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    • 6. 发明申请
    • MASS SPECTROMETER AND MASS SPECTROMETRY METHOD
    • 质谱仪和质谱方法
    • US20130228682A1
    • 2013-09-05
    • US13885435
    • 2011-11-17
    • Hiroyuki YasudaShinji Yoshioka
    • Hiroyuki YasudaShinji Yoshioka
    • H01J49/14H01J49/00
    • H01J49/14H01J49/0031H01J49/0045H01J49/063H01J49/4255
    • A mass spectrometer is provided including: a collision chamber of generating fragment ions by superimposingly applying an AC voltage and a first DC voltage between linear multipolar electrodes, and accelerating the fragment ions by applying a second DC voltage between a front stage electrode and a later stage electrode; a mass spectrometer unit of carrying out mass separation of the fragment ions; and a control unit of determining the second DC voltage based on the mass-to-charge ratios such that the rates of the fragment ions in the collision chamber become equal regardless of the mass-to-charge ratios. Herein, the control unit increases the second DC voltage as the mass-to-charge ratios selected by the mass spectrometer unit become larger. This allows the mass window to be wider even when a DC electric field is generated in order to solve a crosstalk drawback, in the movement direction of the molecular ions.
    • 提供一种质谱仪,包括:通过在线性多极电极之间叠加施加AC电压和第一DC电压来产生碎片离子的碰撞室,并且通过在前级电极和后级电极之间施加第二DC电压来加速碎片离子 电极; 进行碎片离子的质量分离的质谱仪单元; 以及控制单元,其基于所述质荷比来确定所述第二DC电压,使得所述碰撞室中的碎片离子的速率与所述质荷比无关,变得相等。 这里,当由质谱仪单元选择的质荷比变大时,控制单元增加第二DC电压。 这样即使产生直流电场,为了解决分子离子的移动方向上的串扰缺陷,也可以使质量窗口更宽。