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1. 发明授权

US06372879B1 Polyester polycondensation with catalyst and a catalyst enhancer 失效
标题翻译：与催化剂和催化剂增强剂的聚酯缩聚
公开(公告)号：US06372879B1
公开(公告)日：2002-04-16
申请号：US09895990
申请日：2001-06-29
申请人： Conor M. Dowling , Bin Chen , Sri R. Seshadri
发明人： Conor M. Dowling , Bin Chen , Sri R. Seshadri
IPC分类号： C08G6302
CPC分类号： C08G63/85 , B01J21/063 , B01J31/04 , B01J31/2239 , B01J31/26 , B01J2531/0205 , B01J2531/10 , B01J2531/20 , B01J2531/46 , B01J2531/52 , C08G63/82 , C08G63/83 , C08G63/84 , C08G63/87
摘要： The present invention is based upon the discovery that nontitanyl oxalates can enhance the catalytic functionality of titanyl oxalate catalysts. This invention provides a novel catalytic composition containing a titanyl oxalate catalyst and a metallic oxalate catalyst enhancer and optionally containing a metallic cocatalyst such as an antimony based catalyst. A synergistic relationship has been discovered between titanyl oxalate catalyst and the catalyst enhancer. A synergistic relationship has also been discovered between the titanyl oxalate catalyst, catalyst enhancer and a metallic cocatalyst such as antimony oxide or antimony triacetate. Also provided is an improved process of producing polyester by the polycondensation of polyester forming reactants in the presence of a catalytically effective amount of a polycondensation catalyst, wherein the improvement comprises utilizing, as the polycondensation catalyst, the novel catalyst composition containing a titanyl oxalate such as lithium titanyl oxalate and a catalyst enhancer such as a nontitanyl metallic oxalate like lithium oxalate and optionally containing a metallic catalyst such as antimony oxide or antimony triacetate. The improved process produces an improved polyester having lower acetaldehyde numbers and good color. The titanyl oxalate/catalyst enhancer composition can be used as a polycondensation catalyst in combination with other catalysts to achieve synergistic catalytic activity. Preferred is a combination of lithium or potassium titanyl oxalate, Li2 or K2TiO(C2O4)2, lithium or potassium oxalate, Li2 or K2(C2O4)2 with antimony oxide or antimony triacetate or antimony trisglycoxide.
摘要翻译：本发明基于以下发现，即草酸钛酸酯可以增强草酸氧钛催化剂的催化功能。本发明提供一种含有草酸氧钛催化剂和金属草酸盐催化剂增强剂并任选地含有金属助催化剂如锑基催化剂的新型催化组合物。在草酸氧钛催化剂和催化剂增强剂之间已经发现协同关系。在草酸氧钛催化剂，催化剂增强剂和金属助催化剂如氧化锑或三乙酸锑之间也发现了协同关系。还提供了通过在催化有效量的缩聚催化剂存在下，通过聚酯形成反应物的缩聚来生产聚酯的改进方法，其中改进包括利用含有草酸氧钛的新型催化剂组合物作为缩聚催化剂，草酸氧钛酸锂和催化剂增强剂如非钛酸金属草酸盐如草酸锂，并任选地含有金属催化剂如氧化锑或三乙酸锑。改进的方法产生具有较低乙醛数和良好颜色的改进的聚酯。草酸氧钛/催化剂增强剂组合物可以与其它催化剂组合用作缩聚催化剂以实现协同催化活性。优选的是草酸锂或钾钛酸盐，Li 2或K 2 TiO（C 2 O 4）2，草酸锂或钾，Li 2或K 2（C 2 O 4）2与氧化锑或三乙酸锑或三羟基氧化锑的组合。

2. 发明授权

US06258925B1 Polyester polycondensation with titanyl oxalate catalyst and a catalyst enhancer 失效
标题翻译：与草酸氧钛催化剂和催化剂增强剂的聚酯缩聚
公开(公告)号：US06258925B1
公开(公告)日：2001-07-10
申请号：US09747115
申请日：2000-12-22
申请人： Conor M. Dowling , Sri R. Seshadri
发明人： Conor M. Dowling , Sri R. Seshadri
IPC分类号： C08G6302
CPC分类号： B01J31/2239 , B01J21/063 , B01J23/18 , B01J31/04 , B01J31/22 , B01J31/26 , B01J31/38 , B01J2531/0216 , B01J2531/10 , B01J2531/11 , B01J2531/13 , B01J2531/46 , C07F7/28 , C08G63/82 , C08G63/83 , C08G63/84 , C08G63/85 , C08G63/87
摘要： The present invention is based upon the discovery that nontitanyl oxalates can enhance the catalytic functionality of titanyl oxalate catalysts. This invention provides a novel catalytic composition containing a titanyl oxalate catalyst and a metallic oxalate catalyst enhancer and optionally containing a metallic cocatalyst such as an antimony based catalyst. A synergistic relationship has been discovered between titanyl oxalate catalyst and the catalyst enhancer. A synergistic relationship has also been discovered between the titanyl oxalate catalyst, catalyst enhancer and a metallic cocatalyst such as antimony oxide or antimony triacetate. Also provided is an improved process of producing polyester by the polycondensation of polyester forming reactants in the presence of a catalytically effective amount of a polycondensation catalyst, wherein the improvement comprises utilizing, as the polycondensation catalyst, the novel catalyst composition containing a titanyl oxalate such as lithium titanyl oxalate and a catalyst enhancer such as a nontitanyl metallic oxalate like lithium oxalate and optionally containing a metallic catalyst such as antimony oxide or antimony triacetate. The improved process produces an improved polyester having lower acetaldehyde numbers and good color. The titanyl oxalate/catalyst enhancer composition can be used as a polycondensation catalyst in combination with other catalysts to achieve synergistic catalytic activity. Preferred is a combination of lithium titanyl oxalate, Li2TiO(C2O4)2, lithium oxalate, Li2(C2O4)2 with antimony oxide or antimony triacetate or antimony trisglycoxide.
摘要翻译：本发明基于以下发现，即草酸钛酸酯可以增强草酸氧钛催化剂的催化功能。本发明提供一种含有草酸氧钛催化剂和金属草酸盐催化剂增强剂并任选地含有金属助催化剂如锑基催化剂的新型催化组合物。在草酸氧钛催化剂和催化剂增强剂之间已经发现协同关系。在草酸氧钛催化剂，催化剂增强剂和金属助催化剂如氧化锑或三乙酸锑之间也发现了协同关系。还提供了通过在催化有效量的缩聚催化剂存在下，通过聚酯形成反应物的缩聚来生产聚酯的改进方法，其中改进包括利用含有草酸氧钛的新型催化剂组合物作为缩聚催化剂，草酸氧钛酸锂和催化剂增强剂如非钛酸金属草酸盐如草酸锂，并任选地含有金属催化剂如氧化锑或三乙酸锑。改进的方法产生具有较低乙醛数和良好颜色的改进的聚酯。草酸氧钛/催化剂增强剂组合物可以与其它催化剂组合用作缩聚催化剂以实现协同催化活性。优选草酸氧钛锂，二氧化钛（C 2 O 4）2，草酸锂，Li 2（C 2 O 4）2与氧化锑或三乙酸锑或三氧化锑的组合。

3. 发明申请

US20080255215A1 Combinations of Alkylalkanolamines and Alkylbisalkanolamines for Antimicrobial Compositions 审中-公开
标题翻译：烷基链烷醇胺和烷基双链烷醇胺的组合用于抗微生物组合物
公开(公告)号：US20080255215A1
公开(公告)日：2008-10-16
申请号：US12066691
申请日：2006-08-31
申请人： Michael D. Gernon , Conor M. Dowling
发明人： Michael D. Gernon , Conor M. Dowling
IPC分类号： A01N43/80 , A01N25/00
CPC分类号： A01N33/08 , A01N25/02 , A01N43/80 , A01N2300/00
摘要： An antimicrobial composition includes an effective amount of a biocide, and a biocide enhancer consisting of one or more compounds according to formula (I) and one or more compounds according to formula (II): R1—NH—CH2CHR3OH (I) R2—NH(CH2CHR4OH)2 (II) wherein R1 and R2 are each individually selected from the group consisting of branched and linear C4 to C16 alkyl groups and wherein R3 and R4 are each individually H or methyl. Compositions incorporating these antimicrobial formulations may include treated fluids, for example organic fluids or mixtures of organic fluids and aqueous fluids. Such treated compositions may be used for metalworking or for any of a number of other applications.
摘要翻译：抗微生物组合物包括有效量的杀生物剂和由一种或多种根据式（I）的化合物和一种或多种根据式（II）的化合物组成的杀生物剂增强剂：<？in-line-formula description =“In 线式“end =”lead“→R 1→-NH-CH 2 CHR 3 OH（I）<？ -formulae description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> R （CH 2）CHR 4 OH）2（II）<？in-line-formula description =“In-line Formulas”end =“ 其中R 1和R 2各自独立地选自支链和直链的C 4至C 16烷基，并且其中R 3，R 3， SUP>和R 4各自各自为H或甲基。结合这些抗微生物制剂的组合物可以包括处理过的流体，例如有机流体或有机流体和含水流体的混合物。这种处理的组合物可用于金属加工或用于许多其它应用中的任何一种。

4. 发明申请

US20100041801A1 AMINE NEUTRALIZING AGENTS FOR LOW VOLATILE COMPOUND ORGANIC PAINTS 审中-公开
标题翻译：用于低挥发性有机涂料的胺中和剂
公开(公告)号：US20100041801A1
公开(公告)日：2010-02-18
申请号：US12521924
申请日：2008-01-03
申请人： Conor M. Dowling , Michael D. Gernon , Nicholas M. Martyak
发明人： Conor M. Dowling , Michael D. Gernon , Nicholas M. Martyak
IPC分类号： C08K5/17
CPC分类号： C09D5/024 , C08K5/17 , C09D5/027 , C09D7/63
摘要： Latex paint formulations that contain at least one N-alkyldialkanolamine as the neutralizing agent and methods for their use are disclosed. N-alkyldialkanolamines provide paint formulations that have low odor, increased open time, and reduced volatile organic compounds (VOC). N-alkyldialkanolamines also aid in pigment dispersion so less pigment dispersant is required for paint formulations in which the pigment volume concentration (PVC) of the formulation is 10% to 70%.
摘要翻译：公开了含有至少一种N-烷基二烷醇胺作为中和剂的乳胶漆配方及其使用方法。 N-烷基二烷醇胺提供具有低气味，增加的开放时间和降低的挥发性有机化合物（VOC）的油漆制剂。 N-烷基二烷醇胺还有助于颜料分散，因此制剂的颜料体积浓度（PVC）为10％至70％的涂料配方需要较少的颜料分散剂。

5. 发明授权

US08231694B2 Use of mixtures of alkylalkanolamines and alkylhydroxylamines as stabilizers for alkyl ester fuels 有权
标题翻译：使用烷基链烷醇胺和烷基羟胺的混合物作为烷基酯燃料的稳定剂
公开(公告)号：US08231694B2
公开(公告)日：2012-07-31
申请号：US12303972
申请日：2007-05-23
申请人： Michael D. Gernon , Nicholas M. Martyak , Conor M. Dowling
发明人： Michael D. Gernon , Nicholas M. Martyak , Conor M. Dowling
IPC分类号： C10L1/18 , C10L1/22
CPC分类号： C10L1/22 , C10L1/2225 , C10L1/23
摘要： A stabilized alkyl ester fuel is disclosed. The stabilized alkyl ester fuel comprises alkyl esters, an effective amount of an alkylalkanolamine, and an effective amount of an alkylhydroxylamine. The alkyl ester fuel is stabilized to oxidative degradation of the alkyl esters of unsaturated fatty acids found in alkyl ester fuels.
摘要翻译：公开了一种稳定的烷基酯燃料。稳定的烷基酯燃料包括烷基酯，有效量的烷基链烷醇胺和有效量的烷基羟胺。烷基酯燃料被稳定以在烷基酯燃料中发现的不饱和脂肪酸的烷基酯的氧化降解。

6. 发明申请

US20110154724A1 FATTY ESTER COMPOSITIONS WITH IMPROVED OXIDATIVE STABILITY 审中-公开
标题翻译：脂肪酯组合物具有改善的氧化稳定性
公开(公告)号：US20110154724A1
公开(公告)日：2011-06-30
申请号：US13059375
申请日：2009-08-28
申请人： Nicholas M. Martyak , Daniel Alford , Conor M. Dowling , Michael D. Gernon
发明人： Nicholas M. Martyak , Daniel Alford , Conor M. Dowling , Michael D. Gernon
IPC分类号： C10L1/00 , C10L1/232 , C10L1/22 , C10L1/18
CPC分类号： C11B5/005 , C10L1/14 , C10L1/19 , C10L1/22 , C10L1/2225 , C10L1/23 , C10L1/232 , C10L1/2412 , C10L1/2425
摘要： Compositions containing unsaturated fatty esters may be stabilized against atmospheric oxidation by the addition of an antioxidant package containing at least one nitroxide free-radical scavenger and at least one alkylalkanolamine. Compositions treated in this manner show good resistance to atmospheric oxidation and resultant viscosity increase. An advantage of the nitroxide free-radical scavenger is that it stops the oxidation of the unsaturated fatty esters already during the initiation stage. Moreover, it is much less volatile than for example the known alkylhydroxylamine oxygen scavengers. By the use of a nitroxide free-radical scavenger, the composition can thus be stabilized for a longer period of time. The stability period is moreover less affected by the supply of oxygen to the composition. The solubility problem of the nitroxide in the fatty ester component can be solved by dissolving the nitroxide first in the alkylalkanolamine.
摘要翻译：含有不饱和脂肪酸酯的组合物可以通过加入含有至少一种氮氧自由基清除剂和至少一种烷基链烷醇胺的抗氧化剂包装来稳定，防止大气氧化。以这种方式处理的组合物显示出良好的耐大气氧化性和最终的粘度增加。硝基氧自由基清除剂的优点是在起始阶段已经停止了不饱和脂肪酸酯的氧化。此外，它比例如已知的烷基羟胺氧清除剂挥发性低得多。通过使用氮氧自由基清除剂，组合物因此可以稳定更长时间。此外，稳定期较少受到组合物供氧的影响。通过将氮氧化物首先溶解在烷基链烷醇胺中可以解决氮氧化物在脂肪酸酯组分中的溶解度问题。

7. 发明申请

US20100175310A1 ACRYLIC POLYMER LOW TEMPERATURE FLOW MODIFIERS IN BIO-DERIVED FUELS 有权
标题翻译：生物燃料中的丙烯酸聚合物低温流动改性剂
公开(公告)号：US20100175310A1
公开(公告)日：2010-07-15
申请号：US12601341
申请日：2008-06-11
申请人： Nicholas M. Martyak , Noah E. Macy , Michael D. Gernon , Scott C. Schmidt , Conor M. Dowling
发明人： Nicholas M. Martyak , Noah E. Macy , Michael D. Gernon , Scott C. Schmidt , Conor M. Dowling
IPC分类号： C10L1/196
CPC分类号： C10L1/1963 , C08F293/005 , C10G2300/1011 , C10L1/00 , C10L1/026 , C10L1/143 , C10L10/14 , C10L10/16 , Y02P30/20
摘要： The present invention relates to acrylic block polymers, either block copolymers or homopolymers, synthesized by a controlled free-radical process, and their use as low temperature flow modifiers in bio-derived fuel compositions. They are especially useful in modifying the low temperature flow behavior in bio-derived fuels. The acrylic polymers are especially useful as cold filter plugging control additives in bio-derived fuels.
摘要翻译：本发明涉及通过控制的自由基方法合成的丙烯酸嵌段聚合物，嵌段共聚物或均聚物，以及它们在生物衍生燃料组合物中作为低温流动改性剂的用途。它们在改变生物衍生燃料中的低温流动行为方面特别有用。丙烯酸聚合物特别适用于生物衍生燃料中的冷滤器堵塞控制添加剂。

8. 发明申请

US20080209798A1 Method of Reducing Fuel Corrosiveness 审中-公开
标题翻译：降低燃料腐蚀性的方法
公开(公告)号：US20080209798A1
公开(公告)日：2008-09-04
申请号：US11996129
申请日：2006-06-26
申请人： Michael D. Gernon , Nicholas M. Martyak , Conor M. Dowling , Daniel Alford
发明人： Michael D. Gernon , Nicholas M. Martyak , Conor M. Dowling , Daniel Alford
IPC分类号： C10L1/222
CPC分类号： C10L1/2225 , C10L10/04
摘要： Fuels containing biodiesel, petroleum distillates, or blends of these may be treated by the addition of small amounts of one or more alkanolamines according to formula (I) Rn—N(CH2CHR1OH)3-n ; (I) wherein n is 1 or 2, R1 is H or CH3, and each R is independently selected from the group consisting of hydrogen and branched, linear, and cyclic C3-C24 alkyl groups, provided that at least one R is not hydrogen. Fuels treated in this manner may be less corrosive toward metals with which they are in contact.
摘要翻译：含有生物柴油，石油馏分或这些混合物的燃料可以通过加入少量根据式（I）的一种或多种链烷醇胺来处理<？in-line-formula description =“In-Line Formulas”end =“lead “ - > R n -N（CH 2 CHR 1 OH）3-n （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中n为1或2，R 1为H或CH 3， / SUB，并且每个R独立地选自氢和支链，直链和环状的C 3 -C 24烷基，条件是至少一个R不是氢。以这种方式处理的燃料对与其接触的金属的腐蚀性较小。

9. 发明授权

US08236069B2 Acrylic polymer low temperature flow modifiers in bio-derived fuels 有权
标题翻译：丙烯酸聚合物低温流动改性剂在生物衍生燃料中
公开(公告)号：US08236069B2
公开(公告)日：2012-08-07
申请号：US12601341
申请日：2008-06-11
申请人： Nicholas M. Martyak , Noah E. Macy , Michael D. Gernon , Scott C. Schmidt , Conor M. Dowling
发明人： Nicholas M. Martyak , Noah E. Macy , Michael D. Gernon , Scott C. Schmidt , Conor M. Dowling
IPC分类号： C10L1/18
CPC分类号： C10L1/1963 , C08F293/005 , C10G2300/1011 , C10L1/00 , C10L1/026 , C10L1/143 , C10L10/14 , C10L10/16 , Y02P30/20
摘要： The present invention relates to acrylic block polymers, either block copolymers or homopolymers, synthesized by a controlled free-radical process, and their use as low temperature flow modifiers in bio-derived fuel compositions. They are especially useful in modifying the low temperature flow behavior in bio-derived fuels. The acrylic polymers are especially useful as cold filter plugging control additives in bio-derived fuels.
摘要翻译：本发明涉及通过控制的自由基方法合成的丙烯酸嵌段聚合物，嵌段共聚物或均聚物，以及它们在生物衍生燃料组合物中作为低温流动改性剂的用途。它们在改变生物衍生燃料中的低温流动行为方面特别有用。丙烯酸聚合物特别适用于生物衍生燃料中的冷滤器堵塞控制添加剂。

10. 发明申请

US20110203167A1 USE OF MIXTURES OF ALKYLALKANOLAMINES AND ALKYLHYDROXYLAMINES AS STABILIZERS FOR ALKYL ESTER FUELS 有权
标题翻译：作为烷基酯燃料的稳定剂使用烷基醇胺和烷基羟基甲硅烷的混合物
公开(公告)号：US20110203167A1
公开(公告)日：2011-08-25
申请号：US12303972
申请日：2007-05-23
申请人： Michael D. Gernon , Nicholas M. Martyak , Conor M. Dowling
发明人： Michael D. Gernon , Nicholas M. Martyak , Conor M. Dowling
IPC分类号： C10L1/19
CPC分类号： C10L1/22 , C10L1/2225 , C10L1/23
摘要： A stabilized alkyl ester fuel is disclosed. The stabilized alkyl ester fuel comprises alkyl esters, an effective amount of an alkylalkanolamine, and an effective amount of an alkylhydroxylamine. The alkyl ester fuel is stabilized to oxidative degradation of the alkyl esters of unsaturated fatty acids found in alkyl ester fuels.
摘要翻译：公开了一种稳定的烷基酯燃料。稳定的烷基酯燃料包括烷基酯，有效量的烷基链烷醇胺和有效量的烷基羟胺。烷基酯燃料被稳定以在烷基酯燃料中发现的不饱和脂肪酸的烷基酯的氧化降解。

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