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1. 发明授权

US5004824A Fluorine-containing organosilicon compound 失效
标题翻译：含氟有机硅化合物
公开(公告)号：US5004824A
公开(公告)日：1991-04-02
申请号：US372528
申请日：1989-06-28
申请人： Akio Takaoka , Hiroshi Inomata
发明人： Akio Takaoka , Hiroshi Inomata
IPC分类号： C07F7/12 , C07F7/10 , C08G65/22 , C08G65/24
CPC分类号： C07F7/10
摘要： A novel fluorine-containing organosilicon compound represented by Formula (I): ##STR1## wherein n represents an integer of 0 or more, R.sup.1 and R.sup.2 may be the same or different and each represent a hydrogen atom or a fluorine atom, and R.sup.3 represents an alkylene group having 1 to 6 carbon atoms.This compound is useful as silica treatments, or surface treatments capable of imparting water repellency, oil repellency, etc. on the surface of glassware or the like.
摘要翻译：由式（I）表示的新颖的含氟有机硅化合物：其中n表示0以上的整数，R 1和R 2可以相同或不同，表示氢原子或氟原子， R3表示碳原子数1〜6的亚烷基。该化合物可用作二氧化硅处理或能够在玻璃器皿等表面赋予防水性，拒油性等的表面处理。

2. 发明授权

US4987267A Oligohexafluoropropylene oxide compound terminated with vinyl group at its one end 失效
标题翻译：在其一端用乙烯基封端的六氟环氧丙烷化合物
公开(公告)号：US4987267A
公开(公告)日：1991-01-22
申请号：US463349
申请日：1990-01-11
申请人： Akio Takaoka , Noriyuki Koike , Hideki Fujii
发明人： Akio Takaoka , Noriyuki Koike , Hideki Fujii
IPC分类号： C07C43/17 , C08F16/14 , C08F214/26 , C08F216/14 , C08F290/00 , C08F299/00 , C08G77/38 , C08G77/385
CPC分类号： C07C43/17
摘要： An oligohexafluoropropylene oxide compound having the general formula (I): ##STR1## wherein n represents an integer of 2 to 5. The compound is useful for preparing a polymer having good thermal resistance, chemical stability, non-adhesion properties, water and oil repellencies, and flexibility, when copolymerized if other monomers.
摘要翻译：具有通式（I）的低聚六氟环氧丙烷化合物：其中n表示2至5的整数。该化合物可用于制备具有良好耐热性，化学稳定性，非粘合性，水如果其它单体共聚，则具有防油性和柔软性。

3. 发明授权

US4552694A Fluorinated benzodiazepins 失效
标题翻译：氟化苯并二氮杂
公开(公告)号：US4552694A
公开(公告)日：1985-11-12
申请号：US635681
申请日：1984-07-30
申请人： Nobuo Ishikawa , Akio Takaoka
发明人： Nobuo Ishikawa , Akio Takaoka
IPC分类号： C07D243/12
CPC分类号： C07D243/12
摘要： New fluorinated benzodiazepins are described. They are expressed by the following general formula: ##STR1## wherein A.sup.1 and A.sup.2 are the same or different groups, each expressed by one of the following general formulas ##STR2## R.sup.2 being a hydrogen atom, aliphatic hydrocarbon group, fluorine-substituted aliphatic hydrocarbon group, aminoalkyl, N,N-dialkylaminoalkyl, or alkylsulfonylalkyl group and R.sup.3 a hydrogen atom, aliphatic or aromatic hydrocarbon group, halogen-substituted aliphatic or aromatic hydrocarbon group, while R.sup.1 is a hydrogen atom, aliphatic or aromatic hydrocarbon group, fluorine-substituted aliphatic or aromatic hydrocarbon group and X is a hydrogen atom, aliphatic hydrocarbon group, fluorine-substituted aliphatic hydrocarbon group, halogen atom, nitro group or the like.
摘要翻译：描述了新的氟化苯并二氮杂。它们由以下通式表示：其中A 1和A 2是相同或不同的基团，各自由以下通式之一表示：R 2是氢原子，脂族烃基，氟取代的脂族烃基团，氨基烷基，N，N-二烷基氨基烷基或烷基磺酰基烷基，R 3为氢原子，脂族或芳族烃基，卤素取代的脂族或芳族烃基，而R1为氢原子，脂族或芳族烃基，氟取代脂肪族或芳香族烃基，X为氢原子，脂肪族烃基，氟取代脂肪族烃基，卤素原子，硝基等。

4. 发明授权

US4540524A Methods for preparing lower alkyl .alpha.-fluoro-.alpha.-cyanoacetate and its carbanion 失效
标题翻译：制备低级烷基α-氟-α-氰基乙酸酯及其碳阴离子的方法
公开(公告)号：US4540524A
公开(公告)日：1985-09-10
申请号：US669178
申请日：1984-11-07
申请人： Nobuo Ishikawa , Akio Takaoka
发明人： Nobuo Ishikawa , Akio Takaoka
IPC分类号： C07C255/32 , C07C121/00
CPC分类号： C07C255/00
摘要： A method for preparing lower alkyl .alpha.-fluoro-.alpha.-cyanoacetate and its carbanion by reacting hexafluoropropene with ammonia, and then reacting the obtained product with an alkali hydroxide in a lower alkyl alcohol. The carbanion is prepared by reacting the product .alpha.-fluoro-.alpha.-cyanoacetate with an alkali fluoride.
摘要翻译：通过六氟丙烯与氨反应制备低级烷基α-氟-α-氰基乙酸酯及其碳负离子的方法，然后使所得产物与低级烷基醇中的碱金属氢氧化物反应。碳负离子是通过使α-氟-α-氰基乙酸酯与碱金属氟化物反应来制备的。

5. 发明授权

US4614742A Fluorinated isophthalonitrile compound and nonmedical fungicide containing the same 失效
标题翻译：氟化间苯二腈化合物和含有相同的非医药杀真菌剂
公开(公告)号：US4614742A
公开(公告)日：1986-09-30
申请号：US770481
申请日：1985-08-29
申请人： Nobuo Ishikawa , Akio Takaoka , Takashi Isono , Masatoshi Motoyoshi , Kazuhiro Kojima
发明人： Nobuo Ishikawa , Akio Takaoka , Takashi Isono , Masatoshi Motoyoshi , Kazuhiro Kojima
IPC分类号： A01N37/40 , A01N37/44 , A01N39/00 , A01N43/08 , A01N43/48 , A01N43/50 , A01N43/52 , A01N43/54 , A01N43/653 , C07C255/53 , C07C255/58 , C07D235/30 , C07D239/46 , C07D239/54 , C07D239/553 , C07D249/14 , C07D307/12 , C07D521/00 , A01N43/84 , A01N37/34 , C07C121/78
CPC分类号： C07D239/47 , A01N37/40 , A01N37/44 , A01N39/00 , A01N43/08 , A01N43/50 , A01N43/52 , A01N43/54 , A01N43/653 , C07C255/00 , C07C323/00 , C07D231/12 , C07D233/56 , C07D235/30 , C07D239/553 , C07D249/08 , C07D249/14 , C07D307/12
摘要： A fluorinated isophthalonitrile compound having the general formula ##STR1## wherein Y is --O, --S, or --N(R'), R and R' are independently hydrogen, an alkyl group, an alkyl group, an alkynyl group, a haloalkyl group, an alkoxyl group, alkoxyalkyl group, a phenyl group which may be substituted, a tetrahydrofurfuryl group, or a cycloalkyl group, provided that, in the case of Y=--N(R'), R and R' or Y may be a tetrahydrofurfuryl group, or a cycloalkyl group, a heterocyclic compound residue.This fluorinated isophthalonitrile compound is suitable for use as an agricultural fungicide.
摘要翻译：具有通式为其中Y为-O，-S或-N（R'）的通式（I）的氟化间苯二腈化合物，R和R'独立地为氢，烷基，烷基，炔基卤代烷基，烷氧基，烷氧基烷基，可被取代的苯基，四氢糠基或环烷基，条件是在Y = -N（R'），R和R'或 Y可以是四氢糠基，或环烷基，杂环化合物残基。该氟化的间苯二腈化合物适合用作农业杀真菌剂。

6. 发明授权

US5099053A Fluorine-containing organic silicon compounds and a manufacturing method thereof 失效
标题翻译：含氟有机硅化合物及其制造方法
公开(公告)号：US5099053A
公开(公告)日：1992-03-24
申请号：US528425
申请日：1990-05-25
申请人： Akio Takaoka , Noriyuki Koike , Hideki Fujii
发明人： Akio Takaoka , Noriyuki Koike , Hideki Fujii
IPC分类号： C07F7/08 , C07F7/12
CPC分类号： C07F7/12 , C07F7/0818
摘要： Fluorine-containing organic silicon compounds represented by the following general formula: ##STR1## wherein n is any integer of 1 to 4, and x is any integer or 0 to 3; and a method of manufacturing the same compounds consisting of hydrosilylization between a hexafluoropropeneoxide oligoether derivative having an isopropenyl group at one end represented by the following formula: ##STR2## wherein n is any integer from 1 to 4, and a silane represented by the following formula: ##STR3## wherein x is any integer from 0 to 3.
摘要翻译：由以下通式表示的含氟有机硅化合物：其中n是1至4的整数，x是任何整数或0至3; 以及由下式表示的一端具有异丙烯基的六氟丙烯类低聚醚衍生物之间的氢化甲硅烷基化的相同化合物的制造方法：其中n为1〜4的整数，由下式表示的硅烷：其中x是从0到3的任何整数。

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