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1. 发明授权

US5206414A Process for the preparation of hydroxyphenylpropionic acid esters 失效
标题翻译：羟基苯丙酸酯的制备方法
公开(公告)号：US5206414A
公开(公告)日：1993-04-27
申请号：US876813
申请日：1992-04-29
申请人： Samuel Evans , Paul Dubs , Milos Rusek , Zdenek Mazour , Arpad Major
发明人： Samuel Evans , Paul Dubs , Milos Rusek , Zdenek Mazour , Arpad Major
IPC分类号： C07C67/03 , C07C67/347 , C07C69/732
CPC分类号： C07C67/03 , C07C67/347
摘要： A process for the preparation of compounds of the general formula ##STR1## where R.sub.1 and R.sub.2 are identical or different and are hydrogen, C.sub.1 -C.sub.18 alkyl, phenyl, C.sub.1 -C.sub.4 alkyl-substituted phenyl, C.sub.7 -C.sub.9 phenylalkyl, C.sub.5 -C.sub.12 cycloalkyl or C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.12 cycloalkyl,R.sub.3 is hydrogen or methyl,m is 0, 1, 2 or 3, andn is a number from 1 to 4 or 6, andA is as defined in the description,by reacting a compound of the formula II ##STR2## where m, R.sub.1 and R.sub.2 are as defined above, with a compound of the formula III ##STR3## where A and n are as defined in the description, which comprises carrying out the reaction in the presence of a catalyst which contains, as active material, an alkali metal compound of the formula IVM.sub.m An (IV)in whichM is Li, Na, K, Rb or Cs,m is the valency of An, andAn is a fluoride, hydroxide, phosphate, formate, acetate or --OR.sub.5 radical, andR.sub.5 is alkyl having 1 to 4 carbon atoms or phenyl,and, as support, an alkaline material which, measured in 10% strength by weight aqueous suspension, has a pH>10, selected from one or more groups of substances from the series comprising the alkaline earth metal oxides, hydroxides, aluminates or silicates.
摘要翻译：制备通式为（I）的化合物的方法，其中R 1和R 2相同或不同，为氢，C 1 -C 18烷基，苯基，C 1 -C 4烷基取代的苯基，C 7 -C 9苯基烷基，C 5 -C 12环烷基或 C 1 -C 4烷基取代的C 5 -C 12环烷基，R 3是氢或甲基，m是0,1,2或3，n是1至4或6的数，A如说明书中所定义，通过化合物式（II）其中m，R 1和R 2如上定义，与式IIIA（H）n，（III）的化合物反应，其中A和n如说明书中所定义，其包含在含有M为Li，Na，K，Rb或Cs的式IV MmAn（IV）的碱金属化合物作为活性物质的催化剂存在下进行反应，m为An的化合价，并且An是氟化物，氢氧化物，磷酸盐，甲酸盐，乙酸盐或-OR 5基团，R 5是具有1至4个碳原子的烷基或苯基，作为载体，碱性物质以10％重量百分比的含水悬浮液，pH> 10，选自一组或多组来自包含碱土金属氧化物，氢氧化物，铝酸盐或硅酸盐的系列的物质。

2. 发明授权

US06596796B1 Stabilizers for emulsion crude rubbers, synthetic latex and natural rubber latex 失效
标题翻译：乳化乳胶，合成胶乳和天然橡胶胶乳的稳定剂
公开(公告)号：US06596796B1
公开(公告)日：2003-07-22
申请号：US09688417
申请日：2000-10-16
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Paul Dubs , Samuel Evans
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Paul Dubs , Samuel Evans
IPC分类号： C08K5134
CPC分类号： C08K5/134 , C08L21/02
摘要： There are described compositions comprising a) an emulsion crude rubber, synthetic latex or natural rubber latex subject to oxidative, thermal, dynamic and/or light-induced degradation, and b) as stabilizer at least one compound of formula I wherein R1 is C8-C20alkyl; and optionally c) as further stabilizer at least one compound of formula II wherein R2 is C8-C12alkyl, R3 is hydrogen, C1-C12alkyl, cyclohexyl, 1-methylcyclohexyl, benzyl, &agr;-methylbenzyl, &agr;,&agr;-dimethylbenzyl or —CH2—S—R2, R4 is C1-C12alkyl, benzyl, &agr;-methylbenzyl, 60 ,&agr;-dimethylbenzyl or —CH2—S—R2, and R5 is hydrogen or methyl.
摘要翻译：描述的组合物包括：a）经受氧化，热，动态和/或光诱导降解的乳液粗橡胶，合成胶乳或天然橡胶胶乳，和b）作为稳定剂的至少一种式I化合物，其中R1是C8-C20烷基;和任选地，c）作为其它稳定剂的至少一种式II化合物，其中R2是C8-C12烷基，R3是氢，C1-C12烷基，环己基，1-甲基环己基，苄基，α-甲基苄基，α，α-二甲基苄基或-CH2-S-R2 R 4是C 1 -C 12烷基，苄基，α-甲基苄基，60，α-二甲基苄基或-CH 2 -S-R 2，R 5是氢或甲基。

3. 发明授权

US6046263A Liquid antioxidants as stabilizers 失效
标题翻译：液体抗氧化剂作为稳定剂
公开(公告)号：US6046263A
公开(公告)日：2000-04-04
申请号：US81432
申请日：1998-05-19
申请人： Michael Rasberger , Samuel Evans , Paul Dubs , Stephan Allenbach
发明人： Michael Rasberger , Samuel Evans , Paul Dubs , Stephan Allenbach
IPC分类号： C08K5/134 , C08K5/20 , C08K5/372 , C08K5/09 , C08K15/04
CPC分类号： C08K5/1345 , C08K5/20 , C08K5/372
摘要： Products are described which are obtainable by reacting compounds of formula I with compounds of formula IIa or/and IIb and IIIa or/and IIIb and additionally, where appropriate, IV ##STR1## wherein the general symbols are as defined in claim 1, the compound of formula I being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate, the compound of formula IIa being, for example, diethanolamine, the compound of formula IIIa being, for example, methyl oleate, and the compound of formula IV being, for example, sulfur. The cited products can be used as liquid antioxidants in organic materials.
摘要翻译：描述了可通过使式I化合物与式IIa或/和IIb和IIIa或/和IIIb化合物反应而得到的产物，另外在适当情况下使其中通式如权利要求1所定义，式I化合物作为例如3-（3'，5'-二叔丁基-4'-羟基苯基）丙酸甲酯，式IIa的化合物是例如二乙醇胺，式IIIa的化合物是例如，油酸甲酯，式Ⅳ化合物为例如硫。所引用的产品可用作有机材料中的液体抗氧化剂。

4. 发明授权

US5668206A Liquid antioxidants as stabilizers 失效
标题翻译：液体抗氧化剂作为稳定剂
公开(公告)号：US5668206A
公开(公告)日：1997-09-16
申请号：US466520
申请日：1995-06-06
申请人： Paul Dubs , Roger Martin , Samuel Evans
发明人： Paul Dubs , Roger Martin , Samuel Evans
IPC分类号： C07C69/28 , C07C67/62 , C07C69/30 , C07C69/732 , C07C215/08 , C07C323/12 , C08K5/00 , C08K5/134 , C08K5/3435 , C09K15/08 , C08K5/04 , C08K5/06 , C08K5/10
CPC分类号： C08K5/3435 , C07C215/08 , C07C323/12 , C07C67/62 , C07C69/732 , C08K5/005 , C08K5/134 , C09K15/08
摘要： Products are described which can be obtained by reacting components a), b) and c), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II and component c) is a compound of the formula III or a mixture of compounds of the formula III, ##STR1## in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,4-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, and the compound of the formula III being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate. The abovementioned products can be used as liquid antioxidants in polymers and lubricants.
摘要翻译：描述了通过使组分a），b）和c）反应得到的产物，其中组分a）是式I化合物或式I化合物的混合物，组分b）是式II化合物或式II化合物和组分c）的化合物的混合物是式III的化合物或式III化合物，X（Y）a，（I），（II）权利要求1中，式I化合物为例如季戊四醇，硫代二甘醇，1,4-丁二醇，1,4-丙二醇，二甘醇，三甘醇，二乙醇胺或甘油，式II化合物为例如向日葵油或椰子脂肪，式III化合物为例如3-（3'，5'-二叔丁基-4'-羟基苯基）丙酸甲酯。上述产品可用作聚合物和润滑剂中的液体抗氧化剂。

5. 发明授权

US5427701A Substituted phenols as stabilizers 失效
标题翻译：取代酚作为稳定剂
公开(公告)号：US5427701A
公开(公告)日：1995-06-27
申请号：US275689
申请日：1994-07-14
申请人： Hans R. Meier , Samuel Evans , Paul Dubs
发明人： Hans R. Meier , Samuel Evans , Paul Dubs
IPC分类号： C07C323/16 , C07C323/52 , C08K5/13 , C08K5/36 , C08K5/37 , C08K5/375 , C08L75/04 , C08L101/00 , C09K15/14 , C10M135/22 , C10M135/24 , C10M135/26 , C10M135/28 , C10N30/00 , C10N30/08 , C10N30/10 , C10N40/25 , C07C321/00
CPC分类号： C10M135/28 , C07C323/00 , C08K5/375 , C09K15/14 , C10M135/24 , C10M135/26 , C10M2219/084 , C10M2219/085 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： Novel compositions are described which comprises an elastomer or a lubricant and at least one compound of the formulae I or II ##STR1## The symbols R.sub.1, R.sub.2, R.sub.3, Z.sub.1 and Z.sub.2 are as defined in claim 1.The compounds of the formula II and some of the compounds of the formula I are novel, and they are used especially as antioxidants.
摘要翻译：描述了新的组合物，其包含弹性体或润滑剂和至少一种式I或II的化合物。（I）符号R1，R2，R3，Z1和Z2如权利要求中所定义。式II化合物和一些式I化合物是新颖的，它们特别用作抗氧化剂。

6. 发明授权

US5273669A Lubricant composition 失效
标题翻译：润滑油组成
公开(公告)号：US5273669A
公开(公告)日：1993-12-28
申请号：US951377
申请日：1992-09-25
申请人： Rolf Schumacher , Samuel Evans , Paul Dubs
发明人： Rolf Schumacher , Samuel Evans , Paul Dubs
IPC分类号： C10M133/02 , C10M141/08 , C10M141/10 , C10M135/36 , C10M133/40
CPC分类号： C10M141/10 , C10M133/02 , C10M141/08 , C10M2207/023 , C10M2207/024 , C10M2207/026 , C10M2207/027 , C10M2207/287 , C10M2215/00 , C10M2215/06 , C10M2215/062 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/067 , C10M2215/068 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/12 , C10M2215/122 , C10M2215/18 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/28 , C10M2215/30 , C10M2217/00 , C10M2217/02 , C10M2217/028 , C10M2217/04 , C10M2217/042 , C10M2217/043 , C10M2217/044 , C10M2217/045 , C10M2217/06 , C10M2219/06 , C10M2219/083 , C10M2219/084 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/106 , C10M2219/108 , C10M2223/04 , C10M2223/042 , C10M2223/065 , C10M2227/04 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： A lubricant based on a mineral or synthetic oil is stabilized against oxidative degradation by the addition of a mixture comprising at least one specified aromatic amine of the formula I or II ##STR1## and at least one sterically hindered amine. The lubricant may contain other antioxidants or other additives. It is preferably used as motor oil.
摘要翻译：基于矿物或合成油的润滑剂通过加入包含至少一种特定的式I或II芳香胺（I）（II）的芳族胺和至少一种空间位阻的混合物而稳定，防止氧化降解受阻胺。润滑剂可能含有其他抗氧化剂或其他添加剂。优选用作机油。

7. 发明授权

US5073278A Lubricant composition 失效
标题翻译：润滑剂组合物
公开(公告)号：US5073278A
公开(公告)日：1991-12-17
申请号：US380563
申请日：1989-07-13
申请人： Rolf Schumacher , Samuel Evans , Paul Dubs
发明人： Rolf Schumacher , Samuel Evans , Paul Dubs
IPC分类号： C10M129/10 , C10M133/00 , C10M133/02 , C10M133/04 , C10M133/06 , C10M133/12 , C10M133/14 , C10M133/40 , C10M135/22 , C10M137/02 , C10M137/04 , C10M141/08 , C10M141/10 , C10M141/12 , C10N30/10 , C10N40/25
CPC分类号： C10M133/02 , C10M141/08 , C10M141/10 , C10M2207/023 , C10M2207/024 , C10M2207/026 , C10M2207/027 , C10M2207/287 , C10M2215/00 , C10M2215/06 , C10M2215/062 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/067 , C10M2215/068 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/12 , C10M2215/122 , C10M2215/18 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/28 , C10M2215/30 , C10M2217/00 , C10M2217/02 , C10M2217/028 , C10M2217/04 , C10M2217/042 , C10M2217/043 , C10M2217/044 , C10M2217/045 , C10M2217/06 , C10M2219/06 , C10M2219/083 , C10M2219/084 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/106 , C10M2219/108 , C10M2223/04 , C10M2223/042 , C10M2223/065 , C10M2227/04 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： A lubricant based on a mineral or synthetic oil is stabilized against oxidative degradation by the addition of a mixture comprising at least one specified aromatic amine of the formula I ##STR1## and at least one sterically hindered amine. The lubricant may contain other antioxidants or other additives. It is preferably used as motor oil.
摘要翻译：基于矿物或合成油的润滑剂通过加入包含至少一种具有式I（I）的特定芳族胺和至少一种空间位阻胺的混合物来稳定，防止氧化降解。润滑剂可能含有其他抗氧化剂或其他添加剂。优选用作机油。

8. 发明授权

US5739341A Liquid antioxidants as stabilizers 失效
标题翻译：液体抗氧化剂作为稳定剂
公开(公告)号：US5739341A
公开(公告)日：1998-04-14
申请号：US462254
申请日：1995-06-02
申请人： Paul Dubs , Roger Martin , Samuel Evans
发明人： Paul Dubs , Roger Martin , Samuel Evans
IPC分类号： C07C69/28 , C07C67/62 , C07C69/30 , C07C69/732 , C07C215/08 , C07C323/12 , C08K5/00 , C08K5/134 , C08K5/3435 , C09K15/08 , C07D211/44
CPC分类号： C08K5/3435 , C07C215/08 , C07C323/12 , C07C67/62 , C07C69/732 , C08K5/005 , C08K5/134 , C09K15/08
摘要： Products are described which can be obtained by reacting components a), b) and c), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II and component c) is a compound of the formula III or a mixture of compounds of the formula III, ##STR1## in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,4-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, and the compound of the formula III being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate. The abovementioned products can be used as liquid antioxidants in polymers and lubricants.
摘要翻译：描述了通过使组分a），b）和c）反应得到的产物，其中组分a）是式I化合物或式I化合物的混合物，组分b）是式II化合物或式II化合物和组分c）的化合物的混合物是式III的化合物或式III化合物，X（Y）a，（I），（II）权利要求1中，式I化合物为例如季戊四醇，硫代二甘醇，1,4-丁二醇，1,4-丙二醇，二甘醇，三甘醇，二乙醇胺或甘油，式II化合物为例如向日葵油或椰子脂肪，式III化合物为例如3-（3'，5'-二叔丁基-4'-羟基苯基）丙酸甲酯。上述产品可用作聚合物和润滑剂中的液体抗氧化剂。

9. 发明授权

US5663128A Liquid antioxidants as stabilizers 失效
标题翻译：液体抗氧化剂作为稳定剂
公开(公告)号：US5663128A
公开(公告)日：1997-09-02
申请号：US308339
申请日：1994-09-19
申请人： Samuel Evans , Paul Dubs , Hugo Camenzind
发明人： Samuel Evans , Paul Dubs , Hugo Camenzind
IPC分类号： C07D251/38 , C07B45/00 , C07C69/732 , C07D211/08 , C07D493/04 , C07F9/165 , C07F9/547 , C08K5/134 , C08K5/34 , C08K5/3432 , C08K5/3435 , C08L23/02 , C09K15/08 , C09K15/14 , C09K15/30 , C09K15/32 , C10M159/12 , C10N30/10 , C10N40/08 , C10N40/20 , C10N40/25 , C10M107/46
CPC分类号： C07C69/732 , C07B45/00 , C07F9/165 , C08K5/1345 , C09K15/14 , C09K15/32
摘要： Products are described which can be obtained by reacting components a), b), c) and d), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II, component c) is a compound of the formula III or a mixture of compounds of the formula III and component d) is a compound of the formula IV or a mixture of compounds of the formula IV, ##STR1## in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,2-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, the compound of the formula III being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate and the compound of the formula IV, being for example, sulfur or diisopropyl dithiophosphate. The abovementioned products can be used as liquid antioxidants in polymers and lubricants.
摘要翻译：描述了可以通过使组分a），b），c）和d）反应得到的产物，其中组分a）是式I化合物或式I化合物的混合物，组分b）是式II或式II化合物的组合物c）的化合物是式III的化合物或式III化合物和组分d）的混合物是式Ⅳ的化合物或式Ⅳ化合物的混合物式IV，其中通式为如权利要求1所定义的X（Y）a（I）其中，（III）D（IV）其中式I化合物为例如，季戊四醇，硫二甘醇，1,4-丁二醇，1,2-丙二醇，二甘醇，三甘醇，二乙醇胺或甘油，式II化合物为例如向日葵油或椰子油，式III化合物例如，3-（3'，5'-二叔丁基-4'-羟基苯基）丙酸甲酯和式IV化合物，例如硫 r二异丙基二硫代磷酸酯。上述产品可用作聚合物和润滑剂中的液体抗氧化剂。

10. 发明授权

US4692258A Tetrahydroquinolines as antioxidants for lubricants 失效
标题翻译：四氢喹啉作为润滑剂的抗氧化剂
公开(公告)号：US4692258A
公开(公告)日：1987-09-08
申请号：US810543
申请日：1985-12-18
申请人： Michael Rasberger , Paul Dubs , Samuel Evans
发明人： Michael Rasberger , Paul Dubs , Samuel Evans
IPC分类号： C10M133/38 , C10M133/40 , C10M141/00 , C10N30/10 , C10N50/10 , C10M105/56
CPC分类号： C10M141/00 , C10M133/40 , C10M2207/024 , C10M2207/026 , C10M2207/046 , C10M2207/283 , C10M2207/289 , C10M2215/08 , C10M2215/082 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/28 , C10M2215/30 , C10M2219/084 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10N2250/10
摘要： Lubricants can be rendered more resistant to oxidation with the aid of compounds of the formula I ##STR1## wherein R.sub.1 and R.sub.2 are independently hydrogen, alkyl or benzyl, R'.sub.2 is hydrogen or alkyl, R.sub.3 and R.sub.4 are independently alkyl, phenyl or benzyl, R.sub.5 is hydrogen or alkyl, and R.sub.6 is alkyl. In a preferred embodiment, these compounds are combined with a customary phenolic antioxidant.
摘要翻译：借助于式I（I）的化合物，可以使润滑剂更耐氧化，其中R1和R2独立地是氢，烷基或苄基，R'2是氢或烷基，R3和R4独立地是烷基，苯基或苄基，R5是氢或烷基，R6是烷基。在优选的实施方案中，这些化合物与常规的酚类抗氧化剂组合。

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