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    • 61. 发明授权
    • Process for the preparation of hydroxyphenylpropionic acid esters
    • 羟基苯丙酸酯的制备方法
    • US5206414A
    • 1993-04-27
    • US876813
    • 1992-04-29
    • Samuel EvansPaul DubsMilos RusekZdenek MazourArpad Major
    • Samuel EvansPaul DubsMilos RusekZdenek MazourArpad Major
    • C07C67/03C07C67/347C07C69/732
    • C07C67/03C07C67/347
    • A process for the preparation of compounds of the general formula ##STR1## where R.sub.1 and R.sub.2 are identical or different and are hydrogen, C.sub.1 -C.sub.18 alkyl, phenyl, C.sub.1 -C.sub.4 alkyl-substituted phenyl, C.sub.7 -C.sub.9 phenylalkyl, C.sub.5 -C.sub.12 cycloalkyl or C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.12 cycloalkyl,R.sub.3 is hydrogen or methyl,m is 0, 1, 2 or 3, andn is a number from 1 to 4 or 6, andA is as defined in the description,by reacting a compound of the formula II ##STR2## where m, R.sub.1 and R.sub.2 are as defined above, with a compound of the formula III ##STR3## where A and n are as defined in the description, which comprises carrying out the reaction in the presence of a catalyst which contains, as active material, an alkali metal compound of the formula IVM.sub.m An (IV)in whichM is Li, Na, K, Rb or Cs,m is the valency of An, andAn is a fluoride, hydroxide, phosphate, formate, acetate or --OR.sub.5 radical, andR.sub.5 is alkyl having 1 to 4 carbon atoms or phenyl,and, as support, an alkaline material which, measured in 10% strength by weight aqueous suspension, has a pH>10, selected from one or more groups of substances from the series comprising the alkaline earth metal oxides, hydroxides, aluminates or silicates.
    • 制备通式为(I)的化合物的方法,其中R 1和R 2相同或不同,为氢,C 1 -C 18烷基,苯基,C 1 -C 4烷基取代的苯基,C 7 -C 9苯基烷基,C 5 -C 12环烷基或 C 1 -C 4烷基取代的C 5 -C 12环烷基,R 3是氢或甲基,m是0,1,2或3,n是1至4或6的数,A如说明书中所定义,通过化合物 式(II)其中m,R 1和R 2如上定义,与式IIIA(H)n,(III)的化合物反应,其中A和n如说明书中所定义,其包含 在含有M为Li,Na,K,Rb或Cs的式IV MmAn(IV)的碱金属化合物作为活性物质的催化剂存在下进行反应,m为An的化合价, 并且An是氟化物,氢氧化物,磷酸盐,甲酸盐,乙酸盐或-OR 5基团,R 5是具有1至4个碳原子的烷基或苯基,作为载体,碱性物质以10% 重量百分比的含水悬浮液,pH> 10,选自一组或多组来自包含碱土金属氧化物,氢氧化物,铝酸盐或硅酸盐的系列的物质。
    • 65. 发明授权
    • Phenol phosphorus compounds as polyolefin stabilizers
    • 酚类磷化合物作为聚烯烃稳定剂
    • US4246170A
    • 1981-01-20
    • US4612
    • 1979-01-18
    • Samuel Evans
    • Samuel Evans
    • C07C67/00C07C69/96C07C301/00C07C301/02C07C303/06C07C303/08C07C303/24C07C305/22C07C325/00C07C329/00C07C329/04C07F9/08C07F9/12C07F9/145C07F9/32C07F9/40C07F9/48C08K5/00C08K5/10C08K5/13C08K5/36C08K5/51C08K5/52C08L23/00C08L101/00C09K15/08C09K15/14C09K15/32
    • C09K15/322C07C301/02C07C305/24C07C323/16C07C329/04C07F9/12C07F9/145C07F9/4075C07F9/4084C07F9/4875C08K5/005C08K5/51C09K15/14
    • Phenols of the formula I ##STR1## wherein n has a value from 1 to 15,each of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently is a hydrogen atom, a C.sub.1 - .sub.18 -alkyl group, an aryl group, a C.sub.5 -C.sub.12 -cycloalkyl group or a C.sub.7 -C.sub.13 -aralkyl group,R.sub.5 is a hydrogen atom or a C.sub.1 -C.sub.18 -alkyl group,Y is a carbonyl, thiocarbonyl, sulphinyl, sulphonyl, -P(OR.sub.7)-, -P(.dbd.O) (OR.sub.7)-, -P(.dbd.O) (R.sub.7)- or -P(R.sub.7)- group, andR.sub.6 is a radical --CHR.sub.8 --CHR.sub.9 --S--CR.sub.10 R.sub.11 R.sub.12, wherein each of R.sub.8 and R.sub.9 independently is a hydrogen atom or a C.sub.1 -C.sub.6 -alkyl group, R.sub.10 is a hydrogen atom, a C.sub.1 -C.sub.19 -alkyl group, a C.sub.2 -C.sub.4 -alkenyl group or an aryl group, R.sub.11 is a hydrogen atom or a methyl group and R.sub.12 is a hydrogen atom or a methyl group, or, if R.sub.11 is a hydrogen atom, is a C.sub.2 -C.sub.6 -alkyl group, or, if R.sub.10 is a hydrogen atom, R.sub.11 and R.sub.12 together with the carbon atom to which they are attached represent a cycloalkyl group, or R.sub.10, R.sub.11 and R.sub.12 together with the carbon atom to which they are attached represent an aryl group, or if Y is a thiocarbonyl, sulphinyl or sulphonyl group,R.sub.6 can also be a hydrogen atom or a C.sub.1 -C.sub.18 -alkyl group or an aryl group, andR.sub.7 is a hydrogen atom, a C.sub.1 -C.sub.18 -alkyl group or an aryl group,as stabilizers for organic material.
    • 式I的苯酚(1)其中n具有1至15的数值,R 1,R 2,R 3和R 4各自独立地为氢原子,C 1 -C 18 - 烷基,芳基,C 5 -C 12 - 环烷基或C 7 -C 13 - 芳烷基,R 5为氢原子或C 1 -C 18烷基,Y为羰基,硫代羰基,亚磺酰基,磺酰基,-P(OR 7) - , - P(= O)(OR 7) - , - P(= O)(R 7) - 或-P(R 7) - 基团,R 6是基团-CHR 8 -CHR 9 -S-CR 10 R 11 R 12,其中R 8和R 9各自独立地为氢 原子或C1-C6-烷基,R10是氢原子,C1-C19 - 烷基,C2-C4-烯基或芳基,R11是氢原子或甲基,R12是氢 或者如果R 11为氢原子,则为C2-C6-烷基,或者,如果R10为氢原子,则R11和R12与它们所连接的碳原子一起代表环烷基 ,或R 10,R 11和R 12与它们所连接的碳原子一起表示芳基,或者如果Y是硫代羰基,则硫 正丁基或磺酰基,R 6也可以是氢原子或C 1 -C 18烷基或芳基,R 7是氢原子,C 1 -C 18烷基或芳基作为有机材料的稳定剂。
    • 66. 发明授权
    • Piperidine stabilizers
    • 哌啶稳定剂
    • US4197236A
    • 1980-04-08
    • US931439
    • 1978-08-07
    • Siegfried RosenbergerSamuel Evans
    • Siegfried RosenbergerSamuel Evans
    • C07D211/46C07D211/58C08K5/00C08K5/34
    • C08K5/005C07C323/00C07D211/46C07D211/58
    • Compounds of the general formula I ##STR1## or their acid addition salts in which one of R.sub.1 and R.sub.3 is --OH and the other is hydrogen and R.sub.2 denotes C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.9 -aralkyl and R.sub.4 and R.sub.5 are hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.9 -aralkyl and R.sub.6 denotes hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sub.7 is hydrogen or C.sub.1 -C.sub.8 -alkyl and R.sub.8 is hydrogen, oxyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.4 -alkinyl, C.sub.2 -C.sub.21 -alkoxyalkyl, C.sub.7 -C.sub.8 -aralkyl, 2,3-epoxypropyl, an aliphatic acyl group with 1-4 C atoms or one of the groups --CH.sub.2 COOR.sub.9, --CH.sub.2 --CH(R.sub.10)--OR.sub.11, --COOR.sub.12 or -- CONHR.sub.12, in which R.sub.9 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, phenyl, C.sub.7 -C.sub.8 -aralkyl or cyclohexyl and R.sub.10 is hydrogen, methyl or phenyl and R.sub.11 denotes hydrogen or an aliphatic or aromatic, araliphatic or alicyclic acyl group with 1-18 C atoms, in which the aromatic part can optionally be substituted by chlorine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.8 -alkoxy and/or by hydroxyl, or a group ##STR2## and R.sub.12 denotes C.sub.1 -C.sub.12 -alkyl, cyclohexyl, phenyl or benzyl and X is --O-- or --NR.sub.13 --, in which R.sub.13 denotes hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.7 -C.sub.9 -aralkyl and A is one of the groups --(C.sub.n H.sub.2n)--, which can optionally be interrupted by --S-- or ##STR3## in which n denotes 0 to 12 and Y is one of the groups ##STR4## in which R.sub.7, R.sub.8 and X have the meaning defined above and R.sub.14 denotes C.sub.1 -C.sub.12 -alkyl, phenyl or tolyl as stabilizers for organic material.
    • 通式I的化合物(I)或其酸加成盐,其中R 1和R 3中的一个是-OH,另一个是氢,R 2表示C 1 -C 12 - 烷基,C 5 -C 7 - 环烷基,C 6 -C 10 芳基或C 7 -C 9 - 芳烷基,R 4和R 5是氢,C 1 -C 12 - 烷基,C 5 -C 7 - 环烷基,C 6 -C 10 - 芳基或C 7 -C 9 - 芳烷基,R 6表示氢,C 1 -C 12烷基,C 5 C 7 - 环烷基,苯基或苄基,R 7是氢或C 1 -C 8 - 烷基,R 8是氢,氧基,C 1 -C 12 - 烷基,C 3 -C 6 - 烯基,C 3 -C 4 - 炔基,C 2 -C 21 - 烷氧基烷基, -C 1-8芳烷基,2,3-环氧丙基,具有1-4个C原子的脂族酰基或基团-CH 2 COOR 9,-CH 2 -CH(R 10)-OR 11,-COOR 12或-CONHR 12中的一个,其中R 9为C 1 C 12 - 烷基,C 3 -C 6 - 烯基,苯基,C 7 -C 8 - 芳烷基或环己基,R 10是氢,甲基或苯基,R 11表示氢或具有1-18个C原子的脂族或芳族,芳脂族或脂环族酰基, 其中芳族部分可以任选被氯,C 1 -C 4烷基或C 1 -C 8 - 烷氧基和/或被羟基取代,或基团 并且R 12表示C 1 -C 12烷基,环己基,苯基或苄基,X是-O-或-NR 13 - ,其中R 13表示氢,C 1 -C 12 - 烷基,C 5 -C 7 - 环烷基或C 7 -C 9 - 芳烷基和A是可以任选地被-S-或间隔的基团之一(C n H 2n) - ,其中n表示0至12,Y是其中R7,R8和 X具有上述定义,R 14表示C 1 -C 12 - 烷基,苯基或甲苯基作为有机材料的稳定剂。
    • 67. 发明授权
    • Novel phenol stabilizers
    • 新型苯酚稳定剂
    • US4196119A
    • 1980-04-01
    • US4611
    • 1979-01-18
    • Samuel Evans
    • Samuel Evans
    • C07C317/00C07F9/12C07F9/145C07F9/40C07F9/48C08K5/00C08K5/04C09K15/14C09K15/28C09K15/32C08K5/41C07C141/16C07C145/00
    • C07C305/00C07C323/00C07F9/12C07F9/145C07F9/4084C07F9/48C08K5/005C09K15/14C09K15/322
    • Phenols of the formula I ##STR1## wherein n has a value from 1 to 15, each ofR.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently is a hydrogen atom, a C.sub.1 -C.sub.18 -alkyl group, an aryl group, a C.sub.5 -C.sub.12 -cycloalkyl group or a C.sub.7 -C.sub.13 -aralkyl group,R.sub.5 is a hydrogen atom or a C.sub.1 -C.sub.18 -alkyl group,Y is a carbonyl, thiocarbonyl, sulphinyl, sulphonyl, P(OR.sub.7), --P(.dbd.O)(OR.sub.7)--, --P(.dbd.O)(R.sub.7)-- or --P(R.sub.7)-- group, andR.sub.6 is a radical --CHR.sub.8 --CHR.sub.9 --S--CR.sub.10 R.sub.11 R.sub.12, wherein each of R.sub.8 and R.sub.9 independently is a hydrogen atom or a C.sub.1 -C.sub.6 -alkyl group, R.sub.10 is a hydrogen atom, a C.sub.1 -C.sub.19 -alkyl group, a C.sub.2 -C.sub.4 -alkenyl group or an aryl group, R.sub.11 is a hydrogen atom or a methyl group and R.sub.12 is a hydrogen atom or a methyl group, or, if R.sub.11 is a hydrogen atom, is a C.sub.2 -C.sub.6 -alkyl group, or, if R.sub.10 is a hydrogen atom, R.sub.11 and R.sub.12 together with the carbon atom to which they are attached represent a cycloalkyl group, or R.sub.10, R.sub.11 and R.sub.12 together with the carbon atom to which they are attached represent an aryl group, or if Y is a thiocarbonyl, sulphinyl or sulphonyl group,R.sub.6 can also be a hydrogen atom or a C.sub.1 -C.sub.18 -alkyl group or an aryl group, andR.sub.7 is a hydrogen atom, a C.sub.1 -C.sub.18 -alkyl group or an aryl group, as stabilizers for organic material.
    • 式I的苯酚(I)其中n具有1至15的值,R 1,R 2,R 3和R 4各自独立地为氢原子,C 1 -C 18 - 烷基,芳基 ,C 5 -C 12 - 环烷基或C 7 -C 13 - 芳烷基,R 5为氢原子或C 1 -C 18烷基,Y为羰基,硫代羰基,亚磺酰基,磺酰基,P(OR 7) = O)(OR 7) - , - P(= O)(R 7) - 或-P(R 7) - 基团,R 6是基团-CHR 8 -CHR 9 -S-CR 10 R 11 R 12,其中R 8和R 9各自独立地为 氢原子或C1-C6烷基,R10为氢原子,C1-C19 - 烷基,C2-C4-烯基或芳基,R11为氢原子或甲基,R12为 氢原子或甲基,或者如果R 11是氢原子,则为C 2 -C 6烷基,或者如果R 10是氢原子,则R 11和R 12与它们所连接的碳原子一起代表环烷基 基团或R 10,R 11和R 12与它们所连接的碳原子一起表示芳基,或者如果Y是硫代羰基,则 二苯基或磺酰基,R6也可以是氢原子或C1-C18烷基或芳基,R7是氢原子,C1-C18烷基或芳基作为有机材料的稳定剂。
    • 68. 发明授权
    • 5-Triazin-2-yl phosphonates
    • US4151356A
    • 1979-04-24
    • US840705
    • 1977-10-11
    • Samuel EvansMichael Rasberger
    • Samuel EvansMichael Rasberger
    • C08K5/00C07F9/6521C07F9/6558C08K5/53C08K5/5373C08L7/00C08L21/00C08L23/00C08L51/00C08L51/02C08L77/00C08L101/00C07D251/48
    • C07F9/65583C07F9/65216C08K5/5373
    • A triazine of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.18 -aryl, C.sub.7 -C.sub.18 -aralkyl or a radical of the formula II or III ##STR2## in which R.sub.3 is hydrogen or C.sub.1 -C.sub.8 -alkyl and R.sub.4 is hydrogen, oxyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.4 -alkinyl, C.sub.2 -C.sub.21 -alkoxyalkyl, C.sub.7 -C.sub.8 -aralkyl, 2,3-epoxypropyl, an aliphatic acyl group with 1-9 C atoms or one of the groups --CH.sub.2 COOR.sub.5, --CH.sub.2 --CH(R.sub.6)--OR.sub.7, --COOR.sub.8 or --CONHR.sub.8, in which R.sub.5 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, phenyl, C.sub.7 -C.sub.8 -aralkyl or cyclohexyl and R.sub.6 is hydrogen, methyl or phenyl and R.sub.7 denotes hydrogen, an aliphatic or aromatic, araliphatic or alicyclic acyl group with 1-18 C atoms, in which the aromatic part can optionally be substituted by chlorine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.8 -alkoxy and/or by hydroxyl, and R.sub.8 denotes C.sub.1 -C.sub.12 -alkyl, cyclohexyl, phenyl or benzyl and A is a radical of the formula IV or V ##STR3## in which R.sub.3 and R.sub.4 have the above meaning, n is 1, 2 or 3 and R.sub.9 is hydrogen or hydroxyl and Y is --O-- or --NR.sub.10 --, in which R.sub.10 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.10 -aryl, C.sub.7 -C.sub.18 -aralkyl or a radical of the formula II with the above meaning, or A is --P(=O)(OR.sub.1)OR.sub.2, --S--R.sub.11, --NR.sub.12 R.sub.13 or --OR.sub.14, in which R.sub.1 and R.sub.2 have the above meaning, R.sub.11 is C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.6 -C.sub.10 -aryl, C.sub.7 -C.sub.9 -aralkyl or the group --(C.sub.p H.sub.2p)--CO--OR.sub.15, in which R.sub.15 is C.sub.1 -C.sub.18 -alkyl, and p denotes 1 to 6 and R.sub.12 and R.sub.13 independently of one another are hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.3 -C.sub.4 -alkenyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.6 -C.sub.10 -aryl, C.sub.7 -C.sub.9 -aralkyl or a radical of the formula II with the above meaning, and R.sub.14 denotes C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.9 -aralkyl, and B is a radical of the formula IV or V with the above meaning or is --P(=O)(OR.sub.1)OR.sub.2, in which R.sub.1 is a radical of the formula II or III with the above meaning and R.sub.2 has the above meaning, and its salts, as additives for stabilizing organic material.