合物中使用膦配体的Suzuki交叉偶联反应的方法
公开(公告)号：US06265601B1
公开(公告)日：2001-07-24
申请号：US09296226
申请日：1999-04-22
申请人： Anil Guram , Xiaohong Bei
发明人： Anil Guram , Xiaohong Bei
IPC分类号： C07C25552
CPC分类号： B01J31/2295 , B01J31/2404 , B01J2231/4211 , B01J2531/0205 , B01J2531/821 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/84 , C07B37/04 , C07B43/04 , C07C1/321 , C07C45/68 , C07C209/10 , C07C253/30 , C07C2531/24 , C07F9/5018 , C07F9/5022 , C07F9/65515 , C07C49/784 , C07C255/50
摘要： The present invention discloses new efficient processes for various bond forming reactions, including Suzuki reactions. Organic compounds (e.g., ligands), their metal complexes and compositions using those compounds, provide useful catalysts. The invention also relates to performing Suzuki cross coupling reactions with unreactive aryl-chlorides.
摘要翻译：本发明公开了用于形成各种键形成反应的新的有效方法，包括Suzuki反应。有机化合物（例如配体），它们的金属络合物和使用这些化合物的组合物提供有用的催化剂。本发明还涉及用非反应性芳基氯化物进行Suzuki交叉偶联反应。

64. 发明授权

US06218559B1 Hydrogenation catalyst, process for the preparation thereof and hydrogenation process 有权
标题翻译：氢化催化剂，其制备方法和氢化方法
公开(公告)号：US06218559B1
公开(公告)日：2001-04-17
申请号：US09267486
申请日：1999-03-11
申请人： Felix Spindler , Ulrich Pittelkow
发明人： Felix Spindler , Ulrich Pittelkow
IPC分类号： C07F726
CPC分类号： B01J31/1845 , B01J31/04 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J31/2419 , B01J31/2452 , B01J31/26 , B01J31/30 , B01J2231/643 , B01J2531/0205 , B01J2531/0266 , B01J2531/827 , B01J2531/842 , C07C209/52 , C07F15/004 , C07F17/02
摘要： Reaction products of an iridium(III) salt or a hydrate thereof, a diphosphine having secondary phosphine groups and a metal or ammonium chloride, bromide or iodide are excellent hydrogenation catalysts for ketimine. Using chiral diphosphines and prochiral ketimines, diastereoisomeric secondary amines are obtained in high optical yields.
摘要翻译：铱（III）盐或其水合物，具有仲膦基的二膦和金属或氯化铵，溴化物或碘化物的反应产物是用于酮亚胺的优异的氢化催化剂。使用手性二膦和前手性酮亚胺，以高光学收率获得非对映异构仲胺。

65. 发明授权

US6143682A Bimetallocyclic transition metal catalyst systems 失效
标题翻译：双金属过渡金属催化剂体系
公开(公告)号：US6143682A
公开(公告)日：2000-11-07
申请号：US473693
申请日：1995-06-07
申请人： Richard Allen Fisher
发明人： Richard Allen Fisher
IPC分类号： C08F4/642 , C08F4/619 , C08F4/62 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/00 , B01J2531/0205 , B01J2531/40 , B01J2531/50 , B01J2531/57 , B01J2531/58 , B01J31/143 , B01J31/1608 , B01J31/2265 , C08F2410/03 , C08F4/619 , C08F4/61908 , C08F4/61912
摘要： This invention relates to single site catalyst systems comprising activated bimetallocyclic transition metal compounds, and the use of these catalyst systems for the polymerization of ethylenically and acetylenically unsaturated monomers. The bimetallocyclic compounds comprise two metal atoms, selected from the group consisting of Group 4 or Group 5 metal atoms, connected through two covalent bridging links so as to form a cyclic compound having delocalized bonding in the cyclic structure. The exemplary bimetallocyclic compound bis-M-(trimethylsilyl-methylidyne) tetrakis-(trimethylsilylmethyl) ditantalum activated with alumoxane and borate compounds is shown to be useful for preparing ethylene polymers having M.sub.n of at least 267,000 and MWD of about 2.3.
摘要翻译：本发明涉及包含活性双金属过渡金属化合物的单中心催化剂体系，以及这些催化剂体系用于烯属和炔属不饱和单体聚合的用途。双金属环化合物包含通过两个共价桥连连接的选自第4族或第5族金属原子的两个金属原子，以形成在环状结构中具有离域键合的环状化合物。显示出用铝氧烷和硼酸盐化合物活化的示例性双金属摩尔化合物双-M-（三甲基甲硅烷基 - 甲基亚乙基）四（三甲基甲硅烷基甲基）二钽，用于制备Mn至少为267,000，MWD为约2.3的乙烯聚合物。

66. 发明授权

US6127557A Method for producing silasequioxane metal complexes, novel silasesquioxane metal complexes and use thereof 失效
标题翻译：硅倍半氧烷金属络合物的制备方法，新型硅烷倍半硅烷金属配合物及其用途
公开(公告)号：US6127557A
公开(公告)日：2000-10-03
申请号：US403260
申请日：1999-10-18
申请人： Rutger Anthony Van Santen , Hendrikus Cornesis Louis Abbenhuis , Martinus Lambertus Wilhelmus Vorstenbosch
发明人： Rutger Anthony Van Santen , Hendrikus Cornesis Louis Abbenhuis , Martinus Lambertus Wilhelmus Vorstenbosch
IPC分类号： B01J31/02 , B01J31/12 , B01J31/16 , B01J31/22 , C07D301/02 , C07D301/03 , C07F7/08 , C07F9/00 , C07F17/00 , C08G77/398 , C07D301/12 , C07D301/19 , C07F7/02 , C07F7/21 , C07F7/28
CPC分类号： C08G77/398 , B01J31/125 , B01J31/1675 , B01J31/2226 , C07D301/02 , C07F17/00 , C07F7/0836 , C07F7/0856 , C07F9/00 , C07F9/005 , B01J2231/70 , B01J2231/72 , B01J2531/0205 , B01J2531/0288 , B01J2531/46 , B01J2531/48 , B01J2531/56
摘要： A method for producing silasesquioxane metal complexes of the formula (II)((R.sup.1 SiO.sub.1,5).sub.n (R.sup.2a SiO.sub.1,5).sub.m ((B).sub.q (O).sub.r)).sub.u (M).sub.v (Y).sub.win which R.sup.1 represents C.sub.5 -C.sub.10 -cycloalkyl, norbornyl or adamantyl; R.sup.2a represents oxygen; B represents H, OH, halogen, alkoxy, SiR.sup.3.sub.y in which R.sup.3 can be C.sub.1 -C.sub.4 alkyl, aryl or substituted silyl groups, and y represents 2 or 3, and R.sup.1 and R.sup.3 can be functionalized; M represents metals of the 4.sup.th to 7.sup.th subgroups of the periodic system of elements; Y represents C.sub.1 -C.sub.20 alkyl or aryl groups devoid of beta-hydrogen, silyl, alkoxy, OH, halogen, oxo, imido, fluorenyl, indenyl, cyclopentadienyl, in which the individual ligands can be substituted; n=6 or 7; m=0 or 1; q=0-2; r=0-2; u=1-4; v=1-4; w=0-12, in which a metal compound of the 4.sup.th to 7.sup.th subgroups of the periodic system of elements and at least one silasesquioxane compound of the formula (I)(R.sup.1 SiO.sub.1,5).sub.n (R.sup.2 SiO.sub.1,5).sub.m ((H).sub.p (B).sub.q (O).sub.r))in which R.sup.1, B, n, m, q and r have the above meanings; R.sup.2 represents OH, and p equals 0-4, are suspended in an alkylated aromatic hydrocarbon, optionally in the presence of a basic compound, with stirring at -80 to +110.degree. C., and a reaction product is separated at room temperature. The invention also relates to metal complexes which include an oxidic metal cluster containing titanium atoms, in which each titanium atom has been coordinated .times.6, and to the use of such metal complexes as catalysts for oxidation or epoxidation of unsaturated hydrocarbons or alcohols in an aqueous medium.
摘要翻译： PCT No.PCT / EP98 / 01932 Sec。 371 1999年10月18日第 102（e）日期1999年10月18日PCT提交1998年4月2日PCT公布。第WO98 / 46352号公报日期：1998年10月22日制备式（II）（（R1SiO1,5）n（R2aSiO5,5）m（（B）q（O）r））u（M）v（Y）的硅烷倍半硅烷金属络合物的方法 R1代表C5-C10-环烷基，降冰片基或金刚烷基; R2a代表氧; B表示H，OH，卤素，烷氧基，SiR 3y，其中R 3可以是C 1 -C 4烷基，芳基或取代的甲硅烷基，y表示2或3，R 1和R 3可以官能化; M表示元素周期性系统的第4至第7个亚组的金属; Y表示不含β-氢，甲硅烷基，烷氧基，OH，卤素，氧代，亚氨基，芴基，茚基，环戊二烯基的C1-C20烷基或芳基，其中各配体可以被取代; n = 6或7; m = 0或1; q = 0-2; r = 0-2; u = 1-4; v = 1-4; w = 0-12，其中元素周期元素的第4至第7族的金属化合物和至少一种式（I）的硅烷四倍子恶烷化合物（R 1 SiO 15）n（R 2 SiO 15）m（（H ）p（B）q（O）r）），其中R 1，B，n，m，q和r具有上述含义; R 2表示OH，p等于0-4，任选在碱性化合物的存在下，在-80至+ 110℃下搅拌悬浮在烷基化芳烃中，并在室温下分离出反应产物。本发明还涉及金属配合物，其包括含有钛原子的氧化金属簇，其中每个钛原子已配位x6，以及在水性介质中使用这种金属络合物作为不饱和烃或醇的氧化或环氧化催化剂。

67. 发明授权

US6084114A Dipalladaphosphacyclobutanes and a process for preparing the same 失效
标题翻译：二环磷杂环丁烷及其制备方法
公开(公告)号：US6084114A
公开(公告)日：2000-07-04
申请号：US308259
申请日：1999-07-19
申请人： Holger Geissler , Peter Gross , Bianca Guckes
发明人： Holger Geissler , Peter Gross , Bianca Guckes
IPC分类号： B01J31/24 , C07F15/00 , C07F9/02
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/2423 , B01J31/2447 , C07F15/006 , B01J2231/4261 , B01J2531/0205 , B01J2531/824 , B01J2540/225
摘要： The invention relates to palladaphosphacyclobutanes of the formula (I) ##STR1## where R.sup.1, R.sup.2 are, independently of one another, hydrogen, (C.sub.1 -C.sub.4)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl, (C.sub.1 -C.sub.4)-alkoxy, fluorine, N[(C.sub.1 -C.sub.4)-alkyl].sub.2, CO.sub.2 -(C.sub.1 -C.sub.4)-alkyl, OCO-(C.sub.1 -C.sub.4)-alkyl or aryl;R.sup.3, R.sup.4, R.sup.5, R.sup.6 are, independently of one another, (C.sub.1 -C.sub.8)-alkyl, (C.sub.3 -C.sub.12)-cycloalkyl or aryl;or where R.sup.1 and R.sup.2, R.sup.1 or R.sup.2 and R.sup.3 or R.sup.4, R.sup.3 and R.sup.4, R.sup.3 or R.sup.4 and R.sup.5 or R.sup.6, or R.sup.5 and R.sup.6 together form an aliphatic ring; or where R.sup.5 and R.sup.6, R.sup.3 or R.sup.4 and R.sup.5 or R.sup.6 together form an aromatic ring; andY is an anion of an inorganic or organic acid, with the exception of the compoundsdi-.mu.-chloro-bis[2-[bis(1,1-dimethylethyl)phosphino]-2-methylpropyl-C,P]dipalladium(II)di-.mu.-bromo-bis[2-[bis(1,1 -dimethylethyl)phosphino]-2-methylpropyl-C,P]dipalladium(II)di-.mu.-trifluoroacetato-bis[2-[bis(1,1 -dimethylethyl)phosphino]-2-methylpropyl-C,P]dipalladium(II)di-.mu.-chloro-bis[2-[(1,1 -dimethylethyl)phenylphosphino]-2-methylpropyl-C,P]dipalladium(II).mu.-chloro-.mu.-methoxy-bis[2-[bis(1,1 -dimethylethyl)phosphino]-2-methylpropyl-C,P]dipalladium(II).
摘要翻译： PCT No.PCT / EP97 / 06327 Sec。 371日期1999年7月19日第 102（e）1999年7月19日PCT 1997年11月13日PCT公布。公开号WO98 / 22485 日本公开日1998年5月28日本发明涉及式（I）的聚苯撑磷杂环丁烷，其中R1，R2彼此独立地为氢，（C1-C4） - 烷基，（C3-C12） - 环烷基，（C1-C4） - 烷氧基，氟，N [（C 1 -C 4） - 烷基] 2，CO 2 - （C 1 -C 4） - 烷基，OCO-（C 1 -C 4） - 烷基或芳基; R3，R4，R5，R6彼此独立地为（C1-C8） - 烷基，（C3-C12） - 环烷基或芳基; 或其中R 1和R 2，R 1或R 2和R 3或R 4，R 3和R 4，R 3或R 4和R 5或R 6或R 5和R 6一起形成脂族环; 或其中R 5和R 6，R 3或R 4和R 5或R 6一起形成芳环; 并且Y是无机或有机酸的阴离子，除了化合物二氯 - 双[2- [二（1,1-二甲基乙基）膦基] -2-甲基丙基-C，P]二钯（ II）二 - 双 - 双 - [2- [二（1,1-二甲基乙基）膦基] -2-甲基丙基-C，P]二 - （三氟乙酰）双[ ，1-二甲基乙基）膦基] -2-甲基丙基-C，P]二钯（II）二氯 - 双[2 - [（1,1-二甲基乙基）苯基膦基] -2-甲基丙基C，P]二钯（II） - 氯 - 甲氧基 - 双[2- [二（1,1-二甲基乙基）膦基] -2-甲基丙基-C，P]二钯（II）。

68. 发明授权

US5880301A Optically active bidentate phosphine ligand palladium complex 失效
标题翻译：光活性二齿膦配体钯络合物
公开(公告)号：US5880301A
公开(公告)日：1999-03-09
申请号：US894520
申请日：1997-09-16
申请人： Masakatsu Shibasaki , Mikiko Sodeoka , Kazuhiko Ohrai
发明人： Masakatsu Shibasaki , Mikiko Sodeoka , Kazuhiko Ohrai
IPC分类号： B01J31/24 , C07F15/00 , C07F9/02
CPC分类号： B01J31/2295 , B01J31/2409 , B01J31/2414 , B01J31/2452 , C07F15/0066 , B01J2231/4272 , B01J2531/0205 , B01J2531/0266 , B01J2531/824 , B01J2531/842
摘要： The present invention provides a novel optically active bidentate phosphine ligand palladium complex of formula (I) or (II) which can be used for the preparation of optically active .beta.-hydroxyketones: ##STR1## �wherein Y.sup.- represents an anion pair which may form salt; X represents ##STR2## {wherein R.sup.1 represents hydrogen atom, C.sub.1-6 alkyl group, C.sub.1-6 alkoxyl group, cyano group, nitro group, halogen atom or phenyl group, etc.; m represents 1 or 2; when m is 2, two R.sup.1 s may be same or different}; andA and B each independently represents phenyl group or cyclohexyl group {said phenyl group and cyclohexyl group each is unsubstituted or substituted by R.sup.2 (R.sup.2 has the same meaning as defined in R.sup.1)}).
摘要翻译： PCT No.PCT / JP96 / 00418 Sec。 371日期：1997年9月16日 102（e）日期1997年9月16日PCT提交1996年2月23日PCT公布。出版物WO96 / 26210 日期：1996年8月29日本发明提供了可用于制备光学活性β-羟基酮的式（I）或（II）的新型光学活性二齿膦配体钯络合物：（II）[其中Y-表示可形成盐的阴离子对; X代表原子，C 1-6烷基，C 1-6烷氧基，氰基，硝基，卤原子或苯基等; m表示1或2; 当m为2时，两个R1可以相同或不同}; A和B各自独立地表示苯基或环己基（所述苯基和环己基各自未被取代或被R 2取代（R 2具有与R 1中定义相同的含义）}）。

69. 发明授权

US5618983A Hydroformylation process 失效
标题翻译：加氢甲酰化过程
公开(公告)号：US5618983A
公开(公告)日：1997-04-08
申请号：US519833
申请日：1995-08-25
申请人： Patrick M. Burke
发明人： Patrick M. Burke
IPC分类号： B01J31/02 , B01J31/24 , C07C45/50 , C07C47/02 , C07C67/347 , C07C253/30
CPC分类号： C07C253/30 , B01J31/0227 , B01J31/04 , B01J31/2409 , C07C45/50 , C07C67/347 , B01J2231/321 , B01J2531/0205 , B01J2531/824 , B01J2531/828 , B01J2531/842 , B01J2531/96 , B01J2540/225
摘要： A hydroformylation process for the production of linear aldehydes from linear olefins, by the reaction of the olefin with hydrogen and carbon monoxide in a solvent containing a catalyst having a platinum component or palladium component, a bidentate diaryl phosphine component where the bridging group is ferrocenyl or 3 to 6 carbon atoms, and a metal promoter component.
摘要翻译：通过烯烃与氢气和一氧化碳在含有铂组分或钯组分的催化剂的溶剂中反应制备直链醛的加氢甲酰化方法，其中桥联基团是二茂铁基的二齿二芳基膦组分或 3至6个碳原子，和金属促进剂组分。

70. 发明授权

US5536883A Highly active double metal cyanide catalysts and epoxide polymerization 失效
标题翻译：高活性双金属氰化物催化剂和环氧化物聚合
公开(公告)号：US5536883A
公开(公告)日：1996-07-16
申请号：US453194
申请日：1995-05-30
申请人： Bi Le-Khac
发明人： Bi Le-Khac
IPC分类号： C08K3/28 , B01J27/26 , B01J31/02 , B01J31/06 , B01J31/16 , B01J31/22 , C08F4/26 , C08G59/68 , C08G59/70 , C08G65/10 , C08G65/26 , C08G65/28 , C08G65/30 , C08K5/05 , C08L71/00 , C08L71/02 , C07C41/03 , C07C43/10 , C07C43/13
CPC分类号： B01J31/2213 , B01J27/26 , B01J31/0202 , B01J31/068 , B01J31/165 , C08G65/2663 , C08G65/30 , B01J2531/0205 , B01J2531/845 , B01J2531/96
摘要： Highly active double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC complex, and organic complexing agent, and from about 5 to about 80 wt. %, based on the amount of catalyst, of a polyether having a number average molecular weight greater than about 500. A method of preparing the catalysts is also disclosed. The catalysts are easy to prepare, have exceptional activity, and are readily removed, if desired, from polymer products. The catalysts are used for polymerizing epoxides.
摘要翻译：公开了高活性双金属氰化物（DMC）催化剂。催化剂包含DMC复合物和有机络合剂，和约5至约80wt。基于催化剂的量，数均分子量大于约500的聚醚。还公开了制备催化剂的方法。催化剂易于制备，具有特殊的活性，并且如果需要，可以从聚合物产物中容易地除去。催化剂用于聚合环氧化物。

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