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61. 发明授权

US08299196B2 Adhesive composition 有权
标题翻译：粘合剂组合物
公开(公告)号：US08299196B2
公开(公告)日：2012-10-30
申请号：US13085510
申请日：2011-04-13
申请人： Mikio Shiono , Noriyuki Koike
发明人： Mikio Shiono , Noriyuki Koike
IPC分类号： C08G77/08
CPC分类号： C09D183/08 , C08G77/24 , C08L71/02
摘要： An adhesive composition is provided comprising (A) a fluorinated amide compound containing at least two vinyl groups and having a polyfluoro structure, (B) a fluorinated organosilicon compound containing a fluorinated organic group, at least two SiH groups, and an alkyl, aryl or aralkyl group, and (C) a platinum catalyst, and (D) an organosiloxane containing a SiH group and an epoxy and/or trialkoxysilyl group. The composition is cured on brief heating into a product which achieves adhesion to various substrates and has solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability, electric insulation, and acid resistance.
摘要翻译：提供一种粘合剂组合物，其包含（A）含有至少两个乙烯基并具有多氟结构的氟化酰胺化合物，（B）含氟化有机基团的氟化有机硅化合物，至少两个SiH基团和烷基，芳基或芳族烷基，（C）铂催化剂，（D）含有SiH基和环氧基和/或三烷氧基甲硅烷基的有机硅氧烷。该组合物在短暂加热下固化成实现对各种基材的粘合性的产品，并具有耐溶剂性，耐化学性，耐热性，低温性，低透湿性，电绝缘性和耐酸性。

62. 发明授权

US5874617A Process of producing anilide compound 失效
标题翻译：酰苯胺化合物的制备方法
公开(公告)号：US5874617A
公开(公告)日：1999-02-23
申请号：US008302
申请日：1998-01-16
申请人： Shinichi Sato , Noriyuki Koike
发明人： Shinichi Sato , Noriyuki Koike
IPC分类号： C07C231/02 , C07C235/16 , C07F7/08 , C07C209/02
CPC分类号： C07F7/0818 , C07C231/02 , C07C235/16 , C07F7/083
摘要： A process of producing an anilide compound, including reacting an acid fluoride with an N-silylaniline compound in the presence of a basic compound, is provided. According to the process, a desired anilide compound can be produced in a high yield without requiring a filtering step.
摘要翻译：提供了在碱性化合物存在下，使酰氟化物与N-甲硅烷基苯胺化合物反应的酰苯胺化合物的制造方法。根据该方法，可以高产率地制备所需的酰苯胺化合物，而不需要过滤步骤。

63. 发明授权

US5414119A Hexafluoropropylene oxide compounds and a method of making same 失效
标题翻译：六氟环氧丙烷化合物及其制备方法
公开(公告)号：US5414119A
公开(公告)日：1995-05-09
申请号：US203250
申请日：1994-03-01
申请人： Yasuo Tarumi , Noriyuki Koike , Toshio Takago
发明人： Yasuo Tarumi , Noriyuki Koike , Toshio Takago
IPC分类号： C07C59/60 , C07C51/58
CPC分类号： C07C59/60
摘要： Hexafluoropropylene oxide (HFPO) compounds, including polymers, expressed by the general chemical formula (1) below: ##STR1## wherein R.sup.1 is a single bond, an alkylene group of 1 to 10 carbon atoms, or said alkylene group in which a part of, or all of, the hydrogen atoms are substituted by fluorine atoms, Rf is a fluorine atom, a perfluoroalkyl group of 1 to 10 carbon atoms, or a perfluoroalkyl ether group, and n is 0 or an integer of at least 1. A manufacturing method for the HFPO compounds which is characterized by the reaction between hexafluoropropylene oxide and a vinyl group containing compound, expressed by the general chemical formula (2) below: ##STR2## wherein R.sup.1 and Rf are same as above. The compounds have utility as important intermediate raw materials for the production of novel functional silicone compounds having HFPO polymer units.
摘要翻译：由下列通式（1）表示的六氟环氧丙烷（HFPO）化合物，包括聚合物：其中R 1为单键，1至10个碳原子的亚烷基或所述亚烷基，其中一部分或全部氢原子被氟原子取代，Rf为氟原子，1-10个碳原子的全氟烷基或全氟烷基醚基，n为0或至少为1的整数以下通式（2）表示的特征在于六氟环氧丙烷与含乙烯基的化合物反应的HFPO化合物的制造方法：其中R1和Rf与上述相同。该化合物可用作生产具有HFPO聚合物单元的新型功能硅氧烷化合物的重要中间体原料。

64. 发明授权

US5278340A Oligohexafluoropropylene oxide derivative and process of producing the same 失效
标题翻译：低聚六氟环氧丙烷衍生物及其制备方法
公开(公告)号：US5278340A
公开(公告)日：1994-01-11
申请号：US903967
申请日：1992-06-26
申请人： Noriyuki Koike , Masayuki Oyama , Toshio Takago
发明人： Noriyuki Koike , Masayuki Oyama , Toshio Takago
IPC分类号： C08G65/00 , C07C43/12 , C07C51/58 , C07C59/135 , C07C59/315 , C08G65/22 , C08G65/32 , C07C51/04
CPC分类号： C08G65/226 , C07C59/135 , C07C59/315
摘要： Oligohexafluoropropylene oxide derivatives represented by the general formula (I): ##STR1## wherein R.sub.f represents a perfluoroalkyl group having 1 to 10 carbon atoms and n is an integer of 0 to 100 or the general formula (II): ##STR2## wherein R.sub.f ' represents a perfluoroalkylene group having 2 to 10 carbon atoms and a and b are each independently an integer of 0 to 20. These compounds are novel and are useful as intermediates for synthesizing iodine-containing oligohexafluoropropylene oxides useful as raw materials for fluororesins, fluororubbers, and fluorine-containing surfactants.
摘要翻译：由通式（I）表示的低聚六氟环氧丙烷衍生物：（*化学结构*）（I）其中，Rf表示碳原子数1〜10的全氟烷基，n表示0〜100的整数或通式（II）：（*化学结构*）（II）其中Rf'表示具有2〜10个碳原子的全氟亚烷基，a和b各自独立地为0〜20的整数。这些化合物是新的，可用作合成含碘的中间体可用作氟树脂，氟橡胶和含氟表面活性剂的原料的低聚六氟环氧丙烷。

65. 发明授权

US5101057A Fluorinated carboxylic acid derivatives and methods for making 失效
标题翻译：氟化羧酸衍生物及其制备方法
公开(公告)号：US5101057A
公开(公告)日：1992-03-31
申请号：US562320
申请日：1990-08-03
申请人： Shinichi Satoh , Noriyuki Koike , Hideki Fujii
发明人： Shinichi Satoh , Noriyuki Koike , Hideki Fujii
IPC分类号： B01J31/22 , C07B61/00 , C07F7/12 , C07F7/18
CPC分类号： C07F7/1896 , C07F7/182 , C07F7/1828 , C07F7/1836
摘要： Novel fluorinated carboxylic acid derivatives of the general formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently selected from substituted or unsubstituted monovalent hydrocarbon groups, Rf is a divalent perfluoroalkyl or perfluoropolyether group, X is a hydrogen atom or triorganosilyl group, and a is equal to 2 or 3 are useful curing catalysts for RTV organopolysiloxane compositions. These fluorinated carboxylic acid derivatives are prepared by effecting hydrosilylation between alkenyl-containing fluorinated carboxylic acid derivatives and hydrosilanes in the presence of catalysts.
摘要翻译：新的具有以下通式的氟化羧酸衍生物：其中R 1和R 2独立地选自取代或未取代的一价烃基，R f是二价全氟烷基或全氟聚醚基团，X是氢原子或三有机甲硅烷基，和 a等于2或3是用于RTV有机聚硅氧烷组合物的有用固化催化剂。这些氟化羧酸衍生物通过在催化剂存在下进行含烯基的含氟羧酸衍生物和氢化硅烷之间的氢化硅烷化来制备。

66. 发明授权

US4987267A Oligohexafluoropropylene oxide compound terminated with vinyl group at its one end 失效
标题翻译：在其一端用乙烯基封端的六氟环氧丙烷化合物
公开(公告)号：US4987267A
公开(公告)日：1991-01-22
申请号：US463349
申请日：1990-01-11
申请人： Akio Takaoka , Noriyuki Koike , Hideki Fujii
发明人： Akio Takaoka , Noriyuki Koike , Hideki Fujii
IPC分类号： C07C43/17 , C08F16/14 , C08F214/26 , C08F216/14 , C08F290/00 , C08F299/00 , C08G77/38 , C08G77/385
CPC分类号： C07C43/17
摘要： An oligohexafluoropropylene oxide compound having the general formula (I): ##STR1## wherein n represents an integer of 2 to 5. The compound is useful for preparing a polymer having good thermal resistance, chemical stability, non-adhesion properties, water and oil repellencies, and flexibility, when copolymerized if other monomers.
摘要翻译：具有通式（I）的低聚六氟环氧丙烷化合物：其中n表示2至5的整数。该化合物可用于制备具有良好耐热性，化学稳定性，非粘合性，水如果其它单体共聚，则具有防油性和柔软性。

67. 发明申请

US20120184100A1 CHEMICALLY AMPLIFIED POSITIVE RESIST COMPOSITION AND PATTERNING PROCESS 审中-公开
标题翻译：化学放大正电阻组合物和图案化方法
公开(公告)号：US20120184100A1
公开(公告)日：2012-07-19
申请号：US13353700
申请日：2012-01-19
申请人： Hiroyuki Yasuda , Katsuya Takemura , Noriyuki Koike
发明人： Hiroyuki Yasuda , Katsuya Takemura , Noriyuki Koike
IPC分类号： H01L21/3205 , G03F7/20 , G03F7/039
CPC分类号： G03F7/0048 , G03F7/0046 , G03F7/0392 , G03F7/0755 , G03F7/0757
摘要： A chemically amplified positive resist composition comprising (A) a substantially alkali insoluble polymer having an acidic functional group protected with an acid labile group, (B) an acid generator, and (C) a perfluoroalkyl ethylene oxide adduct or a nonionic fluorinated organosiloxane compound is coated, exposed to UV radiation having a wavelength of at least 150 nm, and developed. The composition has advantages of uniformity and minimized edge crown upon coating, and no scum formation after development.
摘要翻译：一种化学放大正性抗蚀剂组合物，其包含（A）具有由酸不稳定基团保护的酸性官能团的基本上不溶于碱的聚合物，（B）酸产生剂和（C）全氟烷基环氧乙烷加合物或非离子氟化有机硅氧烷化合物，涂覆，暴露于具有至少150nm的波长的UV辐射，并显影。该组合物具有均匀性和涂覆后边缘冠最小化的优点，并且在显影后没有浮渣形成。

68. 发明授权

US08129435B2 Perfluoropolyether-modified polysiloxane, a method for preparing the same and a defoaming agent comprising the same 有权
标题翻译：全氟聚醚改性聚硅氧烷，其制备方法和包含该聚硅氧烷的消泡剂
公开(公告)号：US08129435B2
公开(公告)日：2012-03-06
申请号：US12817656
申请日：2010-06-17
申请人： Hiromasa Yamaguchi , Noriyuki Koike , Kazuyuki Takewaki
发明人： Hiromasa Yamaguchi , Noriyuki Koike , Kazuyuki Takewaki
IPC分类号： C09K3/00
CPC分类号： C08G77/46 , B01D19/0409
摘要： The present invention relates to a perfluoropolyether-modified polysiloxane represented by general formula (1): wherein Rf is a linear or branched perfluoroalkyl group having 1 to 10 carbon atoms; X is a fluorine atom or a trifluoromethyl group; Q is a divalent organic group having 1 to 12 carbon atoms; R1, R2, and R3 are, independently of each other, an alkyl group having 1 to 10 carbon atoms or an aryl group; a, b, c, and d are, independently of each other, an integer of from 0 to 200, provided that a total of a, b, c and d is 1 or larger; e is an integer of 0 or 1; and z is an integer of from 5 to 100; a method for preparing the same; and a defoaming agent comprising the same.
摘要翻译：本发明涉及由通式（1）表示的全氟聚醚改性聚硅氧烷：其中Rf是具有1-10个碳原子的直链或支链全氟烷基; X是氟原子或三氟甲基; Q为碳原子数1〜12的二价有机基团。 R 1，R 2和R 3彼此独立地为具有1至10个碳原子的烷基或芳基; a，b，c和d彼此独立地为0至200的整数，条件是a，b，c和d的总数为1或更大; e为0或1的整数; z为5〜100的整数。其制备方法; 和包含该消泡剂的消泡剂。

69. 发明授权

US06787662B2 Fluorinated organosilicon compounds 失效
标题翻译：氟化有机硅化合物
公开(公告)号：US06787662B2
公开(公告)日：2004-09-07
申请号：US10287669
申请日：2002-11-05
申请人： Noriyuki Koike , Hiromasa Yamaguchi
发明人： Noriyuki Koike , Hiromasa Yamaguchi
IPC分类号： C07F704
CPC分类号： C08G77/045 , C07F7/0838
摘要： Fluorinated organosilicon compounds having perfluoroalkyl or perfluorooxyalkyl radicals and at least four SiH radicals are highly compatible with base polymers having high fluorine contents and useful as a crosslinking agent therefor to produce addition cured rubber having desired hardness and modulus.
摘要翻译：具有全氟烷基或全氟氧基烷基和至少四个SiH基团的氟化有机硅化合物与具有高氟含量的基础聚合物高度相容，并且可用作交联剂以产生具有所需硬度和模量的加成固化橡胶。

70. 发明授权

US06528562B2 Curable fluoropolyether rubber compositions 有权
公开(公告)号：US06528562B2
公开(公告)日：2003-03-04
申请号：US09901108
申请日：2001-07-10
申请人： Takashi Matsuda , Shinichi Sato , Noriyuki Koike
发明人： Takashi Matsuda , Shinichi Sato , Noriyuki Koike
IPC分类号： C08K518
CPC分类号： C08F8/42 , C08G65/007 , C08G65/336 , C08K5/54 , C08F14/18 , C08L71/00
摘要： A fluoropolyether rubber composition comprising (A) a linear fluoropolyether compound containing at least two alkenyl groups and having a perfluoroalkyl ether structure in its backbone, (B) an organosilicon compound having at least two silicon atom-bound hydrogen atoms which all form H—Si(CaH2a)Si structures wherein “a” is 1, 2 or 3, (C) a hydrosilylation catalyst, and (D) an antidegradant, typically an aromatic secondary amine compound is curable into products having heat resistance, chemical resistance, solvent resistance, parting property, water repellency, oil repellency, and weather resistance as well as resistance to acid, alkali and oxidative degradation.

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