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    • 2. 发明授权
    • Carrier-bound ketocarboxylic acids as corrosion inhibitors
    • 载体结合的酮羧酸作为腐蚀抑制剂
    • US5489447A
    • 1996-02-06
    • US263692
    • 1994-06-20
    • Andreas KramerAdalbert Braig
    • Andreas KramerAdalbert Braig
    • C07C65/32C07C59/84C07C59/88C07C59/90C07C69/76C07C205/56C07C229/42C07C255/49C07C255/57C07C323/62C07C327/26C07C329/04C09D5/08C09K15/06B05D3/02
    • C07C59/88C07C229/42C07C255/49C07C59/84C07C59/90C09D5/086
    • A description is given of carrier-bound compounds of the formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently of one another are hydrogen, halogen, nitro, cyano, CF.sub.3, C.sub.1 -C.sub.15 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.2 -C.sub.15 alkenyl, C.sub.1 -C.sub.12 haloalkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 aryloxy, C.sub.7 -C.sub.12 arylalkyl, --CO.sub.2 R.sub.6, --COR.sub.6 or ##STR2## in which at least one of the radicals R.sub.1 to R.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.15 alkyl, and, in addition, the radicals R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 together with the carbon atoms to which they are attached form a benzo or cyclohexenyl ring,R.sub.6 is C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkyl which is interrupted by oxygen, sulfur or >N--R.sub.9 ; or is C.sub.7 -C.sub.12 arylalkyl,R.sub.7 and R.sub.8 independently of one another are hydrogen, C.sub.1 -C.sub.24 alkyl or C.sub.2 -C.sub.24 alkyl which is interrupted by oxygen, sulfur or >N--R.sub.9,R.sub.9 is hydrogen or C.sub.1 -C.sub.8 alkyl, andn is an integer from the range from 1 to 10,as corrosion inhibitors in coating compositions for protecting metallic surfaces.
    • 给出式I(I)的载体结合化合物,其中R 1,R 2,R 3,R 4和R 5彼此独立地是氢,卤素,硝基,氰基,CF 3,C 1 -C 15烷基,C 5 -C 12环烷基,C 2 -C 15烯基,C 1 -C 12卤代烷基,C 1 -C 12烷氧基,C 1 -C 12烷硫基,C 6 -C 10芳基,C 6 -C 10芳氧基,C 7 -C 12芳烷基,-CO 2 R 6,-COR 6或其中至少一个基团R 1〜 R 5是氢,卤素或C 1 -C 15烷基,此外,基团R 1和R 2,R 2和R 3,R 3和R 4或R 4和R 5与它们所连接的碳原子一起形成苯并或环己烯基环,R 6 是C 1 -C 20烷基,被氧,硫或> N-R 9中断的C 2 -C 20烷基; 或者是C 7 -C 12芳基烷基,R 7和R 8彼此独立地是氢,C 1 -C 24烷基或被氧,硫或> N-R 9中间的C 2 -C 24烷基,R 9是氢或C 1 -C 8烷基,n是 在1至10的范围内,作为用于保护金属表面的涂料组合物中的腐蚀抑制剂。
    • 4. 发明授权
    • Pesticidal benzoylurea compounds
    • 杀虫剂苯甲酰脲化合物
    • US4666942A
    • 1987-05-19
    • US889523
    • 1986-07-24
    • Martin Anderson
    • Martin Anderson
    • A01N47/34A01P7/04C07C67/00C07C213/00C07C217/90C07C239/00C07C253/00C07C255/54C07C255/60C07C273/02C07C275/54C07C313/34C07C325/00C07C329/04C07C381/04C07C381/08C07D207/48A01N47/28
    • A01N47/34C07C313/34C07D207/48
    • Compounds of the general formula ##STR1## in which each of A and B independently represents a halogen atom or an alkyl group; m is 0 or 1; R represents a hydrogen atom or a group --S.CO.sub.2 R.sup.1, --S.SO.sub.2 R.sup.1 or --S.NR.sup.2 R.sup.3, in which R.sup.1 represents an optionally substituted alkyl or aryl group; R.sup.2 represents an optionally substituted alkyl or aryl group; and R.sup.3 represents an optionally substituted alkyl or aryl group, or a group of formula --CO.sub.2 R.sup.4, --SO.sub.2 R.sup.4, --COR.sup.4, --CO.CO.sub.2 R.sup.4, --CO.NR.sup.5 R.sup.6 or --SO.sub.2 NR.sup.5 R.sup.6, in which R.sup.4 represents an optionally substituted alkyl or aryl group, and each of R.sup.5 and R.sup.6 independently represents an optionally substituted alkyl or aryl group; or R.sup.2 and R.sup.3 together or R.sup.5 and R.sup.6 together represent an optionally substituted alkylene group; in each case, the optional substituents for an alkyl or alkylene group being selected from halogen, alkoxy, alkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkylsulphonyl and haloalkylsulphonyl, and the optional substituents for an aryl group being selected from these substituents and also alkyl, haloalkyl, cyano and nitro; X represents a halogen atom or a cyano, nitro, alkyl or haloalkyl group; each of Y and Z independently represents a halogen atom or a cyano, nitro or haloalkyl group; n is 0, 1, 2 or 3; and p is 0, 1 or 2; have useful pesticidal activity.
    • A和B各自独立地表示卤素原子或烷基的通式“IMAGE”的化合物; m为0或1; R表示氢原子或-S.CO2R1,-S.SO2R1或-S.NR2R3基团,其中R1表示任选取代的烷基或芳基; R2表示任选取代的烷基或芳基; R 3表示任选取代的烷基或芳基,或式-CO 2 R 4,-SO 2 R 4,-COR 4,-CO.CO 2 R 4,-CO.NR 5 R 6或-SO 2 NR 5 R 6的基团,其中R 4表示任选取代的烷基或芳基, R 5和R 6各自独立地表示任选取代的烷基或芳基; 或R 2和R 3一起或R 5和R 6一起表示任选取代的亚烷基; 在每种情况下,烷基或亚烷基的任选取代基选自卤素,烷氧基,烷氧基羰基,卤代烷氧基羰基,烷基羰基,卤代烷基羰基,烷基磺酰基和卤代烷基磺酰基,以及芳基的任选取代基选自这些取代基,还有烷基, ,氰基和硝基; X表示卤素原子或氰基,硝基,烷基或卤代烷基; Y和Z各自独立地表示卤素原子或氰基,硝基或卤代烷基; n为0,1,2或3; p为0,1或2; 具有有用的杀虫活性。
    • 6. 发明授权
    • Novel phenol stabilizers
    • 新型苯酚稳定剂
    • US4148820A
    • 1979-04-10
    • US786177
    • 1977-04-11
    • Samuel Evans
    • Samuel Evans
    • C07C67/00C07C69/96C07C301/00C07C301/02C07C303/06C07C303/08C07C303/24C07C305/22C07C325/00C07C329/00C07C329/04C07F9/08C07F9/12C07F9/145C07F9/32C07F9/40C07F9/48C08K5/00C08K5/10C08K5/13C08K5/36C08K5/51C08K5/52C08L23/00C08L101/00C09K15/08C09K15/14C09K15/32
    • C09K15/322C07C301/02C07C305/24C07C323/16C07C329/04C07F9/12C07F9/145C07F9/4075C07F9/4084C07F9/4875C08K5/005C08K5/51C09K15/14
    • Phenols of the formula I ##STR1## wherein N HAS A VALUE FROM 1 TO 15,Each of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently is a hydrogen atom, a C.sub.1 -C.sub.18 -alkyl group, an aryl group, a C.sub.5 -C.sub.12 -cyclo-alkyl group or a C.sub.7 -C.sub.13 -aralkyl group,R.sub.5 is a hydrogen atom or a C.sub.1 -C.sub.18 -alkyl group,Y is a carbonyl, thiocarbonyl, sulphinyl, sulphonyl, --P(OR.sub.7)--P(.dbd.O)(OR.sub.7)--, --P(.dbd.O)(R.sub.7)-- or --P(R.sub.7)-- group, and R.sub.6 is a radical --CHR.sub.8 --CHR.sub.9 --S--CR.sub.10 R.sub.11 R.sub.12, wherein each of R.sub.8 and R.sub.9 independently is a hydrogen atom or a C.sub.1 -C.sub.6 -alkyl group, R.sub.10 is a hydrogen atom, a C.sub.1 -C.sub.19 -alkyl group, a C.sub.2 -C.sub.4 -alkenyl group or an aryl group, R.sub.11 is a hydrogen atom or a methyl group and R.sub.12 is a hydrogen atom or a methyl group, or, if R.sub.11 is a hydrogen atom, is a C.sub.2 -C.sub.6 -alkyl group, or, if R.sub.10 is a hydrogen atom, R.sub.11 and R.sub.12 together with the carbon atom to which they are attached represent a cycloalkyl group, or R.sub.10, R.sub.11 and R.sub.12 together with the carbon atom to which they are attached represent an aryl group, or if Y is a thiocarbonyl, sulphinyl or sulphonyl group,R.sub.6 can also be a hydrogen atom or a C.sub.1 -C.sub.18 -alkyl group or an aryl group, andR.sub.7 is a hydrogen atom, a C.sub.1 -C.sub.18 -alkyl group or an aryl group, as stabilizers for organic material.
    • 式I的化合物(I)其中N为1至15,R 1,R 2,R 3和R 4各自独立地为氢原子,C 1 -C 18烷基,芳基 ,C 5 -C 12 - 环烷基或C 7 -C 13 - 芳烷基,R 5是氢原子或C 1 -C 18烷基,Y是羰基,硫代羰基,亚磺酰基,磺酰基,-P(OR 7) - P(= O)(OR 7) - , - P(= O)(R 7) - 或-P(R 7) - 基,R 6是基团-CHR 8 -CHR 9 -S-CR 10 R 11 R 12,其中R 8和R 9各自独立地 是氢原子或C1-C6烷基,R10是氢原子,C1-C19 - 烷基,C2-C4-烯基或芳基,R11是氢原子或甲基,R12 或者如果R 11为氢原子,则为C 2 -C 6 - 烷基,或者如果R 10为氢原子,则R 11和R 12与它们所连接的碳原子一起代表 环烷基或R 10,R 11和R 12与它们所连接的碳原子一起表示芳基,或者如果Y是硫代羰基,则 二苯基或磺酰基,R6也可以是氢原子或C1-C18烷基或芳基,R7是氢原子,C1-C18烷基或芳基作为有机材料的稳定剂。
    • 9. 发明授权
    • Process for the preparation of pyrazole carboxylic acid amides
    • 制备吡唑羧酸酰胺的方法
    • US08895757B2
    • 2014-11-25
    • US13981913
    • 2012-01-25
    • Miroslav TerinekDominik FaberStefan Koenig
    • Miroslav TerinekDominik FaberStefan Koenig
    • C07D231/14C07C251/56C07C329/04C07C231/14C07C329/02C07C251/64
    • C07C231/14C07C251/56C07C251/64C07C329/02C07C329/04C07C2603/66C07D231/14
    • The invention relates to a process for the preparation of 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid (9-dichloromethylene-1,2,3,4-tetrahydro-1,4-methano-naphthalen-5-yl)-amide by acylating the oxime oxygen of the compound of formula (VIII), in the presence of a solvent and an acylating agent of formula (XI) R1C(X)—CI (XI); wherein X is oxygen or sulfur; R1 is chloro if X is oxygen or sulfur; or R1 is C1-C6alkoxy, CH3—C(═CH2)—O—, phenoxy or trichloromethoxy if X is oxygen; and a) if R1 is chloro and the compound of formula (XI) was added to the compound of formula (VIII); reacting the so obtained product of formula (XIIa) wherein X is oxygen or sulfur; with the compound of formula (IX) b) if R1 is chloro and the compound of formula (VIII) was added to the compound of formula (XI); or R1 is C1-C6alkoxy, CH3—C(═CH2)—O—, phenoxy or trichloromethoxy if X is oxygen; reacting the so obtained product of formula (XII) wherein X is oxygen or sulfur; R1 is chloro if X is oxygen or sulfur; or R1 is C1-C6alkoxy, CH3—C(═CH2)—O—, phenoxy or trichloromethoxy if X is oxygen; with the compound of formula (IX).
    • 本发明涉及制备3-二氟甲基-1-甲基-1H-吡唑-4-羧酸(9-二氯亚甲基-1,2,3,4-四氢-1,4-亚甲基 - 萘-5 (XI)R1C(X)-CⅠ(XI)的溶剂和酰化剂的存在下酰化式(Ⅷ)化合物的肟氧; 其中X是氧或硫; 如果X是氧或硫,则R1是氯; 或者如果X是氧,则R1是C1-C6烷氧基,CH3-C(= CH2)-O-,苯氧基或三氯甲氧基; 和a)如果R1是氯,并且将式(XI)化合物加入到式(VIII)化合物中; 使所得的式(XIIa)化合物与X为氧或硫反应; 与式(Ⅸ)化合物b)如果R 1是氯,并将式(Ⅷ)化合物加到式(Ⅺ)化合物中; 或者如果X是氧,则R1是C1-C6烷氧基,CH3-C(= CH2)-O-,苯氧基或三氯甲氧基; 使所得的式(XII)化合物(其中X是氧或硫)反应; 如果X是氧或硫,则R1是氯; 或者如果X是氧,则R1是C1-C6烷氧基,CH3-C(= CH2)-O-,苯氧基或三氯甲氧基; 与式(IX)的化合物反应。